  We have measured total absolute cross sections for the Mutual Neutralization
(MN) of O- with O+/N+. A fine resolution (of about 50 meV) in the kinetic
energy spectra of the product neutral atoms allows unique identification of the
atomic states participating in the mutual neutralization process. Cross
sections and branching ratios have also been calculated down to 1 meV
center-of-mass collision energy for these two systems with a multi-channel
Landau-Zener model and an asymptotic method for the ionic-covalent coupling
matrix elements. The importance of two-electron processes in one-electron
transfer is demonstrated by the dominant contribution of a core-excited
configuration of the nitrogen atom in N+ + O- collisions. This effect is
partially accounted for by introducing configuration mixing in the evaluation
of coupling matrix elements.
