  We measured the infrared vibrational properties of bulk and nanoparticle
WS$_2$ in order to investigate the structure-property relations in these novel
materials. In addition to the symmetry-breaking effects of local strain,
nanoparticle curvature modifies the local charging environment of the bulk
material. Performing a charge analysis on the \emph{xy}-polarized E$_{1u}$
vibrational mode, we find an approximate 1.5:1 intralayer charge difference
between the layered 2H material and inorganic fullerene-like (IF)
nanoparticles. This effective charge difference may impact the solid-state
lubrication properties of nanoscale metal dichalcogenides.
