  We study solutions of $-\Delta u + V u = \lambda u$ on $\mathbb{R}^n$. Such
solutions localize in the `allowed' region $\left\{x \in \mathbb{R}^n: V(x)
\leq \lambda\right\}$ and decay exponentially in the `forbidden' region
$\left\{x \in \mathbb{R}^n: V(x) > \lambda\right\}$. One way of making this
precise is Agmon's inequality implying decay estimates in terms of the Agmon
metric. We prove a complementary decay estimate in terms of harmonic measure
which can improve on Agmon's estimate, connect the Agmon metric to decay of
harmonic measure and prove a sharp pointwise Agmon estimate.
