  Na0.5CoO2 exhibits a metal-insulator transition at 53 K upon cooling. The
nature of another transition at 88 K has not been fully clarified yet. We
report the results of measurements of the electrical conductivity, the magnetic
susceptibility and 23Na NMR on a powder sample of Na0.5CoO2, including the
mapping of NMR spectra, as well as probing the spin-lattice relaxation rate and
the spin-spin relaxation rate, in the temperature range between 30 K and 305 K.
The NMR data reflect the transition at T_X very well but provide less evidence
for the metal-insulator transition at T_MI. The temperature evolution of the
shape of the spectra implies the formation of a staggered internal field below
T_X, not accompained by a rearrangement of the electric charge distribution.
Our results thus indicate that in Na0.5CoO2, an unusual type of magnetic
ordering in the metallic phase precedes the onset of charge ordering, which
finally induces an insulating ground state.
