  We present an investigation of the energy dependence of the full charge
counting statistics in diffusive
normal-insulating-normal-insulating-superconducting junctions. It is found that
the current in general is transported via a correlated transfer of pairs of
electrons. Only in the case of strongly asymmetric tunnel barriers or energies
much larger than the Thouless energy is the pair transfer uncorrelated. The
second cumulant, the noise, is found to depend strongly on the applied voltage
and temperature. For a junction resistance dominated by the tunnel barrier to
the normal reservoir, the differential shot noise shows a double peak feature
at voltages of the order of the Thouless energy, a signature of an ensemble
averaged electron-hole resonance.
