  We have investigated by means of first principles calculations the structural
and electronic properties of hydrogenated graphene structures with distinct
grain boundary defects. Our total energy results reveal that the adsorption of
a single H is more stable at grain boundary defect. The electronic structure of
the grains boundaries upon hydrogen adsorption have been examined. Further
total energy calculations indicate that the adsorption of two H on two neighbor
carbons, forming a basic unit of graphane, is more stable at the defect region.
Therefore, we expect that these extended defects would work as a nucleation
region for the formation of a narrow graphane strip embedded in graphene
region.
