  In this sturdy, we determine the roles of two successive phase transitions in
the new spin-Peierls system TiOBr by electron and synchrotron X-ray diffraction
analyses. Results show an incommensurate superstructure along the h- and
k-directions between Tc1=27K and Tc2=47K, and a twofold superstructure which is
related to a spin-Peierls lattice distortion below Tc1. The diffuse scattering
observed above Tc2 indicates that a structural correlation develops at a high
temperature. We conclude that Tc2 is a second-order lock-in temperature, which
is related to the spin-Peierls lattice distortion with the incommensurate
structure, and that Tc1 is from incommensurate to commensurate phase transition
temperature accompanying the first-order spin-Peierls lattice distortion.
