  Oxide superlattices and microstructures hold the promise for creating a new
class of devices with unprecedented functionalities. Density-functional studies
of the recently fabricated superlattices of lattice-matched perovskite
titanates (SrTiO3)n/(LaTiO3)m reveal a classic wedge-shaped potential
originating from the Coulomb potential of a charged sheet of La atoms. The
potential in turn confines the electrons in the vicinity of the sheet, leading
to an Airy-function localization of the electron states. Magnetism is
suppressed for structures with a single LaTiO3 monolayer, while the bulk
antiferromagnetism is recovered in the structures with a thicker LaTiO3, with a
narrow transition region separating the magnetic LaTiO3 and the non-magnetic
SrTiO3.
