  During recent years some non-thermal radio emitting OB stars have been
discovered to be binary, or multiple systems. The non-thermal emission is due
to synchrotron radiation that is emitted by electrons accelerated up to high
energies. The electron acceleration occurs at the strong shocks created by the
collision of radiatively-driven winds. Here we summarize the available radio
data and more recent observations for the binary Cyg OB2 No. 9. We also show a
new emission model which is being developed to compare the theoretical total
radio flux and the spectral index with the observed radio light curves. This
comparison will be useful in order to solve fundamental questions, such as the
determination of the stellar mass loss rates, which are perturbed by clumping.
