  Intramolecular spin alignment in pi-conjugated molecules is studied
theoretically in a model of a Peierls-Hubbard chain coupled with two localized
spins. By means of the exact diagonalization technique, we demonstrate that a
spin singlet (S=0) to quartet (S=3/2) transition can be induced by electronic
doping, depending on the chain length, the positions of the localized spins,
and the sign of the electron-spin coupling. The calculated results provides a
theoretical basis for understanding the mechanism of spin alignment recently
observed in a diradical donor molecule.
