  Precise fitting of the experimental data analyzed separately for each
identified crystallographic phase alpha, omega, beta, beta prime and beta
double prime yield different bulk moduli Bo and Bo prime and different zero
pressure volumes (Vo) than those claimed in the literature. Special attention
is given to the bcc phases indicating cascading transitions beta to beta prime
to beta double prime associated with volume collapse. The present analysis
reveals the existence of a bcc-beta prime phase which is reported here for the
first time. It is shown that the first order volume collapse at about 58GPa
beta to beta prime is followed by a moderate transition to the bcc-beta double
prime phase. The beta prime phase is stable up to 110GPa. Above 110GPa the
bcc-beta double prime is dominant and stable up to about 220GPa. The derived
bcc-double prime bulk moduli are confirmed by the Lindemann-Gilvarry criterion
as Bo and Bo prime simultaneously fit both the P-V EOS and the P-T melting data
points (combined approach). The calculated melting curve of elemental Zr,
taking into account the thermal pressure Poth shift and the elevated melting
Tmo prime at Poth , yield very good fit of the experimental melting data
permitting a safe extrapolation to high pressures and temperatures. In
addition, the combined approach lead to direct determination of the Greuneisen
parameter gammao, needed for applying the approximated Lindemann-Gilvarry
melting formula.
