  We report on the detection of vinyl cyanide (CH2CHCN), cyanomethyl radical
(CH2CN), methylacetylene (CH3CCH) and thioformaldehyde (H2CS) in the C-rich
star IRC +10216. These species, which are all known to exist in dark clouds,
are detected for the first time in the circumstellar envelope around an AGB
star. The four molecules have been detected trough pure rotational transitions
in the course of a 3 mm line survey carried out with the IRAM 30-m telescope.
The molecular column densities are derived by constructing rotational
temperature diagrams. A detailed chemical model of the circumstellar envelope
is used to analyze the formation of these molecular species. We have found
column densities in the range 5 x 10^(12)- 2 x 10^(13) cm^(-2), which
translates to abundances relative to H2 of several 10^(-9). The chemical model
is reasonably successful in explaining the derived abundances through gas phase
synthesis in the cold outer envelope. We also find that some of these
molecules, CH2CHCN and CH2CN, are most probably excited trough infrared pumping
to excited vibrational states. The detection of these species stresses the
similarity between the molecular content of cold dark clouds and C-rich
circumstellar envelopes. However, some differences in the chemistry are
indicated by the fact that in IRC +10216 partially saturated carbon chains are
present at a lower level than those which are highly unsaturated, while in
TMC-1 both types of species have comparable abundances.
