  The complex impedance of a Pr0.67Ca0.33MnO3 crystal has been measured. The
frequency dependence is studied for a wide range of temperatures (50K-403K) and
is found to be characteristic of relaxation process with a single Debye time
relaxation constant, which is interpreted as a dielectric constant of the
material. A strong peak is observed in this dielectric constant (up to two
millions) at the charge ordering transition suggesting an interpretation in
terms of ordering of electric dipoles at TCO or in term of phase separation.
Comparison with Pr0.63Ca0.37MnO3 - in which the phase separation is much
smaller and the peak in the dielectric constant is absent - suggests an
interpretation in term of phase separation between insulating and metallic
states.
