  We present a density-functional theory study addressing the on-surface
adsorption of oxygen at the Pd(11N) (N =3,5,7) vicinal surfaces, which exhibit
(111) steps and (100) terraces of increasing width. We find the binding to be
predominantly governed by the local coordination at the adsorption site. This
leads to very similar bonding properties at the threefold step sites of all
three vicinal surfaces, while the binding at the central fourfold hollow site
in the four atomic row terrace of Pd(117) is already very little disturbed by
the presence of the neighboring steps.
