  The third Fermi-LAT catalog (3FGL) presented the data of the first four years
of observations from the Fermi Gamma-ray Space Telescope mission. There are
3034 sources, 1010 of which still remain unidentified. Identifying and
classifying gamma-ray emitters is of high significance with regard to studying
high-energy astrophysics. We demonstrate that optical polarimetry can be an
advantageous and practical tool in the hunt for counterparts of the
unidentified gamma-ray sources (UGSs). Using data from the RoboPol project, we
validated that a significant fraction of active galactic nuclei (AGN)
associated with 3FGL sources can be identified due to their high optical
polarization exceeding that of the field stars. We performed an optical
polarimetric survey within $3\sigma$ uncertainties of four unidentified 3FGL
sources. We discovered a previously unknown extragalactic object within the
positional uncertainty of 3FGL J0221.2+2518. We obtained its spectrum and
measured a redshift of $z=0.0609\pm0.0004$. Using these measurements and
archival data we demonstrate that this source is a candidate counterpart for
3FGL J0221.2+2518 and most probably is a composite object: a star-forming
galaxy accompanied by AGN. We conclude that polarimetry can be a powerful asset
in the search for AGN candidate counterparts for unidentified Fermi sources.
Future extensive polarimetric surveys at high galactic latitudes (e.g.,
PASIPHAE) will allow the association of a significant fraction of currently
unidentified gamma-ray sources.
