  The Zeeman splitting of the donor spectra in cubic- and hexagonal-GaN are
studied using an effective mass theory approach. Soft-core pseudopotentials
were used to describe the chemical shift of the different substitutional
dopants. The donor ground states calculated range from 29.5 to 33.7 meV, with
typically 1 meV higher binding in the hexagonal phase. Carbon is found to
produce the largest donor binding energy. The ionization levels and excited
states are in excellent agreement with Hall and optical measurements, and
suggest the presence of residual C in recent experiments.
