Water treatment describes those processes used to make water more acceptable for a desired end-use. These can include use as drinking water, industrial processes, medical and many other uses. The goal of all water treatment process is to remove existingcontaminants in the water, or reduce the concentration of such contaminants so the water becomes fit for its desired end-use. One such use is returning water that has been used back into the natural environment without adverse ecological impact.
Potable water purification
Water purification is the removal of contaminants from untreated water to produce drinking water that is pure enough for its intended use, most commonly human consumption. Substances that are removed during the process of drinking water treatment include bacteria, algae, viruses, fungi,minerals such as iron, manganese and sulphur, and man-made chemical pollutants including fertilisers.
It is important to take measures to make available water of desirable quality at the consumer end. That leads to protection of the treated water during conveyance and distribution after treatment. It is common practice to have residual disinfectants in the treated water in order to kill any bacteriological contamination after water treatment.
World Health Organisation (WHO) guidelines are generally followed throughout the world for drinking water quality requirements. In addition of the WHO guidelines, each country or territory or water supply body can have their own guidelines in order for consumers to have access to safe drinking water.
Processes for drinking water
The combination of following processes is used for municipal drinking water treatment worldwide:
- Pre-chlorination – for algae control and arresting any biological growth
- Aeration – along with pre-chlorination for removal of dissolved iron and manganese
- Coagulation – for flocculation
- Coagulant aids also known as polyelectrolytes – to improve coagulation and for thicker floc formation
- Sedimentation – for solids separation, that is, removal of suspended solids trapped in the floc
- Filtration – for removal of carried over floc
- Disinfection – for killing bacteria
There is no unique solution (selection of processes) for any type of water. Also, it is difficult to standardise the solution in the form of processes for water from different sources. Treatability studies for each source of water in different seasons need to be carried out to arrive at most appropriate processes.
Sewage treatment is the process that removes the majority of the contaminants from wastewater or sewage and produces both a liquid effluent suitable for disposal to the natural environment and a sludge. To be effective, sewage must be conveyed to a treatment plant by appropriate pipes and infrastructure and the process itself must be subject to regulation and controls. Some wastewaters require different and sometimes specialized treatment methods. At the simplest level, treatment of sewage and most wastewaters is carried out through separation of solids from liquids, usually by settlement. By progressively converting dissolved material into solids, usually a biological floc which is then settled out, an effluent stream of increasing purity is produced.
In developing countries
As of 2006, waterborne diseases are estimated to cause 1.8 million deaths each year. These deaths are attributable to inadequate public sanitation systems and it is clear that propersewerage (or other options as small-scale water treatment) need to be installed.
Appropriate technology options in water treatment include both community-scale and household-scale point-of-use (POU) designs. Military surplus water treatment units like theERDLator are still seen in developing countries. Newer military style Reverse Osmosis Water Purification Units (ROWPU) are portable, self-contained water treatment plants are becoming more available for public use.
In order for the decrease of waterborne diseases to have long term effects, water treatment programs implemented by research and development groups in developing countries must be sustainable by its own residents. This can ensure the efficiency of such programs after the departure of the research team as monitoring is difficult because of the remoteness of many locations.
Industrial wastewater treatment
Industrial wastewater treatment covers the mechanisms and processes used to treat waters that have been contaminated in some way by anthropogenic industrial or commercial activities prior to its release into the environment or its re-use.
Most industries produce some wet waste although recent trends in the developed world have been to minimise such production or recycle such waste within the production process. However, many industries remain dependent on processes that produce wastewaters.
Sources of industrial wastewater
Iron and steel industry
The production of iron from its ores involves powerful reduction reactions in blast furnaces. Cooling waters are inevitably contaminated with products especially ammonia and cyanide. Production of coke from coal in coking plants also requires water cooling and the use of water in by-products separation. Contamination of waste streams includes gasification products such as benzene, naphthalene, anthracene, cyanide, ammonia, phenols, cresols together with a range of more complex organic compounds known collectively as polycyclic aromatic hydrocarbons (PAH).
The conversion of iron or steel into sheet, wire or rods requires hot and cold mechanical transformation stages frequently employing water as a lubricant and coolant. Contaminants includehydraulic oils, tallow and particulate solids. Final treatment of iron and steel products before onward sale into manufacturing includes pickling in strong mineral acid to remove rust and prepare the surface for tin or chromium plating or for other surface treatments such as galvanisation or painting. The two acids commonly used are hydrochloric acid and sulfuric acid. Wastewaters include acidic rinse waters together with waste acid. Although many plants operate acid recovery plants, (particularly those using Hydrochloric acid), where the mineral acid is boiled away from the iron salts, there remains a large volume of highly acid ferrous sulfate or ferrous chloride to be disposed of. Many steel industry wastewaters are contaminated by hydraulic oil also known as soluble oil.
Mines and quarries
The principal waste-waters associated with mines and quarries are slurries of rock particles in water. These arise from rainfall washing exposed surfaces and haul roads and also from rock washing and grading processes. Volumes of water can be very high, especially rainfall related arisings on large sites. Some specialized separation operations, such as coal washing to separate coal from native rock using density gradients, can produce wastewater contaminated by fine particulate haematite and surfactants. Oils and hydraulic oils are also common contaminants. Wastewater from metal mines and ore recovery plants are inevitably contaminated by the minerals present in the native rock formations. Following crushing and extraction of the desirable materials, undesirable materials may become contaminated in the wastewater. For metal mines, this can include unwanted metals such as zinc and other materials such asarsenic. Extraction of high value metals such as gold and silver may generate slimes containing very fine particles in where physical removal of contaminants becomes particularly difficult.
Wastewater generated from agricultural and food operations has distinctive characteristics that set it apart from common municipal wastewater managed by public or private wastewater treatment plants throughout the world: it is biodegradable and nontoxic, but that has high concentrations of biochemical oxygen demand (BOD) and suspended solids (SS). The constituents of food and agriculture wastewater are often complex to predict due to the differences in BOD and pH in effluents from vegetable, fruit, and meat products and due to the seasonal nature of food processing and postharvesting.
Processing of food from raw materials requires large volumes of high grade water. Vegetable washing generates waters with high loads of particulate matter and some dissolved organics. It may also contain surfactants.
Animal slaughter and processing produces very strong organic waste from body fluids, such as blood, and gut contents. This wastewater is frequently contaminated by significant levels ofantibiotics and growth hormones from the animals and by a variety of pesticides used to control external parasites. Insecticide residues in fleeces is a particular problem in treating waters generated in wool processing.
Processing food for sale produces wastes generated from cooking which are often rich in plant organic material and may also contain salt, flavourings, colouring material and acids or alkali. Very significant quantities of oil or fats may also be present.
Complex organic chemicals industry
A range of industries manufacture or use complex organic chemicals. These include pesticides, pharmaceuticals, paints and dyes, petro-chemicals, detergents, plastics, paper pollution, etc. Waste waters can be contaminated by feed-stock materials, by-products, product material in soluble or particulate form, washing and cleaning agents, solvents and added value products such as plasticisers.
The waste production from the nuclear and radio-chemicals industry is dealt with at Radioactive waste.
Water treatment for the production of drinking water is dealt with elsewhere. (See water purification.) Many industries have a need to treat water to obtain very high quality water for demanding purposes. Water treatment produces organic and mineral sludges from filtration and sedimentation. Ion exchange using natural or synthetic resins removes calcium, magnesiumand carbonate ions from water, replacing them with hydrogen and hydroxyl ions. Regeneration of ion exchange columns with strong acids and alkalis produces a wastewater rich in hardness ions which are readily precipitated out, especially when in admixture with other wastewaters.
Treatment of industrial wastewater
The different types of contamination of wastewater require a variety of strategies to remove the contamination.
Most solids can be removed using simple sedimentation techniques with the solids recovered as slurry or sludge. Very fine solids and solids with densities close to the density of water pose special problems. In such case filtration or ultrafiltration may be required. Although, flocculation may be used, using alum salts or the addition of polyelectrolytes.
Oils and grease removal
Many oils can be recovered from open water surfaces by skimming devices. Considered a dependable and cheap way to remove oil, grease and other hydrocarbons from water, oil skimmers can sometimes achieve the desired level of water purity. At other times, skimming is also a cost-efficient method to remove most of the oil before using membrane filters and chemical processes. Skimmers will prevent filters from blinding prematurely and keep chemical costs down because there is less oil to process.
Because grease skimming involves higher viscosity hydrocarbons, skimmers must be equipped with heaters powerful enough to keep grease fluid for discharge. If floating grease forms into solid clumps or mats, a spray bar, aerator or mechanical apparatus can be used to facilitate removal.
However, hydraulic oils and the majority of oils that have degraded to any extent will also have a soluble or emulsified component that will require further treatment to eliminate. Dissolving or emulsifying oil using surfactants or solventsusually exacerbates the problem rather than solving it, producing wastewater that is more difficult to treat.
The wastewaters from large-scale industries such as oil refineries, petrochemical plants, chemical plants, and natural gas processing plants commonly contain gross amounts of oil and suspended solids. Those industries use a device known as an API oil-water separator which is designed to separate the oil and suspended solids from their wastewatereffluents. The name is derived from the fact that such separators are designed according to standards published by the American Petroleum Institute (API).
The API separator is a gravity separation device designed by using Stokes Law to define the rise velocity of oil droplets based on their density and size. The design is based on the specific gravity difference between the oil and the wastewater because that difference is much smaller than the specific gravity difference between the suspended solids and water. The suspended solids settles to the bottom of the separator as a sediment layer, the oil rises to top of the separator and the cleansed wastewater is the middle layer between the oil layer and the solids.
Typically, the oil layer is skimmed off and subsequently re-processed or disposed of, and the bottom sediment layer is removed by a chain and flight scraper (or similar device) and a sludge pump. The water layer is sent to further treatment consisting usually of a Electroflotation module for additional removal of any residual oil and then to some type of biological treatment unit for removal of undesirable dissolved chemical compounds.
Parallel plate separators are similar to API separators but they include tilted parallel plate assemblies (also known as parallel packs). The parallel plates provide more surface for suspended oil droplets to coalesce into larger globules. Such separators still depend upon the specific gravity between the suspended oil and the water. However, the parallel plates enhance the degree of oil-water separation. The result is that a parallel plate separator requires significantly less space than a conventional API separator to achieve the same degree of separation.
Removal of biodegradable organics
Biodegradable organic material of plant or animal origin is usually possible to treat using extended conventionalwastewater treatment processes such as activated sludge or trickling filter. Problems can arise if the wastewater is excessively diluted with washing water or is highly concentrated such as neat blood or milk. The presence of cleaning agents, disinfectants, pesticides, or antibiotics can have detrimental impacts on treatment processes.
Activated sludge process
Activated sludge is a biochemical process for treating sewage and industrial wastewater that uses air (or oxygen) andmicroorganisms to biologically oxidize organic pollutants, producing a waste sludge (or floc) containing the oxidized material. In general, an activated sludge process includes:
- An aeration tank where air (or oxygen) is injected and thoroughly mixed into the wastewater.
- A settling tank (usually referred to as a “clarifier” or “settler”) to allow the waste sludge to settle. Part of the waste sludge is recycled to the aeration tank and the remaining waste sludge is removed for further treatment and ultimate disposal.
Trickling filter process
A trickling filter consists of a bed of rocks, gravel, slag, peat moss, or plastic media over which wastewater flows downward and contacts a layer (or film) of microbial slime covering the bed media. Aerobic conditions are maintained by forced air flowing through the bed or by natural convection of air. The process involves adsorption of organic compounds in the wastewater by the microbial slime layer, diffusion of air into the slime layer to provide the oxygen required for the biochemical oxidation of the organic compounds. The end products include carbon dioxide gas, water and other products of the oxidation. As the slime layer thickens, it becomes difficult for the air to penetrate the layer and an inner anaerobic layer is formed.
The components of a complete trickling filter system are: fundamental components:
- A bed of filter medium upon which a layer of microbial slime is promoted and developed.
- An enclosure or a container which houses the bed of filter medium.
- A system for distributing the flow of wastewater over the filter medium.
- A system for removing and disposing of any sludge from the treated effluent.
The treatment of sewage or other wastewater with trickling filters is among the oldest and most well characterized treatment technologies.
A trickling filter is also often called a trickle filter, trickling biofilter, biofilter, biological filter or biological trickling filter.
Treatment of acids and alkalis
Acids and alkalis can usually be neutralised under controlled conditions. Neutralisation frequently produces a precipitate that will require treatment as a solid residue that may also be toxic. In some cases, gasses may be evolved requiring treatment for the gas stream. Some other forms of treatment are usually required following neutralisation.
Waste streams rich in hardness ions as from de-ionisation processes can readily lose the hardness ions in a buildup of precipitated calcium and magnesium salts. This precipitation process can cause severe furring of pipes and can, in extreme cases, cause the blockage of disposal pipes. A 1 metre diameter industrial marine discharge pipe serving a major chemicals complex was blocked by such salts in the 1970s. Treatment is by concentration of de-ionisation waste waters and disposal to landfill or by careful pH management of the released wastewater.
Treatment of toxic materials
Toxic materials including many organic materials, metals (such as zinc, silver, cadmium, thallium, etc.) acids, alkalis, non-metallic elements (such as arsenic or selenium) are generally resistant to biological processes unless very dilute. Metals can often be precipitated out by changing the pH or by treatment with other chemicals. Many, however, are resistant to treatment or mitigation and may require concentration followed by landfilling or recycling. Disolved organics can be incinerated within the wastewater by Advanced Oxidation Processes.