  In 1987-89 were synthesized soluble nano-composites of polyacetylene (NPA)
with an abnormally high intensity of Raman scattering and high stability under
laser radiation. Here we demonstrate that the key pre-condition to the
outstanding characteristics of NPA is the vibrational and rotational mobility
of nano-particles, provided by plasticized layers of water on their surface.
The results afford a connection between optical properties of NPA and the
three-dimensional coherent order arising from self-organization of
nanoparticles at synthesis and during film formation. The driving force behind
self-organization is the abnormal high vibrational hyper-polarizability of
macromolecules leading to coherent dispersive interactions. The principles of
synthesis employed can further be used to create 3-D coherently ordered photon
crystals and meta-materials.
