  We report on observations of thermal motion of a single, Doppler-cooled ion
along the axis of a linear radio-frequency quadrupole trap. We show that for a
harmonic potential the thermal occupation of energy levels leads to Gaussian
distribution of the ion's axial position. The dependence of the spatial thermal
spread on the trap potential is used for precise calibration of our imaging
system's point spread function and sub-milliKelvin thermometry. We employ this
technique to investigate the laser detuning dependence of the Doppler
temperature.
