  Carbon spheres (CS) with diameters in the range $2 - 10 \mu m$ were prepared
via hydrolysis of a sucrose solution at $200^o C,$ and later annealed in $N_2$
at $800^o C.$ The spheres were highly conducting but difficult to process into
thin films or pressed pellets. In our previous work, composite samples of CS
and the insulating polymer polyethylene oxide (PEO) were prepared and their
charge transport was analyzed in the temperature range $ 80 K < T < 300 K. $
Here, we analyze charge transport in CS coated with a thin polyaniline (PANi)
film doped with hydrochloric acid (HCl), in the same temperature range. The
goal is to study charge transport in the CS using a conducting polymer (PANi)
as a binder and compare with that occurring at CS/PEO. A conductivity maxima
was observed in the CS/PEO composite but was absent in CS/PANi. Our data
analysis shows that variable range hopping of electrons between polymeric
chains in PANi-filled gaps between CS takes on a predominant part in transport
through CS/PANi composites, whereas in CS/PEO composites, electrons travel
through gaps between CS solely by means of direct tunneling. This difference in
transport mechanisms results in different temperature dependences of the
conductivity.
