  The origin and structure of self assembled chiral liquid crystalline Blue
Phase III (BPIII) have remained an enigma despite efforts spreading over
decades. We report here an off-lattice NVT molecular dynamics simulation study
of a system of polar chiral ellipsoidal molecules, which spontaneously exhibits
BPIII , considering coarse-grained attractive-repulsive pair interaction
appropriate for anisotropic liquid crystal mesogens. We have observed that
suitable selection of chiral and dipolar strengths not only gives rise to
thermodynamically stable BPIII but novel Smectic and Bilayered BPIII as well.
Further, we have demonstrated that occurence of BPIII and its layered
counterparts depend crucially on molecular elongation.
