  The experimental evidence of the ultra-high electron mobility and strong
spin-orbit coupling in the two-dimensional (2D) layered bismuth-based
oxyselenide, Bi$_{2}$O$_{2}$Se, makes it a potential material for spintronic
devices. However, its spin-related properties have not been extensively studied
due to the centrosymmetric nature of its crystal structure. By using
first-principles density-functional theory calculation, this study reports the
emergence of Rashba-spin-valley states in Bi$_{2}$O$_{2}$Se monolayer (ML).
Breaking the crystal inversion symmetry of Bi$_{2}$O$_{2}$Se ML using an
external electric field enables the Rashba-spin-valley formation, causing the
appearance of the Rashba-type splitting around the $\Gamma$ valley and
spin-valley coupling at the $D$ valleys located near the middle of $\Gamma-M$
line. In addition to the typical Rashba-type spin textures around the $\Gamma$
valley, the study also observed in-plane unidirectional spin textures around
the $D$ valleys, which is a rare phenomenon in 2D materials. The observed
Rashba-spin-valley states are driven by the lowering point group symmetry of
the crystal from $D_{4h}$ to $C_{4v}$ enforced by the electric field, as
clarified through $\vec{k}\cdot\vec{p}$ model derived from symmetry analysis.
More importantly, tuning the Rashba and spin-valley states by using biaxial
strain offers a promising route to regulate the spin textures and spin
splitting preventing the electron from back-scattering in spin transport.
Finally, we proposed a more realistic system, namely, Bi$_{2}$O$_{2}$Se
ML/SrTiO$_{3}$ (001) heterointerface that supports the strong
Rashba-spin-valley states and highlighting the potential of the
Bi$_{2}$O$_{2}$Se ML for future spintronics and valleytronics-based devices.
