  Angle-resolved photoemission spectroscopy (ARPES) is a powerful technique for
the study of electronic structure, but it lacks a direct ability to study
buried interfaces between two materials. We address this limitation by
combining ARPES with soft x-ray standing-wave (SW) excitation (SWARPES), in
which the SW profile is scanned through the depth of the sample. We have
studied the buried interface in a prototypical magnetic tunnel junction
La0.7Sr0.3MnO3/SrTiO3. Depth- and momentum-resolved maps of Mn 3d eg and t2g
states from the central, bulk-like and interface-like regions of La0.7Sr0.3MnO3
exhibit distinctly different behavior consistent with a change in the Mn
bonding at the interface. We compare the experimental results to
state-of-the-art density-functional and one-step photoemission theory, with
encouraging agreement that suggests wide future applications of this technique.
