  The electronic structure and total energy were calculated for ordered and
disordered MgO-CaO solid solutions within the multiple scattering theory in
real space and the local density approximation. Based on the dependence of the
total energy on the unit cell volume the equilibrium lattice parameter and
formation energy were determined for different solution compositions. The
formation energy of the solid solutions is found to be positive that is in
agreement with the experimental phase diagram, which shows a miscibility gap.
