  By considering a metal/polymer/metal structure within a tight-binding
one-dimensional model, we have investigated the polaron formation in the
presence of an electric field. When a sufficient voltage bias is applied to one
of the metal electrodes, an electron is injected into the polymer chain, then a
self-trapped polaron is formed at a few hundreds of femtoseconds while it moves
slowly under a weak electric field (not larger than $% 1.0\times 10^4$ V/cm).
At an electric field between $1.0\times 10^4$ V/cm and $% 8.0\times 10^4$ V/cm,
the polaron is still formed, since the injected electron is bounded between the
interface barriers for quite a long time. It is shown that the electric field
applied at the polymer chain reduces effectively the potential barrier in the
metal/polymer interface.
