  Atom-surface interactions can significantly modify the intensity and phase of
atom de Broglie waves diffracted by a silicon nitride grating. This affects the
operation of a material grating as a coherent beam splitter. The phase shift
induced by diffraction is measured by comparing the relative phases of serveral
interfering paths in a Mach-Zehnder Na atom interferometer formed by three
material gratings. The values of the diffraction phases are consistent with a
simple model which includes a van der Waals atom-surface interaction between
the Na atoms and the silicon nitride grating bars.
