  In this paper we derive the tree-level S-matrix of the effective theory of
Goldstone bosons known as the non-linear sigma model (NLSM) from string theory.
This novel connection relies on a recent realization of tree-level
open-superstring S-matrix predictions as a double copy of super-Yang-Mills
theory with Z-theory --- the collection of putative scalar effective field
theories encoding all the alpha'-dependence of the open superstring. Here we
identify the color-ordered amplitudes of the NLSM as the low-energy limit of
abelian Z-theory. This realization also provides natural higher-derivative
corrections to the NLSM amplitudes arising from higher powers of alpha' in the
abelian Z-theory amplitudes, and through double copy also to Born-Infeld and
Volkov-Akulov theories. The Kleiss-Kuijf and Bern-Carrasco-Johansson relations
obeyed by Z-theory amplitudes thereby apply to all alpha'-corrections of the
NLSM. As such we naturally obtain a cubic-graph parameterization for the
abelian Z-theory predictions whose kinematic numerators obey the duality
between color and kinematics to all orders in alpha'.
