  Iron-pnictides Ca(Fe1-xRhx)2As2 (x = 0, 0.035, and 0.19) were studied across
the tetragonal-orthorhombic and uncollapsed to collapsed tetragonal phase
transitions using Raman spectroscopy. The effect of the phase separation was
observed in the high-temperature phase for the first time. Two phases with the
low-spin and high-spin states of the Fe2+ ions coexist in the undoped (x = 0)
and doped (x = 0.035) samples at ambient conditions. These two phases are
present on a larger length scale and they are not limited to the local
distortions. Both phases in the undoped sample successfully undergo
tetra-to-ortho phase transitions approximately at the same temperature T0 = 160
K. In doped samples, a cascade of phase transitions is observed at temperatures
T* = 100 K and Tc = 72 K with cooling for the first time. A complex type of the
re-entrant magnetic structure is realized in the x = 0.035 sample at
temperatures below Tc, which is distinct from the usual orthorhombic twofold
one. The overdoped sample (x = 0.19) also shows phase separation at
temperatures 7 - 295 K in Raman spectra similar to these of the remnant phase.
