  Two-dimensional charge carrier accumulation at oxide heterointerfaces
presents a paradigm shift for oxide electronics. Like a capacitor, interfacial
charge buildup couples to an electric field across the dielectric medium. To
prevent the so-called polar catastrophe, several charge screening mechanisms
emerge, including polar distortions and interfacial intermixing which reduce
the sharpness of the interface. Here, we examine how atomic intermixing at
oxide interfaces affect the balance between polar distortions and electric
potential across the dielectric medium. We find that intermixing moves the peak
charge distribution away from the oxide/oxide interface; thereby changing the
direction of polar distortions away from this boundary with minimal effect on
the electric field. This opposing electric field and polar distortions is
equivalent to the transient phase transition tipping point observed in double
well ferroelectrics; resulting in an anomalous dielectric response -- a
possible signature of local negative differential capacitance, with
implications for designing dissipationless oxide electronics.
