  Nuclear spin hyperpolarization techniques, such as dynamic nuclear
polarization (DNP) and parahydrogen-induced polarization (PHIP), have
revolutionized nuclear magnetic resonance and magnetic resonance imaging. In
these methods, a readily available source of high spin order, either electron
spins in DNP or singlet states in hydrogen for PHIP, is brought into close
proximity with nuclear spin targets, enabling efficient transfer of spin order
under external quantum control. Despite vast disparities in energy scales and
interaction mechanisms between electron spins in DNP and nuclear singlet states
in PHIP, a pseudo-spin formalism allows us to establish an intriguing
equivalence. As a result, the important low-field polarization transfer regime
of PHIP can be mapped onto an analogous system equivalent to pulsed-DNP. This
establishes a correspondence between key polarization transfer sequences in
PHIP and DNP, facilitating the transfer of sequence development concepts. This
promises fresh insights and significant cross-pollination between DNP and PHIP
polarization sequence developers.
