  We present a theoretical study of lifetimes of interface states (IS) on
metal-organic interfaces PTCDA/Ag(111), NTCDA/Ag(111), PFP/Ag(111), and
PTCDA/Ag(100), describing and explaining the recent experimental data. By means
of unfolding the band structure of one of the interfaces under study onto the
Ag(111) Brillouin zone we demonstrate, that the Brillouin zone folding upon
organic monolayer deposition plays a minor role in the phase space for electron
decay, and hence weakly affects the resulting lifetimes. The presence of the
unoccupied molecular states below the IS gives a small contribution to the IS
decay rate mostly determined by the change of the phase space of bulk states
upon the energy shift of the IS. The calculated lifetimes follow the
experimentally observed trends. In particular, we explain the trend of the
unusual increase of the IS lifetimes with rising temperature.
