  We report the first spectroscopic identification of massive Galactic
asymptotic giant branch (AGB) stars at the beginning of the thermal pulse (TP)
phase. These stars are the most Li-rich massive AGBs found to date, super
Li-rich AGBs with logE(Li)~3-4. The high Li overabundances are accompanied by
weak or no s-process element (i.e. Rb and Zr) enhancements. A comparison of our
observations with the most recent hot bottom burning (HBB) and s-process
nucleosynthesis models confirms that HBB is strongly activated during the first
TPs but the 22Ne neutron source needs many more TP and third dredge-up episodes
to produce enough Rb at the stellar surface. We also show that the short-lived
element Tc, usually used as an indicator of AGB genuineness, is not detected in
massive AGBs which is in agreement with the theoretical predictions when the
22Ne neutron source dominates the s-process nucleosynthesis.
