  Equilibration of N/Z in binary breakup of an excited and transiently deformed
projectile-like fragment (PLF*), produced in peripheral collisions of 64Zn +
27Al, 64Zn, 209Bi at E/A = 45 MeV, is examined. The composition of emitted
light fragments (3<=Z<=6) changes with the decay angle of the PLF*. The most
neutron-rich fragments observed are associated with a small rotation angle. A
clear target dependence is observed with the largest initial N/Z correlated
with the heavy, neutron-rich target. Using the rotation angle as a clock, we
deduce that N/Z equilibration persists for times as long as 3-4 zs (1zs = 1 x
10^-21 s = 300 fm/c). The rate of N/Z equilibration is found to depend on the
initial neutron gradient within the PLF*.
