  We calculate exactly both the microcanonical and canonical thermodynamic
functions (TDFs) for a one-dimensional model system with piecewise constant
Lennard-Jones type pair interactions. In the case of an isolated $N$-particle
system, the microcanonical TDFs exhibit (N-1) singular (non-analytic)
microscopic phase transitions of the formal order N/2, separating N
energetically different evaporation (dissociation) states. In a suitably
designed evaporation experiment, these types of phase transitions should
manifest themselves in the form of pressure and temperature oscillations,
indicating cooling by evaporation. In the presence of a heat bath (thermostat),
such oscillations are absent, but the canonical heat capacity shows a
characteristic peak, indicating the temperature-induced dissociation of the
one-dimensional chain. The distribution of complex zeros (DOZ) of the canonical
partition may be used to identify different degrees of dissociation in the
canonical ensemble.
