  We consider the problem of the validity of a statistical mechanical
description of two-site entanglement in an infinite spin chain described by the
XY model Hamiltonian. We show that the two-site entanglement of the state,
evolved from the initial equilibrium state, after a change of the magnetic
field, does not approach its equilibrium value. This suggests that two-site
entanglement, like (single-site) magnetization, is a nonergodic quantity in
this model. Moreover we show that these two nonergodic quantities behave in a
complementary way.
