  We studied structural, optical and magnetic properties of high-quality 5 and
15% Co-doped ZnO films grown by plasma-assisted molecular beam epitaxy (MBE) on
(0001)-sapphire substrates. Magnetic force microscopy (MFM) and magnetic
measurements with SQUID magnetometer show clear ferromagnetic behavior of the
films up to room temperature whereas they are antiferromagnetic below 200 K
approximately. Temperature dependence of the carrier mobility was determined
using Raman line shape analysis of the longitudinal-optical-phonon-plasmon
coupled modes. It shows that the microscopic mechanism for ferromagnetic
ordering is coupling mediated by free electrons between spins of Co atoms.
These results bring insight into a subtle interplay between charge carriers and
magnetism in MBE-grown Zn(1-x)CoxO films.
