  Si1-xGex/Si1-yGey/Si(100) heterostructures grown by Molecular Beam Epitaxy
(MBE) were used in order to study B surface segregation during growth and B
lattice diffusion. Ge concentration and stress effects were separated. Analysis
of B segregation during growth shows that: i) for layers in epitaxy on
(100)Si), B segregation decreases with increasing Ge concentration, i.e. with
increased compressive stress, ii) for unstressed layers, B segregation
increases with Ge concentration, iii) at constant Ge concentration, B
segregation increases for layers in tension and decreases for layers in
compression. The contrasting behaviors observed as a function of Ge
concentration in compressively stressed and unstressed layers can be explained
by an increase of the equilibrium segregation driving force induced by Ge
additions and an increase of near-surface diffusion in compressively stressed
layers. Analysis of lattice diffusion shows that: i) in unstressed layers, B
lattice diffusion coefficient decreases with increasing Ge concentration, ii)
at constant Ge concentration, the diffusion coefficient of B decreases with
compressive biaxial stress and increases with tensile biaxial stress, iii) the
volume of activation of B diffusion () is positive for biaxial stress while it
is negative in the case of hydrostatic pressure. This confirms that under a
biaxial stress the activation volume is reduced to the relaxation volume.
