  The pseudospin of Dirac electrons in graphene manifests itself in a peculiar
momentum anisotropy for photo-excited electron-hole pairs. These interband
excitations are in fact forbidden along the direction of the light
polarization, and are maximum perpendicular to it. Here, we use time- and
angle-resolved photoemission spectroscopy to investigate the resulting
unconventional hot carrier dynamics, sampling carrier distributions as a
function of energy and in-plane momentum. We first show that the
rapidly-established quasi-thermal electron distribution initially exhibits an
azimuth-dependent temperature, consistent with relaxation through collinear
electron-electron scattering. Azimuthal thermalization is found to occur only
at longer time delays, at a rate that depends on the substrate and the static
doping level. Further, we observe pronounced differences in the electron and
hole dynamics in n-doped samples. By simulating the Coulomb- and
phonon-mediated carrier dynamics we are able to disentangle the influence of
excitation fluence, screening, and doping, and develop a microscopic picture of
the carrier dynamics in photo-excited graphene. Our results clarify new aspects
of hot carrier dynamics that are unique to Dirac materials, with relevance for
photo-control experiments and optoelectronic device applications.
