  Electron transport through Si-C bound alkyl chains, sandwiched between n-Si
and Hg, is characterized by two distinct types of barriers, each dominating in
a different voltage range. At low voltage, current depends strongly on
temperature but not on molecular length, suggesting transport by thermionic
emission over a barrier in the Si. At higher voltage, the current decreases
exponentially with molecular length, suggesting tunneling through the
molecules. The tunnel barrier is estimated, from transport and photoemission
data, to be ~1.5 eV with a 0.25me effective mass.
