  Electron injection from an adsorbed molecule to the substrate (heterogeneous
electron transfer) is studied. One reaction coordinate is used to model this
process. The surface phonons and/or the electron-hole pairs together with the
internal degrees of freedom of the adsorbed molecule as well as possibly a
liquid surrounding the molecule provide a dissipative environment, which may
lead to dephasing, relaxation, and sometimes excitation of the relevant system.
In the process studied the adsorbed molecule is excited by a light pulse. This
is followed by an electron transfer from the excited donor state to the
quasi-continuum of the substrate. It is assumed that the substrate is a
semiconductor. The effects of dissipation on electron injection are
investigated.
