  We report the synthesis and characterization of Li2ZnV3O8, which is a new
Zn-doped LiV2O4 system containing only tetravalent vanadium. A Curie-Weiss
susceptibility with a Curie-Weiss temperature of <theta>CW ~214 K suggests the
presence of strong antiferromagnetic correlations in this system. We have
observed a splitting between the zero-field cooled ZFC and field cooled FC
susceptibility curves below 6 K. A peak is present in the ZFC curve around 3.5
K suggestive of spin-freezing . Similarly, a broad hump is also seen in the
inferred magnetic heat capacity around 9 K. The consequent entropy change is
only about 8% of the value expected for an ordered S = 1=2 system. This
reduction indicates continued presence of large disorder in the system in spite
of the large <theta>CW, which might result from strong geometric frustration in
the system. We did not find any temperature T dependence in our 7Li nuclear
magnetic resonance NMR shift down to 6 K (an abrupt change in the shift takes
place below 6 K) though considerable T-dependence has been found in literature
for LiV2O4- undoped or with other Zn/Ti contents. Consistent with the above
observation, the 7Li nuclear spin-lattice relaxation rate 1/T1 is relatively
small and nearly T-independent except a small increase close to the freezing
temperature, once again, small compared to undoped or 10% Zn or 20% Ti-doped
LiV2O4.
