  Why do plants reflect in the green and have a 'red edge' in the red, and
should extrasolar photosynthesis be the same? We provide: 1) a brief review of
how photosynthesis works; 2) an overview of the diversity of photosynthetic
organisms, their light harvesting systems, and environmental ranges; 3) a
synthesis of photosynthetic surface spectral signatures; 4) evolutionary
rationales for photosynthetic surface reflectance spectra with regard to
utilization of photon energy and the planetary light environment. Given the
surface incident photon flux density spectrum and resonance transfer in light
harvesting, we propose some rules with regard to where photosynthetic pigments
will peak in absorbance: a) the wavelength of peak incident photon flux; b) the
longest available wavelength for core antenna or reaction center pigments; and
c) the shortest wavelengths within an atmospheric window for accessory
pigments. That plants absorb less green light may not be an inefficient legacy
of evolutionary history, but may actually satisfy the above criteria.
