  Two-dimensional hexagonal boron nitride (h-BN) single crystals with various
shapes have been synthesized by chemical vapor deposition over the past several
years. Here we report the formation of three-leaf dart (3LD)-shaped single
crystals of h-BN on Cu foil by atmospheric-pressure chemical vapor deposition.
The leaves of the 3LD-shaped h-BN are as long as 18 {\mu}m and their edges are
smooth armchair on one side and stepped armchair on the other. Careful analysis
revealed that surface oxygen plays an important role in the formation of the
3LD shape. Oxygen suppressed h-BN nucleation by passivating Cu surface active
sites and lowered the edge attachment energy, which caused the growth kinetics
to change to a diffusion-controlled mode.
