  We report experimental results on the diffractive imaging of
three-dimensionally aligned 2,5-diiodothiophene molecules. The molecules were
aligned by chirped near-infrared laser pulses, and their structure was probed
at a photon energy of 9.5 keV ($\lambda\approx130 \text{pm}$) provided by the
Linac Coherent Light Source. Diffracted photons were recorded on the CSPAD
detector and a two-dimensional diffraction pattern of the equilibrium structure
of 2,5-diiodothiophene was recorded. The retrieved distance between the two
iodine atoms agrees with the quantum-chemically calculated molecular structure
to within 5 %. The experimental approach allows for the imaging of intrinsic
molecular dynamics in the molecular frame, albeit this requires more
experimental data which should be readily available at upcoming
high-repetition-rate facilities.
