  Neutron capture cross-section measurements are fundamental in the study of
the slow neutron capture (s-) process of nucleosynthesis and for the
development of innovative nuclear technologies. One of the best suited methods
to measure radiative neutron capture (n,$\gamma$) cross sections over the full
stellar range of interest for all the applications is the time-of-flight (TOF)
technique. Overcoming the current experimental limitations for TOF
measurements, in particular on low mass unstable samples, requires the
combination of facilities with high instantaneous flux, such as the CERN n_TOF
facility, with detection systems with an enhanced detection sensitivity and
high counting rate capabilities. This contribution presents a summary about the
recent highlights in the field of (n,$\gamma$) measurements at n_TOF. The
recent upgrades in the facility and in new detector concepts for (n,\g)
measurements are described. Last, an overview is given on the existing
limitations and prospects for TOF measurements involving unstable targets and
the outlook for activation measurements at the brand new high-flux n_TOF-NEAR
station.
