  The nucleation and growth kinetics of highly ordered nanocrystal
superlattices during the evaporation of nanocrystal colloidal droplets was
elucidated by in situ time resolved small-angle x-ray scattering. We
demonstrated for the first time that evaporation kinetics can affect the
dimensionality of the superlattices. The formation of two-dimensional
nanocrystal superlattices at the liquid-air interface of the droplet has an
exponential growth kinetics that originates from interface "crushing".
