  We observe a zero-bias conductance peak (ZBCP) in the ab-plane quasiparticle
tunneling spectra of thin film grain-boundary Josephson junctions made of the
electron doped cuprate superconductor LaCeCuO. An applied magnetic field
reduces the spectral weight around zero energy and shifts it non-linearly to
higher energies consistent with a Doppler shift of the Andreev bound states
(ABS) energy. For all magnetic fields the ZBCP appears simultaneously with the
onset of superconductivity. These observations strongly suggest that the ZBCP
results from the formation of ABS at the junction interfaces, and,
consequently, that there is a sign change in the symmetry of the
superconducting order parameter of this compound consistent with a d-wave
symmetry.
