  The pivotal point of the paper is to discuss the behavior of temperature,
pressure, energy density as a function of volume along with determination of
caloric EoS from following two model: $w(z)=w_{0}+w_{1}\ln(1+z)$ & $
w(z)=-1+\frac{(1+z)}{3}\frac{A_{1}+2A_{2}(1+z)}{A_{0}+2A_{1}(1+z)+A_{2}(1+z)^{2}}$.
The time scale of instability for this two models is discussed. In the paper we
then generalize our result and arrive at general expression for energy density
irrespective of the model. The thermodynamical stability for both of the model
and the general case is discussed from this viewpoint. We also arrive at a
condition on the limiting behavior of thermodynamic parameter to validate the
third law of thermodynamics and interpret the general mathematical expression
of integration constant $U_{0}$ (what we get while integrating energy
conservation equation) physically relating it to number of micro states. The
constraint on the allowed values of the parameters of the models is discussed
which ascertains stability of universe. The validity of thermodynamical laws
within apparent and event horizon is discussed.
