  We report a measurement of the CP-odd fraction and the time-dependent CP
violation in B0 to D*+D*- decays, using 657.10^6 BBbar events collected at the
Upsilon(4S) resonance with the Belle detector at the KEKB asymmetric-energy
e+e- collider. We measure a CP-odd fraction of
Rperp=0.125+/-0.043(stat)+/-0.023(syst). From the distributions of the
proper-time intervals between a B0to D*+D*- decay and the other B meson in the
event, we obtain evidence of CP violation with measured parameters
AD*+D*-=0.15+/-0.13(stat)+/-0.04(syst) and
SD*+D*-=-0.96+/-0.25(stat)-0.16+0.13(syst).
