  HD76431 is a slow rotating post-HB star that shows an underabundance of
helium by 0.5 dex relative to the solar value. These observational facts
suggest that atomic diffusion could be active in its atmosphere. We have used
the MMT and Bok spectra to estimate the atmospheric parameters of the target
star using the model atmospheres and synthetic spectra calculated with TLUSTY
and SYNSPEC. The derived values of the effective temperature, surface gravity,
helium abundance are consistent with those obtained by Ramspeck et al. (2001b).
It appears that NLTE effect are not important for HD76431. We have used Stokes
I spectra from ESPaDOnS at CFHT to perform an abundance analysis and a search
for observational evidence of vertical stratification of the abundance of
certain elements. The results of our abundance analysis are in good agreement
with previously published data with respect to average abundances. Our
numerical simulations show that carbon and nitrogen reveal signatures of
vertical abundance stratification in the atmosphere of HD76431. It appears that
the carbon abundance increases toward the deeper atmospheric layers. Nitrogen
also shows a similar behaviour, but in deeper atmospheric layers we obtain a
significant dispersion for the estimates of its abundance. To our knowledge,
this is the first demonstration of vertical abundance stratification of metals
in a post-HB star and up to now it is the hottest star to show such
stratification features. We also report the detection of two SiIII and one
TiIII emission lines in the spectra of HD76431 that were not detected in
previous studies.
