  Characterizing time delays in molecular photoionization as a function of the
ejected electron emission direction relative to the orientation of the molecule
and the light polarization axis pro-vides unprecedented insights into the
attosecond dynamics induced by extreme ultraviolet or X-ray one-photon
absorption, including the role of electronic correlation and continuum resonant
states. Here, we report completely resolved experimental and computational
angular depend-ence of single-photon ionization delays in NO molecules across a
shape resonance, relying on synchrotron radiation and time independent ab
initio calculations. The angle-dependent time delay variations of few hundreds
of attoseconds, resulting from the interference of the resonant and
non-resonant contributions to the dynamics of the ejected electron, are well
described using a multichannel Fano model where the resonance time delay is
angle-independent. Comparing these results with the same resonance computed in
e-NO+ scattering highlights the connection of photoionization delays with
Wigner scattering time delays.
