  Based on crystal engineering and density functional theory DFT calculations a
transformational pathway is proposed from qtz (quartz-based) topology
characterized by distorted tetrahedra to dia (diamond-like) regular tetrahedra
topology. The protocol consists of carbon insertions into orthorhombic (space
group P222, No. 16) within C5, C6, and C7, leading to ultimate C8 identified as
diamond-like. The induced structural and physical changes are assessed with
elastic properties pointing to ultra hardness, larger for qtz-C6 than dia-C8,
whilst intermediate C7 is compressible due to its diamond-defective structure.
The dynamic stability was shown from the phonons, and thermodynamic quantities
as the specific heat CV was addressed in comparison with diamond experimental
data. The electronic band structures reveal semi-conducting C6, metallic C7
characterized by diamond-defect structure, and insulating C8.
