  The realization of green and economically friendly energy storage systems
needs materials with outstanding properties. Future batteries based on Na as an
abundant element take advantage of non-flammable ceramic electrolytes with very
high conductivities. $\rm Na{_{3}}Zr{_{2}}(SiO{_{4}}){_{2}}PO{_{4}}$-type
superionic conductors are expected to pave the way for inherently safe and
sustainable all-solid-state batteries. So far, only little information has been
extracted from spectroscopic measurements to clarify the origins of fast ionic
hopping on the atomic length scale. Here we combined broad-band conductivity
spectroscopy and nuclear magnetic resonance (NMR) relaxation to study Na ion
dynamics from the {\mu}m to the angstrom length scale. Spin-lattice relaxation
NMR revealed a very fast Na ion exchange process in $\rm
Na{_{3.4}}Sc{_{0.4}}Zr{_{1.6}}(SiO{_{4}}){_{2}}PO{_{4}}$ that is characterized
by an unprecedentedly high self-diffusion coefficient of $\rm 9 \times
10{^{-12}} m{^{2}}s{^{-1}}$ at $\rm -10{\deg}C$. Thus, well below ambient
temperature the Na ions have access to elementary diffusion processes with a
mean residence time $\rm {\tau}_{NMR}$ of only $\rm 2\; ns$. The underlying
asymmetric diffusion-induced NMR rate peak and the corresponding conductivity
isotherms measured in the MHz range reveal correlated ionic motion. Obviously,
local but extremely rapid $\rm Na{^{+}}$ jumps, involving especially the
transition sites in Sc-NZSP, trigger long-range ion transport and push ionic
conductivity up to $\rm 2\; mS\; cm{^{-1}}$ at room temperature.
