  The debate around the potential superiority of quantum annealers over their
classical counterparts has been ongoing since the inception of the field by
Kadowaki and Nishimori close to two decades ago. Recent technological
breakthroughs in the field, which have led to the manufacture of experimental
prototypes of quantum annealing optimizers with sizes approaching the practical
regime, have reignited this discussion. However, the demonstration of quantum
annealing speedups remains to this day an elusive albeit coveted goal. Here, we
examine the power of quantum annealers to provide a different type of quantum
enhancement of practical relevance, namely, their ability to serve as useful
samplers from the ground-state manifolds of combinatorial optimization
problems. We study, both numerically by simulating ideal stoquastic and
non-stoquastic quantum annealing processes, and experimentally, using a
commercially available quantum annealing processor, the ability of quantum
annealers to sample the ground-states of spin glasses differently than
classical thermal samplers. We demonstrate that i) quantum annealers in general
sample the ground-state manifolds of spin glasses very differently than thermal
optimizers, ii) the nature of the quantum fluctuations driving the annealing
process has a decisive effect on the final distribution over ground-states, and
iii) the experimental quantum annealer samples ground-state manifolds
significantly differently than thermal and ideal quantum annealers. We
illustrate how quantum annealers may serve as powerful tools when complementing
standard sampling algorithms.
