  Carbonates have repeatedly been discussed as possible carriers of stardust
emission bands. However, the band assignments proposed so far were mainly based
on room temperature powder transmission spectra of the respective minerals.
Since very cold calcite grains have been claimed to be present in protostars
and in Planetary Nebulae such as NGC 6302, the changes of their dielectric
functions at low temperatures are relevant from an astronomical point of view.
We have derived the IR optical constants of calcite and dolomite from
reflectance spectra - measured at 300, 200, 100 and 10K - and calculated small
particle spectra for different grain shapes, with the following results: i) The
absorption efficiency factors both of calcite and dolomite are extremely
dependent on the particle shapes. This is due to the high peak values of the
optical constants of CaCO3 and CaMg[CO3]2. ii) The far infrared properties of
calcite and dolomite depend also very significantly on the temperature. Below
200K, a pronounced sharpening and increase in the band strengths of the FIR
resonances occurs. iii) In view of the intrinsic strength and sharpening of the
44 mum band of calcite at 200-100K, the absence of this band -- inferred from
Infrared Space Observatory data -- in PNe requires dust temperatures below 45K.
iv) Calcite grains at such low temperatures can account for the '92' mum band,
while our data rule out dolomite as the carrier of the 60-65 mum band. The
optical constants here presented are publicly available in the electronic
database http://www.astro.uni-jena.de/Laboratory/OCDB
