  The Raman spectra of the parent compound NaxCoO2 (x=0.75) and the
superconducting oxyhydrates NaxCoO2.yH2O with different superconducting
temperatures (Tc) have been measured. Five Raman active phonons around 195 cm-1
(E1g), 482 cm-1, 522 cm-1, 616 cm-1 (3E2g), 663 cm-1 (A1g) appear in all
spectra. These spectra change systematically along with the intercalation of
H2O and superconducting properties. In particular, the Raman active phonons
(A1g and E1g) involving the oxygen motions within the Co-O layers show up
monotonous decrease in frequency along with superconducting temperature Tc. The
fundamental properties and alternations of other active Raman phonons in the
superconducting materials have also been discussed.
