  Molecular dynamics simulations of aqueous NaCl, KCl, NaI, and KI solutions
are used to study the effects of salts on the properties of the liquid/vapor
interface. The simulations use the models which include both charge transfer
and polarization effects. Pairing and the formation of larger ion clusters
occurs both in the bulk and surface region, with a decreased tendency to form
larger clusters near the interface. An analysis of the roughness of the surface
reveals that the chloride salts, which have less tendency to be near the
surface, have a roughness that is less than pure water, while the iodide salts,
which have a greater surface affinity, have a larger roughness. This suggests
that ions away from the surface and ions near the surface affect the interface
in opposite ways.
