  Electronic correlations together with dimensional constraints lead to some of
the most fascinating properties known in condensed matter physics. As possible
candidates where these conditions are realized, semiconductor (111) surfaces
and adatom systems on surfaces have been under investigation for quite some
time. However, state-of-the-art theoretical studies on these materials that
include many body effects beyond the band picture are rare. First principles
estimates of inter-electronic Coulomb interactions for the correlated states
are missing entirely, and usually these interactions are treated as adjustable
parameters. In the present work, we report on calculations of the interaction
parameters for the group IV surface-adatom systems in the \alpha-phase series
of Si(111):\{C, Si, Sn, Pb\}. For all systems investigated, interelectronic
Coulomb interactions are indeed large compared to the kinetic energy of the
states in question. Moreover, our study reveals that intersite interactions
cannot be disregarded. We explicitly construct an extended Hubbard model for
the series of group IV surface-adatom systems on silicon, which can be used for
further many-body calculations.
