  We investigate the nature of the mid-IR excess for 31 intermediate-mass stars
that exhibit an 8 micron excess in either the Galactic Legacy Infrared
Mid-Plane Survey Extraordinaire or the Mid-Course Space Experiment using high
resolution optical spectra to identify stars surrounded by warm circumstellar
dust. From these data we determine projected stellar rotational velocities and
estimate stellar effective temperatures for the sample. We estimate stellar
ages from these temperatures, parallactic distances, and evolutionary models.
Using MIPS [24] measurements and stellar parameters we determine the nature of
the infrared excess for 19 GLIMPSE stars. We find that 15 stars exhibit Halpha
emission and four exhibit Halpha absorption. Assuming that the mid-IR excesses
arise in circumstellar disks, we use the Halpha fluxes to model and estimate
the relative contributions of dust and free-free emission. Six stars exhibit
Halpha fluxes that imply free-free emission can plausibly explain the infrared
excess at [24]. These stars are candidate classical Be stars. Nine stars
exhibit Halpha emission, but their Halpha fluxes are insufficient to explain
the infrared excesses at [24], suggesting the presence of a circumstellar dust
component. After the removal of the free-free component in these sources, we
determine probable disk dust temperatures of Tdisk~300-800 K and fractional
infrared luminosities of L(IR)/L(*)~10^-3. These nine stars may be
pre-main-sequence stars with transitional disks undergoing disk clearing. Three
of the four sources showing Halpha absorption exhibit circumstellar disk
temperatures ~300-400 K, L(IR)/L(*)~10^-3, IR colors K-[24]< 3.3, and are warm
debris disk candidates. One of the four Halpha absorption sources has K-[24]>
3.3 implying an optically thick outer disk and is a transition disk candidate.
