  The possible redox (oxidation reduction) chemical methods for precisely
determining the oxygen content in the perovskite manganites including
hole-doped La1-xCaxMnOy and electron-doped La1-xTexMnOy compounds are
described. For manganites annealed at different temperatures, the oxygen
content of the samples was determined by a redox back titration in which the
powder samples taken in a quartz crucible were dissolved in (1+1) sulfuric acid
containing an excess of sodium oxalate, and the excess sodium oxalate was
titrated with permanganate standard solution. The results indicate that the
method is effective and highly reproducible. Moreover, the variation of oxygen
content is also reflected in significantly affecting the electrical transport
property of the samples, which is mainly considered to be closely related to
introduce oxygen vacancies in the Mn-O-Mn network.
