  The pressure behavior of the absorption edge of PbWO4 was studied up to 15.3
GPa. It red-shifts at -71 meV/GPa below 6.1 GPa, but at 6.3 GPa the band-gap
collapses from 3.5 eV to 2.75 eV. From 6.3 GPa to 11.1 GPa, the absorption edge
moves with a pressure coefficient of -98 meV/GPa, undergoing additional changes
at 12.2 GPa. The results are discussed in terms of the electronic structure of
PbWO4 which attribute the behavior of the band-gap to changes in the local
atomic structure. The changes observed at 6.3 GPa and 12.2 GPa are attributed
to phase transitions.
