  In this article, we investigated the effect of Cr substitution in place of Fe
on the structural, magnetic and transport properties of $\mathrm{Co_2FeSi}$
alloy. A comprehensive structural analysis is done using X-ray diffraction
(XRD) and extended X-ray absorption fine structure (EXAFS) spectroscopy.
Quaternary Heusler compounds $\mathrm{Co_2Fe_{1-x}Cr_xSi}$ with Cr content (x =
0.1, 0.3, 0.5) were found to crystallize in cubic structure. The synchrotron
based EXAFS studies reveal that the anti-site disorder increases with the
increase in Cr concentration. The saturation magnetization values in all the
alloys are found to be less than those expected from the Slater-Pauling rule,
which may be due to the some inherent disorder. A detailed resistivity analysis
in the temperature range of 5-300 K is done, taking into account different
scattering mechanisms. The residual resistivity ratio is found to decrease with
increasing Cr concentration. A disorder induced resistivity minimum due to weak
localization effect is seen for x = 0.5. The resistivity measurements also
indicate that the half-metallic character survives upto 100 K for x = 0.1,
whereas the alloys with x= 0.3 and 0.5 show signature of half- metallic nature
even at higher temperatures. First principles calculation done with a more
robust exchange correlation functional (namely HSE-06) confirms the half
metallicity in the entire concentration range. Theoretically simulated band gap
and magnetic moments compliment the experimental findings and are compared
wherever possible. All these properties make $\mathrm{Co_2Fe_{1-x}Cr_xSi}$ a
promising material for spintronics application.
