  A novel Bloch-waves based one-step theory of photoemission is developed
within the augmented plane wave formalism. Implications of multi-Bloch-wave
structure of photoelectron final states for band mapping are established.
Interference between Bloch components of initial and final states leads to
prominent spectral features with characteristic frequency dispersion
experimentally observed in VSe_2 and TiTe_2. Interference effects together with
a non-free-electron nature of final states strongly limit the applicability of
the common direct transitions band mapping approach, making the tool of
one-step analysis indispensable.
