  We investigate the magnetocaloric properties of certain antiferromagnetic
spin systems that have already been or very likely can be synthesized as
magnetic molecules. It turns out that the special geometric frustration which
is present in antiferromagnets that consist of corner-sharing triangles leads
to an enhanced magnetocaloric effect with high cooling rates in the vicinity of
the saturation field. These findings are compared with the behavior of a simple
unfrustrated spin ring as well as with the properties of the icosahedron. To
our surprise, also for the icosahedron large cooling rates can be achieved but
due to a different kind of geometric frustration.
