  This is a revised version of a manuscript that was originally posted here in
February of 2014. It has been accepted at the journal Inorganic Chemistry after
reviews that included those of two crystallographers who made sure all the t's
were crossed and the i's were dotted. The old work (from 1968) that said that
Cd3As2 was noncentrosymmetric was mistaken, with the authors of that study
making a type of error that in the 1980s became infamous in crystallography. As
a result of the increased scrutiny of the issue of centrosymmetricity of the
1980's, there are now much better analysis tools to resolve the issue fully,
and its important to understand that not just our crystals are centrosymmetric,
even the old guy's crystals were centrosymmetric (and by implication everyone's
are). There is no shame in having made that error back in the day and those
authors would not find the current centrosymmetric result controversial; their
paper is excellent in all other aspects. This manuscript describes how the
structure is determined, explains the structure schematically, calculates the
electronic structure based on the correct centrosymmetric crystal structure,
and gives the structural details that should be used for future analysis and
modeling.
