  The unambiguous detection and quantification of entanglement is a hot topic
of scientific research, though it is limited to low dimensions or specific
classes of states. Here we identify an additional class of quantum states, for
which bipartite entanglement measures can be efficiently computed, providing
new rigorous results. Such states are written in arbitrary $d\times d$
dimensions, where each basis state in the subsystem A is paired with only one
state in B. This new class, that we refer to as pair basis states, is
remarkably relevant in many physical situations, including quantum optics. We
find that negativity is a necessary and sufficient measure of entanglement for
mixtures of states written in the same pair basis. We also provide analytical
expressions for a tight lower-bound estimation of the entanglement of
formation, a central quantity in quantum information.
