  We consider the surface melting of metal nanowires by solving a
phenomenological two-parabola Landau model and by conducting molecular dynamics
simulations of nickel and aluminium nanowires. The model suggests that surface
melting will precede bulk melting when the spreading parameter $\Delta \gamma$
for the melt in contact with the solid surface is positive (i.e. if the melt
wets or partially wets the surface) and the wire is sufficiently thick, as is
the case for planar surfaces and sufficiently large nanoparticles. Surface
melting does not occur if $\Delta \gamma$ is negative. We test this model,
which assumes the surface energies of the wire are isotropic, using molecular
dynamics simulations. For nickel, we observe the onset of anisotropic surface
melting associated with each of the two surface facets present, but this gives
way to uniform surface melting and the solid melts radially until the solid
core eventually breaks up. For aluminium, while we observe complete surface
melting of one facet, the lowest energy surface remains partially dry even up
to the point where the melt completely penetrates the solid core.
