  We present a comprehensive abundance analysis of 27 heavy elements in bright
giant stars of the globular clusters M4 and M5 based on high resolution, high
signal-to-noise ratio spectra obtained with the Magellan Clay Telescope. We
confirm and expand upon previous results for these clusters by showing that (1)
all elements heavier than, and including, Si have constant abundances within
each cluster, (2) the elements from Ca to Ni have indistinguishable
compositions in M4 and M5, (3) Si, Cu, Zn, and all s-process elements are
approximately 0.3 dex overabundant in M4 relative to M5, and (4) the r-process
elements Sm, Eu, Gd, and Th are slightly overabundant in M5 relative to M4. The
cluster-to-cluster abundance differences for Cu and Zn are intriguing,
especially in light of their uncertain nucleosynthetic origins. We confirm that
stars other than Type Ia supernovae must produce significant amounts of Cu and
Zn at or below the clusters' metallicities. If intermediate-mass AGB stars or
massive stars are responsible for the Cu and Zn enhancements in M4, the similar
[Rb/Zr] ratios and (preliminary) Mg isotope ratios in both clusters may be
problematic for either scenario. For the elements from Ba to Hf, we assume that
the s- and r-process contributions are scaled versions of the solar s- and
r-process abundances. We quantify the relative fractions of s- and r-process
material for each cluster and show that they provide an excellent fit to the
observed abundances.
