Verdigris is made by placing a plate or blade of copper, brass or bronze, slightly warmed, into a vat of fermenting wine, leaving it there for several weeks, and then scraping off and drying the green powder that forms on the metal. The process of making verdigris was described in ancient times by Pliny. It was used by the Romans in the murals of Pompeii, and in Celtic medieval manuscripts as early as the 5th century AD. It produced a blue-green which no other pigment could imitate, but it had drawbacks; it was unstable, it could not resist dampness, it did not mix well with other colors, it could ruin other colors with which it came into contact., and it was toxic. Leonardo da Vinci, in his treatise on painting, warned artists not to use it. It was widely used in miniature paintings in Europe and Persia in the 16th and 17th centuries. Its use largely ended in the late 19th century, when it was replaced by the safer and more stable chrome green. Viridian, also called chrome green, is a pigment made with chromium oxide dihydrate, was patented in 1859. It became popular with painters, since, unlike other synthetic greens, it was stable and not toxic. Vincent van Gogh used it, along with Prussian blue, to create a dark blue sky with a greenish tint in his painting Cafe terrace at night.
When was Prussian blue patented?