  We report a theoretical study suggesting a novel type of electronic switching
effect, driven by the geometrical reconstruction of nanoscale graphene-based
junctions. We considered junction struc- tures which have alternative
metastable configurations transformed by rotations of local carbon dimers. The
use of external mechanical strain allows a control of the energy barrier
heights of the potential profiles and also changes the reaction character from
endothermic to exothermic or vice-versa. The reshaping of the atomic details of
the junction encode binary electronic ON or OFF states, with ON/OFF
transmission ratio that can reach up to 10^4-10^5. Our results suggest the
possibility to design modern logical switching devices or mechanophore sensors,
monitored by mechanical strain and structural rearrangements.
