  Engineering the electronic properties of graphene has triggered great
interest for potential applications in electronics and opto-electronics. Here
we demonstrate the possibility to tune the electronic transport properties of
graphene monolayers and multilayers by functionalisation with fluorine. We show
that by adjusting the fluorine content different electronic transport regimes
can be accessed. For monolayer samples, with increasing the fluorine content,
we observe a transition from electronic transport through Mott variable range
hopping in two dimensions to Efros - Shklovskii variable range hopping.
Multilayer fluorinated graphene with high concentration of fluorine show
two-dimensional Mott variable range hopping transport, whereas CF0.28
multilayer flakes have a band gap of 0.25eV and exhibit thermally activated
transport. Our experimental findings demonstrate that the ability to control
the degree of functionalisation of graphene is instrumental to engineer
different electronic properties in graphene materials.
