  Does the quasi one-dimensional titanium pyroxene NaTiSi2O6 exhibit the novel
{\it orbital-Peierls} state? We calculate its groundstate properties by three
methods: Monte Carlo simulations, a spin-orbital decoupling scheme and a
mapping onto a classical model. The results show univocally that for the spin
and orbital ordering to occur at the same temperature --an experimental
observation-- the crystal field needs to be small and the orbitals are active.
We also find that quantum fluctuations in the spin-orbital sector drive the
transition, explaining why canonical bandstructure methods fail to find it. The
conclusion that NaTiSi2O6 shows an orbital-Peierls transition is therefore
inevitable.
