  Full quantum dynamics calculations have been carried out for the ionic
reaction 4He2+ + 3He and state-to-state reactive probabilities have been
obtained using both a time-dependent (TD) and a time-independent (TI) approach.
An accurate ab-initio potential energy surface has been employed for the
present quantum dynamics and the two sets of results are shown to be in
agreement with each other. The results for zero total angular momentum suggest
a marked presence of atom exchange (isotopic replacement) reaction with
probabilities as high as 60%. The reaction probabilities are only weakly
dependent on the initial vibrational state of the reactants while they are
slightly more sensitive to the degree of rotational excitation. A brief
discussion of the results for selected higher total angular momentum values is
also presented, while the l-shifting approximation [1] has been used to provide
estimates of the total reaction rates for the title process. Such rates are
found to be large enough to possibly become experimentally accessible.
