  There is a close relation between the problems of second layer nucleation in
epitaxial crystal growth and chemical surface reactions, such as hydrogen
recombination, on interstellar dust grains. In both cases standard rate
equation analysis has been found to fail because the process takes place in a
confined geometry. Using scaling arguments developed in the context of second
layer nucleation, I present a simple derivation of the hydrogen recombination
rate for small and large grains. I clarify the reasons for the failure of rate
equations for small grains, and point out a logarithmic correction to the
reaction rate when the reaction is limited by the desorption of hydrogen atoms
(the second order reaction regime).
