  We report a neutron and Raman scattering study of a single-crystal of
La(2)CuO(4.05) prepared by high temperature electrochemical oxidation. Elastic
neutron scattering measurements show the presence of two phases, corresponding
to the two edges of the first miscibility gap, all the way up to 300 K. An
additional oxygen redistribution, driven by electronic energies, is identified
at 250 K in Raman scattering (RS) experiments by the simultaneous onset of
two-phonon and two-magnon scattering, which are fingerprints of the insulating
phase. Elastic neutron scattering measurements show directly an
antiferromagnetic ordering below a N\'eel temperature of T_N =210K. The opening
of the superconducting gap manifests itself as a redistribution of electronic
Raman scattering below the superconducting transition temperature, T_c = 24K. A
pronounced temperature-dependent suppression of the intensity of the (100)
magnetic Bragg peak has been detected below T_c. We ascribe this phenomenon to
a change of relative volume fraction of superconducting and antiferromagnetic
phases with decreasing temperature caused by a form of a superconducting
proximity effect.
