  Context. Ionization plays a central role in the gas-phase chemistry of
molecular clouds. Since ions are coupled with magnetic fields, which can in
turn counteract gravitational collapse, it is of paramount importance to
measure their abundance in star-forming regions. Aims. We use spectral line
observations of the high-mass star-forming region NGC 6334 I to derive the
abundance of two of the most abundant molecular ions, HCO+ and N2H+, and
consequently, the cosmic ray ionization rate. In addition, the line profiles
provide information about the kinematics of this region. Methods. We present
high-resolution spectral line observations conducted with the HIFI instrument
on board the Herschel Space Observatory of the rotational transitions with Jup
> 5 of the molecular species C17O, C18O, HCO+, H13CO+, and N2H+. Results. The
HCO+ and N2H+ line profiles display a redshifted asymmetry consistent with a
region of expanding gas. We identify two emission components in the spectra,
each with a different excitation, associated with the envelope of NGC 6334 I.
The physical parameters obtained for the envelope are in agreement with
previous models of the radial structure of NGC 6334 I based on submillimeter
continuum observations. Based on our new Herschel/HIFI observations, combined
with the predictions from a chemical model, we derive a cosmic ray ionization
rate that is an order of magnitude higher than the canonical value of 10^(-17)
s-1. Conclusions. We find evidence of an expansion of the envelope surrounding
the hot core of NGC 6334 I, which is mainly driven by thermal pressure from the
hot ionized gas in the region. The ionization rate seems to be dominated by
cosmic rays originating from outside the source, although X-ray emission from
the NGC 6334 I core could contribute to the ionization in the inner part of the
envelope.
