  Solid-state cooling based on caloric effects is considered a viable
alternative to replace the conventional vapor-compression refrigeration
systems. Regarding barocaloric materials, recent results show that elastomers
are promising candidates for cooling applications around room-temperature. In
the present paper, we report supergiant barocaloric effects observed in acetoxy
silicone rubber - a very popular, low-cost and environmentally friendly
elastomer. Huge values of adiabatic temperature change and reversible
isothermal entropy change were obtained upon moderate applied pressures and
relatively low strains. These huge barocaloric changes are associated both to
the polymer chains rearrangements induced by confined compression and to the
first-order structural transition. The results are comparable to the best
barocaloric materials reported so far, opening encouraging prospects for the
application of elastomers in near future solid-state cooling devices.
