  Nuclear Magnetic Resonance (NMR) was successfully employed to test several
protocols and ideas in Quantum Information Science. In most of these
implementations the existence of entanglement was ruled out. This fact
introduced concerns and questions about the quantum nature of such bench tests.
In this article we address some issues related to the non-classical aspects of
NMR systems. We discuss some experiments where the quantum aspects of this
system are supported by quantum correlations of separable states. Such
quantumness, beyond the entanglement-separability paradigm, is revealed via a
departure between the quantum and the classical versions of information theory.
In this scenario, the concept of quantum discord seems to play an important
role. We also present an experimental implementation of an analogous of the
single-photon Mach-Zehnder interferometer employing two nuclear spins to encode
the interferometric paths. This experiment illustrate how non-classical
correlations of separable states may be used to simulate quantum dynamics. The
results obtained are completely equivalent to the optical scenario, where
entanglement (between two field modes) may be present.
