  The aim of this work is to improve the modelling of ion populations in higher
density, lower temperature astrophysical plasmas, of the type commonly found in
lower solar and stellar atmospheres. Ion population models for these regions
frequently employ the coronal approximation, which assumes conditions more
suitable to the upper solar atmosphere, where high temperatures and lower
densities prevail. Using the coronal approximation for modelling the solar
transition region gives theoretical lines intensities for the Li-like and
Na-like isoelectronic sequences which can be factors of 2-5 times lower than
observed. The works of Burgess & Summers (1969) and Nussbaumer & Storey (1975)
showed the important part ions in excited levels play when included in the
modelling. Their models, however, used approximations for the atomic rates to
determine the ion balance. Presented here is the first stage in updating these
earlier models of carbon by using rates from up-to-date atomic calculations and
more recent photo-ionising radiances for the quiet Sun. Where such atomic rates
are not readily available, in the case of electron-impact direct ionisation and
excitation--auto-ionisation, new calculations have been made and compared to
theoretical and experimental studies. The effects each atomic process has on
the ion populations as density changes is demonstrated, and final results from
the modelling are compared to the earlier works. Lastly, the new results for
ion populations are used to predict line intensities for the solar transition
region in the quiet Sun, and these are compared with predictions from
coronal-approximation modelling and with observations. Significant improvements
in the predicted line intensities are seen in comparison to those obtained from
zero-density modelling of carbon.
