  We search for an infrared signature of the transiting extrasolar planet HD
209458b during secondary eclipse. Our method, which we call `occultation
spectroscopy,' searches for the disappearance and reappearance of weak spectral
features due to the exoplanet as it passes behind the star and later reappears.
We argue that at the longest infrared wavelengths, this technique becomes
preferable to conventional `transit spectroscopy'. We observed the system in
the wing of the strong nu-3 band of methane near 3.6 microns during two
secondary eclipses, using the VLT/ISAAC spectrometer at a spectral resolution
of 3300. Our analysis, which utilizes a model template spectrum, achieves
sufficient precision to expect detection of the spectral structure predicted by
an irradiated, low-opacity (cloudless), low-albedo, thermochemical equilibrium
model for the exoplanet atmosphere. However, our observations show no evidence
for the presence of this spectrum from the exoplanet, with the statistical
significance of the non-detection depending on the timing of the secondary
eclipse, which depends on the assumed value for the orbital eccentricity. Our
results reject certain specific models of the atmosphere of HD 209458b as
inconsistent with our observations at the 3-sigma level, given assumptions
about the stellar and planetary parameters.
