  We present a thermodynamic analysis of the driving forces for intercalation
and conversion reactions in battery cathodes across a range of possible working
ion, transition metal, and anion chemistries. Using this body of results, we
analyze the importance of polymorph selection as well as chemical composition
on the ability of a host cathode to support intercalation reactions. We find
that the accessibility of high energy charged polymorphs in oxides generally
leads to larger intercalation voltages favoring intercalation reactions,
whereas sulfides and selenides tend to favor conversion reactions. Furthermore,
we observe that Cr-containing cathodes favor intercalation more strongly than
those with other transition metals. Finally, we conclude that two-electron
reduction of transition metals (as is possible with the intercalation of a $2+$
ion) will favor conversion reactions in the compositions we studied.
