  Different peak trends of tiny grains carbon film have been observed under the
investigations of Raman spectroscopy and energy loss spectroscopy. Carbon films
known in nanocrystalline and ultra-nanocrystalline diamond films are
synthesized by employing microwave-based vapor deposition system. Carbon atoms
exhibit several state behaviors depending on the incurred positions of their
electrons. Different morphology of tiny grains under different chamber pressure
is related to different rate of arriving typical energies at/near substrate
surface. Those tiny grains of carbon film which evolved in graphitic state
atoms are converted to structure of smooth elements where elongation of atoms
of one-dimensional arrays is as per exerting surface format forces along
opposite poles from their centers. Such tiny grains in the film are the cause
of v1 peak under the investigation of the Raman spectrum because of the
enhanced propagation of input laser signals through channelized inter-state
electron gaps of elongated graphitic state atoms. Those tiny grains of carbon
film which evolved in fullerene state are the cause of v2 peak. The tiny grains
related to v1 peak possess a low intensity as compared to the ones which
comprised atoms having state behaviors known in their exceptional hardness.
Tiny grains representing v1 peak in the Raman spectrum are also the cause of
field emission characteristic of a carbon film. Different peak recordings were
made for the Raman at defined positions indicating a different state of carbon
atoms for a different phase of deposited tiny grains, which is in line to their
energy loss spectroscopy.
