  PEP-PEO block copolymer micelles offer the possibility to investigate phase
behaviour and interactions of star polymers (ultra-soft colloids). A star-like
architecture is achieved by an extremely asymmetric block ratio (1:20).
Micellar functionality f can be smoothly varied by changing solvent composition
(interfacial tension). Structure factors obtained by SANS can be quantitatively
described in terms of an effective potential developed for star polymers. The
experimental phase diagram reproduces to a high level of accuracy the predicted
liquid/solid transition. Whereas for intermediate f a bcc phase is observed,
for high f the formation of a fcc phase is preempted by glass formation.
