  In this paper, we consider static self-gravitating spherical spacetime and
determine various anisotropic solutions through the extended gravitational
decoupling technique in
$f(\mathcal{R},\mathcal{T},\mathcal{R}_{\lambda\xi}\mathcal{T}^{\lambda\xi})$
gravity to analyze the influence of electromagnetic field on them. We construct
two different sets of modified field equations by employing the transformations
on both radial as well as temporal metric potentials. The first set symbolizes
the isotropic fluid distribution, thus we take Krori-Barua solution to deal
with it. The indefinite second sector comprises the influence of anisotropy. In
this regard, we apply some constraints to determine unknowns. Further, we
observe the impact of charge as well as decoupling parameter $\zeta$ on the
developed physical variables (such as energy density,~radial and tangential
pressures) and anisotropy. We also analyze other physical features of the
compact geometry like mass, compactness and redshift along with the energy
conditions. Eventually, we find that our both solutions show less stable
behavior for higher values of charge near the boundary in this gravity.
