  X-ray absorption spectroscopy (XAS) on the O 1s threshold was applied to
Bi-based, single crystalline high temperature superconductors (HTc's), whose
hole densities in the CuO2 planes was varied by different methods. XAS gives
the intensity of the so-called pre-peak of the O 1s line due to the unoccupied
part of the Zhang-Rice (ZR) singlet state. The effects of variation of the
number n of CuO2 - planes per unit cell (n = 1,2,3) and the effect of
La-substitution for Sr for the n = 1 and n = 2 phase were studied
systematically. Furthermore the symmetry of the states could be probed by the
polarization of the impinging radiation.
