  Rigorous bounds on the rate of energy exchanges between vibrational and
translational degrees of freedom are established in simple classical models of
diatomic molecules. The results are in agreement with an elementary
approximation introduced by Landau and Teller. The method is perturbative
theory ``beyond all orders'', with diagrammatic techniques (tree expansions) to
organize and manipulate terms, and look for compensations, like in recent
studies on KAM theorem homoclinic splitting.
