  Along the line of singular value estimates for commutators by
Rochberg-Semmes, Lord-McDonald-Sukochev-Zanin and Fan-Lacey-Li, we establish
the endpoint weak Schatten class estimate for commutators of Riesz transforms
with multiplication operator $M_f$ on Heisenberg groups via homogeneous Sobolev
norm of the symbol $f$. The new tool we exploit is the construction of a
singular trace formula on Heisenberg groups, which, together with the use of
double operator integrals, allows us to bypass the use of Fourier analysis and
provides a solid foundation to investigate the singular values estimates for
similar commutators in general stratified Lie groups.
