  We show that burning of a small mass fraction of carbon in a neutron star
ocean is thermally unstable at low accumulated masses when the ocean contains
heavy ashes from the hydrogen burning rapid proton (rp) process. The key to
early unstable ignition is the low thermal conductivity of a heavy element
ocean. The instability requires accretion rates in excess of one-tenth the
Eddington limit when the carbon mass fraction is 0.1 or less. The unstable
flashes release 10^{42} to 10^{43} ergs over hours to days, and are likely the
cause of the recently discovered large Type I X-ray bursts (so-called
``superbursts'') from six Galactic low mass X-ray binaries. In addition to
explaining the energetics, recurrence times, and durations of the superbursts,
these mixed carbon/heavy element flashes have an accretion rate dependence of
unstable burning similar to that observed. Though the instability is present at
accretion rates near Eddington, there is less contrast with the accretion
luminosity there, explaining why most detections are made at accretion rates
between 0.1 and 0.3 Eddington. Future comparisons of time dependent
calculations with observations will provide new insights into the rp process.
