  We study the nature of the [TiII] and [NiII] emission from the so-called
strontium filament found in the ejecta of eta Carinae. To this purpose we
employ multilevel models of the TiII and NiII systems which are used to
investigate the physical condition of the filament and the excitation
mechanisms of the observed lines. For the TiII ion, for which no atomic data
was previously available, we carry out ab initio calculations of radiative
transition rates and electron impact excitation rate coefficients. It is found
that the observed spectrum is consistent with the lines being excited in a
mostly neutral region with an electron density of the order of $10^7$ cm$^{-3}$
and a temperature around 6000 K. In analyzing three observations with different
slit orientations recorded between March~2000 and November~2001 we find line
ratios that change among various observations, in a way consistent with changes
of up to an order of magnitude in the strength of the continuum radiation
field. These changes result from different samplings of the extended filament,
due to the different slit orientations used for each observation, and yield
clues on the spatial extent and optical depth of the filament. The observed
emission indicates a large Ti/Ni abundance ratio relative to solar abundances.
It is suggested that the observed high Ti/Ni ratio in gas is caused by dust-gas
fractionation processes and does not reflect the absolute Ti/Ni ratio in the
ejecta of \etacar. We study the condensation chemistry of Ti, Ni and Fe within
the filament and suggest that the observed gas phase overabundance of Ti
