  When a drop of water is placed on a rough surface, there are two possible
extreme regimes of wetting: the one called Cassie-Baxter (CB) with air pockets
trapped underneath the droplet and the one characterized by the homogeneous
wetting of the surface, called the Wenzel (W) state. A way to investigate the
transition between these two states is by means of evaporation experiments, in
which the droplet starts in a CB state and, as its volume decreases, penetrates
the surface's grooves, reaching a W state. Here we present a theoretical model
based on the global interfacial energies for CB and W states that allows us to
predict the thermodynamic wetting state of the droplet for a given volume and
surface texture. We first analyze the influence of the surface geometric
parameters on the droplet's final wetting state with constant volume, and show
that it depends strongly on the surface texture. We then vary the volume of the
droplet keeping fixed the geometric surface parameters to mimic evaporation and
show that the drop experiences a transition from the CB to the W state when its
volume reduces, as observed in experiments. To investigate the dependency of
the wetting state on the initial state of the droplet, we implement a cellular
Potts model in three dimensions. Simulations show a very good agreement with
theory when the initial state is W, but it disagrees when the droplet is
initialized in a CB state, in accordance with previous observations which show
that the CB state is metastable in many cases. Both simulations and theoretical
model can be modified to study other types of surface.
