  The determination of velocities of stars from precise Doppler measurements is
described here using relativistic theory of astronomical reference frames so as
to determine the Keplerian and post-Keplerian parameters of binary systems. We
apply successive Lorentz transformations and the relativistic equation of light
propagation to establish the exact treatment of Doppler effect in binary
systems both in special and general relativity theories. As a result, the
Doppler shift is a sum of (1) linear in $c^{-1}$ terms, which include the
ordinary Doppler effect and its variation due to the secular radial
acceleration of the binary with respect to observer; (2) terms proportional to
$c^{-2}$, which include the contributions from the quadratic Doppler effect
caused by the relative motion of binary star with respect to the Solar system,
motion of the particle emitting light and diurnal rotational motion of
observer, orbital motion of the star around the binary's barycenter, and
orbital motion of the Earth; and (3) terms proportional to $c^{-2}$, which
include the contributions from redshifts due to gravitational fields of the
star, star's companion, Galaxy, Solar system, and the Earth. After
parameterization of the binary's orbit we find that the presence of
periodically changing terms in the Doppler schift enables us disentangling
different terms and measuring, along with the well known Keplerian parameters
of the binary, four additional post-Keplerian parameters, including the
inclination angle of the binary's orbit, $i$. We briefly discuss feasibility of
practical implementation of these theoretical results, which crucially depends
on further progress in the technique of precision Doppler measurements.
