Okay, let's tackle this math problem. We're starting with 86335 and subtracting 33962.

Step 1: We'll start by subtracting the digit 2 and the borrow 0 from 5 in column 1 and get 3.
3 is the first digit of our result.

Step 2: We'll start by subtracting the digit 6 and the borrow 0 from 3 in column 2 and get -3.
We add -3 to 10 and get 7 as the next digit of the result.

Step 3: We'll start by subtracting the digit 9 and the borrow 1 from 3 in column 3 and get -7.
We add -7 to 10 and get 3 as the next digit of the result.

Step 4: We'll start by subtracting the digit 3 and the borrow 1 from 6 in column 4 and get 2.
2 is the next digit of our result.

Step 5: We'll start by subtracting the digit 3 and the borrow 0 from 8 in column 5 and get 5.
5 is the next digit of our result.

So, 86335 - 33962 = 52373.