  Recent direct experimental observation of multiple highly-dispersive C$_{60}$
valence bands has allowed for a detailed analysis of the unique photoemission
traits of these features through photon energy- and polarization-dependent
measurements. Previously obscured dispersions and strong photoemission traits
are now revealed by specific light polarizations. The observed intensity
effects prove the locking in place of the C$_{60}$ molecules at low
temperatures and the existence of an orientational order imposed by the
substrate chosen. Most importantly, photon energy- and polarization-dependent
effects are shown to be intimately linked with the orbital character of the
C$_{60}$ band manifolds which allows for a more precise determination of the
orbital character within the HOMO-2. Our observations and analysis provide
important considerations for the connection between molecular and crystalline
C$_{60}$ electronic structure, past and future band structure studies, and for
increasingly popular C$_{60}$ electronic device applications, especially those
making use of heterostructures.
