  We use the density functional perturbation theory to determine for the first
time the pressure evolution of the Raman intensities for a mineral, the two
high-pressure structures of MgSiO3 perovskite and post-perovskite. At high
pressures, the Raman powder spectra reveals three main peaks for the perovskite
structure and one main peak for the post-perovskite structure. Due to the large
differences in the spectra of the two phases Raman spectroscopy can be used as
a good experimental indication of the phase transition.
