  The adsorption structure of the molecular switch azobenzene on Ag(111) is
investigated by a combination of normal incidence x-ray standing waves and
dispersion-corrected density functional theory. The inclusion of non-local
collective substrate response (screening) in the dispersion correction improves
the description of dense monolayers of azobenzene, which exhibit a substantial
torsion of the molecule. Nevertheless, for a quantitative agreement with
experiment explicit consideration of the effect of vibrational mode
anharmonicity on the adsorption geometry is crucial.
