  We report on the first measurements of the isotopic ratio 14N/15N in N2H+
toward a statistically significant sample of high-mass star forming cores. The
sources belong to the three main evolutionary categories of the high-mass star
formation process: high-mass starless cores, high-mass protostellar objects,
and ultracompact HII regions. Simultaneous measurements of 14N/15N in CN have
been made. The 14N/15N ratios derived from N2H+ show a large spread (from ~180
up to ~1300), while those derived from CN are in between the value measured in
the terrestrial atmosphere (~270) and that of the proto-Solar nebula (~440) for
the large majority of the sources within the errors. However, this different
spread might be due to the fact that the sources detected in the N2H+
isotopologues are more than those detected in the CN ones. The 14N/15N ratio
does not change significantly with the source evolutionary stage, which
indicates that time seems to be irrelevant for the fractionation of nitrogen.
We also find a possible anticorrelation between the 14N/15N (as derived from
N2H+) and the H/D isotopic ratios. This suggests that 15N enrichment could not
be linked to the parameters that cause D enrichment, in agreement with the
prediction by recent chemical models. These models, however, are not able to
reproduce the observed large spread in 14N/15N, pointing out that some
important routes of nitrogen fractionation could be still missing in the
models.
