  In the (ab) polarized Raman scattering spectra of NaV2O5 single crystals,
measured with 647.1 nm laser line at T < Tc, we found two modes at 86, and 126
cm-1 not previously reported. These two modes, together with 66, and 106 cm-1
modes, make an array of four low-energy equidistant modes below the energy
onset of the continuum at about 132 cm-1. All four modes are strongly
suppressed by increasing Na deficiency, indicating their nonvibrational origin
and the existence of a quantum phase transition at critical Na deficiency
between 3 and 4%. These results question current understanding of NaV2O5 as
quasi one-dimensional Heisenberg antiferromagnet.
