  In this paper we study the electromagnetic fields generated by a Killing
vector field in vacuum space-times (Papapetrou fields). The motivation of this
work is to provide new tools for the resolution of Maxwell's equations as well
as for the search, characterization, and study of exact solutions of Einstein's
equations. The first part of this paper is devoted to an algebraic study in
which we give an explicit and covariant procedure to construct the principal
null directions of a Papapetrou field. In the second part, we focus on the main
differential properties of the principal directions, studying when they are
geodesic, and in that case we compute their associated optical scalars. With
this information we get the conditions that a principal direction of the
Papapetrou field must satisfy in order to be aligned with a multiple principal
direction of the Weyl tensor in the case of algebraically special vacuum
space-times. Finally, we illustrate this study using the Kerr, Kasner and pp
waves space-times.
