  Topological materials which are also superconducting are of great current
interest, since they may exhibit a non-trivial topologically-mediated
superconducting phase. Although there have been many reports of pressure-tuned
or chemical-doping-induced superconductivity in a variety of topological
materials, there have been few examples of intrinsic, ambient pressure
superconductivity in a topological system having a stoichiometric composition.
Here, we report that the pure intermetallic CaSn3 not only exhibits topological
fermion properties but also has a superconducting phase at 1.178 K under
ambient pressure. The topological fermion properties, including the nearly zero
quasi-particle mass and the non-trivial Berry phase accumulated in cyclotron
motions, were revealed from the de Haas-van Alphen (dHvA) quantum oscillation
studies of this material. Although CaSn3 was previously reported to be
superconducting at 4.2K, our studies show that the superconductivity at 4.2K is
extrinsic and caused by Sn on the degraded surface, whereas its intrinsic bulk
superconducting transition occurs at 1.178 K. These findings make CaSn3 a
promising candidate for exploring new exotic states arising from the interplay
between non-trivial band topology and superconductivity, e.g. topological
superconductivity
