  This paper reports the detection of a heavy element enriched RV Tauri
variable with an abundance pattern that differs significantly from a standard
s-process enriched object: V453 Oph. Based on optical high-resolution spectra,
we determined that this object of low intrinsic metallicity ([Fe/H] = -2.2) has
a mild, but significant, enrichment ([s/Fe] ~ +0.5) of heavy elements for which
the distribution points to slow neutron capture nucleosynthesis. This result is
strengthened by a comparative analysis to the non-enriched RV Tauri star DS Aqr
([s/Fe] = 0.0). Although V453 Oph is the first RV Tauri star showing a strong
s-process signature, it is NOT accompanied by C enhancement, challenging our
current nucleosynthetic models of post-AGB stars that predict a simultaneous
enrichment in C and s-process elements. The low N abundance excludes CN cycling
as being responsible for the low C abundance. We explore three different
scenarios to explain the heavy element distribution in this evolved object: an
enrichment of the parental cloud, an accretion scenario in which the chemical
patterns were acquired by mass transfer in a binary system and an intrinsic
enrichment by dredge-up.
