  We have investigated the behaviour of the work function of La1.2Sr1.8Mn2O7 as
a function of temperature by means of photoemission. We found a decrease of 55
+/- 10 meV in going from 60 K to just above the Curie temperature (125 K) of
the sample. Above T_C the work function appears to be roughly constant. Our
results are exactly opposite to the work function changes calculated from the
double-exchange model by Furukawa, but are consistent with other measurements.
The disagreement with double-exchange can be explained using a general
thermodynamic relation valid for second order transitions and including the
extra processes involved in the manganites besides double-exchange interaction.
