  We report the detection of unusual superconductivity up to 49 K in single
crystalline CaFe2As2 via electron-doping by partial replacement of Ca by
rare-earth. The superconducting transition observed suggests the possible
existence of two phases: one starting at ~ 49 K, which has a low critical field
~ 4 Oe, and the other at ~ 21 K, with a much higher critical field > 5 T. Our
observations are in strong contrast to previous reports of doping or
pressurizing layered compounds AeFe2As2 (or Ae122), where Ae = Ca, Sr or Ba. In
Ae122, hole-doping has been previously observed to generate superconductivity
with a transition temperature (Tc) only up to 38 K and pressurization has been
reported to produce superconductivity with a Tc up to 30 K. The unusual 49 K
phase detected will be discussed.
