  Molecular segregation in methanol-water mixtures is studied across a wide
concentration range as a function of temperature and pressure. Cluster
distributions obtained from both neutron diffraction and molecular dynamics
simulations point to significantly enhanced segregation as the mixtures are
cooled or compressed. This evolution toward greater molecular heterogenity in
the mixture accounts for the observed changes in the water-water radial
distribution function and there are indications also of a change in the
topology of the water clusters. The observed behavior is consistent with an
approach to an upper critical solution point. Such a point would appear to be
``hidden'' below the freezing line, thereby precluding observation of the
two-fluid region.
