  Ferromagnetic van der Waals (vdW) materials are in demand for spintronic
devices with all-two-dimensional-materials heterostructures. Here, we
demonstrate mechanical exfoliation of magnetic-atom-intercalated transition
metal dichalcogenide Cr1/3TaS2 from its bulk crystal; previously such
intercalated materials were thought difficult to exfoliate. Magnetotransport in
exfoliated tens-of-nanometres-thick flakes revealed ferromagnetic ordering
below its Curie temperature TC ~ 110 K as well as strong in-plane magnetic
anisotropy; these are identical to its bulk properties. Further, van der Waals
heterostructure assembly of Cr1/3TaS2 with another intercalated ferromagnet
Fe1/4TaS2 is demonstrated using a dry-transfer method. The fabricated
heterojunction composed of Cr1/3TaS2 and Fe1/4TaS2 with a native Ta2O5 oxide
tunnel barrier in between exhibits tunnel magnetoresistance (TMR), revealing
possible spin injection and detection with these exfoliatable ferromagnetic
materials through the vdW junction.
