  We study the ground-state properties of an extended periodic Anderson model
to understand the role of Hund's coupling between localized and itinerant
electrons using the density-matrix renormalization group algorithm. By
calculating the von Neumann entropies we show that two phase transitions occur
and two new phases appear as the hybridization is increased in the symmetric
half-filled case due to the competition between Kondo-effect and Hund's
coupling. In the intermediate phase, which is bounded by two critical points,
we found a dimerized ground state, while in the other spatially homogeneous
phases the ground state is Haldane-like and Kondo-singlet-like, respectively.
We also determine the entanglement spectrum and the entanglement diagram of the
system by calculating the mutual information thereby clarifying the structure
of each phase.
