  Electronic structure of HCl+ and HBr+ molecular ions is calculated using the
symmetry-adapted-cluster configuration interaction (SAC-CI) method. In this
paper, we analyse dipole moments (DM) for a series of low-lying six 2Pi-states
and transition dipole moments (TDM for transitions from the ground state X2Pi
to the excited 2Pi-series. Behavior of DMs with change of interatomic distances
is different for these ions for the excited 2Pi-states in correspondence with
different dissociation paths. TDMs reveal the pronounced maxima at the
beginning steps of dissociation.
