  We present a study of 16 PNe where fullerenes have been detected in their
Spitzer spectra. This large sample of objects offers an unique opportunity to
test conditions of fullerene formation and survival under different metallicity
environments as we are analyzing five sources in our own Galaxy, four in the
LMC, and seven in the SMC. Among the 16 PNe under study, we present the first
detection of C60 (possibly also C70) fullerenes in the PN M 1-60 as well as of
the unusual 6.6, 9.8, and 20 um features (possible planar C24) in the PN K
3-54. Although selection effects in the original samples of PNe observed with
Spitzer may play a potentially significant role in the statistics, we find that
the detection rate of fullerenes in C-rich PNe increases with decreasing
metallicity (5% in the Galaxy, 20% in the LMC, and 44% in the SMC). CLOUDY
photoionization modeling matches the observed IR fluxes with central stars that
display a rather narrow range in effective temperature (30,000-45,000 K),
suggesting a common evolutionary status of the objects and similar fullerene
formation conditions. The observed C60 intensity ratios in the Galactic sources
confirm our previous finding in the MCs that the fullerene emission is not
excited by the UV radiation from the central star. CLOUDY models also show that
line- and wind-blanketed model atmospheres can explain many of the observed
[NeIII]/[NeII] ratios by photoionization suggesting that possibly the UV
radiation from the central star, and not shocks, are triggering the
decomposition of the circumstellar dust grains. With the data at hand, we
suggest that the most likely explanation for the formation of fullerenes and
graphene precursors in PNe is that these molecular species are built from the
photo-chemical processing of a carbonaceous compound with a mixture of aromatic
and aliphatic structures similar to that of HAC dust.
