  We study the phase behavior of solutions consisting of positive and negative
ions of valence z to which a third ionic species of valence Z>z is added. Using
a discretized Debye-Hueckel theory, we analyze the phase behavior of such
systems for different values of the ratio Z/z. We find, for Z/z>1.934, a
three-phase coexistence region and, for Z/z>2, a closed (reentrant) coexistence
loop at high temperatures. We characterize the behavior of these ternary ionic
mixtures as function of charge asymmetry and temperature, and show the complete
phase diagrams for the experimentally relevant cases of Z/z=2 and Z/z=3,
corresponding to addition of divalent and trivalent ions to monovalent ionic
fluids, respectively.
