  For a simple graph $G=(V,E),$ let $\mathcal{S}_+(G)$ denote the set of real
positive semidefinite matrices $A=(a_{ij})$ such that $a_{ij}\neq 0$ if
$\{i,j\}\in E$ and $a_{ij}=0$ if $\{i,j\}\notin E$. The maximum positive
semidefinite nullity of $G$, denoted $\operatorname{M}_+(G),$ is
$\max\{\operatorname{null}(A)|A\in \mathcal{S}_+(G)\}.$ A tree cover of $G$ is
a collection of vertex-disjoint simple trees occurring as induced subgraphs of
$G$ that cover all the vertices of $G$. The tree cover number of $G$, denoted
$T(G)$, is the cardinality of a minimum tree cover. It is known that the tree
cover number of a graph and the maximum positive semidefinite nullity of a
graph are equal for outerplanar graphs, and it was conjectured in 2011 that
$T(G)\leq M_+(G)$ for all graphs [Barioli et al., Minimum semidefinite rank of
outerplanar graphs and the tree cover number, $ Elec. J. Lin. Alg.,$ 2011]. We
show that the conjecture is true for certain graph families. Furthermore, we
prove bounds on $T(G)$ to show that if $G$ is a connected outerplanar graph on
$n\geq 2$ vertices, then $\operatorname{M}_+(G)=T(G)\leq
\left\lceil\frac{n}{2}\right\rceil$, and if $G$ is a connected outerplanar
graph on $n\geq 6$ vertices with no three or four cycle, then
$\operatorname{M}_+(G)=T(G)\leq \frac{n}{3}$. We also characterize connected
outerplanar graphs with
$\operatorname{M}_+(G)=T(G)=\left\lceil\frac{n}{2}\right\rceil.$
