  The origin of ultrahigh piezoelectricity in the relaxor ferroelectric
PbZn1/3Nb2/3O3-PbTiO3 was studied with an electric field applied along the
[001] direction. The zero-field rhombohedral R phase starts to follow the
direct polarization path to tetragonal symmetry via an intermediate monoclinic
M phase, but then jumps irreversibly to an alternate path involving a different
type of monoclinic distortion. Details of the structure and domain
configuration of this novel phase are described. This result suggests that
there is a nearby R-M phase boundary as found in the Pb(Ti,Zr)O3 system.
