  We present a comparative study of our valence band photoemission results on
Nb2Pd1.2Se5 and Nb2Pd0.95S5 superconductors which is supported by our DFT based
electronic structure calculations. We observe that the VB spectra of both the
compounds are qualitatively similar, except slight difference in the binding
energy position of all features between the two compounds which could be the
result of different electronegativity of Se and S atom. The calculated density
of states reveal that the VB features are mainly composed of Pd Se S hybridized
states. The nature of DOS originating from the distinctly coordinated Pd atoms
is different. Further, the involvement of the various Pd 4d and Nb 4d states in
crossing of Fermi level signifies the multiband character of these compounds.
In addition, we find a temperature dependent pseudogap in Nb2Pd0.95S5 which is
absent in Nb2Pd1.2Se5.
