  Electronic correlation is of fundamental importance to high temperature
superconductivity. Iron-based superconductors are believed to possess moderate
correlation strength, which combined with their multi-orbital nature makes them
a fascinating platform for the emergence of exotic phenomena. A particularly
striking form is the emergence of an orbital selective Mott phase, where the
localization of a subset of orbitals leads to a drastically reconstructed Fermi
surface. Here, we report spectroscopic evidence of the reorganization of the
Fermi surface from FeSe to FeTe as Se is substituted by Te. We uncover a
particularly transparent way to visualize the localization of the $d_{xy}$
electron orbital through the suppression of its hybridization with the more
coherent $d$ electron orbitals, which leads to a redistribution of the
orbital-dependent spectral weight near the Fermi level. These noteworthy
features of the Fermi surface are accompanied by a divergent behavior of a band
renormalization in the $d_{xy}$ orbital. All of our observations are further
supported by our theoretical calculations to be salient spectroscopic
signatures of such a non-thermal evolution from a strongly correlated metallic
phase towards an orbital-selective Mott phase in FeTe$_{1-x}$Se$_x$ as Se
concentration is reduced.
