  We present results of our dense spectroscopic monitoring of Nova V5668 Sgr.
Starting on March 19 in 2015, only a few days after discovery, we have obtained
a series of spectra with the TIGRE telescope and its HEROS echelle spectrograph
which offers a resolution of R = 20,000 and covers the optical wavelength range
from 3800 to 8800 {\AA}. We performed a line identification of the discernible
features for four spectra which are representative for the respective phases in
the light curve evolution of that nova. By simultaneously analysing the
variations in the visual light curve and the corresponding spectra of Nova
V5668 Sgr, we found that during the declining phases of the nova the absorption
features in all hydrogen and many other lines had shifted to higher expansion
velocities of -2000 km s^-1. Conversely, during the rise towards the following
maximum, these observed absorption features had returned to lower expansion
velocities.We found that the absorption features of some Fe II lines displayed
the same behaviour, but in addition disappeared for a few days during some
declining phases. Features of several N I lines also disappeared while new N II
lines appeared in emission for a few days during some of the declining phases
of the light curve of Nova V5668 Sgr. The shape of the emission features is
changing during the evolution and shows a clear double peak structure after the
deep minimum.
