  Polycyclic aromatic hydrocarbons (PAHs) have been proposed as potential
carriers of the unidentified infrared bands (UIRs) and the diffuse interstellar
bands (DIBs). PAHs are not likely to form by gas-phase or solid-state
interstellar chemistry, but rather might be produced in the outflows of
carbon-rich evolved stars. PAHs could form from acetylene addition to the
phenyl radical (C6H5), which is closely chemically related to benzene (C6H6)
and ortho-benzyne (o-C6H4). To date, circumstellar chemical models have been
limited to only a partial treatment of benzene-related chemistry, and so the
expected abundances of these species are unclear. A detection of benzene has
been reported in the envelope of the proto-planetary nebula (PPN) CRL 618, but
no other benzene-related species has been detected in this or any other source.
The spectrum of o-C6H4 is significantly simpler and stronger than that of C6H5,
and so we conducted deep Ku-, K- and Q-band searches for o-C6H4 with the Green
Bank Telescope. No transitions were detected, but an upper limit on the column
density of 8.4x10^13 cm^-2 has been determined. This limit can be used to
constrain chemical models of PPNe, and this study illustrates the need for
complete revision of these models to include the full set of benzene-related
chemistry.
