  Raman spectroscopic studies have been carried out on CaCrO4 under pressure up
to 26GPa at ambient temperature. The Raman spectra showed CaCrO4 experienced a
continuous structural phase transition started at near 6GPa, and finished at
about 10GPa. It is found that the high-pressure phase could be quenched to
ambient conditions. Pressure dependence of the Raman peaks suggested there
existed four pressure regions related to different structural characters. We
discussed these characters and inferred that the nonreversible structural
transition in CaCrO4, most likely was from a zircon-type (I41/amd) ambient
phase to a scheelite-type high pressure structure (I41/a).
