  We determine the temporal evolution of the luminosity L(WD), radius R(WD) and
effective temperature Teff of the white dwarf (WD) pseudophotosphere of V339
Del from its discovery to around day 40. Another main objective was studying
the ionization structure of the ejecta. These aims were achieved by modelling
the optical/near-IR spectral energy distribution (SED) using low-resolution
spectroscopy (3500 - 9200 A), UBVRcIc and JHKLM photometry. During the fireball
stage (Aug. 14.8 - 19.9, 2013), Teff was in the range of 6000 - 12000 K, R(WD)
was expanding non-uniformly in time from around 66 to around 300 (d/3 kpc)
R(Sun), and L(WD) was super-Eddington, but not constant. After the fireball
stage, a large emission measure of 1.0-2.0E+62 (d/3 kpc)**2 cm**(-3)
constrained the lower limit of L(WD) to be well above the super-Eddington
value. The evolution of the H-alpha line and mainly the transient emergence of
the Raman-scattered O VI 1032 A line suggested a biconical ionization structure
of the ejecta with a disk-like H I region persisting around the WD until its
total ionization, around day 40. It is evident that the nova was not evolving
according to the current theoretical prediction. The unusual non-spherically
symmetric ejecta of nova V339 Del and its extreme physical conditions and
evolution during and after the fireball stage represent interesting new
challenges for the theoretical modelling of the nova phenomenon.
