  Graphene, a zero-gap semimetal, can be transformed into a metallic,
semiconducting or insulating state by either physical or chemical modification.
Superconductivity is conspicuously missing among these states despite
considerable experimental efforts as well as many theoretical proposals. Here,
we report superconductivity in calcium-decorated graphene achieved by
intercalation of graphene laminates that consist of well separated and
electronically decoupled graphene crystals. In contrast to intercalated
graphite, we find that Ca is the only dopant that induces superconductivity in
graphene laminates above 1.8 K among intercalants used in our experiments such
as potassium, caesium and lithium. Ca-decorated graphene becomes
superconducting at ~ 6 K and the transition temperature is found to be strongly
dependent on the confinement of the Ca layer and the induced charge carrier
concentration. In addition to the first evidence for superconducting graphene,
our work shows a possibility of inducing and studying superconductivity in
other 2D materials using their laminates.
