  It is shown that the proton-neutron interacting boson model (pnIBM) admits
new symmetry limits with O(12) algebra which break F-spin but preserves the
quantum number M_F. The generators of O(12) are derived and the quantum number
`v' of O(12) for a given boson number N is determined by identifying the
corresponding quasi-spin algebra. The O(12) algebra generates two symmetry
schemes and for both of them, complete classification of the basis states and
typical spectra are given. With the O(12) algebra identified, complete
classification of pnIBM symmetry limits with good M_F is established.
