  The analysis of the total kinetic energy release (TKER) of the photofragments
pyrrolyl + H-atom formed in the photodissociation of pyrrole in the low-lying
state $^1\!A_2(\pi \sigma^*)$ is presented. The TKER distributions contain
complementary and often more precise information on the fragmentation process
than the broad diffuse absorption spectra. The distributions are calculated
quantum mechanically for the diabatic state $^1\!A_2(\pi \sigma^*)$ either
isolated or coupled to the ground electronic state at an exit channel conical
intersection. The calculations use the novel ab initio quasi-diabatic potential
energy matrix constructed in paper I. The approximate overlap integral-based
adiabatic mapping approach is introduced with which the quantum mechanical TKER
distributions can be efficiently and accurately reproduced. Finally, the
calculated TKERs are compared with the experimental results. The main features
of the measured vibrationally resolved distributions are reproduced, and the
spectral peaks are assigned and interpreted in detail.
