  The ground and excited state properties of small helium clusters, 4He_N,
containing nanoscale (~3-10 Angstroms) planar aromatic molecules have been
studied with quantum Monte Carlo methods. Ground state structures and energies
are obtained from importance-sampled, rigid-body diffusion Monte Carlo. Excited
state energies due to helium vibrational motion are evaluated using the
projection operator, imaginary time spectral evolution technique. We examine
the adsorption of N helium atoms (N less than or equal to 24) on a series of
planar aromatic molecules (benzene, naphthalene, anthracene, tetracene,
phthalocyanine). The first layer of helium atoms is well-localized on the
molecule surface, and we find well-defined localized excitations due to
in-plane vibrational motion of helium on the molecule surface. We discuss the
implications of these confined excitations for the molecule spectroscopy.
