  The high luminosity of Very Massive Stars (VMS) means that radiative forces
play an important, dynamical role both in the structure and stability of their
stellar envelope, and in driving strong stellar-wind mass loss. Focusing on the
interplay of radiative flux and opacity, with emphasis on key distinctions
between continuum vs. line opacity, this chapter reviews instabilities in the
envelopes and winds of VMS. Specifically, we discuss how: 1) the iron opacity
bump can induce an extensive inflation of the stellar envelope; 2) the density
dependence of mean opacity leads to strange mode instabilities in the outer
envelope; 3) desaturation of line-opacity by acceleration of near-surface
layers initiates and sustains a line-driven stellar wind outflow; 4) an
associated line-deshadowing instability leads to extensive small-scale
structure in the outer regions of such line-driven winds; 5) a star with
super-Eddington luminosity can develop extensive atmospheric structure from
photon bubble instabilities, or from stagnation of flow that exceeds the
"photon tiring" limit; 6) the associated porosity leads to a reduction in
opacity that can regulate the extreme mass loss of such continuum-driven winds.
Two overall themes are the potential links of such instabilities to Luminous
Blue Variable (LBV) stars, and the potential role of radiation forces in
establishing the upper mass limit of VMS.
