  A study of an impurity driven phase-transition into a magnetically ordered
state in the spin-liquid Haldane chain compound PbNi2V2O8 is presented. Both,
macroscopic magnetization as well as 51V nuclear magnetic resonance (NMR)
measurements reveal that the spin nature of dopants has a crucial role in
determining the stability of the induced long-range magnetic order. In the case
of nonmagnetic (Mg2+) doping on Ni2+ spin sites (S=1) a metamagnetic transition
is observed in relatively low magnetic fields. On the other hand, the magnetic
order in magnetically (Co2+) doped compounds survives at much higher magnetic
fields and temperatures, which is attributed to a significant anisotropic
impurity-host magnetic interaction. The NMR measurements confirm the predicted
staggered nature of impurity-liberated spin degrees of freedom, which are
responsible for the magnetic ordering. In addition, differences in the
broadening of the NMR spectra and the increase of nuclear spin-lattice
relaxation in doped samples, indicate a diverse nature of electron spin
correlations in magnetically and nonmagnetically doped samples, which begin
developing at rather high temperatures with respect to the antiferromagnetic
phase transition.
