  This research focused on synthesis, characterization and determination of
biological activities of Fe$^{2+}$ Co$^{2+}$ and Ni$^{2+}$ complexes of a novel
L- Tryptophan-Vanillin Schiff base ligand. They were synthesized and
characterized by determination of their Purity, Solubility, Elemental analyses
using phase match XRD data, FT-IR spectra, Molar conductivities, Magnetic
susceptibilities, PXRD and Biological activities. Results from the analyses
revealed that, mpt of Schiff base ligand (SL)84 85 oC, Fe$^{2+}$ SL 245 - 246
oC, Co$^{2+}$-SL 271 - 272 oC while Ni$^{2+}$ - SL is >350 oC. Molar
conductivities were found to be 10300, 5000, 17300 and 52900 Sm2 mol-1 for the
Schiff base and the complexes respectively. It indicates that, the complexes
are non-electrolytic in nature. Magnetic susceptibilities of the complexes
found to be higher than the spin only values due to unpaired electrons
(Fe$^{2+}$ = 5.73 B.M, Co$^{2+}$= 4.52 B.M while for Ni$^{2+}$ = 3.46 B.M,
suggesting an octahedral geometry. Electronic absorption ({\lambda}max) for
Fe$^{2+}$ = 480, Co$^{2+}$ = 520nm while Ni$^{2+}$ shows two bands at 480 and
570 which signifies, n-{\pi}* and {\pi}-{\pi}* transition respectively. Their
crystallinity index was also assessed using xrd technique, it shows that
complexes are 75, 80 and 85 % crystalline with average crystallite size of
21.63 nm. Antimicrobial test results revealed that, Co$^{2+}$ and Fe$^{2+}$
complexes have excellent activities against gram negative bacteria (E. coli, F.
Shigella. and S. Typi).
