  We report results on polarization-dependent photoinduced discharge in
oriented fibers and films of ladder-type, electron-transporting polymer poly
(benzimidazobenzophenanthroline), BBL. The photocarrier generation efficiency
in the fiber which is indicated by the rate of discharge, is found to be
distinctly higher for light polarized parallel to the fiber axis as compared to
the radially perpendicular direction . Similar results, with photocarrier
generation efficiency anisotropy ~ 10 are obtained for oriented films. These
observations are different from previously obtained results on
polyparaphenylenevinylene (PPV). The results are compared with the
polarization-dependent steady- state photoconductivity measurements. We
interpret these results on the basis of molecular and macroscopic features of
the material.
