  The interaction of electrons with a periodic potential of atoms in
crystalline solids gives rise to band structure. The band structure of existing
materials can be measured by photoemission spectroscopy and accurately
understood in terms of the tight-binding model, however not many experimental
approaches exist that allow to tailor artificial crystal lattices using a
bottom-up approach. The ability to engineer and study atomically crafted
designer materials by scanning tunnelling microscopy and spectroscopy (STM/STS)
helps to understand the emergence of material properties. Here, we use atom
manipulation of individual vacancies in a chlorine monolayer on Cu(100) to
construct one- and two-dimensional structures of various densities and sizes.
Local STS measurements reveal the emergence of quasiparticle bands, evidenced
by standing Bloch waves, with tuneable dispersion. The experimental data are
understood in terms of a tight-binding model combined with an additional
broadening term that allows an estimation of the coupling to the underlying
substrate.
