  We report evidence for a close relation between the thermal activation of the
rattling motion of the filler guest atoms, and inhomogeneous spin dynamics of
the Eu2+ spins. The spin dynamics is probed directly by means of Eu2+ electron
spin resonance (ESR), performed in both X-band (9.4 GHz) and Q-band (34 GHz)
frequencies in the temperature interval 4.2 < T < 300 K. A comparative study
with ESR measurements on the Beta-Eu8Ga16Ge30 clathrate compound is presented.
Our results point to a correlation between the rattling motion and the spin
dynamics which may be relevant for the general understanding of the dynamics of
cage systems.
