  We consider the production of muon pairs from the scattering of pions on
longitudinally polarized protons. We calculate the cross section and the single
spin asymmetry for this process, taking into account pion bound state effects.
We work in the kinematic region where the photon has a large longitudinal
momentum fraction, which allows us to treat the bound state problem
perturbatively. Our predictions are directly proportional to the pion
distribution amplitude. A measurement of the polarized Drell-Yan cross section
thus allows the determination of the shape of the pion distribution amplitude.
