  The formation of ultracold metastable RbCs molecules is observed in a double
species magneto-optical trap through photoassociation below the
^85Rb(5S_1/2)+^133Cs(6P_3/2) dissociation limit followed by spontaneous
emission. The molecules are detected by resonance enhanced two-photon
ionization. Using accurate quantum chemistry calculations of the potential
energy curves and transition dipole moment, we interpret the observed
photoassociation process as occurring at short internuclear distance, in
contrast with most previous cold atom photoassociation studies. The vibrational
levels excited by photoassociation belong to the 5th 0^+ or the 4th 0^-
electronic states correlated to the Rb(5P_1/2,3/2)+Cs(6S_1/2) dissociation
limit. The computed vibrational distribution of the produced molecules shows
that they are stabilized in deeply bound vibrational states of the lowest
triplet state. We also predict that a noticeable fraction of molecules is
produced in the lowest level of the electronic ground state.
