  We report a first-order phase transition at T_M=357 K in single crystal
Ca_2RuO_4, an isomorph to the superconductor Sr_2RuO_4. The discontinuous
decrease in electrical resistivity signals the near destruction of the Mott
insulating phase and is triggered by a structural transition from the low
temperature orthorhombic to a high temperature tetragonal phase. The magnetic
susceptibility, which is temperature dependent but not Curie-like decreases
abruptly at TM and becomes less temperature dependent. Unlike most insulator to
metal transitions, the system is not magnetically ordered in either phase,
though the Mott insulator phase is antiferromagnetic below T_N=110 K.
