  We report the observation of a change in Fermi surface topology of
Bi2Sr2CaCu2O8 with doping. By collecting high statistics ARPES data from
moderately and highly overdoped samples and dividing the data by the Fermi
function, we answer a long standing question about the Fermi surface shape of
Bi2Sr2CaCu2O8 close to the (pi,0) point. For moderately overdoped samples
(Tc=80K) we find that both the bonding and antibonding sheets of the Fermi
surface are hole-like. However for a doping level corresponding to Tc=55K we
find that the antibonding sheet becomes electron-like. This change does not
directly affect the critical temperature and therefore the superconductivity.
However, since similar observations of the change of the topology of the Fermi
surface were observed in LSCO and Bi2Sr2Cu2O6, it appears to be a generic
feature of hole-doped superconductors. Because of bilayer splitting, though,
this doping value is considerably lower than that for the single layer
materials, which again argues that it is unrelated to Tc.
