  A new tool for modeling electrochemical kinetics is presented. An extension
of the Stochastic Simulation Algorithm framework to electrochemical systems is
proposed. The physical justifications and constraints for the derivation of a
chemical master equation are provided and discussed. The electrochemical
driving forces are included in the mathematical framework, and equations are
provided for the associated electric responses. The implementation for
potentiostatic and galvanostatic systems is presented, with results pointing
out the stochastic nature of the algorithm. The electric responses presented
are in line with the expected results from the deterministic theory.
