  We report the synthesis of novel edge-sharing chain systems Na(3)Cu(2)O(4)
and Na(8)Cu(5)O(10), which form insulating states with commensurate charge
order. We identify these systems as one-dimensional Wigner lattices, where the
charge order is determined by long-range Coulomb interaction and the number of
holes in the d-shell of Cu. Our interpretation is supported by X-ray structure
data as well as by an analysis of magnetic susceptibility and specific heat
data. Remarkably, due to large second neighbor Cu-Cu hopping, these systems
allow for a distinction between the (classical) Wigner lattice and the 4k_F
charge-density wave of quantum mechanical origin.
