  The L2,3 X-ray emission of Cu metal has been measured using monochromatic
synchrotron radiation. The self-absorption effect in the spectra is shown to be
very small in our experimental geometry. From the quantitative analysis of
spectra recorded at different excitation energies, the L3/L2 emission intensity
ratio and the partial Auger-width are extracted. High-energy satellite features
on the L3 emission line are separated by a subtraction procedure. The satellite
intensity is found to be slowly increasing for excitation energies between the
L3, L2 and L1 core-level thresholds due to shake-up and shake-off transitions.
As the excitation energy passes the L2 threshold, a step of rapidly increasing
satellite intensity of the L3 emission is found due to additional Coster-Kronig
processes.
