  Thermoelectric effects are highly sensitive to the asymmetry in the density
of states around the Fermi energy and can be exploited as probes of the
electronic structure. We experimentally study thermopower in high-quality
monolayer graphene, within heterostructures consisting of complete hBN
encapsulation and 1D edge contacts, where the graphene and hBN lattices are
aligned. When graphene is aligned to one of the hBN layers, we demonstrate the
presence of additional sign reversals in the thermopower as a function of
carrier density, directly evidencing the presence of the moir\'e superlattice.
We show that the temperature dependence of the thermopower enables the
assessment of the role of built-in strain variation and van Hove singularities
and hints at the presence of Umklapp electron-electron scattering processes. As
the thermopower peaks around the neutrality point, this allows to probe the
energy spectrum degeneracy. Further, when graphene is double-aligned with the
top and bottom hBN crystals, the thermopower exhibits features evidencing
multiple cloned Dirac points caused by the differential super-moir\'e lattice.
For both cases we evaluate how well the thermopower agrees with Mott's
equation. Finally, we show the same superlattice device can exhibit a
temperature-driven thermopower reversal from positive to negative and vice
versa, by controlling the carrier density. The study of thermopower provides an
alternative approach to study the electronic structure of 2D superlattices,
whilst offering opportunities to engineer the thermoelectric response on these
heterostructures.
