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Калиев перманганат Калиев перманганат се нарича химическото съединение с формула KMnO4. В тази сол манганът е в степен на окисление +7. Перманганатният йон е силен окислител. Той се разтваря във вода и дава ярковиолетови разтвори, които след изпаряване дават призматични виолетовочерни лъскави кристали. [1] Не е добре да се приема вътрешно - много е отровен.За дезинфекция може да се използва разтвора на 2-3 кристалчета калиев перманганат в 1 литър вода (до бледорозов разтвор). Ако е по-голямо количество може да причини изгаряния на кожата. Ето няколко химични реакции с участието на калиевият перманганат. Приложения Почти всички приложения на калиевия перманганат са свързани със свойството му на силен окислител. Като силен оксидант, който не отделя токсични съпътстващи вещества, KMnO4 има много приложения. Калиевият перманганат е един от основните химикали, използван във филмовата и телевизионна индустрия за изкуствено състаряване на печатни материали, тъкани, дървесина и стъкло. Оксидиращият му ефект създава вид на остарял материал. Дезинфектант Тъй като е силен окислител, калиевият перманганат може да бъде използван като антисептично вещество. Например, разредени разтвори се използват за обработка на шанкърни поражения - язви, дезинфекция на ръцете и обработка на леки дерматити и гъбични инфекции на ръцете и краката. Исторически е бил използван за дезинфекция на питейната вода. В селски райони е използван за отделяне на желязото и водородния сулфид от отпадните води. Органичен синтез Освен за пречистване на води, друго голямо приложение на калиевия перманганат е като катализатор при синтезирането на някои органични съединения. Значителни количества са необходими при синтезиране на аскорбинова киселина, хлорамфеникол, захарин, изоникотинова киселина. Съхраняване на плодове Добавки от калиев перманганат към партида банани адсорбира етилена и удължава двойно периода на узряване на плодовете.
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Potassium permanganate Potassium permanganate is an inorganic chemical compound with the chemical formula KMnO4. It is a salt consisting of K+ and MnO− 4 ions. Formerly known as permanganate of potash or Condy's crystals, it is a strong oxidizing agent. It dissolves in water to give intensely pink or purple solutions, the evaporation of which leaves prismatic purplish-black glistening crystals.[2] In 2000, worldwide production was estimated at 30,000 tonnes.[3] In this compound, manganese is in the +7 oxidation state. Contents - 1 History - 2 Preparation - 3 Structure - 4 Reactions - 5 Uses - 6 Safety and handling - 7 References - 8 External links History[edit] In 1659, Johann Rudolf Glauber fused a mixture of the mineral pyrolusite (manganese dioxide, MnO2) and potassium carbonate to obtain a material that, when dissolved in water, gave a green solution (potassium manganate) which slowly shifted to violet and then finally red. This report represents the first description of the production of potassium permanganate.[4] Just under 200 years later, London chemist Henry Bollmann Condy had an interest in disinfectants; he found that fusing pyrolusite with sodium hydroxide (NaOH) and dissolving it in water produced a solution with disinfectant properties. He patented this solution, and marketed it as 'Condy's Fluid'. Although effective, the solution was not very stable. This was overcome by using potassium hydroxide (KOH) rather than NaOH. This was more stable, and had the advantage of easy conversion to the equally effective potassium permanganate crystals. This crystalline material was known as 'Condy's crystals' or 'Condy's powder'. Potassium permanganate was comparatively easy to manufacture, so Condy was subsequently forced to spend considerable time in litigation to stop competitors from marketing similar products.[5] Early photographers used it as a component of flash powder. It is now replaced with other oxidizers, due to the instability of permanganate mixtures. Aqueous solutions of KMnO4 have been used together with T-Stoff (i.e. 80% hydrogen peroxide) as propellant for the rocket plane Messerschmitt Me 163. In this application, it was known as Z-Stoff. This combination of propellants is sometimes still used in torpedoes. Preparation[edit] Potassium permanganate is produced industrially from manganese dioxide, which also occurs as the mineral pyrolusite. The MnO2 is fused with potassium hydroxide and heated in air or with another source of oxygen, like potassium nitrate or potassium chlorate.[3] This process gives potassium manganate: - 2 MnO2 + 4 KOH + O2 → 2 K2MnO4 + 2 H2O (Using sodium hydroxide the end product is not sodium manganate but an Mn(V) compound which is one reason the potassium permanganate is more commonly used than sodium permanganate. Furthermore the potassium salt crystallizes better[3]). The potassium manganate is then be converted into permanganate by electrolytic oxidation in alkaline media: - K2MnO4 + H2O → KMnO4 + KOH + 1/2 H2 Other methods[edit] Although of no commercial importance, potassium manganate can be oxidized by chlorine or by disproportionation under acid conditions [6] The chlorine oxidation reaction is: - 2 K2MnO4 + Cl2 → 2 KMnO4 + 2 KCl And the acid-induced disproportionation reaction may be written: - 3 K2MnO4 + 4 HCl → 2 KMnO4 + MnO2 + 2 H2O + 4 KCl A weak acid such as carbonic acid is sufficient for this reaction: - 3 K2MnO4 + 2 CO2 → 2 KMnO4 + 2 K2CO3 + MnO2 Potassium permanganate crystallizes from the concentrated reaction solution. Permanganate salts can also be generated by treating a solution of Mn2+ ions with strong oxidants such as lead dioxide (PbO2), or sodium bismuthate (NaBiO3). Tests for the presence of manganese exploit the vivid violet color of permanganate produced by these reagents. Structure[edit] KMnO4 forms orthorhombic crystals with constants: a = 910.5 pm, b = 572.0 pm, c = 742.5 pm. The overall motif is similar to that for barium sulfate, with which it forms solid solutions.[7] In the solid (as in solution), each MnO4− centres are tetrahedral. The Mn-O distances are 1.62 Å.[8] Reactions[edit] Organic chemistry[edit] Dilute solutions of KMnO4 convert alkenes into diols (glycols). This behaviour is also used as a qualitative test for the presence of double or triple bonds in a molecule, since the reaction decolorizes the initially purple permanganate solution and generates a brown precipitate (MnO2). It is sometimes referred to as Baeyer's reagent. However, bromine serves better in measuring unsaturation (double or triple bonds) quantitatively, since KMnO4, being a very strong oxidizing agent, can react with a variety of groups. Under acidic conditions, the alkene double bond is cleaved to give the appropriate carboxylic acid:[9] - CH3(CH2)17CH=CH2 + 2 KMnO4 + 3 H2SO4 → CH3(CH2)17COOH + CO2 + 4 H2O + K2SO4 + 2 MnSO4 Potassium permanganate oxidizes aldehydes to carboxylic acids, such as the conversion of n-heptanal to heptanoic acid:[10] - 5 C6H13CHO + 2 KMnO4 + 3 H2SO4 → 5 C6H13COOH + 3 H2O + K2SO4 + 2 MnSO4 Even an alkyl group (with a benzylic hydrogen) on an aromatic ring is oxidized, e.g. toluene to benzoic acid.[11] - 5 C6H5CH3 + 6 KMnO4 + 9 H2SO4 → 5 C6H5COOH + 14 H2O + 3 K2SO4 + 6 MnSO4 Glycols and polyols are highly reactive toward KMnO4. For example, addition of potassium permanganate to an aqueous solution of sugar and sodium hydroxide produces the chemical chameleon reaction, which involves dramatic color changes associated with the various oxidation states of manganese. A related vigorous reaction is exploited as a fire starter in survival kits. For example, a mixture of potassium permanganate and glycerol or pulverized glucose ignites readily.[12] Its sterilizing properties are another reason for inclusion of KMnO4 in a survival kit. By itself, potassium permanganate does not dissolve in many organic solvents. If an organic solution of permanganate is desired, "purple benzene" may be prepared, either by treating a two phase mixture of aqueous potassium permanganate and benzene with a quaternary ammonium salt,[13] or by sequestering the potassium cation with a crown ether.[14] Reaction with acids[edit] Concentrated sulfuric acid reacts with KMnO4 to give Mn2O7, which can be explosive.[15] Its reaction with concentrated hydrochloric acid gives chlorine. The Mn-containing products from redox reactions depend on the pH. Acidic solutions of permanganate are reduced to the faintly pink manganese(II) ion (Mn2+) and water. In neutral solution, permanganate is only reduced by three electrons to give MnO2, wherein Mn is in a +4 oxidation state. This is the material that stains one's skin when handling KMnO4. KMnO4 spontaneously reduces in an alkaline solution to green K2MnO4, wherein manganese is in the +6 oxidation state. A curious reaction occurs upon addition of concentrated sulfuric acid to potassium permanganate. Although no reaction may be apparent, the vapor over the mixture will ignite paper impregnated with alcohol. Potassium permanganate and sulfuric acid react to produce some ozone, which has a high oxidising power and rapidly oxidises the alcohol, causing it to combust. As the reaction also produces explosive Mn2O7, this should only be attempted with great care.[16][17] Thermal decomposition[edit] Solid potassium permanganate decomposes when heated: - 2KMnO4 → K2MnO4 + MnO2(s) + O2 Uses[edit] Almost all applications of potassium permanganate exploit its oxidizing properties.[3] As a strong oxidant that does not generate toxic byproducts, KMnO4 has many niche uses. Water treatment and disinfection[edit] As an oxidant, potassium permanganate can act as an antiseptic. For example, dilute solutions are used to treat canker sores (ulcers), disinfectant for the hands and treatment for mild pompholyx, dermatitis,[18][19] and fungal infections of the hands or feet.[20] Potassium permanganate is used extensively in the water treatment industry. It is used as a regeneration chemical to remove iron and hydrogen sulfide (rotten egg smell) from well water via a "Manganese Greensand" Filter. "Pot-Perm" is also obtainable at pool supply stores, is used additionally to treat waste water. Historically it was used to disinfect drinking water.[21][22] It currently finds application in the control of nuisance organisms such as Zebra mussels in fresh water collection and treatment systems.[23] Synthesis of organic compounds[edit] Aside from its use in water treatment, the other major application of KMnO4 is as a reagent for the synthesis of organic compounds.[24] Significant amounts are required for the synthesis of ascorbic acid, chloramphenicol, saccharin, isonicotinic acid, and pyrazinoic acid.[3] Analytical use[edit] Potassium permanganate can be used to quantitatively determine the total oxidisable organic material in an aqueous sample. The value determined is known as the permanganate value. In analytical chemistry, a standardized aqueous solution of KMnO4 is sometimes used as an oxidizing titrant for redox titrations (permanganometry). In a related way, it is used as a reagent to determine the Kappa number of wood pulp. For the standardization of KMnO4 solutions, reduction by oxalic acid is often used.[25] Aqueous, acidic solutions of KMnO4 are used to collect gaseous mercury in flue gas during stationary source emissions testing.[26] In histology, potassium permanganate was used as a bleaching agent.[27][28] Fruit preservation[edit] Ethylene absorbents extend storage time of bananas even at high temperatures. This effect can be exploited by packing bananas in polyethylene together with potassium permanganate. By removing ethylene by oxidation, the permanganate delays the ripening., increasing the fruit's shelf life up to 4 weeks without the need for refrigeration.[29][30][31] Survival kits[edit] Potassium permanganate is typically included in survival kits: as a fire starter (mixed with antifreeze from a car radiator or glycerin),[12] water sterilizer, and for creating distress signals on snow.[32] Fire service[edit] Potassium permanganate is used in the "plastic sphere dispensers" used to set backfires, burnouts, and prescribed fires. Polymer spheres resembling ping-pong balls containing small amounts of permanganate are injected with ethylene glycol and projected towards the area where ignition is desired, where they spontaneously ignite seconds later.[33][34] Both handheld[34] and helicopter-[33] or boat-mounted[34] plastic sphere dispensers are used. Other uses[edit] Potassium permanganate is one of the principal chemicals used in the film and television industries to "age" props and set dressings. Its ready conversion to brown MnO2 create "hundred-year-old" or "ancient" looks on Hessian cloth, ropes, timber, and glass.[35] Safety and handling[edit] As an oxidizer that generates the dark brown product MnO2, potassium permanganate rapidly stains virtually any organic material such as skin, paper, and clothing. Solid KMnO4 is a strong oxidizer, thus should be kept separated from oxidizable substances. Reaction with concentrated sulfuric acid produces the highly explosive manganese(VII) oxide (Mn2O7). When solid, KMnO4 mixed with pure glycerol or other simple alcohols will result in a violent combustion reaction. References[edit] - ^ http://chem.sis.nlm.nih.gov/chemidplus/rn/7722-64-7 - ^ Burriel, F.; Lucena, F.; Arribas, S. and Hernández, J. (1985), Química Analítica Cualitativa, p. 688, ISBN 84-9732-140-5. - ^ a b c d e Reidies, Arno H. (2002) "Manganese Compounds" in Ullmann's Encyclopedia of Industrial Chemistry, Wiley-VCH, Weinheim. - ^ Weeks, M. E. and Leicester, H. M.; Discovery of the Elements, Journal of Chemical Education 1968 - ^ "Important Trade Mark Case". Otago Witness 2 (2420): 53. 2 August 1900. - ^ Walton, H. F. (1948) Inorganic Preparations. New York. - ^ "Handbook of Preparative Inorganic Chemistry" Brauer, E., Ed.; Academic: New York, 1963 - ^ Palenik, Gus J. (1967). "Crystal structure of potassium permanganate". Inorg. Chem. - ^ Donald G. Lee, Shannon E. Lamb, and Victor S. Chang (1990). "Carboxylic Acids from the Oxidation of Terminal Alkenes by Permanganate: Nonadecanoic Acid". Org. Synth.; Coll. Vol. - ^ Ruhoff, John R. "n-Heptanoic acid". Org. Synth.; Coll. Vol. - ^ Gardner KA, Mayer JM (1995). "Understanding C-H Bond Oxidations: H· and H- Transfer in the Oxidation of Toluene by Permanganate". - ^ a b Gillis, Bob and Labiste, Dino. "Fire by Chemical Reaction". - ^ Arthur W. Herriott (1977). "Purple benzene: Solubilization of anions in organic solvents". Chem. Educ. - ^ Doheny, Anthony J., Jr. and Ganem, Bruce (1980). "Purple benzene revisited". Chem. Educ. - ^ Cotton, F. A.; Wilkinson, G.; Murillo, C. A. and Bochmann, M. (1999). Advanced Inorganic Chemistry, 6th Edition. Wiley-VCH. - ^ Barthel, H. and Duvinage, B. (2000). "Clemens Winkler. His Experiments with Ozone in 1892". Praxis der Naturwissenschaften, Chemie 49: 18ff. - ^ Dzhabiev, T. S.; Denisov, N. N.; Moiseev, D. N. and Shilov, A. E. (2005). "Formation of Ozone During the Reduction of Potassium Permanganate in Sulfuric Acid Solutions". Russian Journal of Physical Chemistry 79: 1755–1760. - ^ BIRT AR (March 1964). "Drugs for eczema of children". Can Med Assoc J 90 (11): 693–4. - ^ Stalder JF, Fleury M, Sourisse M, Allavoine T, Chalamet C, Brosset P, Litoux P (1992). "Comparative effects of two topical antiseptics (chlorhexidine vs KMnO4) on bacterial skin flora in atopic dermatitis". Acta Derm Venereol Suppl (Stockh) 176: 132–4. - ^ Program for Appropriate Technology in Health PATH (1988). "Skin diseases". Health Technol Dir 8 (3): 1–10. - ^ Assembly of Life Sciences (U.S.). Safe Drinking Water Committee (1977). Drinking water and health, Volume 2. National Academies Press. - ^ Downey, Robyn and Barrington, Mike (28 February 2005) "Red faces over pink water", The Northern Advocate. - ^ EPA Guidance Manual Alternative Disinfectants and Oxidants. epa.gov "The Classical Permanganate Ion: Still a Novel Oxidant in Organic Chemistry". - ^ Kovacs KA, Grof P, Burai L, Riedel M (2004). "Revising the Mechanism of the Permanganate/Oxalate Reaction". Phys. Chem. - ^ Code of Federal Regulations(7-1-07) Edition, Title 40, Part 60, Appendix A-8, Method 29, Section 7.3.1 - ^ Picken, MM. "Amyloidosis-where are we now and where are we heading?". Arch Pathol Lab Med 134 (4): 545–51. - ^ Murphy CL, Eulitz M, Hrncic R, Sletten K, Westermark P, Williams T, Macy SD, Wooliver C, Wall J, Weiss DT, Solomon A (2001). "Chemical typing of amyloid protein contained in formalin-fixed paraffin-embedded biopsy specimens". Clin. Pathol. - ^ Scott, KJ, McGlasson WB and Roberts EA (1970). "Potassium Permanganate as an Ethylene Absorbent in Polyethylene Bags to Delay the Ripening of Bananas During Storage". Australian Journal of Experimental Agriculture and Animal Husbandry 10 (43): 237. - ^ Scott KJ, Blake, JR, Stracha, G, Tugwell, BL and McGlasson WB (1971). "Transport of Bananas at Ambient Temperatures using Polyethylene Bags". Tropical Agriculture (Trinidad) 48: 163–165. - ^ Scott, KJ and Gandanegara, S (1974). "Effect of Temperature on the Storage Life of bananas Held in Polyethylene Bags with an Ethylene Absorbent". Tropical Agriculture (Trinidad) 51: 23–26. - ^ "Distress Signals". Evening Post CXXI (107): 5. - ^ a b Plastic Sphere Dispenser - US Forest Service - ^ a b c ""Wetland Warrior"". Dirty Jobs. Season 6. Episode 2. - ^ Brody, Ester (February 2000). "Victor DeLor contractor profile". PaintPRO 2 (1). One of the techniques DeLor is known for among designers and clients is the special effects he creates with various chemical solutions. When applied to wood surfaces, these chemicals give a weathered appearance to new wood. To achieve the aesthetic on interior surfaces, DeLor often uses a mixture of water and potassium permanganate, a dry powder chemical. External links[edit] - International Chemical Safety Card 0672 - National Pollutant Inventory: Manganese and compounds Fact Sheet - The use of potassium permanganate in fish ponds - Sugar, NaOH and KMnO4 - Atropine# - Biperiden - Diazepam# - Oximes - see also: Cholinesterase - Primary alcohols: Ethanol - Fomepizole - iodine-131 - Methylthioninium chloride# - oxidizing agent - Potassium permanganate - Prednisolone/promethazine - #WHO-EM - ‡Withdrawn from market - Clinical trials: