  The transition metal coordination compound (pyrimidine)2FeCl2 crystallizes in
a chiral lattice, space group I 4_1 2 2 (or I4_3 2 2). Combined magnetization,
Mossbauer spectroscopy and powder neutron diffraction studies reveal that it is
a canted antiferromagnet below T_N = 6.4 K with an unusually large canting of
the magnetic moments of 14 deg. from their general antiferromagnetic alignment,
one of the largest reported to date. This results in weak ferromagnetism with a
ferromagnetic component of 1 mu_B. The large canting is due to the interplay
between the antiferromagnetic exchange interaction and the local single-ion
anisotropy in the chiral lattice. The magnetically ordered structure of
(pyrimidine)2FeCl2, however, is not chiral. The implications of these findings
for the search of molecule based materials exhibiting chiral magnetic ordering
is discussed.
