  We study the time-resolved photoassociation of ultracold sodium in an optical
dipole trap. The photoassociation laser excites pairs of atoms to molecular
states of large total angular momentum at high intensities (above 20
kW/cm$^{2}$). Such transitions are generally suppressed at ultracold
temperatures by the centrifugal barriers for high partial waves. Time-resolved
ionization measurements reveal that the atoms are accelerated by the dipole
potential of the photoassociation beam. We change the collision energy by
varying the potential depth, and observe a strong variation of the
photoassociation rate. These results demonstrate the important role of light
forces in cw photoassociation at high intensities.
