  Observations of the Pluto-Charon system, acquired with the ALMA
interferometer on June 12-13, 2015, have yielded a detection of the CO(3-2) and
HCN(4-3) rotational transitions from Pluto, providing a strong confirmation of
the presence of CO, and the first observation of HCN, in Pluto's atmosphere.
The CO and HCN lines probe Pluto's atmosphere up to ~450 km and ~900 km
altitude, respectively. The CO detection yields (i) a much improved
determination of the CO mole fraction, as 515+/-40 ppm for a 12 ubar surface
pressure (ii) clear evidence for a well-marked temperature decrease (i.e.,
mesosphere) above the 30-50 km stratopause and a best-determined temperature of
70+/-2 K at 300 km, in agreement with recent inferences from New Horizons /
Alice solar occultation data. The HCN line shape implies a high abundance of
this species in the upper atmosphere, with a mole fraction >1.5x10-5 above 450
km and a value of 4x10-5 near 800 km. The large HCN abundance and the cold
upper atmosphere imply supersaturation of HCN to a degree (7-8 orders of
magnitude) hitherto unseen in planetary atmospheres, probably due to the slow
kinetics of condensation at the low pressure and temperature conditions of
Pluto's upper atmosphere. HCN is also present in the bottom ~100 km of the
atmosphere, with a 10-8 - 10-7 mole fraction; this implies either HCN
saturation or undersaturation there, depending on the precise stratopause
temperature. The HCN column is (1.6+/-0.4)x10^14 cm-2, suggesting a
surface-referred net production rate of ~2x10^7 cm-2s-1. Although HCN
rotational line cooling affects Pluto's atmosphere heat budget, the amounts
determined in this study are insufficient to explain the well-marked mesosphere
and upper atmosphere's ~70 K temperature. We finally report an upper limit on
the HC3N column density (< 2x10^13 cm-2) and on the HC15N / HC14N ratio (<
1/125).
