  We explore neutrino capture during r-process nucleosynthesis in
neutrino-driven ejecta from nascent neutron stars. We focus on the interplay
between charged-current weak interactions and element synthesis, and we
delineate the important role of equilibrium nuclear dynamics. During the period
of coexistence of free nucleons and light and/or heavy nuclei, electron
neutrino capture inhibits the r-process. At all stages, capture on free
neutrons has a larger impact than capture on nuclei. However, neutrino capture
on heavey nuclei by itself, if it is very strong, is also detrimental to the
r-process until large nuclear equilibrium clusters break down and the classical
neutron-capture phase of the r-process begins. The sensitivity of the r-process
to neutrino irradiation means that neutrino-capture effects can strongly
constrain the r-process site, neutrino physics, or both. These results apply
also to r-process scenarios other than neutrino-heated winds.
