  In the ac polarized Raman spectra of NaV2O5 we have found anomalous phonon
broadening, and an energy shift of the low-frequency mode as a function of the
temperature. These effects are related to the breaking of translational
symmetry, caused by electrical disorder that originates from the fluctuating
nature of the V {4.5+} valence state of vanadium. The structural correlation
length, obtained from comparisons between the measured and calculated Raman
scattering spectra, diverges at T< 5 K, indicating the existence of the
long-range charge order at very low temperatures, probably at T=0 K.
