  Angle-resolved photoelectron spectroscopy, supplemented by theoretical
calculations has been applied to study the electronic structure of
heavy-fermion material CeFePO, a homologue to the Fe-based high-temperature
superconductors, and CeFeAs_0.7P_0.3O, where the applied chemical pressure
results in a ferromagnetic order of the 4f moments. A comparative analysis
reveals characteristic differences in the Fe-derived band structure for these
materials, implying a rather different hybridization of valence electrons to
the localized 4f orbitals. In particular, our results suggest that the
ferromagnetism of Ce moments in CeFeAs_0.7P_0.3O is mediated mainly by Fe
3d_xz/yz orbitals, while the Kondo screening in CeFePO is instead due to a
strong interaction of Fe 3d_3z^2-r^2 orbitals.
