  Recent calculations have shown that the UV bump at about 217.5 nm in the
extinction curve can be explained by a complex mixture of PAHs in several
charge states. Other studies proposed that the carriers are a restricted
population made of neutral and singly-ionised dehydrogenated coronene molecules
(C24Hn, n less than 3), in line with models of the hydrogenation state of
interstellar PAHs predicting that medium-sized species are highly
dehydrogenated. To assess the observational consequences of the latter
hypothesis we have undertaken a systematic study of the electronic spectra of
dehydrogenated PAHs. We use our first results to see whether such spectra show
strong general trends upon dehydrogenation. We used state-of-the-art techniques
in the framework of the density functional theory (DFT) to obtain the
electronic ground-state geometries, and of the time- dependent DFT to evaluate
the electronic excited-state properties. We computed the absorption
cross-section of the species C24Hn (n=12,10,8,6,4,2,0) in their neutral and
cationic charge-states. Similar calculations were performed for other PAHs and
their fullydehydrogenated counterparts. pi electron energies are always found
to be strongly affected by dehydrogenation. In all cases we examined,
progressive dehydrogenation translates into a correspondingly progressive blue
shift of the main electronic transitions. In particular, the pi-pi* collective
resonance becomes broader and bluer with dehydrogenation. Its calculated energy
position is therefore predicted to fall in the gap between the UV bump and the
far-UV rise of the extinction curve. Since this effect appears to be
systematic, it poses a tight observational limit on the column density of
strongly dehydrogenated medium-sized PAHs.
