  We have observed the S(0), S(1), S(2), S(3), S(4) and S(5) rotational lines
of molecular hydrogen (H2) towards the peak of the photodissociation region
(PDR) associated with the reflection nebula NGC 7023. The observed H2 line
ratios show that they arise in warm gas with kinetic temperatures ~300 - 700 K.
However, the data cannot be fitted by an ortho- to para- (OTP) ratio of 3. An
OTP ratio in the range ~1.5 - 2 is necessary to explain our observations. This
is the first detection of a non-equilibrium OTP ratio measured from the H2
pure-rotational lines in a PDR. The existence of a dynamical PDR is discussed
as the most likely explanation for this low OTP ratio.
