  X- and Q-band electron paramagnetic resonance (EPR) study is reported on the
SrTiO3 single crystals doped with 0.5-at.% MnO. EPR spectra originating from
the S = 2 ground state of Mn3+ ions are shown to belong to the three distinct
types of Jahn-Teller centres. The ordering of the oxygen vacancies due to the
reduction treatment of the samples and consequent formation of oxygen vacancy
associated Mn3+ centres are explained in terms of the localized charge
compensation. The EPR spectra of SrTiO3: Mn crystals show the presence of next
nearest neighbor exchange coupled Mn4+ pairs in the <110> directions.
