  The transport of excess electrons in liquid argon driven out of equilibrium
by an applied electric field is revisited using a multi-term solution of
Boltzmann's equation together with ab initio liquid phase cross-sections
calculated using the Dirac-Fock scattering equations. The calculation of liquid
phase cross-sections extends previous treatments to consider multipole
polarisabilities and a non-local treatment of exchange while the accuracy of
the electron-argon potential is validated through comparison of the calculated
gas phase cross-section with experiment. The results presented highlight the
inadequacy of local treatments of exchange that are commonly used in liquid and
cluster phase cross-section calculations. The multi-term Boltzmann equation
framework accounting for coherent scattering enables the inclusion of the full
anisotropy in the differential cross-section arising from the interaction and
the structure factor, without an a priori assumption of quasi-isotropy in the
velocity distribution function. The model, which contains no free parameters
and accounts for both coherent scattering and liquid phase screening effects,
was found to reproduce well the experimental drift velocities and
characteristic energies.
