  The intermediate valent systems TmSe and SmB6 have been investigated up to 16
and 18 GPa by ac microcalorimetry with a pressure (p) tuning realized in situ
at low temperature. For TmSe, the transition from an antiferromagnetic
insulator for p<3 GPa to an antiferromagnetic metal at higher pressure has been
confirmed. A drastic change in the p variation of the Neel temperature (Tn) is
observed at 3 GPa. In the metallic phase (p>3 GPa), Tn is found to increase
linearly with p. A similar linear p increase of Tn is observed for the
quasitrivalent compound TmS which is at ambiant pressure equivalent to TmSe at
p=7 GPa. In the case of SmB6 long range magnetism has been detected above p=8
GPa, i.e. at a pressure slightly higher than the pressure of the insulator to
metal transition. However a homogeneous magnetic phase occurs only above 10
GPa. The magnetic and electronic properties are related to the renormalization
of the 4f wavefunction either to the divalent or the trivalent configurations.
As observed in SmS, long range magnetism in SmB6 occurs already far below the
pressure where a trivalent Sm3+ state will be reached. It seems possible, to
describe roughly the physical properties of the intermediate valence
equilibrium by assuming formulas for the Kondo lattice temperature depending on
the valence configuration. Comparison is also made with the appearance of long
range magnetism in cerium and ytterbium heavy fermion compounds.
