A chiral coordination polymer of silver(I) with saccharinate and pyridine: Synthesis, spectral, thermal, and structural characterization of [Ag(sac)(py)](n)
S Hamamci, V T Yilmaz, W T A Harrison
The first silver(I) complex of saccharinate (sac) with pyridine (py), [Ag(sac)(py)](n) has been synthesized and characterized by elemental analysis, IR spectroscopy and single crystal X-ray diffractometry. The complex crystallizes in chiral, trigonal space group P3(1)21 (No. 152) with unit cell parameters of a = 11.2605(2) angstrom, c = 17.3300(4) angstrom, V = 1903.02(6) angstrom(3) and Z = 6. [Ag(sac)(py)](n) contains monomeric [Ag(sac)(py)] units linked into infinite helices by way of Ag...Ag interactions [d(Ag...Ag) = 2.909(2) and 2.985(1) angstrom]. The distorted square-planar environment of Ag is completed by an N-bonded sac [Ag-N = 2.084(2) angstrom] and a py molecule [Ag-N = 2.116(2) angstrom]. The N-sac-Ag-N-py angle is 173.85(10). The one-dimensional chains are crosslinked by C-(HO)-O-... interactions involving the carbonyl and sulfonyl O atoms of sac and aromatic-ring hydrogen atoms of both sac and py. The thermal stability of the title complex was investigated using thermogravimetry and differential thermal analysis in a static atmosphere of air. The first decomposition stage between 90 and 160 degrees C corresponds to removal of the py molecule in a single stage, while the degradation of the sac moiety occurs at two stages in the temperature range 370-515 degrees C, giving an end product of metallic Ag.
silver(I)
pyridine
one-dimensional polymer
crystal and molecular structure
RAY CRYSTAL-STRUCTURE
BIS(SACCHARINATO)NICKEL(II)
<M(C7H4NO3S)2(H2O)4>.2H2O
2-PYRIDYLMETHANOL
COPPER(II)
CU(II)
CO(II)
NI(II)
Hamamci, S., Yilmaz, V. T., & Harrison, W. T. A. (2005). A chiral coordination polymer of silver(I) with saccharinate and pyridine: Synthesis, spectral, thermal, and structural characterization of [Ag(sac)(py)](n). Structural Chemistry, 16, 379-383. https://doi.org/10.1007/s11224-005-6068-7
A chiral coordination polymer of silver(I) with saccharinate and pyridine: Synthesis, spectral, thermal, and structural characterization of [Ag(sac)(py)](n). / Hamamci, S ; Yilmaz, V T ; Harrison, W T A .
In: Structural Chemistry, Vol. 16, 2005, p. 379-383.
Hamamci, S, Yilmaz, VT & Harrison, WTA 2005, 'A chiral coordination polymer of silver(I) with saccharinate and pyridine: Synthesis, spectral, thermal, and structural characterization of [Ag(sac)(py)](n)', Structural Chemistry, vol. 16, pp. 379-383. https://doi.org/10.1007/s11224-005-6068-7
Hamamci S, Yilmaz VT, Harrison WTA. A chiral coordination polymer of silver(I) with saccharinate and pyridine: Synthesis, spectral, thermal, and structural characterization of [Ag(sac)(py)](n). Structural Chemistry. 2005;16:379-383. https://doi.org/10.1007/s11224-005-6068-7
Hamamci, S ; Yilmaz, V T ; Harrison, W T A . / A chiral coordination polymer of silver(I) with saccharinate and pyridine: Synthesis, spectral, thermal, and structural characterization of [Ag(sac)(py)](n). In: Structural Chemistry. 2005 ; Vol. 16. pp. 379-383.
@article{6d26612a6e1b4683b234ba6ebd6f136b,
title = "A chiral coordination polymer of silver(I) with saccharinate and pyridine: Synthesis, spectral, thermal, and structural characterization of [Ag(sac)(py)](n)",
abstract = "The first silver(I) complex of saccharinate (sac) with pyridine (py), [Ag(sac)(py)](n) has been synthesized and characterized by elemental analysis, IR spectroscopy and single crystal X-ray diffractometry. The complex crystallizes in chiral, trigonal space group P3(1)21 (No. 152) with unit cell parameters of a = 11.2605(2) angstrom, c = 17.3300(4) angstrom, V = 1903.02(6) angstrom(3) and Z = 6. [Ag(sac)(py)](n) contains monomeric [Ag(sac)(py)] units linked into infinite helices by way of Ag...Ag interactions [d(Ag...Ag) = 2.909(2) and 2.985(1) angstrom]. The distorted square-planar environment of Ag is completed by an N-bonded sac [Ag-N = 2.084(2) angstrom] and a py molecule [Ag-N = 2.116(2) angstrom]. The N-sac-Ag-N-py angle is 173.85(10). The one-dimensional chains are crosslinked by C-(HO)-O-... interactions involving the carbonyl and sulfonyl O atoms of sac and aromatic-ring hydrogen atoms of both sac and py. The thermal stability of the title complex was investigated using thermogravimetry and differential thermal analysis in a static atmosphere of air. The first decomposition stage between 90 and 160 degrees C corresponds to removal of the py molecule in a single stage, while the degradation of the sac moiety occurs at two stages in the temperature range 370-515 degrees C, giving an end product of metallic Ag.",
keywords = "silver(I), saccharin, pyridine, one-dimensional polymer, crystal and molecular structure, RAY CRYSTAL-STRUCTURE, COMPLEXES, BIS(SACCHARINATO)NICKEL(II), <M(C7H4NO3S)2(H2O)4>.2H2O, 2-PYRIDYLMETHANOL, COPPER(II), CU(II), CO(II), NI(II), LIGAND",
author = "S Hamamci and Yilmaz, {V T} and Harrison, {W T A}",
journal = "Structural Chemistry",
T1 - A chiral coordination polymer of silver(I) with saccharinate and pyridine: Synthesis, spectral, thermal, and structural characterization of [Ag(sac)(py)](n)
AU - Hamamci, S
AU - Yilmaz, V T
AU - Harrison, W T A
N2 - The first silver(I) complex of saccharinate (sac) with pyridine (py), [Ag(sac)(py)](n) has been synthesized and characterized by elemental analysis, IR spectroscopy and single crystal X-ray diffractometry. The complex crystallizes in chiral, trigonal space group P3(1)21 (No. 152) with unit cell parameters of a = 11.2605(2) angstrom, c = 17.3300(4) angstrom, V = 1903.02(6) angstrom(3) and Z = 6. [Ag(sac)(py)](n) contains monomeric [Ag(sac)(py)] units linked into infinite helices by way of Ag...Ag interactions [d(Ag...Ag) = 2.909(2) and 2.985(1) angstrom]. The distorted square-planar environment of Ag is completed by an N-bonded sac [Ag-N = 2.084(2) angstrom] and a py molecule [Ag-N = 2.116(2) angstrom]. The N-sac-Ag-N-py angle is 173.85(10). The one-dimensional chains are crosslinked by C-(HO)-O-... interactions involving the carbonyl and sulfonyl O atoms of sac and aromatic-ring hydrogen atoms of both sac and py. The thermal stability of the title complex was investigated using thermogravimetry and differential thermal analysis in a static atmosphere of air. The first decomposition stage between 90 and 160 degrees C corresponds to removal of the py molecule in a single stage, while the degradation of the sac moiety occurs at two stages in the temperature range 370-515 degrees C, giving an end product of metallic Ag.
AB - The first silver(I) complex of saccharinate (sac) with pyridine (py), [Ag(sac)(py)](n) has been synthesized and characterized by elemental analysis, IR spectroscopy and single crystal X-ray diffractometry. The complex crystallizes in chiral, trigonal space group P3(1)21 (No. 152) with unit cell parameters of a = 11.2605(2) angstrom, c = 17.3300(4) angstrom, V = 1903.02(6) angstrom(3) and Z = 6. [Ag(sac)(py)](n) contains monomeric [Ag(sac)(py)] units linked into infinite helices by way of Ag...Ag interactions [d(Ag...Ag) = 2.909(2) and 2.985(1) angstrom]. The distorted square-planar environment of Ag is completed by an N-bonded sac [Ag-N = 2.084(2) angstrom] and a py molecule [Ag-N = 2.116(2) angstrom]. The N-sac-Ag-N-py angle is 173.85(10). The one-dimensional chains are crosslinked by C-(HO)-O-... interactions involving the carbonyl and sulfonyl O atoms of sac and aromatic-ring hydrogen atoms of both sac and py. The thermal stability of the title complex was investigated using thermogravimetry and differential thermal analysis in a static atmosphere of air. The first decomposition stage between 90 and 160 degrees C corresponds to removal of the py molecule in a single stage, while the degradation of the sac moiety occurs at two stages in the temperature range 370-515 degrees C, giving an end product of metallic Ag.
KW - silver(I)
KW - saccharin
KW - pyridine
KW - one-dimensional polymer
KW - crystal and molecular structure
KW - RAY CRYSTAL-STRUCTURE
KW - COMPLEXES
KW - BIS(SACCHARINATO)NICKEL(II)
KW - <M(C7H4NO3S)2(H2O)4>.2H2O
KW - 2-PYRIDYLMETHANOL
KW - COPPER(II)
KW - CU(II)
KW - CO(II)
KW - NI(II)
KW - LIGAND
JO - Structural Chemistry
JF - Structural Chemistry