  Low-temperature scanning tunneling microscopy and spectroscopy are employed
to investigate electron tunneling from a C60-terminated tip into a Cu(111)
surface. Tunneling between a C60 orbital and the Shockley surface states of
copper is shown to produce negative differential conductance (NDC) contrary to
conventional expectations. NDC can be tuned through barrier thickness or C60
orientation up to complete extinction. The orientation dependence of NDC is a
result of a symmetry matching between the molecular tip and the surface states.
