  The superconducting gap structure of recently discovered heavy fermion
superconductor PrOs4Sb12 was investigated by using thermal transport
measurements in magnetic field rotated relative to the crystal axes. We
demonstrate that a novel change in the symmetry of the superconducting gap
function occurs deep inside the superconducting state, giving a clear
indication of the presence of two distinct superconducting phases with twofold
and fourfold symmetries. We infer that the gap functions in both phases have a
point node singularity, in contrast to the familiar line node singularity
observed in almost all unconventional superconductors.
