  The interface of complex oxide heterostructures sets the stage for various
electronic and magnetic phenomena. Many of these collective effects originate
from the precise structural arrangement at the interface that in turn governs
local spin- and charge interactions. Currently, interfacial straining, so the
naturally evolving compressive or tensile strain by mismatch of the neighboring
lattices, is the most common route towards engineering collective material
properties -- yet, significant progress might require exploration of entirely
new approaches towards interface correlations. In this work, we turn the page
by looking at the interface of a perfectly relaxed, unstrained heterostructure,
where we identify a highly ordered Moire lattice at an inherently disordered
SrTiO$_3$ (STO) - LSAT interface. Using high-resolution reciprocal space
mapping via synchrotron based X-Ray diffraction, we find long-ranged ordered
supercells of 106/107 unit cells of STO/LSAT, caused by lattice relaxation
through high-temperature annealing. Model calculations confirm the
experimentally observed scattering phenomena, showing that cross-interfacial
bonding is locally different at the Moire-overlap points. Notably, the presence
of such super-ordered structures in the family of 2D electron gas systems sets
the ideal conditions for Moire-motif tuned plasmonic responses and
ferroelectric super-crystallinity and opens up the possibility to novel
interface functionalities in these simple perovskites.
