  Localized surface plasmon resonances possess very interesting properties for
a wide variety of sensing applications. In many of the existing applications
only the intensity of the reflected or transmitted signals is taken into
account, while the phase information is ignored. At the center frequency of a
(localized) surface plasmon resonance, the electron cloud makes the transition
between in- and out-of-phase oscillation with respect to the incident wave.
Here we show that this information can experimentally be extracted by
performing phase-sensitive measurements, which result in linewidths that are
almost one order of magnitude smaller than those for intensity based
measurements. As this phase transition is an intrinsic property of a plasmon
resonance, this opens up many possibilities for boosting the figure of merit
(FOM) of refractive index sensing by taking into account the phase of the
plasmon resonance. We experimentally investigated this for two model systems:
randomly distributed gold nanodisks and gold nanorings on top of a continuous
gold layer and a dielectric spacer and observed FOM values up to 8.3 and 16.5
for the respective nanoparticles.
