  The internal photoeffect in polythiopentacene (PTP) films is investigated. It
is discovered that, in capacitor cells, the spectral dependence of the frontal
photo-emf Vf correlates with the PTP absorption spectrum, while that of the
back photo-emf Vb anticorrelates with it. The polarities of Vf and Vb coincide.
In this case, the charge of the free PTP surface is negative, whereas that of
the frontal SnO2 electrode is positive. Back low- and strong-absorption
illuminations photogenerate holes that diffuse to the free PTP surface and
decrease Vdf . These illuminations change the polarity of Vb. The spectra of
the density of short-circuit current Jsc of the sandwich cells SnO2 PTPAg and
Vb correlate. Under the modulated illumination of these cells through the SnO2
and Ag electrodes, the drift flow of nonequilibrium holes in the electric
field, conditioned by the antiblocking bending of the PTP bands near these
electrodes, prevails.
