But in statistical mechanics things get more complicated. On one hand, statistical mechanics is far superior to classical thermodynamics, in that thermodynamic behavior, such as glass breaking, can be explained by the fundamental laws of physics paired with a statistical postulate. But statistical mechanics, unlike classical thermodynamics, is time-reversal symmetric. The second law of thermodynamics, as it arises in statistical mechanics, merely states that it is overwhelmingly likely that net entropy will increase, but it is not an absolute law.
What thermodynamic behavior can not be explained by the fundemental laws of physics?