  Raman spectra of the MgB2 ceramic samples were measured as a function of
pressure up to 32 GPa at room temperature. The spectrum at normal conditions
contains a very broad peak at ~590 cm-1 related to the E2g phonon mode. The
frequency of this mode exhibits a strong linear dependence in the pressure
region from 5 to 18 GPa, whereas beyond this region the slope of the
pressure-induced frequency shift is reduced by about a factor of two. The
pressure dependence of the phonon mode up to ~ 5GPa exhibits a change in the
slope as well as a "hysteresis" effect in the frequency vs. pressure behavior.
These singularities in the E2g mode behavior under pressure support the
suggestion that MgB2 may undergo a pressure-induced topological electronic
transition.
