  We observes a signal for the double charm baryon Xi_cc+ in the charged decay
mode Xi_cc+ -> p D+ K- to complement the previously reported decay Xi_cc+ ->
Lambda_c K- pi+ in data from SELEX, the charm hadro-production experiment
(E781) at Fermilab. In this new decay mode we observe an excess of 5.62 events
over an expected background estimated by event mixing to be 1.38+/-0.13 events.
The Poisson probability that a background fluctuation can produce the apparent
signal is less than 6.4E-4. The observed mass of this state is
(3518+/-3)MeV/c^2, consistent with the published result. Averaging the two
results gives a mass of (3518.7+/-1.7)MeV/c^2. The observation of this new weak
decay mode confirms the previous SELEX suggestion that this state is a double
charm baryon. The relative branching ratio Gamma(Xi_cc+ -> pD+K-)/Gamma(Xi_cc+
-> Lambda_c K- pi+) = 0.36+/-0.21.
