  In this paper we select large spectral averages of data from the Cassini
Composite Infrared Spectrometer (CIRS) obtained in limb-viewing mode at low
latitudes (30S--30N), greatly increasing the path length and hence
signal-to-noise ratio for optically thin trace species such as propane. By
modeling and subtracting the emissions of other gas species, we demonstrate
that at least six infrared bands of propane are detected by CIRS, including two
not previously identified in Titan spectra. Using a new line list for the range
1300-1400cm -1, along with an existing GEISA list, we retrieve propane
abundances from two bands at 748 and 1376 cm-1. At 748 cm-1 we retrieve 4.2 +/-
0.5 x 10(-7) (1-sigma error) at 2 mbar, in good agreement with previous
studies, although lack of hotbands in the present spectral atlas remains a
problem. We also determine 5.7 +/- 0.8 x 10(-7) at 2 mbar from the 1376 cm-1
band - a value that is probably affected by systematic errors including
continuum gradients due to haze and also an imperfect model of the n6 band of
ethane. This study clearly shows for the first time the ubiquity of propane's
emission bands across the thermal infrared spectrum of Titan, and points to an
urgent need for further laboratory spectroscopy work, both to provide the line
positions and intensities needed to model these bands, and also to further
characterize haze spectral opacity. The present lack of accurate modeling
capability for propane is an impediment not only for the measurement of propane
itself, but also for the search for the emissions of new molecules in many
spectral regions.
