  We present a new dimensional scaling transformation of the Schrodinger
equation for the two electron bond. This yields, for the first time, a good
description of the two electron bond via D-scaling. There also emerges, in the
large-D limit, an intuitively appealing semiclassical picture, akin to a
molecular model proposed by Niels Bohr in 1913. In this limit, the electrons
are confined to specific orbits in the scaled space, yet the uncertainty
principle is maintained because the scaling leaves invariant the
position-momentum commutator. A first-order perturbation correction,
proportional to 1/D, substantially improves the agreement with the exact ground
state potential energy curve. The present treatment is very simple
mathematically, yet provides a strikingly accurate description of the potential
energy curves for the lowest singlet, triplet and excited states of H_2. We
find the modified D-scaling method also gives good results for other molecules.
It can be combined advantageously with Hartree-Fock and other conventional
methods.
