  The Pixel-Imaging Mass Spectrometry (PImMS) camera allows for 3D charged
particle imaging measurements, in which the particle time-of-flight is recorded
along with $(x,y)$ position. Coupling the PImMS camera to an ultrafast
pump-probe velocity-map imaging spectroscopy apparatus therefore provides a
route to time-resolved multi-mass ion imaging, with both high count rates and
large dynamic range, thus allowing for rapid measurements of complex
photofragmentation dynamics. Furthermore, the use of vacuum ultraviolet
wavelengths for the probe pulse allows for an enhanced observation window for
the study of excited state molecular dynamics in small polyatomic molecules
having relatively high ionization potentials. Herein, preliminary time-resolved
multi-mass imaging results from C$_2$F$_3$I photolysis are presented. The
experiments utilized femtosecond UV and VUV (160.8~nm and 267~nm) pump and
probe laser pulses in order to demonstrate and explore this new time-resolved
experimental ion imaging configuration. The data indicates the depth and power
of this measurement modality, with a range of photofragments readily observed,
and many indications of complex underlying wavepacket dynamics on the excited
state(s) prepared.
