  We report on the lattice evolution of BiFeO3 as function of temperature using
far infrared emissivity, reflectivity, and X-ray absorption local structure. A
power law fit to the lowest frequency soft phonon in the magnetic ordered phase
yields an exponent {\beta}=0.25 as for a tricritical point. At about 200 K
below TN~640 K it ceases softening as consequence of BiFeO3 metastability. We
identified this temperature as corresponding to a crossover transition to an
order-disorder regime. Above ~700 K strong band overlapping, merging, and
smearing of modes are consequence of thermal fluctuations and chemical
disorder. Vibrational modes show band splits in the ferroelectric phase as
emerging from triple degenerated species as from a paraelectric cubic phase
above TC~1090 K. Temperature dependent X-ray absorption near edge structure
(XANES) at the Fe K-edge shows that lower temperature Fe3+ turns into Fe2+.
While this matches the FeO w\"ustite XANES profile, the Bi LIII-edge downshift
suggests a high temperature very complex bond configuration at the distorted A
perovskite site. Overall, our local structural measurements reveal high
temperature defect-induced irreversible lattice changes, below, and above the
ferroelectric transition, in an environment lacking of long-range coherence. We
did not find an insulator to metal transition prior to melting.
