  We use a new idea that emerged in the examination of exposed positive maps
between matrix algebras to investigate in more detail the difference between
positive maps on $M_2(C)$ and $M_3(C)$. Our main tool stems from classical
Grothendieck theorem on tensor product of Banach spaces and is an older and
more general version of Choi-Jamiolkowski isomorphism between positive maps and
block positive Choi matrices. It takes into account the correct topology on the
latter set that is induced by the uniform topology on positive maps. In this
setting we show that in $M_2(C)$ case a large class of nice positive maps can
be generated from the small set of maps represented by self-adjoint unitaries,
$2 P_x$ with $x$ maximally entangled vector and $p\otimes 1$ with $p$ rank 1
projector. We show why this construction fails in $M_3(C)$ case. There are also
similarities. In both $M_2(C)$ and $M_3(C)$ cases any unital positive map
represented by self-adjoint unitary is unitarily equivalent to the
transposition map. Consequently we obtain a large family of exposed maps. We
also investigate a convex structure of the Choi map, the first example of
non-decomposable map. As a result the nature of the Choi map will be explained.
This gives an information on the origin of appearance of non-decomposable maps
on $M_3(C)$.
