  We investigate frustrated antiferromagnetic Heisenberg quantum spin chains at
T=0 for S=3/2 and S=2 using the DMRG method. We localize disorder and Lifshitz
points, confirming that quantum disorder points can be seen as quantum remnants
of classical phase transitions. Both in the S=3/2 and the S=2 chain, we observe
the disappearance of effectively free S=1/2 and S=1 end spins respectively. The
frustrated spin chain is therefore a suitable system for clearly showing the
existence of free end spins S'=[S/2] also in half-integer antiferromagnetic
spin chains with S>1/2. We suggest that the first order transition found for
S=1 in our previous work is present in all frustrated spin chains with S>1/2,
characterized by the disappearance of effectively free end spins with S'=[S/2].
