  The oxygen-order dependent emergence of superconductivity in YBa2Cu3O6+x is
studied, for the first time in a comparative way, on pair samples having the
same oxygen content and thermal history, but different Cu(1)Ox chain
arrangements deriving from their intercalated and deintercalated nature.
Structural and electronic non-equivalence of pairs samples is detected in the
critical region and found to be related, on microscopic scale, to a different
average chain length, which, on being experimentally determined by nuclear
quadrupole resonance (NQR), sheds new light on the concept of critical chain
length for hole doping efficiency.
