  Raman spectroscopy reveals chemically specific information and provides
label-free insight into the molecular world. However, the signals are
intrinsically weak and call for enhancement techniques. Here, we demonstrate
Purcell enhancement of Raman scattering in a tunable high-finesse microcavity,
and utilize it for molecular diagnostics by combined Raman and absorption
imaging. Studying individual single-wall carbon nanotubes, we identify crucial
structural parameters such as nanotube radius, electronic structure and
extinction cross-section. We observe a 320-times enhanced Raman scattering
spectral density and an effective Purcell factor of 6.2, together with a
collection efficiency of 60%. Potential for significantly higher enhancement,
quantitative signals, inherent spectral filtering and absence of intrinsic
background in cavity-vacuum stimulated Raman scattering render the technique a
promising tool for molecular imaging. Furthermore, cavity-enhanced Raman
transitions involving localized excitons could potentially be used for gaining
quantum control over nanomechanical motion and open a route for molecular
cavity optomechanics.
