  Crystal structure and thermodynamic properties of Na$_2$SrCo(PO$_4$)$_2$, the
chemical sibling of the triangular quantum spin-liquid candidate
Na$_2$BaCo(PO$_4$)$_2$, are reported. From single crystal x-ray diffraction and
high-resolution synchrotron x-ray powder diffraction, the compound was found to
crystallize in the monoclinic space group $P2_1/a$ at room temperature, in
contrast to the trigonal Na$_2$BaCo(PO$_4$)$_2$. Above 650 K, the symmetry of
Na$_2$SrCo(PO$_4$)$_2$ changes to $C2/m$, while around 1025 K a further
transformation toward trigonal symmetry is observed. The monoclinic symmetry
leads to a small deformation of the CoO$_6$ octahedra beyond the trigonal
distortion ubiquitous in this structure type, and results in the stronger
$g$-tensor anisotropy ($g_{\text{z}}/g_{\text{xy}} = 1.6 $) as well as the
increased XXZ anisotropy ($J_{\text{z}}/J_{\text{xy}} = 2.1$) compared to the
Ba compound ($g_{\text{z}}/g_{\text{xy}} = 1.1 $, $J_{\text{z}}/J_{\text{xy}} =
1.5$), while the average coupling strength,
$J_{\text{av}}/k_{\text{B}}=(2J_{\text{xy}}+J_{\text{z}})/3k_\text{B}\simeq
1.3\,\text{K}$, remains unchanged. The N\'{e}el temperature increases from 140
mK (Ba) to 600 mK (Sr), and an uncompensated in-plane moment of
$0.066(4)\mu_{\text{B}}/\text{f.u.}$ appears. We show that the ordering
temperature of a triangular antiferromagnet is capably controlled by its
structural distortions.
