  Stellar mass binary black holes of unknown formation mechanism have been
observed, motivating new methods for distinguishing distinct black hole
populations. This work explores how the orbital eccentricity of stellar mass
binary black holes is a viable conduit for making such distinctions. Four
different production mechanisms, and their corresponding eccentricity
distributions, are studied in the context of an experimental landscape composed
of mHz (LISA), dHz (DECIGO), and Hz (LIGO) range gravitational wave detectors.
We expand on prior work considering these effects at fixed population
eccentricity. We show that a strong signal corresponding to subsets of
eccentric populations is effectively hidden from the mHz and dHz range
gravitational wave detectors without the incorporation of high eccentricity
waveform templates. Even with sufficiently large eccentricity templates, we
find dHz range experiments with a LISA-like level of sensitivity are unlikely
to aid in distinguishing different populations. We consider the degree to which
a mHz range detector like LISA can differentiate among black hole populations
independently and in concert with follow-up merger detection for binaries
coalescing within a 10 year period. We find that mHz range detectors, with only
$e < 0.01$ (nearly circular) sensitivity, can successfully discern eccentric
sub-populations except when attempting to distinguish very low eccentricity
distributions. In these cases where $e < 0.01$ sensitivity is insufficient, we
find that the increase in event counts resulting from $e < 0.1$ sensitivity
provides a statistically significant signal for discerning even these low
eccentricity sub-populations. While improvements offered by $e<0.1$ sensitivity
can be generally increased by $\mathcal{O}(1)$ factors with $e<0.4$
sensitivity, going beyond this in eccentricity sensitivity provides negligible
enhancement.
