  Recent experiments have demonstrated that highly charged ions can be guided
through insulating nanocapillaries along the direction of the capillary axis
for a surprisingly wide range of injection angles. Even more surprisingly, the
transmitted particles remain predominantly in their initial charge state, thus
opening the pathway to the construction of novel ion-optical elements without
electric feedthroughs. We present a theoretical treatment of this
self-organized guiding process. We develop a classical trajectory transport
theory that relates the microscopic charge-up with macroscopic material
properties. Transmission coefficients, angular spread of transmitted particles,
and discharge characteristics of the target are investigated. Partial agreement
with experiment is found.
