  We report transport measurements through a single-molecule magnet, the Mn12
derivative [Mn12O12(O2C-C6H4-SAc)16(H2O)4], in a single-molecule transistor
geometry. Thiol groups connect the molecule to gold electrodes that are
fabricated by electromigration. Striking observations are regions of complete
current suppression and excitations of negative differential conductance on the
energy scale of the anisotropy barrier of the molecule. Transport calculations,
taking into account the high-spin ground state and magnetic excitations of the
molecule, reveal a blocking mechanism of the current involving non-degenerate
spin multiplets.
