  The decay of inner-shell vacancy in an atom through radiative and
non-radiative transitions leads to final charged ions. The de-excitation decay
of 3s, 3p and 3d vacancies in Kr atoms are calculated using Monte-Carlo
simulation method. The vacancy cascade pathway resulted from the de-excitation
decay of deep core hole in 3s subshell in Kr atoms is discussed. The generation
of spectator vacancies during the vacancy cascade development gives rise to
Auger satellite spectra. The last transitions of the de-excitation decay of 3s,
3p and 3d holes lead to specific charged ions. Dirac-Fock-Slater wave functions
are adapted to calculate radiative and non-radiative transition probabilities.
The intensity of Kr^{4+} ions are high for 3s hole state, whereas Kr^{3+} and
Kr^{2+} ions have highest intensities for 3p and 3d hole states, respectively.
The present results of ion charge state distributions agree well with the
experimental data.
