  In the Mott-Hubbard insulators YTiO3 and SmTiO3 we study optical excitations
from the lower to the upper Hubbard band, d^1d^1 -> d^0d^2. The multi-peak
structure observed in the optical conductivity reflects the multiplet structure
of the upper Hubbard band in a multi-orbital system. Absorption bands at 2.55
and 4.15 eV in the ferromagnet YTiO3 correspond to final states with a triplet
d^2 configuration, whereas a peak at 3.7 eV in the antiferromagnet SmTiO3 is
attributed to a singlet d^2 final state. A strongly temperature-dependent peak
at 1.95 eV in YTiO3 and 1.8 eV in SmTiO3 is interpreted in terms of a Hubbard
exciton, i.e., a charge-neutral (quasi-)bound state of a hole in the lower
Hubbard band and a double occupancy in the upper one. The binding to such a
Hubbard exciton may arise both due to Coulomb attraction between
nearest-neighbor sites and due to a lowering of the kinetic energy in a system
with magnetic and/or orbital correlations. Furthermore, we observe anomalies of
the spectral weight in the vicinity of the magnetic ordering transitions, both
in YTiO3 and SmTiO3. In the G-type antiferromagnet SmTiO3, the sign of the
change of the spectral weight at T_N depends on the polarization. This
demonstrates that the temperature dependence of the spectral weight is not
dominated by the spin-spin correlations, but rather reflects small changes of
the orbital occupation.
