  Optical excitations in hexagonal nanonetwork materials, for example,
Boron-Nitride (BN) sheets and nanotubes, are investigated theoretically. The
bonding of BN systems is positively polarized at the B site, and is negatively
polarized at the N site. There is a permanent electric dipole moment along the
BN bond, whose direction is from the B site to the N site. When the exciton
hopping integral is restricted to the nearest neighbors, the flat band of the
exciton appears at the lowest energy. The higher optical excitations have
excitation bands similar to the electronic bands of graphene planes and carbon
nanotubes. The symmetry of the flat exciton band is optically forbidden,
indicating that the excitons related to this band will show quite long lifetime
which will cause strong luminescence properties.
