  Angle-resolved ultraviolet photoemission spectra are interpreted by combining
the energetics and spatial properties of the contributing states. One-step
calculations are in excellent agreement with new azimuthal experimental data
for GaAs(110). Strong variations caused by the dispersion of the surface bands
permit an accurate mapping of the electronic structure. The delocalization of
the valence states is discussed analogous to photoelectron diffraction. The
spatial origin of the electrons is determined, and found to be strongly energy
dependent, with uv excitation probing the bonding region.
