  Raman spectra of PbZr1-xTixO3 ceramics with titanium concentration varying
between 0.40 and 0.60 were measured at 7 K. By observing the
concentration-frequency dependence of vibrational modes, we identified the
boundaries among rhombohedral, monoclinic, and tetragonal ferroelectric phases.
The analysis of the spectra was made in the view of theory group analysis
making possible the assignment of some modes for the monoclinic phase.
