  The line intensities of the fundamental rotational transitions of H13CN and
HC15N were observed towards two prestellar cores, L183 and L1544, and lead to
molecular isotopic ratios 140 6 14N/15N 6 250 and 140 6 14N/15N 6 360,
respectively. The range of values reflect genuine spatial variations within the
cores. A comprehensive analysis of the available measurements of the nitrogen
isotopic ratio in prestellar cores show that molecules carrying the nitrile
functional group appear to be systematically 15N-enriched com- pared to those
carrying the amine functional group. A chemical origin for the differential
15N-enhance- ment between nitrile- and amine-bearing interstellar molecules is
proposed. This sheds new light on several observations of Solar System objects:
(i) the similar N isotopic fractionation in Jupiter's NH3 and solar wind N+;
(ii) the 15N-enrichments in cometary HCN and CN (that might represent a direct
inter- stellar inheritance); and (iii) 15N-enrichments observed in organics in
primitive cosmomaterials. The large variations in the isotopic composition of
N-bearing molecules in Solar System objects might then simply reflect the
different interstellar N reservoirs from which they are originating.
