  We present the results of the magnetization and dielectric constant
measurements on untwinned single crystal samples of the frustrated S=1/2 chain
cuprate LiCu_2O_2. Novel magnetic phase transitions were observed. A spin flop
transition of the spiral spin plane was observed for the field orientations
H||a,b. The second magnetic transition was observed at H~15 T for all three
principal field directions. This high field magnetic phase is discussed as a
collinear spin-modulated phase which is expected for an S=1/2 nearest-neighbor
ferromagnetic and next-nearest-neighbor antiferromagnetic chain system.
