  We report a 4.8 sigma detection of water absorption features in the day side
spectrum of the hot Jupiter HD 189733 b. We used high-resolution (R~100,000)
spectra taken at 3.2 microns with CRIRES on the VLT to trace the
radial-velocity shift of the water features in the planet's day side atmosphere
during 5 h of its 2.2 d orbit as it approached secondary eclipse. Despite
considerable telluric contamination in this wavelength regime, we detect the
signal within our uncertainties at the expected combination of systemic
velocity (Vsys=-3 +5-6 km/s) and planet orbital velocity (Kp=154 +14-10 km/s),
and determine a H2O line contrast ratio of (1.3+/-0.2)x10^-3 with respect to
the stellar continuum. We find no evidence of significant absorption or
emission from other carbon-bearing molecules, such as methane, although we do
note a marginal increase in the significance of our detection to 5.1 sigma with
the inclusion of carbon dioxide in our template spectrum. This result
demonstrates that ground-based, high-resolution spectroscopy is suited to
finding not just simple molecules like CO, but also to more complex molecules
like H2O even in highly telluric contaminated regions of the Earth's
transmission spectrum. It is a powerful tool that can be used for conducting an
immediate census of the carbon- and oxygen-bearing molecules in the atmospheres
of giant planets, and will potentially allow the formation and migration
history of these planets to be constrained by the measurement of their
atmospheric C/O ratios.
