  We report synthesis and superconductivity at 3.7K in PrO0.5F0.5BiS2. The
newly discovered material belongs to the layered sulfide based REO0.5F0.5BiS2
compounds having ZrCuSiAs type structure. The bulk polycrystalline compound is
synthesized by vacuum encapsulation technique at 7800C in single step. Detailed
structural analysis has shown that the as synthesized PrO0.5F0.5BiS2 is
crystallized in tetragonal P4/nmm space group with lattice parameters a =
4.015(5) {\AA}, c = 13.362(4) {\AA}. Bulk superconductivity is observed in
PrO0.5F0.5BiS2 below 4K from magnetic and transport measurements. Electrical
transport measurements showed superconducting transition temperature (Tc) onset
at 3.7K and Tc ({\rho}=0) at 3.1K. Hump at Tc related to superconducting
transition is not observed in heat capacity measurement and rather a
Schottky-type anomaly is observed at below ~6K. The compound is slightly
semiconducting in normal state. Isothermal magnetization (MH) exhibited typical
type II behavior with lower critical field (Hc1) of around 8Oe.
