  The Kondo effect of a Co atom on Cu(100) was investigated with a
low-temperature scanning tunneling microscope using a monoatomically sharp
nickel tip. Upon a tip-Co contact, the differential conductance spectra exhibit
a spin-split asymmetric Kondo resonance. The computed ab initio value of the
exchange coupling is too small to suppress the Kondo effect, but sufficiently
large to produce the splitting observed. A quantitative analysis of the line
shape using the numerical renormalization group technique indicates that the
junction spin polarization is weak.
