  Current three-dimensional (3D) hydrodynamical model atmospheres together with
NLTE spectrum synthesis, permit to derive reliable atomic and isotopic chemical
abundances from high-resolution stellar spectra. Not much is known about the
presence of the fragile 6Li isotope in evolved solar-metallicity RGB stars, not
to mention its production in magnetically active targets like HD123351. From
fits of the observed CFHT spectrum with synthetic line profiles based on 1D and
3D model atmospheres, we seek to estimate the abundance of the 6Li isotope and
to place constraints on its origin. We derive A(Li) and the 6Li/7Li isotopic
ratio by fitting different synthetic spectra to the Li-line region of a
high-resolution CFHT spectrum (R=120 000, S/R=400). The synthetic spectra are
computed with four different line lists, using in parallel 3D hydrodynamical
CO5BOLD and 1D LHD model atmospheres and treating the line formation of the
lithium components in non-LTE (NLTE). We find A(Li)=1.69+/-0.11 dex and
6Li/7Li=8.0+/-4.4 % in 3D-NLTE, using the line list of Mel\'endez et al.
(2012), updated with new atomic data for V I, which results in the best fit of
the lithium line profile of HD123351. Two other line lists lead to similar
results but with inferior fit qualities. Our 2-sigma detection of the 6Li
isotope is the result of a careful statistical analysis and the visual
inspection of each achieved fit. Since the presence of a significant amount of
6Li in the atmosphere of a cool evolved star is not expected in the framework
of standard stellar evolution theory, non-standard, external lithium production
mechanisms, possibly related to stellar activity or a recent accretion of rocky
material, need to be invoked to explain the detection of 6Li in HD123351.
