  We present high-resolution optical spectra (at ~0.6--1.8 km s-1) of
interstellar CN, CH, CH^+, \ion{Ca}{1}, \ion{K}{1}, and \ion{Ca}{2} absorption
toward 29 lines of sight in three star-forming regions, \rho Oph, Cep OB2, and
Cep OB3. The observations and data reduction are described. The agreement
between earlier measurements of the total equivalent widths and our results is
quite good. However, our higher resolution spectra reveal complex structure and
closely blended components in most lines of sight. The velocity component
structure of each species is obtained by analyzing the spectra of the six
species for a given sight line together. The tabulated column densities and
Doppler parameters of individual components are determined by using the method
of profile fitting. Total column densities along lines of sight are computed by
summing results from profile fitting for individual components and are compared
with column densities from the apparent optical depth method. A more detailed
analysis of these data and their implications will be presented in a companion
paper.
