  Using first-principles density-functional calculations, we address the
magnetic properties of the ferromagnet/antiferromagnet
La(0.67)Sr(0.33)MnO3/BiFeO3(001) heterojunctions, and investigate possible
driving mechanisms for a ferromagnetic (FM) interfacial ordering of the Fe
spins recently observed experimentally. We find that the chemically abrupt
defect-free La(0.67)Sr(0.33)MnO3/BiFeO3(001) heterojunction displays, as ground
state, an ordering with compensated Fe spins. Cation Fe/Mn intermixing at the
interface tends to favour, instead, a FM interfacial order of the Fe spins,
coupled antiferromagnetically to the bulk La(0.67)Sr(0.33)MnO3 spins, as
observed experimentally. Such trends are understood based on a model
description of the energetics of the exchange interactions.
