  Virtually all detailed gas-phase models of the chemistry of dense
interstellar clouds exclude polycyclic aromatic hydrocarbons (PAH's). This
omission is unfortunate because from the few studies that have been done on the
subject, it is known that the inclusion of PAH's can affect the gas-phase
chemistry strongly. We have added PAH's to our network to determine the role
they play in the chemistry of cold dense cores. In the models presented here,
we include radiative attachment to form PAH-, mutual neutralization between PAH
anions and small positively-charged ions, and photodetachment. We also test the
sensitivity of our results to changes in the size and abundance of the PAH's.
Our results confirm that the inclusion of PAH's changes many of the calculated
abundances of smaller species considerably. In TMC-1, the general agreement
with observations is significantly improved contrary to L134N. This may
indicate a difference in PAH properties between the two regions. With the
inclusion of PAH's in dense cloud chemistry, high-metal elemental abundances
give a satisfactory agreement with observations. As a result, we do not need to
decrease the observed elemental abundances of all metals and we do not need to
vary the elemental C/O ratio in order to produce large abundances of carbon
species in TMC-1 (CP).
