  A new versatile model providing S2 fluorescence spectrum as a function of
time is developed with the aim of interpreting high resolution cometary
spectra. For the S2 molecule, it is important to take into account both
chemical and dynamic processes because S2 has a short lifetime and is confined
in the inner coma where these processes are most important. The combination of
the fluorescence model with a global coma model allows for the comparison with
observations of column densities taken through an aperture and for the analysis
of S2 fluorescence in different parts of the coma. Moreover, the model includes
the rotational structure of the molecule. Such a model is needed for
interpreting recent high spectral resolution observations of cometary S2. A
systematic study of the vibrational-rotational spectrum of S2 is undertaken,
including relevant effects, such as non-equilibrium state superposition and the
number density profile within the coma due to dynamics and chemistry, to
investigate the importance of the above effects on the scale length and
abundance of S2 in comets.
