One of the joys of high-school mathematics is summing a complicated series to get a “closed-form” expression. And of course many of us have tried summing the harmonic series $H_n =\sum \limits_{k \leq n} \frac{1}{k}$, and failed. But should we necessarily fail? 


  More precisely, is it known that $H_n$ cannot be written in terms of the elementary functions, say, the rational functions, $\exp(x)$ and $\ln x$? If so, how is such a theorem proved? 


Note. When I started writing the question, I was going to ask if it is known that the harmonic function cannot be represented simply as a rational function? But this is easy to see, since $H_n$ grows like $\ln n+O(1)$, whereas no rational function grows logarithmically.

Added note: This earlier question asks a similar question for “elementary integration”. I guess I am asking if there is an analogous theory of “elementary summation”. 

There is a theory of elementary summation; the phrase generally used is "summation in finite terms." An important reference is Michael Karr, Summation in finite terms, Journal of the Association for Computing Machinery 28 (1981) 305-350, DOI: 10.1145/322248.322255. Quoting, 


  This paper describes techniques which greatly broaden the scope of what is meant by 'finite terms'...these methods will show that the following sums have no formula as a rational function of $n$:
  $$\sum_{i=1}^n{1\over i},\quad \sum_{i=1}^n{1\over i^2},\quad \sum_{i=1}^n{2^i\over i},\quad \sum_{i=1}^ni!$$


Undoubtedly the particular problem of $H_n$ goes back well before 1981. The references in Karr's paper may be of some help here. 
