  We calculate the photoemission spectral function of the one-dimensional
Hubbard model away from half filling using the dynamical density matrix
renormalization group method. An approach for calculating momentum-dependent
quantities in finite open chains is presented. Comparison with exact Bethe
Ansatz results demonstrates the unprecedented accuracy of our method. Our
results show that the photoemission spectrum of the quasi-one-dimensional
conductor TTF-TCNQ provides evidence for spin-charge separation on the scale of
the conduction band width.
