  The gem-stone dioptase Cu6Si6O18.6H2O has a chiral crystal structure of
equilateral triangular helices consisting of Cu-3d spins. It shows an
antiferromagnetic order with an easy axis along c at TN = 15.5 K under zero
field, and a magnetization jump at HC = 13.5 T when the field is applied along
c-axis. By 29Si-NMR measurements, we have revealed that the high-field state is
essentially the two sub-lattice structure, and that the component within
ab-plane is collinear. The result indicates no apparent match with the
geometrical pattern of helical spin chain.
