  We consider the dynamical properties of dissipative continuous-time quantum
walks on directed graphs. Using a large-deviation approach we construct a
thermodynamic formalism allowing us to define a dynamical order parameter, and
to identify transitions between dynamical regimes. For a particular class of
dissipative quantum walks we propose a quantum generalization of the the
classical PageRank vector, used to rank the importance of nodes in a directed
graph. We also provide an example where one can characterize the dynamical
transition from an effective classical random walk to a dissipative quantum
walk as a thermodynamic crossover between distinct dynamical regimes.
