  We present a VLT/UVES spectrum of a proximate sub-damped Lyman-alpha
(sub-DLA) system at z=2.65618 toward the quasar Q0331-4505
(z_qso=2.6785+/-0.0030). Absorption lines of O I, Si II, Si III, Si IV, C II, C
III, C IV, Fe II, Al II, and O VI are seen in the sub-DLA, which has a neutral
hydrogen column density log N(H I)=19.82+/-0.05. The absorber is at a velocity
of 1820+/-250 km/s from the quasar; however, its low metallicity
[O/H]=-1.64+/-0.07, lack of partial coverage, lack of temporal variations
between observations taken in 2003 and 2006, and non-detection of N V imply the
absorber is not a genuine intrinsic system. By measuring the O VI column
density and assuming equal metallicities in the neutral and ionized gas, we
determine the column density of hot ionized hydrogen in this sub-DLA, and in
two other sub-DLAs with O VI drawn from the literature. Coupling this with
determinations of the typical amount of warm ionized hydrogen in sub-DLAs, we
confirm that sub-DLAs are a more important metal reservoir than DLAs, in total
comprising at least 6-22% of the metal budget at z~2.5.
