  We study neutrino emission from direct Urca processes in pion condensed quark
matter. In compact stars with high baryon density, the emission is dominated by
the gapless modes of the pion condensation which leads to an enhanced
emissivity. While for massless quarks the enhancement is not remarkable, the
emissivity is significantly larger and the cooling of the condensed matter is
considerably faster than that in normal quark matter when the mass difference
between $u$- and $d$-quarks is sizable.
