  In this manuscript the theory and phenomena associated with the Little Effect
are introduced as the spin induced orbital dynamics of confined fermions under
strong magnetic and thermal environments. This Little Effect is considered in
details for the electron transfer reactions associated with redox processes of
Cu-Ag alloy within deionized water and for the orbital dynamics during the iron
catalyzed covalent bond rearrangements associated with amorphous carbon
conversion to diamond. Furthermore, prolong extreme conditions of 74,000 amps,
403 V, strong Lorentz compression, and thermal stresses upon this Cu-Ag- H2O
system on the basis of the Little Effect of high spin, thermally induced
orbital dynamics are predicted and demonstrated to cause the magnetically
organized reverse beta, electron capture, proton capture and neutron capture
processes for various infrequent pycnonuclear transmutations within the Cu-Ag
coil. The general experimental verification and the broad implications of this
Little Effect on chemistry are demonstrated within these two ideal systems: an
ionic case and a molecular case. The Little Effect is contrasted with the
Hedvall Effect as a dynamical phenomenon causing the kinematics of the Hedvall
Effect. The compatibility of the Little Effect with the Woodward-Hoffmann Rule
is demonstrated. The Little Effect provides greater understanding of order in
systems far from equilibrium. The implications of the Little Effect for other
interesting phenomena such as ferromagnetism, unconventional magnetism,
superparamagnetism, superconductivity, and pycnonuclear effects are concluded.
