  The premartensite phase of shape memory and magnetic shape memory alloys
(MSMAs) is believed to be a precursor state of the martensite phase with
preserved austenite phase symmetry. The thermodynamic stability of the
premartensite phase and its relation to the martensitic phase is still an
unresolved issue, even though it is critical to the understanding of the
functional properties of MSMAs. We present here unambiguous evidence for
macroscopic symmetry breaking leading to robust Bain distortion in the
premartensite phase of 10% Pt substituted Ni2MnGa. We show that the robust Bain
distorted premartensite (T2) phase results from another premartensite (T1)
phase with preserved cubic-like symmetry through an isostructural phase
transition. The T2 phase finally transforms to the martensite phase with
additional Bain distortion on further cooling. Our results demonstrate that the
premartensite phase should not be considered as a precursor state with the
preserved symmetry of the cubic austenite phase.
