  Superconducting and normal state properties of sputtered Niobium nanofilms
have been systematically investigated, as a function of film thickness in a
d=9-90 nm range, on different substrates. The width of the
superconducting-to-normal transition for all films remained in few tens of mK,
thus remarkably narrow, confirming their high quality. We found that the
superconducting critical current density exhibits a pronounced maximum, three
times larger than its bulk value, for film thickness around 25 nm, marking the
3D-to-2D crossover. The extracted magnetic penetration depth shows a sizeable
enhancement for the thinnest films, aside the usual demagnetization effects.
Additional amplification effects of the superconducting properties have been
obtained in the case of sapphire substrates or squeezing the lateral size of
the nanofilms. For thickness close to 20 nm we also measured a doubled
perpendicular critical magnetic field compared to its saturation value for d>33
nm, indicating shortening of the correlation length and the formation of small
Cooper pairs in the condensate. Our data analysis evidences an exciting
interplay between quantum-size and proximity effects together with
strong-coupling effects and importance of disorder in the thinnest films,
locating the ones with optimally enhanced critical properties close to the
BCS-BEC crossover regime.
