  Using the framework of Wertheim's thermodynamic perturbation theory we
develop the first density functional theory which accounts for intramolecular
association in chain molecules. To test the theory new Monte Carlo simulations
are performed at a fluid solid interface for a 4 segment chain which can both
intra and intermolecularly associate. The theory and simulation results are
found to be in excellent agreement. It is shown that the inclusion of
intramolecular association can have profound effects on interfacial properties
such as interfacial tension and the partition coefficient.
