  The domain structure of (1-x)Pb(Mg1/3Nb2/3)O3- xPbTiO3 single crystals with
composition x ~ 0.33 in the range of the morphotropic phase boundary (MPB) was
studied. Based on the analysis of spontaneous strain compatibility and charge
of domain walls, we have established the permissible domain arrangements for
the ferroelectric phases of different symmetry, which are expected to occur in
the range of the MPB. Examination of (001)-oriented unpoled and electrically
poled (along the [001] direction) crystal plates in polarizing microscope
reveals a monophase state with the domain structure compatible with the
structure theoretically predicted for the Mc monoclinic phase (space group Pm),
which was recently discovered in the compositions close to the MPB by x-ray and
neutron diffraction studies. In the unpoled crystal the 180 deg. walls between
the domains whose spontaneous polarization vectors are parallel to the plane of
the crystal plate (i.e. a-domains) are observed. The domain structure of the
poled crystal is predominantly composed of crystallographically prominent Wf
walls parallel to (001) (i.e. the plane of the crystal plate) and inclined S
walls parallel to [110] or [1-10] direction. In poled and unpoled samples the
optical rotatory polarization effect is found, which is related to the
inhomogeneity of the sample resulting from the mixture of domains.
