  Miniaturization of electronic devices aims at manufacturing ever smaller
products, from mesoscopic to nanoscopic sizes. This trend is challenging
because the increased levels of dissipated power demands a better understanding
of heat transport in small volumes. A significant amount of the consumed energy
is transformed into heat and dissipated to the environment. Thermoelectric
materials offer the possibility to harness dissipated energy and make devices
less energy-demanding. Heat-to-electricity conversion requires materials with a
strongly suppressed thermal conductivity but still high electronic conduction.
Nanowires can meet nicely these two requirements because enhanced phonon
scattering at the surface and defects reduces the lattice thermal conductivity
while electric conductivity is not deteriorated, leading to an overall
remarkable thermoelectric efficiency. Therefore, nanowires are regarded as a
promising route to achieving valuable thermoelectric materials at the
nanoscale. In this paper, we present an overview of key experimental and
theoretical results concerning the thermoelectric properties of nanowires. The
focus of this review is put on the physical mechanisms by which the efficiency
of nanowires can be improved. Phonon scattering at surfaces and interfaces,
enhancement of the power factor by quantum effects and topological protection
of electron states to prevent the degradation of electrical conductivity in
nanowires are thoroughly discussed.
