  The dependence of the critical current density Jc on hydrostatic pressure to
0.6 GPa is determined for a single 25-degree [001]-tilt grain boundary in a
bicrystalline ring of nearly optimally doped melt-textured YBa2Cu3Ox. Jc is
found to increase rapidly under pressure at +20 %/GPa. A new diagnostic method
is introduced (pressure-induced Jc relaxation) which reveals a sizeable
concentration of vacant oxygen sites in the grain boundary region. Completely
filling such sites with oxygen anions should lead to significant enhancements
in Jc.
