  Plasmon resonances play a pivotal role in enhancing light-matter interactions
in nanophotonics, but their low-quality factors have hindered applications
demanding high spectral selectivity. Even though symmetry-protected bound
states in the continuum with high-quality factors have been realized in
dielectric metasurfaces, impinging light is not efficiently coupled to the
resonant metasurfaces and is lost in the form of reflection due to low
intrinsic losses. Here, we demonstrate a novel design and 3D laser nanoprinting
of plasmonic nanofin metasurfaces, which support symmetry-protected bound
states in the continuum up to 4th order. By breaking the nanofins out-of-plane
symmetry in parameter space, we achieve high-quality factor (up to 180) modes
under normal incidence. We reveal that the out-of-plane symmetry breaking can
be fine-tuned by the triangle angle of the 3D nanofin meta-atoms, opening a
pathway to precisely control the ratio of radiative to intrinsic losses. This
enables access to the under-, critical-, and over-coupled regimes, which we
exploit for pixelated molecular sensing. Depending on the coupling regime we
observe negative, no, or positive modulation induced by the analyte, unveiling
the undeniable importance of tailoring light-matter interaction. Our
demonstration provides a novel metasurface platform for enhanced light-matter
interaction with a wide range of applications in optical sensing, energy
conversion, nonlinear photonics, surface-enhanced spectroscopy, and quantum
optics.
