  The emission from neutral hydrogen (HI) clouds in the post-reionization era
(z < 6), too faint to be individually detected, is present as a diffuse
background in all low frequency radio observations below 1420 MHz. The angular
and frequency fluctuations of this radiation (~ 1 mK) is an important future
probe of the large scale structures in the Universe. We show that such
observations are a very effective probe of the background cosmological model
and the perturbed Universe. In our study we focus on the possibility of
determining the redshift space distortion parameter, coordinate distance and
its derivative with redshift. Using reasonable estimates for the observational
uncertainties and configurations representative of the ongoing and upcoming
radio interferometers, we predict parameter estimation at a precision
comparable with supernova Ia observations and galaxy redshift surveys, across a
wide range in redshift that is only partially accessed by other probes. Future
HI observations of the post-reionization era present a new technique,
complementing several existing one, to probe the expansion history and to
elucidate the nature of the dark energy.
