  The superconducting current-phase relation (CPR) of Nb/Au/(001)YBa2Cu3Ox
heterojunctions prepared on epitaxial c-axis oriented YBa2Cu3Ox thin films has
been measured in a single-junction interferometer. For the first time, the
second harmonic of the CPR of such junctions has been observed. The appearance
of the second harmonic and the relative sign of the first and second harmonics
of the CPR can be explained assuming, that the macroscopic pairing symmetry of
our YBa2Cu3Ox thin films is of the d+s type
