  The single crystal of tris(thiourea)zinc sulphate (Zn[CS(NH2)2]3SO4) was
irradiated by 150 MeV Au9+ swift heavy ions and analyzed in comparison with
pure crystal for crystalline perfection and optical properties. The Fourier
transform infrared and x-ray powder diffraction inferred that swift ions lead
the disordering and breaking of molecular bonds in lattice without formation of
new structural phases. High resolution X-ray diffraction (HRXRD) revealed the
abundance of point defects, and formation of mosaics and low angle grain
boundaries in the irradiated region of crystal. The swift ion irradiation found
to affect the lattice vibrational modes and functional groups significantly.
The defects induced by heavy ions act as the color centers and resulted in
enhance of photoluminescence emission intensity. The optical transparency and
band gap found to be decreased.
