  We present a rationalization of the Raman spectra of orthorhombic and
rhombohedral, stoichiometric and doped, manganese perovskites. In particular we
study RMnO3 (R= La, Pr, Nd, Tb, Ho, Er, Y and Ca) and the different phases of
Ca or Sr doped RMnO3 compounds as well as cation deficient RMnO3. The spectra
of manganites can be understood as combinations of two kinds of spectra
corresponding to two structural configurations of MnO6 octahedra and
independently of the average structure obtained by diffraction techniques. The
main peaks of compounds with regular MnO6 octahedra, as CaMnO3, highly Ca doped
LaMnO3 or the metallic phases of Ca or Sr doped LaMnO3, are bending and tilt
MnO6 octahedra modes which correlate to R-O(1) bonds and Mn-O-Mn angles
respectively. In low and optimally doped manganites, the intensity and width of
the broad bands are related to the amplitude of the dynamic fluctuations
produced by polaron hopping in the paramagnetic insulating regime. The
activation energy, which is proportional to the polaron binding energy, is the
measure of this amplitude. This study permits to detect and confirm the
coexistence, in several compounds, of a paramagnetic matrix with lattice
polaron together with regions without dynamic or static octahedron distortions,
identical to the ferromagnetic metallic phase. We show that Raman spectroscopy
is an excellent tool to obtain information on the local structure of the
different micro or macro-phases present simultaneously in many manganites.
