  We report the Rb nuclear magnetic resonance (NMR) results in a recently
synthesized Na5RbCu4(AsO4)Cl2. This complex novel two-dimensional (2D) cuprate
is an unique magnetic material, which contains layers of coupled Cu4O4
tetramers. In zero applied magnetic field, it orders antiferromagnetically via
a second-order low-entropy phase transition at TN = 15(1) K. We characterise
the ordered state by 87Rb NMR, and suggest for it a noncollinear rather than
collinear arrangement of spins. We discuss the properties of Rb nuclear site
and point out the new structural phase transition(s) around 74 K and 110 K.
