  Under steady flow conditions, the topological complexity inherent to all
random 3D porous media imparts complicated flow and transport dynamics. It has
been established that this complexity generates persistent chaotic advection
via a three-dimensional (3D) fluid mechanical analogue of the baker's map which
rapidly accelerates scalar mixing in the presence of molecular diffusion. Hence
pore-scale fluid mixing is governed by the interplay between chaotic advection,
molecular diffusion and the broad (power-law) distribution of fluid particle
travel times which arise from the non-slip condition at pore walls. To
understand and quantify mixing in 3D porous media, we consider these processes
in a model 3D open porous network and develop a novel stretching continuous
time random walk (CTRW) which provides analytic estimates of pore-scale mixing
which compare well with direct numerical simulations. We find that chaotic
advection inherent to 3D porous media imparts scalar mixing which scales
exponentially with longitudinal advection, whereas the topological constraints
associated with 2D porous media limits mixing to scale algebraically. These
results decipher the role of wide transit time distributions and complex
topologies on porous media mixing dynamics, and provide the building blocks for
macroscopic models of dilution and mixing which resolve these mechanisms.
