  We present the discovery and refinement by neutron powder diffraction of a
new magnetic phase in the Na1-xCaxMn7O12 quadruple perovskite phase diagram,
which is the incommensurate analogue of the well-known pseudo-CE phase of the
simple perovskite manganites. We demonstrate that incommensurate magnetic order
arises in quadruple perovskites due to the exchange interactions between A and
B sites. Furthermore, by constructing a simple mean field Heisenberg exchange
model that generically describes both simple and quadruple perovskite systems,
we show that this new magnetic phase unifies a picture of the interplay between
charge, magnetic and orbital ordering across a wide range of compounds.
