  Photoionization and recombination cross sections and rate coefficients are
calculated for Li-like Fe XXIV and He-like Fe XXV using the Breit-Pauli
R-matrix (BPRM) method. A complete set of total and level-specific parameters
is obtained to enable X-ray photoionization and spectral modeling. The ab
initio calculations for the unified (e + ion) recombination rate coefficients
include both the non-resonant and the resonant recombination (radiative and
di-electronic recombination, RR and DR, respectively) for (e + Fe XXV) -> Fe
XXIV and (e + Fe XXVI) -> Fe XXV. The level specific rates are computed for all
fine structure levels up to n = 10, enabling accurate computation of
recombination-cascade matrices and effective rates for the X-ray lines. The
total recombination rate coefficients for both Fe XXIV and Fe XXV differ
considerably, by several factors, from the sum of RR and DR rates currently
used to compute ionization fractions in astrophysical models. As the
photoionization/recombination calculations are carried out using an identical
eigenfunction expansion, the cross sections for both processes are
theoretically self-consistent; the overall uncertainty is estimated to be about
10-20%. All data for Fe XXIV and Fe XXV (and also for H-like Fe XXVI, included
for completeness) are available electronically.
