  Quantum Stark effect in semiconductor nanocrystals is theoretically
investigated, using the effective mass formalism within a $4\times 4$
Baldereschi-Lipari Hamiltonian model for the hole states. General expressions
are reported for the hole eigenfunctions at zero electric field. Electron and
hole single particle energies as functions of the electric field
($\mathbf{E}_{QD}$) are reported. Stark shift and binding energy of the
excitonic levels are obtained by full diagonalization of the correlated
electron-hole Hamiltonian in presence of the external field. Particularly, the
structure of the lower excitonic states and their symmetry properties in CdSe
nanocrystals are studied. It is found that the dependence of the exciton
binding energy upon the applied field is strongly reduced for small quantum dot
radius. Optical selection rules for absorption and luminescence are obtained.
The electric-field induced quenching of the optical spectra as a function of
$\mathbf{E}_{QD}$ is studied in terms of the exciton dipole matrix element. It
is predicted that photoluminescence spectra present anomalous field dependence
of the emission lines. These results agree in magnitude with experimental
observation and with the main features of photoluminescence experiments in
nanostructures.
