  For the first time, we systematically investigate the potential of
neutrino-nucleus neutral current interactions with $^{13}$C to identify the
origin of the 5 MeV bump observed in reactor anti-neutrino spectra in the
inverse beta decay process. The distinctive signal is obtained from the
de-excitation of $^{13}$C$^*$ into the ground state emitting a 3.685 MeV photon
in various liquid scintillator detectors. Such an interaction predominantly
occurs for the reactor anti-neutrinos within the energy range coinciding with
the 5 MeV bump. For a detector that has a capability of 95\% level photon and
electron separation and small thorium contamination below $5 \times 10^{-17}$
gr/gr located in a site with an overburden of about a few hundred m.w.e, such
as the location of near detectors of RENO and Daya Bay will have a great
sensitivity to resolve the 5 MeV bump. In addition, we propose a novel approach
to track the time evolution of reactor isotopes by analyzing our $^{13}$C
signal shedding light on the contributions from $^{235}$U or $^{239}$Pu to the
observed bump. This provides an extra powerful tool in both discriminating the
flux models and testing any new physics possibilities for the 5 MeV bump at
3$\sigma$ to 5$\sigma$ level with much less systematic uncertainties and
assuming 10 kt.year of data collection. Our detector requirements are
realistic, aligning well with recent studies conducted for existing or
forthcoming experiments.
