  We report on superconducting(SC) characteristics for oxygen-reduced Cu-based
five-layered high-temperature superconductor (Cu,C)Ba2Ca4Cu5Oy(Cu-1245(OPT)),
which includes five-fold outer planes (OP) and four-fold inner planes (IP).As a
result of the reduction of the carrier density, the bulk SC for Cu-1245 (OPT)
takes place at the nearly optimally-doped OP with Tc= 98 K that is different
from previously-reported Cu-1245(OVD) where IP plays a primary role for the
onset of SC. It gives an evidence that the carrier density of the
optimally-doped layer determines its bulk Tc.Static antiferromagnetic(AFM)
order is evidenced at IP's by zero-field Cu-NMR at low temperature,
irrespective of the SC transition at OP's below 98K. This AFM state at IP's is
characterized by a carrier localization at low temperatures due to disorder
effect, whereas the carrier densities in each layer are similar to Hg-1245(OPT)
where the AFM metallic state are realized in IP's. This finding reinforces the
phase diagram in which the AFM metallic phase exists between AFM insulator and
SC states for the case of ideally-flat CuO2 plane without disorder.
