  CaRuO_3 is perovskite with an orthorhombic distortion and is believed to be
close to magnetic ordering. Magnetic studies of single crystal and
polycrystalline CaRu_{1-x}Cu_xO_3 (0\le x \le 15 at.%Cu) reveal that
spin-glass-like transition develops for x\le 7 at.%Cu and obtained value for
effective magnetic moment p_{eff}=3.55 mu_B for x=5 at.% Cu, single crystal,
indicates presence of Ru^{5+}. At higher Cu concentrations more complex
magnetic behaviors are observed. Electrical resistivity measured on
polycrystalline samples shows metal-to-insulator transition (MIT) at 51 K for
only 2 at.% Cu. Charge compensation, which is assumed to be present upon
Cu^{2+/3+} substitution, induces appearance of Ru^{5+} and/or creation of
oxygen vacancies in crystal structure. Since the observed changes in physical
properties are completely attributable to the charge compensation, they cannot
be related to behaviors of pure compound where no such mechanism is present.
This study provides the criterion for "good" chemical probes for studying
Ru-based perovskites.
