  Structural build-up in fresh cement paste at rest is characterized by time
evolutions of storage modulus and yield stress, which both increase linearly in
time during the induction period of hydration, followed by an exponential
evolution after entering the acceleration period. While it is understood that
C-S-H formation at contact points between cement particles dictates build-up in
the acceleration period, the mechanism in the induction period lacks consensus.
Here, we provide experimental evidence that, at least in absence of admixtures,
structural build-up at rest originates in both periods from the same mechanism.
We couple calorimetry and oscillatory shear measurements of OPC at different
w/c ratios, capturing how the storage modulus evolves with changes in
cumulative heat. We obtain an exponential relation between stiffness and heat,
with the same exponent in both the induction and acceleration periods. This
suggests that C-S-H formation dictates build-up at rest in both periods.
