  We report a generally applicable computational and experimental approach to
determine vibronic branching ratios in linear polyatomic molecules to the
$10^{-5}$ level, including for nominally symmetry forbidden transitions. These
methods are demonstrated in CaOH and YbOH, showing approximately two orders of
magnitude improved sensitivity compared with the previous state of the art.
Knowledge of branching ratios at this level is needed for the successful deep
laser cooling of a broad range of molecular species.
