  In order to better understand the reconstructive ferroelectric-paraelectric
transition of Bi2WO6, which is unusual within the Aurivillius family of
compounds, we performed first principles calculations of the dielectric and
dynamical properties on two possible high-temperature paraelectic structures:
the monoclinic phase of A2/m symmetry observed experimentally and the
tetragonal phase of I4/mmm symmetry, common to most Aurivillius phase
components. Both paraelectric structures exhibits various unstable modes, which
after their condensation bring the system toward more stable structures of
lower symmetry. The calculations confirms that, starting from the paraelectric
A2/m phase at high temperature, the system must undergo a reconstructive
transition to reach the P2_1ab ferroelectric ground state.
