  We present a combined theoretical and experimental study of the high-pressure
behavior of thallium. X-ray diffraction experiments have been carried out at
room temperature up to 125 GPa using diamond-anvil cells, nearly doubling the
pressure range of previous experiments. We have confirmed the hcp-fcc
transition at 3.5 GPa and determined that the fcc structure remains stable up
to the highest pressure attained in the experiments. In addition, HP-HT
experiments have been performed up to 8 GPa and 700 K by using a combination of
x-ray diffraction and a resistively heated diamond-anvil cell. Information on
the phase boundaries is obtained, as well as crystallographic information on
the HT bcc phase. The equation of state for different phases is reported. Ab
initio calculations have also been carried out considering several potential
high-pressure structures. They are consistent with the experimental results and
predict that, among the structures considered in the calculations, the fcc
structure of thallium is stable up to 4.3 TPa. Calculations also predict the
post-fcc phase to have a close-packed orthorhombic structure above 4.3 TPa.
