  With the high-resolution spectroscopy now available in the optical and
satellite UV, it is possible to determine the neutral/ionized column density
ratios for several different elements in a single cloud. Assuming ionization
equilibrium for each element, one can make several independent determinations
of the electron density. For the clouds for which such an analysis has been
carried out, these different estimates disagree by large factors, suggesting
that some process (or processes) besides photoionization and radiative
recombination might play an important role in the ionization balance. One
candidate process is collisions of ions with dust grains.
  Making use of recent work quantifying the abundances of polycyclic aromatic
hydrocarbon molecules and other grains in the interstellar medium, as well as
recent models for grain charging, we estimate the grain-assisted ion
recombination rates for several astrophysically important elements. We find
that these rates are comparable to the rates for radiative recombination for
conditions typical of the cold neutral medium. Including grain-assisted ion
recombination in the ionization equilibrium analysis leads to increased
consistency in the various electron density estimates for the gas along the
line of sight to 23 Orionis. However, not all of the discrepancies can be
eliminated in this way; we speculate on some other processes that might play a
role. We also note that grain-assisted recombination of H+ and He+ leads to
significantly lower electron fractions than usually assumed for the cold
neutral medium.
