  Flares on dM stars contain plasmas at very different temperatures and thus
affect a wide wavelength range in the electromagnetic spectrum. While the
coronal properties of flares are studied best in X-rays, the chromosphere of
the star is observed best in the optical and ultraviolet ranges. Therefore,
multiwavelength observations are essential to study flare properties throughout
the atmosphere of a star. We analysed simultaneous observations with UVES/VLT
and XMM-Newton of the active M5.5 dwarf CN Leo (Gl 406) exhibiting a major
flare. The optical data cover the wavelength range from 3000 to 10000 Angstrom.
  From our optical data, we find an enormous wealth of chromospheric emission
lines occurring throughout the spectrum. We identify a total of 1143 emission
lines, out of which 154 are located in the red arm, increasing the number of
observed emission lines in this red wavelength range by about a factor of 10.
Here we present an emission line list and a spectral atlas. We also find line
asymmetries for H I, He I, and Ca II lines. For the last, this is the first
observation of asymmetries due to a stellar flare. During the flare onset,
there is additional flux found in the blue wing, while in the decay phase,
additional flux is found in the red wing. We interpret both features as caused
by mass motions. In addition to the lines, the flare manifests itself in the
enhancement of the continuum throughout the whole spectrum, inverting the
normal slope for the net flare spectrum.
