  The recent claim of potential room-temperature superconductivity in
Pb$_{10-x}$Cu$_{x}$(PO$_{4}$)$_{6}$O has attracted widespread attention.
However, the signature of superconductivity is later attributed to the
Cu$_{2}$S impurity formed during the multiple-step synthesis procedure. Here we
report a simple one-step approach to synthesize single-phase chloride analogue
Cu-doped Pb$_{10}$(PO$_{4}$)$_{6}$Cl$_{2}$ using PbO, PbCl$_{2}$, CuCl$_{2}$,
and NH$_{4}$H$_{2}$PO$_{4}$ as starting materials. Irrespective of the initial
stoichiometry, the Cu doping always leads to a lattice expansion in
Pb$_{10}$(PO$_{4}$)$_{6}$Cl$_{2}$. This indicates that Cu prefers to reside in
the hexagonal channels rather than substitutes at the Pb site, and the chemical
formula is expressed as Pb$_{10}$(PO$_{4}$)$_{6}$Cu$_{x}$Cl$_{2}$. All the
Pb$_{10}$(PO$_{4}$)$_{6}$Cu$_{x}$Cl$_{2}$ (0 $\leq$ $x$ $\leq$ 1.0) samples are
found to be semiconductors with wide band gaps of 4.46-4.59 eV, and the
Cu-doped ones ($x$ = 0.5 and 1.0) exhibit a paramagnetic behavior without any
phase transition between 400 and 1.8 K. Our study calls for a reinvestigation
of the Cu location in Pb$_{10-x}$Cu$_{x}$(PO$_{4}$)$_{6}$O, and supports the
absence of superconductivity in this oxyapatite.
