  Intercalation of Au can produce giant Rashba-type spin-orbit splittings in
graphene but this has not yet been achieved on a semiconductor substrate. For
graphene/SiC(0001), Au intercalation yields two phases with different doping.
Here, we report the preparation of an almost pure p-type graphene phase after
Au intercalation. We observe a 100 meV Rashba-type spin-orbit splitting at 0.9
eV binding energy. We show that this giant splitting is due to hybridization
and much more limited in energy and momentum space than for Au-intercalated
graphene on Ni.
