  The phase relations in the Li2O-V2O3-V2O5 ternary system at 700 C for
compositions in equilibrium with LiV2O4 are reported. This study clarified the
synthesis conditions under which low and high magnetic defect concentrations
can be obtained within the spinel structure of LiV2O4. We confirmed that the
LiV2O4 phase can be obtained containing low (0.006 mol%) to high (0.83 mol%)
magnetic defect concentrations n{defect} and with consistently high magnetic
defect spin S values between 3 and 6.5. The high n{defect} values were obtained
in the LiV2O4 phase in equilibrium with V2O3, Li3VO4, or LiVO2 and the low
values in the LiV2O4 phase in equilibrium with V3O5. A model is suggested to
explain this correlation.
