  The local atomic structure of an amorphous NiZr2 alloy was investigated using
the anomalous wide-angle x-ray scattering (AWAXS), differential anomalous
scattering (DAS) and reverse Monte Carlo (RMC) simulations techniques. The
AWAXS measurements were performed at eight different incident photon energies,
including some close to the Ni and Zr K edges. From the measurements eight
total structure factor S(K,E) were derived. Using the AWAXS data four
differential structure factors DSFi(K,Em,En) were derived, two about the Ni and
Zr edges. The partial structure factors SNi-Ni(K), SNi-Zr(K) and SZr-Zr(K) were
estimated by using two different methods. First, the S(K,E) and DSFi(K,Em,En)
factors were combined and used in a matrix inversion process. Second, three
S(K,E) factors were used as input data in the RMC technique. The coordination
numbers and interatomic distances for the first neighbors extracted from the
partial structure factors obtained by these two methods show a good agreement.
By using the three-dimensional structure derived from the RMC simulations, the
bond-angle distributions were calculated and they suggest the presence of
distorted triangular-faced polyhedral units in the amorphous NiZr2 structure.
We have used the Warren chemical short-range order parameter to evaluate the
chemical short-range order for the amorphous NiZr2 alloy and for the NiZr2
compound. The calculated values show that the chemical short-range order found
in these two materials is similar to that found in a solid solution.
