  A quantum system weakly interacting with a fast environment usually undergoes
a relaxation with complex frequencies whose imaginary parts are damping rates
quadratic in the coupling to the environment, in accord with Fermi's ``Golden
Rule''. We show for various models (spin damped by harmonic-oscillator or
random-matrix baths, quantum diffusion, quantum Brownian motion) that upon
increasing the coupling up to a critical value still small enough to allow for
weak-coupling Markovian master equations, a new relaxation regime can occur. In
that regime, complex frequencies lose their real parts such that the process
becomes overdamped. Our results call into question the standard belief that
overdamping is exclusively a strong coupling feature.
