First let me state two known theorems.

Theorem 1 (for smooth manifolds): Let $(M,g)$ be a smooth compact two dimensional Riemannian manifold. Then
$$ \int \frac{K}{2 \pi} dA = \chi (M) $$
where $K$ is the Gaussian curvature, $dA$ is the area form and $\chi(M)$ is the Euler characteristic.

Theorem 2 (combinatorial version): Let $M$ be a two dimensional simplicial complex, with vertices, edges and faces (essentially a bunch of triangles glued together along the edges). Define the function $K:M \rightarrow \mathbb{R}$ to be zero at any point that is not a vertex. At any vertex sum up all the angles 
at the vertex and look at the deviation from $2 \pi$. This is the value of $K$ at a vertex. Then
$$ \sum_{p\in M} \frac{K(p)}{2 \pi} = \chi(M) . $$

Both these statements are known as Gauss Bonnet Theorem. My question is the following: Is it possible to use Theorem 2 in some way to prove Theorem 1? In other words can one recover Theorem 1 from Theorem 2 as some sort of an appropriate "limit"?

A second question is: Is there are a more general theorem from 
which both theorem 1 and theorem 2 arise as special cases? Probably 
some version of the theorem where $K$ simply has to be a measurable 
function?

The answer is yes, to both questions.
First question first.  For any geodesic $n$-gon  $P$ on $M$, i.e.,   a simply connected  region of $M$ whose boundary consists of $n$-geodesic arcs,   define
$$ \delta(P)= \mbox{sum of the angles of $T$}-(n-2)\pi. $$
Note that if $M$ were flat,  then the defect $\delta(P)$ would be $0$.  This quantity has a remarkable property: if $P= P'\cup P''$,   where $P, P', P''$ are geodesic polygons, then
$$ \delta(P)=\delta(P')+\delta(P'')-\delta(P'\cap P'') $$
which shows that   $\delta$ behaves   like a finitely additive measure. It can be extended to a countably additive measure on $M$, and as such, it turns out to be absolutely continuous with respect to the  the volume  measure $dV_g$ defined by the Riemann metric $g$. $\newcommand{\bR}{\mathbb{R}}$ Thus we can  find a function $\rho: M\to \bR$ such that
$$\delta= \rho dV_g. $$
More concretely for any  $p\in M$ we have
$$\rho(p) =\lim_{P\searrow p} \frac{\delta(P)}{{\rm area}\;(P)}, $$
where the limit is taken over geodesic polygons  $P$ that shrink down to the point $p$. In fact
$$ \rho(p)  = K(p). $$
Now observe that if we have a  geodesic triangulation$\newcommand{\eT}{\mathscr{T}}$  $\eT$ of $M$, the combinatorial  Gauss-Bonnet formula reads
$$\sum_{T\in\eT} \delta(T)=2\pi \chi(M). $$
On the other hand
$$\delta(T) =\int_T \rho(p) dV_g(p), $$
and we deduce
$$ \int_M \rho(p) dV_g(g)=\sum_{T\in \eT}\int_T \rho(p) dV_g(p) =\sum_{T\in\eT} \delta(T)=2\pi \chi(M).  $$
For more details see these notes for a  talk I gave to first year grad students a while back.
As for  the second question, perhaps the most general version of Gauss-Bonnet uses the concept of normal cycle introduced by Joseph Fu.
This is a rather tricky and technical subject, which has an intuitive  description.  Here is roughly the idea.
To each compact and reasonably behaved subset $S\subset \bR^n$  one can associate   an $(n-1)$-dimensional current $\newcommand{\bN}{\boldsymbol{N}}$ $\bN^S$ that lives in  $\Sigma T\bR^n =$ the unit sphere  bundle of the tangent bundle of $\bR^n$.   Think of $\bN^S$ as  oriented $(n-1)$-dimensional submanifold  of $\Sigma T\bR^n$.   The term reasonably behaved is quite generous because it includes   all of the examples that you can  produce in finite time (Cantor-like sets are excluded). For example, any compact, semialgebraic set is  reasonably behaved.
How does $\bN^S$ look?  For example, if $S$ is a submanifold, then $\bN^S$ is the unit sphere bundle of the normal bundle of $S\hookrightarrow \bR^n$.
If $S$ is a compact domain of $\bR^n$ with  $C^2$-boundary,  then $\bN^S$, as a subset of $\bR^N\times S^{n-1}$ can be identified with the graph of the  Gauss  map of $\partial  S$, i.e. the map
$$\bR^n\supset \partial S\ni p\mapsto  \nu(p)\in S^{n-1}, $$
where $\nu(p)$ denotes the unit-outer-normal to $\partial S$ at $p$.
More generally, for any $ S$, consider the tube of radius $\newcommand{\ve}{{\varepsilon}}$ around $S$
$$S_\ve= \bigl\lbrace x\in\bR^n;\;\; {\rm dist}\;(x, S)\leq \ve\;\bigr\rbrace. $$
For $\ve $ sufficiently small, $S_\ve$ is a compact domain with $C^2$-boundary (here I'm winging it a bit)  and we can define $\bN^{S_\ve}$ as before.   $\bN^{S_\ve}$ converges  in an appropriate way to   $\bN^{S}$ as $\ve\to 0$ so that for $\ve$ small, $\bN^{S_\ve}$ is a good approximation  for $\bN^S$. Intuitively, $\bN^S$ is the graph of a (possibly non existent) Gauss-map.
If $S$ is a  convex polyhedron  $\bN^S$ is easy to visualize. In general $\bN^S$ satisfies a remarkable additivity
$$\bN^{S_1\cup S_2}= \bN^{S_1}+\bN^{S_2}-\bN^{S_1\cap S_2}. $$
In particular this leads to quite  detailed description  for  $\bN^S$ for a triangulated space $S$.
Where does the Gauss-Bonnet  formula come in?    As observed by J. Fu,  there are some canonical, $O(n)$-invariant,  degree $(n-1)$ differential forms on $\Sigma T\bR^n$, $\omega_0,\dotsc, \omega_{n-1}$  with lots of properties, one being that for  any compact reasonable subset $S$
$$\chi(S)=\int_{\bN^S}\omega_0. $$
The last  equality  contains as special cases the two formulae  you   included in your question.
I am aware   that the last explanations may feel opaque at a first go, so I suggests some    easier, friendlier sources.
For   the normal cycle of simplicial complexes try these notes. For an exposition of Bernig's elegant approach to normal cycles  try these notes.
Even these  "friendly" expositions  with a minimal amount  technicalities could be taxing since they assume familiarity with  many concepts.
Last, but not  least, you should have a look  at these REU notes on these subject. While the normal cycle does not appear,    its shadow is all over the place in these beautifully written notes.
Also, see these notes for a minicourse on this topic that I gave a while back.
