  In this work we investigate superconducting properties of niobium samples via
application of the muon spin rotation/relaxation (muSR) technique. We employ
for the first time the muSR technique to study samples that are cutout from
large and small grain 1.5 GHz radio frequency (RF) single cell niobium
cavities. The RF test of these cavities was accompanied by full temperature
mapping to characterize the RF losses in each of the samples. Results of the
muSR measurements show that standard cavity surface treatments like mild baking
and buffered chemical polishing (BCP) performed on the studied samples affect
their surface pinning strength. We find an interesting correlation between high
field RF losses and field dependence of the sample magnetic volume fraction
measured via muSR. The muSR line width observed in ZF-muSR measurements matches
the behavior of Nb samples doped with minute amounts of Ta or N impurities. An
upper bound for the upper critical field Hc2 of these cutouts is found.
