  Graphene is the two-dimensional (2d) building block for carbon allotropes of
every other dimensionality. It can be stacked into 3d graphite, rolled into 1d
nanotubes, or wrapped into 0d fullerenes. Its recent discovery in free state
has finally provided the possibility to study experimentally its electronic and
phonon properties. Here we show that graphene's electronic structure is
uniquely captured in its Raman spectrum that clearly evolves with increasing
number of layers. Raman fingerprints for single-, bi- and few-layer graphene
reflect changes in the electronic structure and electron-phonon interactions
and allow unambiguous, high-throughput, non-destructive identification of
graphene layers, which is critically lacking in this emerging research area.
