  The organic materials (TMTSF)2X are unique unconventional superconductors
with archetypal quasi-one-dimensional (Q1D) electronic structures. Here, based
on our comprehensive field-angle-resolved calorimetry of (TMTSF)2ClO4, we
succeeded in mapping the nodal gap structure for the first time in Q1D systems,
by discriminating between the Fermi wavevectors and Fermi velocities. In
addition, the thermodynamic phase diagrams of (TMTSF)2ClO4 for all principal
field directions are obtained. These findings, providing strong evidence of
nodal spin-singlet superconductivity, serves as solid bases for further
elucidation of anomalous superconducting phenomena in (TMTSF)2X.
