  We study by means of molecular dynamics simulations the aging behavior of a
molecular model of ortho-terphenyl. We find evidence of a a non-monotonic
evolution of the volume during an isothermal-isobaric equilibration process, a
phenomenon known in polymeric systems as Kovacs effect. We characterize this
phenomenology in terms of landscape properties, providing evidence that, far
from equilibrium, the system explores region of the potential energy landscape
distinct from the one explored in thermal equilibrium. We discuss the relevance
of our findings for the present understanding of the thermodynamics of the
glass state.
