  A photometric and spectroscopic analysis of 152 cool white dwarf stars is
presented. The discovery of 7 new DA white dwarfs, 2 new DQ white dwarfs, 1 new
magnetic white dwarf, and 3 weak magnetic white dwarf candidates, is reported,
as well as 19 known or suspected double degenerates. The photometric energy
distributions, the Halpha line profiles, and the trigonometric parallax
measurements are combined and compared to model atmosphere calculations to
determine the effective temperature and the radius of each object, and also to
constrain the atmospheric composition. New evolutionary sequences with C/O
cores with thin and thick hydrogen layers are used to derive masses and ages.
We confirm the existence of a range in Teff between 5000 and 6000K where almost
all white dwarfs have H-rich atmospheres. There is little evidence for mixed
H/He dwarfs, with the exception of 2 He-rich DA stars, and 5 C2H white dwarfs
which possibly have mixed H/He/C atmospheres. The DQ sequence terminates near
6500K, below which they are believed to turn into C2H stars. True DC stars
slightly above this temperature are found to exhibit H-like energy
distributions despite the lack of Halpha absorption. Attempts to interpret the
chemical evolution show the problem to be complex. Convective mixing is
necessary to account for the non-DA to DA ratio as a function of temperature.
The presence of helium in cool DA stars, the existence of the non-DA gap, and
the peculiar DC stars are also explained in terms of convective mixing,
although our understanding of how this mechanism works needs to be revised. The
oldest object in our sample is about 7.9 Gyr or 9.7 Gyr old depending on
whether thin or thick hydrogen layer models are used. The mean mass of our
sample is 0.65 +/- 0.20 Msun.
