  The heat transfer properties of the organic molecular crystal ${\alpha}$-RDX
were studied using three phonon-based thermal conductivity models. It was found
that the widely used Peierls-Boltzmann model for thermal transport in
crystalline materials breaks down for ${\alpha}$-RDX. We show this breakdown is
due to a large degree of anharmonicity that leads to a dominance of
diffusive-like carriers. Despite being developed for disordered systems, the
Allen-Feldman theory for thermal conductivity actually gives the best
description of thermal transport. This is likely because diffusive carriers
contribute to over 95% of the thermal conductivity in ${\alpha}$-RDX. The
dominance of diffusive carriers is larger than previously observed in other
fully ordered crystalline systems. These results indicate than van-der Waals
bonded organic crystalline solids conduct heat in a manner more akin to
amorphous materials than simple atomic crystals.
