  We present the first observations at medium-hard X-rays with ASCA in 1998
August--November of four Flat Spectrum Radio Quasars (FSRQs), characterized by
unusually steep soft X-ray spectra (photon index, \Gamma_{0.2-2.4 keV} \sim
2-2.5), as previously measured with ROSAT. Such steep X-ray slopes are similar
to those observed in synchrotron-dominated BL Lacs and are unexpected in the
context of the recent blazar paradigm, where sources with strong emission lines
(such as FSRQs) are dominated in soft X-rays by a flat inverse Compton tail. We
find that the ASCA spectra of the four FSRQs are consistent with a power law
model with \Gamma_{2-10 keV} \sim 1.8, flatter than their ROSAT spectra. This
indicates the onset of an inverse Compton component at energies \gtrsim 2 keV,
in agreement with the blazar unification scheme. However, these objects are
still anomalous within the blazar class for their steep soft X-ray continua
which, together with non-simultaneous data at longer wavelengths, hint at the
possibility that the synchrotron emission extends to soft X-rays. This would
imply an anomalously high synchotron peak frequency for a quasar with luminous
broad lines, challenging current blazar unification schemes. Alternatively, a
plausible explanation for the steep optical-to-soft X-ray continua of the four
FSRQs is thermal emission from the accretion disk, similar to the blazars
3C~273 and 3C~345. In the Appendix, we present fits to the SIS data in an
effort to contribute to the ongoing calibration of the the time-dependence of
the SIS response at low energies.
