  We performed nuclear magnetic resonance (NMR) measurements to investigate the
evolution of spin-density-wave (SDW) and superconducting (SC) states upon
electron doping in CaFe_{1-x}Co_{x}AsF, which exhibits an intermediate phase
diagram between those of LaFeAsO_{1-x}F_x and Ba(Fe_{1-x}Co_x)_2As_2. We found
that homogeneous coexistence of the incommensurate SDW and SC states occurs
only in a narrow doping region around the crossover regime, which supports
S_{+-}-wave symmetry. However, only the structural phase transition survives
upon further doping, which agrees with predictions from orbital fluctuation
theory. The transitional features upon electron doping imply that both spin and
orbital fluctuations are involved in the superconducting mechanism.
