  We measure 13C and 45Sc NMR lineshapes and spin-lattice relaxation times (T1)
to probe the orientational dynamics of the endohedral metallofullerene
Sc3N@C80. The measurements show an activated behavior for molecular
reorientations over the full temperature range with a similar behavior for the
temperature dependence of the 13C and 45Sc data. Combined with spectral data
from Magic Angle Spinning (MAS) NMR, the measurements can be interpreted to
mean the motion of the encapsulated Sc3N molecule is independent of that of the
C80 cage, although this requires the similar temperature dependence of the 13C
and 45Sc spin-lattice relaxation times to be coincidental. For the Sc3N to be
fixed to the C80 cage, one must overcome the symmetry breaking effect this has
on the Sc3N@C80 system since this would result in more than the observed two
13C lines.
