  We study the pre-K-edge structure of the resonant X-ray scattering for
forbidden reflections (anomalous scattering) in LaMnO3, using the band
calculation based on the local density approximation. We find a two-peak
structure with an intensity approximately 1/100 of that of the main peak. This
originates from a mixing of 4p states of Mn to 3d states of neighboring Mn
sites. The effect is enhanced by an interference with the tail of the main
peak. The effect of the quadrupole transition is found to be one order of
magnitude smaller than that of the dipole transition, modifying slightly the
azimuthal-angle dependence.
