  Diffuse neutron scattering is a valuable tool to obtain information about the
size and orientation of the polar nanoregions that are a characteristic feature
of relaxor ferroelectrics. In this paper, we present new diffuse scattering
results obtained on Pb(Zn1/3Nb2/3)O3 (PZN for short) and
(1-x)Pb(Zn1/3Nb2/3)O3-xPbTiO3(PZN-xPT)single crystals (with x=4.5 and 9%),
around various Bragg reflections and along three symmetry directions in the
[100]-[011] zone. Diffuse scattering is observed around reflections with mixed
indices, (100), (011) and (300), and along transverse and diagonal directions
only. No diffuse scattering is found in longitudinal scans. The diffuse
scattering peaks can be fitted well with a Lorentzian function, from which a
correlation length is extracted. The correlation length increases with
decreasing temperatures down to the transition at Tc, first following a
Curie-Weiss law, then departing from it and becoming flat at very low
temperatures. These results are interpreted in terms of three temperature
regions: 1) dynamic polarization fluctuations (i.e. with a finite lifetime) at
high temperatures, 2) static polarization reorientations (condensation of polar
nanoregions) that can still reorient as a unit (relaxor behavior) at
intermediate temperatures and 3) orientational freezing of the polar
nanoregions with random strain fields in pure PZN or a structural phase
transition in PZN-xPT at low temperatures. The addition of PT leads to a
broadening of the diffuse scattering along the diagonal ([111]) relative to the
transverse ([100]) direction, indicating a change in the orientation of the
polar regions. Also, with the addition of PT, the polar nanoregions condense at
a higher temperature above Tc.
