  A well-preserved, ancient delta deposit, in combination with ample exposures
of carbonate rich materials, make Jezero Crater in Nili Fossae a compelling
astrobiological site. We use Compact Reconnaissance Imaging Spectrometer for
Mars (CRISM) observations to characterize the surface mineralogy of the crater
and surrounding watershed. Previous studies have documented the occurrence of
olivine and carbonates in the Nili Fossae region. We focus on correlations
between these two well studied lithologies in the Jezero crater watershed. We
map the position and shape of the olivine 1 {\mu}m absorption band and find
that carbonates are only found in association with olivine which displays a 1
{\mu}m band shifted to long wavelengths. We then use THEMIS coverage of Nili
Fossae and perform tests to investigate whether the long wavelength shifted
olivine signature is correlated with high thermal inertia outcrops. We find no
correlation between thermal inertia and the unique olivine signature. We
discuss a range of formation scenarios, including the possibility that these
olivine and carbonate associations are products of serpentinization reactions
on early Mars. These lithologies provide an opportunity for deepening our
understanding of early Mars, and, given their antiquity, may provide a
framework to study the formation of valley networks, and the thermal history of
the martian crust and interior from the early Noachian to today.
