  We performed resonant and nonresonant x-ray diffraction studies of a
Nd0.5Sr0.5MnO3 thin film that exhibits a clear first-order transition. Lattice
parameters vary drastically at the metal-insulator transition at 170K (=T_MI),
and superlattice reflections appear below 140K (=T_CO). The electronic
structure between T_MI and T_CO is identified as A-type antiferromagnetic with
the d_{x2-y2} ferroorbital ordering. Below T_CO, a new type of antiferroorbital
ordering emerges. The accommodation of the large lattice distortion at the
first-order phase transition and the appearance of the novel orbital ordering
are brought about by the anisotropy in the substrate, a new parameter for the
phase control.
