  We present our second catalog of quadruple star candidates, containing 101
systems discovered in TESS Full-Frame Image data. The targets were initially
detected as eclipsing binary stars with the help of supervised machine learning
methods applied to sectors Sectors 1 through 54. A dedicated team of citizen
scientists subsequently identified through visual inspection two sets of
eclipses following two different periods. All 101 systems presented here pass
comprehensive photocenter motion tests confirming that both sets of eclipses
originate from the target star. Some of the systems exhibit prominent eclipse
time variations suggesting dynamical interactions between the two component
binary stars. One target is an eclipsing quintuple candidate with a (2+1)+2
hierarchical configuration, such that the (2+1) subsystem produces eclipses on
the triple orbit as well. Another has recently been confirmed as the second
shortest period quadruple reported to date. This catalog provides ephemerides,
eclipse depths and durations, sample statistics, and highlights potentially
interesting targets for future studies.
