  Satellite-based quantum communication is an invaluable resource for the
realization of a quantum network at the global scale. In this regard, the use
of satellites well beyond the low Earth orbits gives the advantage of long
communication time with a ground station. However, high-orbit satellites pose a
great technological challenge due to the high diffraction losses of the optical
channel, and the experimental investigation of such quantum channels is still
lacking. Here, we report on the first experimental exchange of single photons
from Global Navigation Satellite System at a slant distance of 20000
kilometers, by exploiting the retroreflector array mounted on GLONASS
satellites. We also observed the predicted temporal spread of the reflected
pulses due to the geometrical shape of array. Finally, we estimated the
requirements needed for an active source on a satellite, aiming towards quantum
communication from GNSS with state-of-the-art technology.
