  The heavy elements formed by neutron capture processes have an interesting
history from which we can extract useful clues to and constraints upon both the
characteristics of the processes themselves and the star formation and
nucleosynthesis history of Galactic matter. Of particular interest in this
regard are the heavy element compositions of extremely metal-deficient stars.
At metallicities [Fe/H] <= -2.5, the elements in the mass region past barium (A
>= 130-140 have been found (in non carbon-rich stars) to be pure r-process
products. The identification of an environment provided by massive stars and
associated Type II supernovae as an r-process site seems compelling. Increasing
levels of heavy s-process (e.g., barium) enrichment with increasing
metallicity, evident in the abundances of more metal-rich halo stars and disk
stars, reflect the delayed contributions from the low- and intermediate-mass (M
\~ 1-3 Msol) stars that provide the site for the main s-process nucleosynthesis
component during the AGB phase of their evolution. New abundance data in the
mass region 60 <~ A <~ 130 is providing insight into the identity of possible
alternative r-process sites. We review recent observational studies of heavy
element abundances both in low metallicity halo stars and in disk stars,
discuss the observed trends in light of nucleosynthesis theory, and explore
some implications of these results for Galactic chemical evolution,
nucleosynthesis, and nucleocosmochronology.
