  Mn3TeO6 exhibits a corundum-related A3TeO6 structure and a complex magnetic
structure involving two magnetic orbits for the Mn atoms [*]. Mn3-xCdxTeO6
(x=0, 1, 1.5 and 2) ceramics were synthesized by solid state reaction and
investigated using X-ray powder diffraction, electron microscopy, calorimetric
and magnetic measurements. Cd2+ replaces Mn2+ cations without greatly affecting
the structure of the compound. The Mn and Cd cations were found to be randomly
distributed over the A-site. Magnetization measurements indicated that the
samples order antiferromagnetically at low temperature with a transition
temperature that decreases with increasing Cd doping. The nuclear and magnetic
structure of one specially prepared 114Cd containing sample:
Mn1.5(114Cd)1.5TeO6, was studied using neutron powder diffraction over the
temperature range 2 to 295 K. Mn1.5(114Cd)1.5TeO6 was found to order in an
incommensurate helical magnetic structure, very similar to that of Mn3TeO6 [*].
However, with a lower transition temperature and the extension of the ordered
structure confined to order 240(10) {\AA}. [*] S. A. Ivanov et al. Mater. Res.
Bull. 46 (2011) 1870.
