Related literature {#sec1}
==================

For potential applications of Pb(II) complexes, see: Fan & Zhu (2006[@bb3]); Hamilton *et al.* (2004[@bb4]); Alvarado *et al.* (2005[@bb1]). For the use of aromatic carboxyl­ates and 2,2′-bipyridine-type ligands in the preparation of metal complexes, see: Wang *et al.* (2006[@bb7]); Masaoka *et al.* (2001[@bb5]).

Experimental {#sec2}
============

 {#sec2.1}

### Crystal data {#sec2.1.1}

\[Pb(C~7~H~5~O~2~)~2~(C~10~H~8~N~2~)\]·C~7~H~6~O~2~*M* *~r~* = 727.71Triclinic,*a* = 9.6298 (2) Å*b* = 10.4264 (2) Å*c* = 28.7365 (5) Åα = 84.843 (1)°β = 88.128 (1)°γ = 72.619 (1)°*V* = 2742.32 (9) Å^3^*Z* = 4Mo *K*α radiationμ = 6.2 mm^−1^*T* = 296 K0.24 × 0.19 × 0.15 mm

### Data collection {#sec2.1.2}

Bruker APEXII CCD area-detector diffractometerAbsorption correction: multi-scan (*SADABS*; Bruker, 2007[@bb2]) *T* ~min~ = 0.253, *T* ~max~ = 0.39549796 measured reflections14302 independent reflections10344 reflections with *I* \> 2σ(*I*)*R* ~int~ = 0.039

### Refinement {#sec2.1.3}

*R*\[*F* ^2^ \> 2σ(*F* ^2^)\] = 0.035*wR*(*F* ^2^) = 0.081*S* = 1.0114302 reflections773 parametersH-atom parameters constrainedΔρ~max~ = 1.17 e Å^−3^Δρ~min~ = −1.13 e Å^−3^

 {#d5e518}

Data collection: *APEX2* (Bruker, 2007[@bb2]); cell refinement: *SAINT* (Bruker, 2007[@bb2]); data reduction: *SAINT*; program(s) used to solve structure: *SHELXS97* (Sheldrick, 2008[@bb6]); program(s) used to refine structure: *SHELXL97* (Sheldrick, 2008[@bb6]); molecular graphics: *SHELXTL* (Sheldrick, 2008[@bb6]); software used to prepare material for publication: *SHELXTL*.

Supplementary Material
======================

Crystal structure: contains datablocks global, I. DOI: [10.1107/S1600536810046489/ya2132sup1.cif](http://dx.doi.org/10.1107/S1600536810046489/ya2132sup1.cif)

Structure factors: contains datablocks I. DOI: [10.1107/S1600536810046489/ya2132Isup2.hkl](http://dx.doi.org/10.1107/S1600536810046489/ya2132Isup2.hkl)

Additional supplementary materials: [crystallographic information](http://scripts.iucr.org/cgi-bin/sendsupfiles?ya2132&file=ya2132sup0.html&mime=text/html); [3D view](http://scripts.iucr.org/cgi-bin/sendcif?ya2132sup1&Qmime=cif); [checkCIF report](http://scripts.iucr.org/cgi-bin/paper?ya2132&checkcif=yes)

Supplementary data and figures for this paper are available from the IUCr electronic archives (Reference: [YA2132](http://scripts.iucr.org/cgi-bin/sendsup?ya2132)).

The authors acknowledge financial support by the Doctoral Foundation of Henan Polytechnic University (B2008--58 648265).

Comment
=======

Complexes containing Pb(II) ion have recently attracted considerable interest not only because of the variety of their architectures, but also because of their potential applications, especially in environmental protection and in systems with different biological properties (Fan & Zhu, 2006; Hamilton *et al.*, 2004; Alvarado *et al.*, 2005). As an important family of bidentate O-donor ligands, aromatic carboxylates have been extensively employed in the preparation of metal complexes of various structural topologies (Wang *et al.*, 2006; Masaoka *et al.*, 2001).

The asymmetric unit of the crystal of the title complex, \[Pb(C~7~H~5~O~2~)~2~(C~10~H~8~N~2~)\].(C~7~H~6~O~2~), contains two molecules of complex, as well as two independent benzoic solvate molecules (Fig.1), one of which is disordered over two positions with almost equal occupancies. Each Pb^II^ atom is hexacoordinated and chelated by four carboxylate O atoms from two benzoic acid and two N atoms from 2,2\'-bipyridine ligand. In both complex molecules the O atoms of one of the carboxylate ligands (O3 and O4 in the first molecule; O7 and O8 in the second molecule) are almost coplanar with the N atoms of the bipy-ligand (N1 and N2 in the first and N3 and N4 in the second molecule). Therefore, if we consider, that the second carboxylate ligand occupies just one coordination site, then coordination environments of Pb1 and Pb2 atoms may be described as pseudo-square-pyramidal.

The weak intermolecular interactions Pb1···O2^i^ \[3.359 (3) Å, ^i^ -*x*, 1 - *y*, 2 - *z*\] and Pb2···O7^ii^ \[3.046 (3) Å, ^ii^ 1 - *x*, 1 - *y*,1 - *z*\] link the molecules of complex into centrosymmetric dimers (Fig.2). The H-bonds involving carboxylic H atoms of solvate benzoic acid molecules and metal coordinated carboxylate O atoms (Table 1), link molecules of the complex and benzoic acid solvates into insular aggregates.

Experimental {#experimental}
============

A mixture of Pb(CH~3~COO)~2~.3H~2~O (0.199 g, 0.52 mmol), benzoic acid (0.102 g, 0.84 mmol), 2,2\'-bipyridine (0.033 g, 0.21 mmol) and distilled water (10 ml) was sealed in a 25 ml Teflon-lined stainless autoclave. The mixture was heated at 393 K for 6 days to give the colorless crystals suitable for X-ray diffraction analysis.

Refinement {#refinement}
==========

All H atoms bound to C atoms were placed in calculated positions and treated in a riding-model approximation, with C ---H = 0.93 Å and *U*~iso~ (H) = 1.2 *U*~eq~(C). The positions of carboxylic H atoms were located in the difference Fourier maps and included in the refinement in riding motion approximation with idealized distance of O---H = 0.85 Å and *U*~iso~ (H) = 1.2 *U*~eq~(O). One of the the benzoic acid molecules \[C56---C57---C58---C59---C60---C61---C62---O11---O12---H12\] showed high thermal parameters and was subsequently represented as disordered over two sites, with refined occupancies of 0.496 (5) and 0.504 (5). The displacement parameters for the corresponding non-hydrogen atoms in the disordered phenyl rings were set equal (six EADP instructions; see, Sheldrick, 2008). The highest residual peak of 1.17 e Å^-3^ is located at the distance of 0.89 Å from Pb1; the deepest hole -1.13 e Å^-3^ is at 0.65 Å from the same atom.

Figures
=======

![The asymmetric unit of the title complex, showing displacement ellipsoids at the 30% probability level and the atom-labeling scheme. The H atoms and one of the components of the disordered benzoic acid molecule have been omitted for clarity.](e-66-m1583-fig1){#Fap1}

![The packing diagram viewed down the a axis; the H atoms not involved in H-bonding and the minor component of the disordered benzoic acid molecule are omitted for clarity. The H-bonds are shown as dashed lines in blue; the weak intermolecular Pb···O interactions are drawn as dashed lines in violet.](e-66-m1583-fig2){#Fap2}

Crystal data {#tablewrapcrystaldatalong}
============

  ----------------------------------------------------- ---------------------------------------
  \[Pb(C~7~H~5~O~2~)~2~(C~10~H~8~N~2~)\]·C~7~H~6~O~2~   *Z* = 4
  *M~r~* = 727.71                                       *F*(000) = 1416
  Triclinic, *P*1                                       *D*~x~ = 1.763 Mg m^−3^
  Hall symbol: -P 1                                     Mo *K*α radiation, λ = 0.71073 Å
  *a* = 9.6298 (2) Å                                    Cell parameters from 9902 reflections
  *b* = 10.4264 (2) Å                                   θ = 0.7--29.0°
  *c* = 28.7365 (5) Å                                   µ = 6.2 mm^−1^
  α = 84.843 (1)°                                       *T* = 296 K
  β = 88.128 (1)°                                       Prism, colorless
  γ = 72.619 (1)°                                       0.24 × 0.19 × 0.15 mm
  *V* = 2742.32 (9) Å^3^                                
  ----------------------------------------------------- ---------------------------------------

Data collection {#tablewrapdatacollectionlong}
===============

  ------------------------------------------------------------ ---------------------------------------
  Bruker APEXII CCD area-detector diffractometer               14302 independent reflections
  Radiation source: fine-focus sealed tube                     10344 reflections with *I* \> 2σ(*I*)
  graphite                                                     *R*~int~ = 0.039
  φ and ω scans                                                θ~max~ = 29.0°, θ~min~ = 0.7°
  Absorption correction: multi-scan (*SADABS*; Bruker, 2007)   *h* = −13→13
  *T*~min~ = 0.253, *T*~max~ = 0.395                           *k* = −14→14
  49796 measured reflections                                   *l* = −39→38
  ------------------------------------------------------------ ---------------------------------------

Refinement {#tablewraprefinementdatalong}
==========

  ------------------------------------- -------------------------------------------------------------------------------------------------
  Refinement on *F*^2^                  Primary atom site location: structure-invariant direct methods
  Least-squares matrix: full            Secondary atom site location: difference Fourier map
  *R*\[*F*^2^ \> 2σ(*F*^2^)\] = 0.035   Hydrogen site location: inferred from neighbouring sites
  *wR*(*F*^2^) = 0.081                  H-atom parameters constrained
  *S* = 1.01                            *w* = 1/\[σ^2^(*F*~o~^2^) + (0.0359*P*)^2^ + 1.7335*P*\] where *P* = (*F*~o~^2^ + 2*F*~c~^2^)/3
  14302 reflections                     (Δ/σ)~max~ = 0.001
  773 parameters                        Δρ~max~ = 1.17 e Å^−3^
  0 restraints                          Δρ~min~ = −1.13 e Å^−3^
  ------------------------------------- -------------------------------------------------------------------------------------------------

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å^2^) {#tablewrapcoords}
==================================================================================================

  ------ --------------- --------------- -------------- -------------------- ------------
         *x*             *y*             *z*            *U*~iso~\*/*U*~eq~   Occ. (\<1)
  Pb1    0.277299 (17)   0.440644 (16)   0.990310 (6)   0.04756 (5)          
  O1     0.2560 (3)      0.3122 (3)      0.92887 (10)   0.0547 (8)           
  O2     0.0401 (4)      0.4189 (4)      0.95610 (12)   0.0651 (9)           
  O3     0.4510 (4)      0.5195 (4)      0.93842 (13)   0.0708 (10)          
  O4     0.2300 (4)      0.6359 (4)      0.91565 (12)   0.0686 (9)           
  N1     0.5126 (4)      0.2401 (4)      1.00026 (13)   0.0481 (8)           
  N2     0.2611 (4)      0.2258 (4)      1.04054 (13)   0.0550 (9)           
  C1     0.1188 (5)      0.3474 (5)      0.92752 (15)   0.0498 (10)          
  C2     0.0484 (4)      0.2956 (5)      0.88972 (14)   0.0472 (10)          
  C3     −0.0994 (5)     0.3513 (6)      0.8821 (2)     0.0701 (15)          
  H3A    −0.1541         0.4177          0.9004         0.084\*              
  C4     −0.1656 (6)     0.3084 (7)      0.8472 (2)     0.0832 (18)          
  H4A    −0.2649         0.3464          0.8422         0.100\*              
  C5     −0.0878 (6)     0.2115 (6)      0.8203 (2)     0.0745 (15)          
  H5A    −0.1329         0.1851          0.7963         0.089\*              
  C6     0.0567 (6)      0.1529 (6)      0.82847 (18)   0.0720 (15)          
  H6A    0.1093          0.0828          0.8112         0.086\*              
  C7     0.1257 (5)      0.1975 (5)      0.86266 (16)   0.0588 (12)          
  H7A    0.2253          0.1601          0.8671         0.071\*              
  C8     0.3649 (5)      0.6109 (5)      0.91275 (16)   0.0550 (11)          
  C9     0.3456 (6)      0.7990 (6)      0.85076 (19)   0.0774 (17)          
  H9A    0.2458          0.8298          0.8561         0.093\*              
  C10    0.4109 (8)      0.8652 (7)      0.8160 (2)     0.101 (2)            
  H10A   0.3540          0.9397          0.7980         0.121\*              
  C11    0.5556 (8)      0.8217 (7)      0.8087 (3)     0.104 (2)            
  H11A   0.5980          0.8650          0.7852         0.125\*              
  C12    0.6389 (7)      0.7157 (7)      0.8353 (3)     0.093 (2)            
  H12A   0.7392          0.6876          0.8306         0.112\*              
  C13    0.5777 (6)      0.6490 (6)      0.86907 (19)   0.0689 (14)          
  H13A   0.6367          0.5758          0.8871         0.083\*              
  C14    0.4301 (5)      0.6884 (5)      0.87676 (15)   0.0524 (11)          
  C15    0.1347 (6)      0.2245 (6)      1.0599 (2)     0.0748 (15)          
  H15A   0.0525          0.2960          1.0518         0.090\*              
  C16    0.1199 (8)      0.1232 (7)      1.0910 (2)     0.0899 (19)          
  H16A   0.0292          0.1248          1.1036         0.108\*              
  C17    0.2395 (9)      0.0198 (7)      1.1034 (2)     0.098 (2)            
  H17A   0.2321          −0.0506         1.1247         0.118\*              
  C18    0.3724 (7)      0.0200 (6)      1.08416 (19)   0.0774 (16)          
  H18A   0.4558          −0.0499         1.0924         0.093\*              
  C19    0.3799 (5)      0.1252 (5)      1.05259 (15)   0.0522 (11)          
  C20    0.5193 (5)      0.1345 (5)      1.03072 (15)   0.0492 (10)          
  C21    0.6504 (6)      0.0360 (5)      1.04115 (19)   0.0673 (14)          
  H21A   0.6527          −0.0403         1.0609         0.081\*              
  C22    0.7757 (6)      0.0531 (7)      1.0220 (2)     0.0832 (18)          
  H22A   0.8650          −0.0083         1.0304         0.100\*              
  C23    0.7700 (5)      0.1604 (6)      0.9904 (2)     0.0806 (17)          
  H23A   0.8542          0.1715          0.9761         0.097\*              
  C24    0.6360 (5)      0.2517 (5)      0.98016 (19)   0.0618 (13)          
  H24A   0.6312          0.3245          0.9584         0.074\*              
  Pb2    0.260139 (17)   0.547049 (16)   0.492170 (5)   0.04398 (5)          
  O5     0.1638 (3)      0.6596 (3)      0.41827 (10)   0.0517 (7)           
  O6     −0.0072 (4)     0.5925 (4)      0.45613 (11)   0.0684 (10)          
  O7     0.4867 (3)      0.4786 (3)      0.44324 (10)   0.0539 (8)           
  O8     0.3453 (4)      0.3496 (3)      0.43410 (12)   0.0654 (9)           
  N3     0.0919 (4)      0.7500 (4)      0.53414 (13)   0.0516 (9)           
  N4     0.3238 (4)      0.7697 (4)      0.48246 (12)   0.0496 (9)           
  C25    0.0347 (5)      0.6481 (4)      0.42089 (14)   0.0462 (10)          
  C26    −0.0617 (5)     0.7019 (4)      0.38005 (15)   0.0468 (10)          
  C27    −0.1856 (6)     0.6646 (7)      0.3762 (2)     0.087 (2)            
  H27A   −0.2102         0.6087          0.4000         0.105\*              
  C28    −0.2740 (7)     0.7079 (8)      0.3380 (3)     0.109 (3)            
  H28A   −0.3568         0.6803          0.3359         0.131\*              
  C29    −0.2417 (7)     0.7903 (7)      0.3033 (2)     0.094 (2)            
  H29A   −0.3013         0.8188          0.2772         0.113\*              
  C30    −0.1203 (6)     0.8320 (6)      0.30662 (18)   0.0682 (14)          
  H30A   −0.0987         0.8904          0.2831         0.082\*              
  C31    −0.0309 (5)     0.7874 (5)      0.34468 (16)   0.0505 (10)          
  H31A   0.0516          0.8155          0.3466         0.061\*              
  C32    0.4552 (5)      0.3858 (4)      0.42343 (15)   0.0476 (10)          
  C33    0.5526 (4)      0.3229 (4)      0.38502 (14)   0.0443 (9)           
  C34    0.6673 (5)      0.3672 (5)      0.36900 (17)   0.0588 (12)          
  H34A   0.6875          0.4360          0.3834         0.071\*              
  C35    0.7531 (6)      0.3129 (6)      0.3324 (2)     0.0751 (16)          
  H35A   0.8297          0.3455          0.3220         0.090\*              
  C36    0.7259 (7)      0.2110 (7)      0.3112 (2)     0.0877 (19)          
  H36A   0.7837          0.1736          0.2864         0.105\*              
  C37    0.6126 (8)      0.1644 (7)      0.3268 (2)     0.096 (2)            
  H37A   0.5944          0.0941          0.3127         0.116\*              
  C38    0.5253 (6)      0.2207 (5)      0.3631 (2)     0.0702 (15)          
  H38A   0.4474          0.1895          0.3729         0.084\*              
  C39    −0.0144 (5)     0.7296 (5)      0.56216 (18)   0.0634 (13)          
  H39A   −0.0436         0.6535          0.5592         0.076\*              
  C40    −0.0815 (6)     0.8135 (6)      0.5945 (2)     0.0759 (16)          
  H40A   −0.1560         0.7963          0.6130         0.091\*              
  C41    −0.0370 (7)     0.9251 (7)      0.5994 (2)     0.0896 (19)          
  H41A   −0.0800         0.9842          0.6217         0.108\*              
  C42    0.0709 (6)      0.9484 (6)      0.57104 (19)   0.0719 (15)          
  H42A   0.1008          1.0244          0.5736         0.086\*              
  C43    0.1358 (5)      0.8587 (4)      0.53846 (15)   0.0489 (10)          
  C44    0.2496 (5)      0.8770 (4)      0.50499 (15)   0.0477 (10)          
  C45    0.2771 (6)      0.9997 (5)      0.49649 (19)   0.0656 (14)          
  H45A   0.2279          1.0718          0.5134         0.079\*              
  C46    0.3775 (6)      1.0149 (6)      0.4629 (2)     0.0761 (16)          
  H46A   0.3948          1.0978          0.4562         0.091\*              
  C47    0.4508 (6)      0.9065 (6)      0.43973 (19)   0.0704 (15)          
  H47A   0.5203          0.9143          0.4173         0.084\*              
  C48    0.4218 (5)      0.7836 (5)      0.44951 (17)   0.0595 (12)          
  H48A   0.4708          0.7104          0.4330         0.071\*              
  O9     0.3064 (6)      0.8312 (6)      0.32918 (16)   0.1072 (16)          
  O10    0.3206 (4)      0.6176 (4)      0.33971 (12)   0.0809 (11)          
  H10    0.2758          0.6364          0.3653         0.097\*              
  C49    0.3429 (5)      0.7208 (8)      0.31470 (19)   0.0713 (16)          
  C50    0.4195 (5)      0.6882 (7)      0.27012 (16)   0.0645 (15)          
  C51    0.4360 (5)      0.7919 (7)      0.23990 (18)   0.0747 (16)          
  H51A   0.3978          0.8807          0.2472         0.090\*              
  C52    0.5129 (6)      0.7617 (9)      0.1968 (2)     0.088 (2)            
  H52A   0.5251          0.8313          0.1760         0.105\*              
  C53    0.5679 (7)      0.6322 (10)     0.1863 (2)     0.098 (2)            
  H53A   0.6174          0.6121          0.1583         0.117\*              
  C54    0.5493 (7)      0.5302 (9)      0.2178 (2)     0.095 (2)            
  H54A   0.5890          0.4411          0.2109         0.113\*              
  C55    0.4748 (6)      0.5561 (7)      0.25873 (19)   0.0782 (18)          
  H55A   0.4612          0.4857          0.2788         0.094\*              
  O11A   0.1002 (9)      0.0133 (8)      0.2570 (3)     0.089 (3)            0.496 (5)
  O12A   0.2529 (7)      0.0710 (6)      0.3016 (2)     0.0624 (19)          0.496 (5)
  H12C   0.2823          −0.0120         0.3113         0.075\*              0.496 (5)
  C56A   0.1453 (11)     0.0975 (10)     0.2712 (4)     0.054 (2)            0.496 (5)
  C57A   0.0816 (7)      0.2391 (6)      0.24973 (19)   0.081 (6)            0.496 (5)
  C58A   −0.0179 (5)     0.2866 (5)      0.21357 (15)   0.089 (6)            0.496 (5)
  H58A   −0.0459         0.2262          0.1969         0.107\*              0.496 (5)
  C59A   −0.0754 (5)     0.4246 (5)      0.2023 (2)     0.101 (5)            0.496 (5)
  H59A   −0.1419         0.4564          0.1781         0.121\*              0.496 (5)
  C60A   −0.0334 (8)     0.5150 (6)      0.2273 (3)     0.098 (5)            0.496 (5)
  H60A   −0.0719         0.6073          0.2197         0.117\*              0.496 (5)
  C61A   0.0661 (9)      0.4674 (8)      0.2634 (2)     0.097 (6)            0.496 (5)
  H61A   0.0941          0.5279          0.2801         0.116\*              0.496 (5)
  C62A   0.1236 (8)      0.3294 (9)      0.2747 (2)     0.088 (5)            0.496 (5)
  H62A   0.1901          0.2976          0.2989         0.105\*              0.496 (5)
  O11B   −0.0444 (8)     0.1612 (5)      0.1905 (2)     0.082 (2)            0.504 (5)
  O12B   −0.0935 (6)     0.3742 (6)      0.16037 (18)   0.066 (2)            0.504 (5)
  H12B   −0.1336         0.3492          0.1384         0.079\*              0.504 (5)
  C56B   −0.0404 (13)    0.2721 (13)     0.1906 (4)     0.057 (3)            0.504 (5)
  C57B   0.0307 (7)      0.3092 (8)      0.2309 (2)     0.045 (3)            0.504 (5)
  C58B   0.0251 (9)      0.4409 (7)      0.2377 (3)     0.066 (3)            0.504 (5)
  H58B   −0.0326         0.5123          0.2186         0.079\*              0.504 (5)
  C59B   0.1058 (10)     0.4660 (7)      0.2732 (3)     0.079 (5)            0.504 (5)
  H59B   0.1020          0.5542          0.2778         0.095\*              0.504 (5)
  C60B   0.1921 (9)      0.3594 (9)      0.3018 (3)     0.082 (4)            0.504 (5)
  H60B   0.2461          0.3762          0.3255         0.098\*              0.504 (5)
  C61B   0.1977 (8)      0.2276 (8)      0.2950 (2)     0.083 (4)            0.504 (5)
  H61B   0.2555          0.1563          0.3141         0.099\*              0.504 (5)
  C62B   0.1171 (8)      0.2025 (6)      0.2595 (3)     0.057 (4)            0.504 (5)
  H62B   0.1208          0.1144          0.2549         0.068\*              0.504 (5)
  ------ --------------- --------------- -------------- -------------------- ------------

Atomic displacement parameters (Å^2^) {#tablewrapadps}
=====================================

  ------ -------------- -------------- -------------- -------------- -------------- --------------
         *U*^11^        *U*^22^        *U*^33^        *U*^12^        *U*^13^        *U*^23^
  Pb1    0.05027 (10)   0.04123 (10)   0.04718 (10)   −0.00703 (7)   −0.00101 (7)   −0.00521 (7)
  O1     0.0420 (16)    0.064 (2)      0.0543 (18)    −0.0066 (14)   −0.0052 (13)   −0.0125 (16)
  O2     0.0580 (19)    0.072 (2)      0.061 (2)      −0.0073 (17)   0.0029 (16)    −0.0239 (18)
  O3     0.070 (2)      0.059 (2)      0.071 (2)      −0.0065 (18)   0.0017 (18)    0.0121 (19)
  O4     0.059 (2)      0.079 (3)      0.063 (2)      −0.0167 (18)   0.0036 (16)    0.0039 (19)
  N1     0.0443 (19)    0.042 (2)      0.056 (2)      −0.0074 (16)   −0.0069 (16)   −0.0083 (17)
  N2     0.051 (2)      0.051 (2)      0.056 (2)      −0.0076 (18)   0.0036 (17)    −0.0005 (18)
  C1     0.051 (3)      0.052 (3)      0.045 (2)      −0.012 (2)     −0.0015 (19)   0.000 (2)
  C2     0.043 (2)      0.055 (3)      0.040 (2)      −0.010 (2)     −0.0002 (17)   −0.002 (2)
  C3     0.041 (2)      0.084 (4)      0.080 (4)      −0.005 (2)     −0.004 (2)     −0.021 (3)
  C4     0.049 (3)      0.096 (5)      0.102 (5)      −0.012 (3)     −0.021 (3)     −0.020 (4)
  C5     0.067 (3)      0.089 (4)      0.074 (4)      −0.030 (3)     −0.021 (3)     −0.011 (3)
  C6     0.077 (4)      0.078 (4)      0.053 (3)      −0.006 (3)     −0.005 (2)     −0.021 (3)
  C7     0.046 (2)      0.071 (3)      0.052 (3)      −0.006 (2)     −0.005 (2)     −0.009 (2)
  C8     0.065 (3)      0.051 (3)      0.043 (2)      −0.006 (2)     −0.001 (2)     −0.009 (2)
  C9     0.070 (3)      0.067 (4)      0.070 (3)      0.010 (3)      0.017 (3)      0.010 (3)
  C10    0.124 (6)      0.071 (4)      0.082 (4)      0.000 (4)      0.021 (4)      0.022 (3)
  C11    0.115 (6)      0.077 (5)      0.107 (5)      −0.019 (4)     0.056 (4)      0.003 (4)
  C12    0.076 (4)      0.093 (5)      0.112 (5)      −0.029 (4)     0.034 (4)      −0.012 (4)
  C13    0.063 (3)      0.064 (3)      0.073 (3)      −0.010 (3)     0.004 (3)      −0.006 (3)
  C14    0.058 (3)      0.050 (3)      0.045 (2)      −0.010 (2)     0.007 (2)      −0.009 (2)
  C15    0.069 (3)      0.073 (4)      0.076 (4)      −0.016 (3)     0.017 (3)      −0.003 (3)
  C16    0.094 (5)      0.088 (5)      0.090 (4)      −0.035 (4)     0.025 (4)      0.002 (4)
  C17    0.127 (6)      0.081 (5)      0.088 (5)      −0.041 (4)     0.010 (4)      0.022 (4)
  C18    0.094 (4)      0.062 (4)      0.070 (4)      −0.018 (3)     −0.010 (3)     0.015 (3)
  C19    0.065 (3)      0.044 (3)      0.045 (2)      −0.011 (2)     −0.006 (2)     −0.006 (2)
  C20    0.052 (2)      0.044 (3)      0.047 (2)      −0.0047 (19)   −0.0122 (19)   −0.010 (2)
  C21    0.065 (3)      0.057 (3)      0.067 (3)      0.002 (2)      −0.013 (3)     0.003 (3)
  C22    0.056 (3)      0.082 (5)      0.092 (4)      0.010 (3)      −0.018 (3)     −0.007 (4)
  C23    0.043 (3)      0.078 (4)      0.113 (5)      −0.005 (3)     −0.001 (3)     −0.015 (4)
  C24    0.047 (3)      0.058 (3)      0.080 (3)      −0.014 (2)     −0.001 (2)     −0.010 (3)
  Pb2    0.05568 (10)   0.04077 (10)   0.03725 (9)    −0.01737 (7)   −0.00074 (7)   −0.00191 (7)
  O5     0.0558 (18)    0.061 (2)      0.0414 (16)    −0.0237 (15)   −0.0062 (13)   0.0025 (14)
  O6     0.078 (2)      0.088 (3)      0.0513 (19)    −0.048 (2)     −0.0061 (16)   0.0106 (18)
  O7     0.0624 (19)    0.052 (2)      0.0499 (17)    −0.0199 (15)   0.0022 (14)    −0.0101 (15)
  O8     0.069 (2)      0.066 (2)      0.073 (2)      −0.0363 (18)   0.0264 (17)    −0.0249 (18)
  N3     0.056 (2)      0.041 (2)      0.060 (2)      −0.0181 (17)   0.0005 (18)    −0.0059 (18)
  N4     0.059 (2)      0.048 (2)      0.046 (2)      −0.0217 (18)   −0.0087 (17)   0.0001 (17)
  C25    0.056 (3)      0.046 (3)      0.039 (2)      −0.020 (2)     −0.0021 (18)   −0.0071 (19)
  C26    0.051 (2)      0.046 (3)      0.046 (2)      −0.017 (2)     −0.0032 (18)   −0.008 (2)
  C27    0.081 (4)      0.114 (5)      0.082 (4)      −0.060 (4)     −0.029 (3)     0.028 (4)
  C28    0.088 (4)      0.140 (7)      0.117 (6)      −0.069 (5)     −0.050 (4)     0.030 (5)
  C29    0.088 (4)      0.101 (5)      0.092 (5)      −0.032 (4)     −0.046 (4)     0.016 (4)
  C30    0.074 (3)      0.065 (3)      0.058 (3)      −0.012 (3)     −0.011 (3)     0.010 (3)
  C31    0.050 (2)      0.046 (3)      0.053 (3)      −0.012 (2)     −0.0044 (19)   −0.004 (2)
  C32    0.057 (3)      0.039 (2)      0.046 (2)      −0.013 (2)     −0.0019 (19)   −0.002 (2)
  C33    0.049 (2)      0.038 (2)      0.045 (2)      −0.0111 (18)   −0.0006 (18)   0.0008 (18)
  C34    0.055 (3)      0.066 (3)      0.059 (3)      −0.024 (2)     0.002 (2)      −0.008 (2)
  C35    0.061 (3)      0.089 (4)      0.075 (4)      −0.025 (3)     0.015 (3)      −0.004 (3)
  C36    0.083 (4)      0.091 (5)      0.084 (4)      −0.017 (4)     0.033 (3)      −0.025 (4)
  C37    0.114 (5)      0.088 (5)      0.101 (5)      −0.042 (4)     0.037 (4)      −0.055 (4)
  C38    0.074 (3)      0.059 (3)      0.087 (4)      −0.031 (3)     0.021 (3)      −0.028 (3)
  C39    0.061 (3)      0.061 (3)      0.070 (3)      −0.022 (3)     0.006 (2)      −0.005 (3)
  C40    0.067 (3)      0.085 (4)      0.078 (4)      −0.026 (3)     0.019 (3)      −0.017 (3)
  C41    0.095 (4)      0.091 (5)      0.088 (4)      −0.028 (4)     0.029 (4)      −0.040 (4)
  C42    0.094 (4)      0.056 (3)      0.072 (4)      −0.027 (3)     0.006 (3)      −0.025 (3)
  C43    0.054 (2)      0.043 (3)      0.049 (2)      −0.013 (2)     −0.0095 (19)   −0.004 (2)
  C44    0.057 (3)      0.037 (2)      0.051 (2)      −0.018 (2)     −0.019 (2)     0.003 (2)
  C45    0.078 (3)      0.044 (3)      0.078 (4)      −0.023 (3)     −0.008 (3)     −0.004 (3)
  C46    0.082 (4)      0.048 (3)      0.104 (5)      −0.032 (3)     −0.012 (3)     0.010 (3)
  C47    0.079 (4)      0.071 (4)      0.071 (3)      −0.043 (3)     −0.001 (3)     0.012 (3)
  C48    0.066 (3)      0.063 (3)      0.055 (3)      −0.028 (3)     0.000 (2)      0.002 (2)
  O9     0.135 (4)      0.127 (4)      0.089 (3)      −0.079 (4)     0.048 (3)      −0.040 (3)
  O10    0.079 (2)      0.096 (3)      0.054 (2)      −0.010 (2)     0.0122 (18)    0.006 (2)
  C49    0.050 (3)      0.115 (5)      0.054 (3)      −0.033 (3)     −0.001 (2)     −0.011 (3)
  C50    0.046 (3)      0.110 (5)      0.043 (3)      −0.030 (3)     −0.001 (2)     −0.008 (3)
  C51    0.056 (3)      0.115 (5)      0.060 (3)      −0.037 (3)     −0.002 (2)     −0.003 (3)
  C52    0.066 (4)      0.144 (7)      0.062 (4)      −0.048 (4)     −0.004 (3)     0.002 (4)
  C53    0.076 (4)      0.169 (8)      0.057 (4)      −0.045 (5)     0.006 (3)      −0.025 (5)
  C54    0.090 (5)      0.129 (6)      0.067 (4)      −0.031 (4)     0.008 (3)      −0.033 (4)
  C55    0.067 (4)      0.104 (5)      0.063 (4)      −0.019 (3)     0.004 (3)      −0.026 (4)
  O11A   0.100 (6)      0.061 (5)      0.117 (7)      −0.035 (5)     −0.016 (5)     −0.022 (5)
  O12A   0.074 (5)      0.040 (4)      0.070 (5)      −0.013 (3)     0.004 (4)      −0.002 (3)
  C56A   0.055 (6)      0.041 (6)      0.064 (6)      −0.013 (5)     0.015 (5)      −0.002 (5)
  C57A   0.096 (11)     0.049 (8)      0.113 (15)     −0.042 (9)     0.071 (11)     −0.041 (10)
  C58A   0.060 (9)      0.136 (17)     0.081 (14)     −0.040 (9)     0.005 (9)      −0.026 (12)
  C59A   0.066 (8)      0.092 (11)     0.121 (13)     −0.002 (7)     0.015 (8)      0.033 (10)
  C60A   0.097 (11)     0.051 (8)      0.135 (14)     −0.015 (7)     0.026 (9)      0.016 (9)
  C61A   0.080 (9)      0.148 (19)     0.076 (11)     −0.053 (11)    0.004 (9)      −0.011 (11)
  C62A   0.067 (7)      0.085 (10)     0.076 (9)      0.013 (7)      0.021 (6)      0.042 (8)
  O11B   0.098 (6)      0.065 (5)      0.090 (6)      −0.032 (4)     −0.020 (4)     −0.008 (4)
  O12B   0.076 (5)      0.063 (5)      0.061 (4)      −0.022 (4)     −0.016 (3)     −0.002 (4)
  C56B   0.055 (6)      0.057 (7)      0.064 (8)      −0.019 (5)     0.005 (5)      −0.018 (6)
  C57B   0.055 (7)      0.030 (5)      0.041 (6)      0.000 (4)      0.007 (4)      0.005 (4)
  C58B   0.068 (8)      0.058 (8)      0.061 (7)      −0.009 (6)     −0.001 (6)     0.008 (6)
  C59B   0.099 (10)     0.052 (8)      0.103 (11)     −0.038 (7)     −0.012 (8)     −0.031 (7)
  C60B   0.092 (9)      0.088 (10)     0.069 (8)      −0.034 (8)     −0.007 (6)     −0.008 (7)
  C61B   0.068 (7)      0.102 (11)     0.066 (7)      −0.010 (7)     −0.002 (5)     0.006 (7)
  C62B   0.054 (6)      0.109 (13)     0.022 (4)      −0.048 (7)     −0.005 (4)     −0.002 (6)
  ------ -------------- -------------- -------------- -------------- -------------- --------------

Geometric parameters (Å, °) {#tablewrapgeomlong}
===========================

  ------------------- ------------- -------------------- ------------
  Pb1---O1            2.359 (3)     C29---H29A           0.9300
  Pb1---O2            2.594 (3)     C30---C31            1.373 (6)
  Pb1---O3            2.477 (4)     C30---H30A           0.9300
  Pb1---O4            2.771 (4)     C31---H31A           0.9300
  Pb1---N1            2.587 (3)     C32---C33            1.491 (6)
  Pb1---N2            2.596 (4)     C33---C34            1.370 (6)
  Pb1---O2^i^         3.359 (3)     C33---C38            1.378 (6)
  O1---C1             1.262 (5)     C34---C35            1.372 (7)
  O2---C1             1.239 (5)     C34---H34A           0.9300
  O3---C8             1.258 (5)     C35---C36            1.365 (8)
  O4---C8             1.247 (6)     C35---H35A           0.9300
  N1---C20            1.331 (6)     C36---C37            1.368 (8)
  N1---C24            1.338 (6)     C36---H36A           0.9300
  N2---C15            1.325 (6)     C37---C38            1.379 (7)
  N2---C19            1.331 (5)     C37---H37A           0.9300
  C1---C2             1.518 (6)     C38---H38A           0.9300
  C2---C7             1.362 (6)     C39---C40            1.347 (7)
  C2---C3             1.384 (6)     C39---H39A           0.9300
  C3---C4             1.379 (7)     C40---C41            1.374 (8)
  C3---H3A            0.9300        C40---H40A           0.9300
  C4---C5             1.353 (8)     C41---C42            1.365 (8)
  C4---H4A            0.9300        C41---H41A           0.9300
  C5---C6             1.361 (7)     C42---C43            1.383 (7)
  C5---H5A            0.9300        C42---H42A           0.9300
  C6---C7             1.390 (7)     C43---C44            1.478 (6)
  C6---H6A            0.9300        C44---C45            1.381 (6)
  C7---H7A            0.9300        C45---C46            1.377 (8)
  C8---C14            1.493 (6)     C45---H45A           0.9300
  C9---C14            1.369 (7)     C46---C47            1.359 (8)
  C9---C10            1.401 (8)     C46---H46A           0.9300
  C9---H9A            0.9300        C47---C48            1.394 (7)
  C10---C11           1.346 (9)     C47---H47A           0.9300
  C10---H10A          0.9300        C48---H48A           0.9300
  C11---C12           1.344 (9)     O9---C49             1.208 (7)
  C11---H11A          0.9300        O10---C49            1.307 (7)
  C12---C13           1.364 (8)     O10---H10            0.8500
  C12---H12A          0.9300        C49---C50            1.472 (7)
  C13---C14           1.373 (7)     C50---C51            1.368 (8)
  C13---H13A          0.9300        C50---C55            1.385 (8)
  C15---C16           1.360 (8)     C51---C52            1.432 (8)
  C15---H15A          0.9300        C51---H51A           0.9300
  C16---C17           1.353 (9)     C52---C53            1.353 (10)
  C16---H16A          0.9300        C52---H52A           0.9300
  C17---C18           1.377 (9)     C53---C54            1.384 (10)
  C17---H17A          0.9300        C53---H53A           0.9300
  C18---C19           1.377 (7)     C54---C55            1.363 (8)
  C18---H18A          0.9300        C54---H54A           0.9300
  C19---C20           1.489 (6)     C55---H55A           0.9300
  C20---C21           1.391 (6)     O11A---C56A          1.197 (12)
  C21---C22           1.364 (8)     O12A---C56A          1.325 (12)
  C21---H21A          0.9300        O12A---H12C          0.8500
  C22---C23           1.364 (8)     C56A---C57A          1.501 (11)
  C22---H22A          0.9300        C57A---C58A          1.3900
  C23---C24           1.377 (7)     C57A---C62A          1.3900
  C23---H23A          0.9300        C58A---C59A          1.3900
  C24---H24A          0.9300        C58A---H58A          0.9300
  Pb2---O5            2.404 (3)     C59A---C60A          1.3900
  Pb2---O6            2.698 (3)     C59A---H59A          0.9300
  Pb2---O7            2.509 (3)     C60A---C61A          1.3900
  Pb2---O8            2.686 (3)     C60A---H60A          0.9300
  Pb2---N3            2.615 (4)     C61A---C62A          1.3900
  Pb2---N4            2.562 (4)     C61A---H61A          0.9300
  Pb2---O7^ii^        3.046 (3)     C62A---H62A          0.9300
  O5---C25            1.283 (5)     O11B---C56B          1.169 (13)
  O6---C25            1.238 (5)     O12B---C56B          1.299 (13)
  O7---C32            1.279 (5)     O12B---H12B          0.8500
  O8---C32            1.247 (5)     C56B---C57B          1.499 (13)
  N3---C39            1.336 (6)     C57B---C58B          1.3900
  N3---C43            1.339 (5)     C57B---C62B          1.3900
  N4---C44            1.343 (6)     C58B---C59B          1.3900
  N4---C48            1.344 (6)     C58B---H58B          0.9300
  C25---C26           1.482 (6)     C59B---C60B          1.3900
  C26---C27           1.372 (6)     C59B---H59B          0.9300
  C26---C31           1.375 (6)     C60B---C61B          1.3900
  C27---C28           1.370 (8)     C60B---H60B          0.9300
  C27---H27A          0.9300        C61B---C62B          1.3900
  C28---C29           1.346 (9)     C61B---H61B          0.9300
  C28---H28A          0.9300        C62B---H62B          0.9300
  C29---C30           1.372 (8)                          
                                                         
  O1---Pb1---O3       85.77 (12)    O6---C25---C26       121.2 (4)
  O1---Pb1---N1       78.51 (10)    O5---C25---C26       117.7 (4)
  O3---Pb1---N1       77.71 (11)    C27---C26---C31      117.6 (4)
  O1---Pb1---O2       52.47 (10)    C27---C26---C25      119.9 (4)
  O3---Pb1---O2       119.86 (12)   C31---C26---C25      122.5 (4)
  N1---Pb1---O2       122.69 (11)   C28---C27---C26      121.4 (5)
  O1---Pb1---N2       81.89 (12)    C28---C27---H27A     119.3
  O3---Pb1---N2       139.91 (11)   C26---C27---H27A     119.3
  N1---Pb1---N2       62.50 (12)    C29---C28---C27      120.4 (5)
  O2---Pb1---N2       81.03 (12)    C29---C28---H28A     119.8
  O1---Pb1---C1       26.42 (11)    C27---C28---H28A     119.8
  O3---Pb1---C1       102.85 (13)   C28---C29---C30      119.6 (5)
  N1---Pb1---C1       101.75 (12)   C28---C29---H29A     120.2
  O2---Pb1---C1       26.10 (11)    C30---C29---H29A     120.2
  N2---Pb1---C1       81.72 (13)    C29---C30---C31      120.0 (5)
  O1---Pb1---O2^i^    113.58 (9)    C29---C30---H30A     120.0
  O3---Pb1---O2^i^    136.89 (10)   C31---C30---H30A     120.0
  N1---Pb1---O2^i^    141.64 (11)   C30---C31---C26      120.9 (4)
  O2---Pb1---O2^i^    61.44 (11)    C30---C31---H31A     119.5
  N2---Pb1---O2^i^    82.59 (10)    C26---C31---H31A     119.5
  C1---Pb1---O2^i^    87.48 (11)    O8---C32---O7        122.7 (4)
  C1---O1---Pb1       97.3 (3)      O8---C32---C33       119.5 (4)
  C1---O2---Pb1       86.8 (3)      O7---C32---C33       117.8 (4)
  C8---O3---Pb1       100.9 (3)     C34---C33---C38      117.8 (4)
  C20---N1---C24      118.6 (4)     C34---C33---C32      122.0 (4)
  C20---N1---Pb1      121.2 (3)     C38---C33---C32      120.2 (4)
  C24---N1---Pb1      119.3 (3)     C33---C34---C35      121.9 (5)
  C15---N2---C19      119.0 (4)     C33---C34---H34A     119.0
  C15---N2---Pb1      118.9 (3)     C35---C34---H34A     119.0
  C19---N2---Pb1      121.4 (3)     C36---C35---C34      119.8 (5)
  O2---C1---O1        123.2 (4)     C36---C35---H35A     120.1
  O2---C1---C2        119.1 (4)     C34---C35---H35A     120.1
  O1---C1---C2        117.8 (4)     C35---C36---C37      119.3 (5)
  O2---C1---Pb1       67.1 (3)      C35---C36---H36A     120.3
  O1---C1---Pb1       56.3 (2)      C37---C36---H36A     120.3
  C2---C1---Pb1       173.2 (3)     C36---C37---C38      120.5 (6)
  C7---C2---C3        118.8 (4)     C36---C37---H37A     119.7
  C7---C2---C1        122.4 (4)     C38---C37---H37A     119.7
  C3---C2---C1        118.8 (4)     C33---C38---C37      120.6 (5)
  C4---C3---C2        120.0 (5)     C33---C38---H38A     119.7
  C4---C3---H3A       120.0         C37---C38---H38A     119.7
  C2---C3---H3A       120.0         N3---C39---C40       123.6 (5)
  C5---C4---C3        120.8 (5)     N3---C39---H39A      118.2
  C5---C4---H4A       119.6         C40---C39---H39A     118.2
  C3---C4---H4A       119.6         C39---C40---C41      118.2 (5)
  C4---C5---C6        119.8 (5)     C39---C40---H40A     120.9
  C4---C5---H5A       120.1         C41---C40---H40A     120.9
  C6---C5---H5A       120.1         C42---C41---C40      119.3 (5)
  C5---C6---C7        120.1 (5)     C42---C41---H41A     120.3
  C5---C6---H6A       120.0         C40---C41---H41A     120.3
  C7---C6---H6A       120.0         C41---C42---C43      119.8 (5)
  C2---C7---C6        120.5 (4)     C41---C42---H42A     120.1
  C2---C7---H7A       119.8         C43---C42---H42A     120.1
  C6---C7---H7A       119.8         N3---C43---C42       120.3 (4)
  O4---C8---O3        122.7 (5)     N3---C43---C44       115.5 (4)
  O4---C8---C14       119.9 (4)     C42---C43---C44      124.2 (4)
  O3---C8---C14       117.3 (4)     N4---C44---C45       121.2 (4)
  C14---C9---C10      119.3 (5)     N4---C44---C43       117.2 (4)
  C14---C9---H9A      120.3         C45---C44---C43      121.6 (4)
  C10---C9---H9A      120.3         C46---C45---C44      119.9 (5)
  C11---C10---C9      120.4 (6)     C46---C45---H45A     120.1
  C11---C10---H10A    119.8         C44---C45---H45A     120.1
  C9---C10---H10A     119.8         C47---C46---C45      118.7 (5)
  C12---C11---C10     120.1 (6)     C47---C46---H46A     120.7
  C12---C11---H11A    119.9         C45---C46---H46A     120.7
  C10---C11---H11A    119.9         C46---C47---C48      120.1 (5)
  C11---C12---C13     120.5 (6)     C46---C47---H47A     120.0
  C11---C12---H12A    119.7         C48---C47---H47A     120.0
  C13---C12---H12A    119.7         N4---C48---C47       120.8 (5)
  C12---C13---C14     120.9 (6)     N4---C48---H48A      119.6
  C12---C13---H13A    119.5         C47---C48---H48A     119.6
  C14---C13---H13A    119.5         C49---O10---H10      114.6
  C9---C14---C13      118.7 (5)     O9---C49---O10       120.6 (5)
  C9---C14---C8       121.4 (4)     O9---C49---C50       124.8 (6)
  C13---C14---C8      120.0 (4)     O10---C49---C50      114.6 (6)
  N2---C15---C16      122.8 (6)     C51---C50---C55      120.2 (5)
  N2---C15---H15A     118.6         C51---C50---C49      118.4 (6)
  C16---C15---H15A    118.6         C55---C50---C49      121.3 (6)
  C17---C16---C15     118.8 (6)     C50---C51---C52      119.1 (6)
  C17---C16---H16A    120.6         C50---C51---H51A     120.4
  C15---C16---H16A    120.6         C52---C51---H51A     120.4
  C16---C17---C18     119.2 (6)     C53---C52---C51      120.2 (7)
  C16---C17---H17A    120.4         C53---C52---H52A     119.9
  C18---C17---H17A    120.4         C51---C52---H52A     119.9
  C19---C18---C17     119.1 (6)     C52---C53---C54      119.0 (6)
  C19---C18---H18A    120.4         C52---C53---H53A     120.5
  C17---C18---H18A    120.4         C54---C53---H53A     120.5
  N2---C19---C18      120.9 (5)     C55---C54---C53      122.1 (7)
  N2---C19---C20      116.5 (4)     C55---C54---H54A     119.0
  C18---C19---C20     122.6 (5)     C53---C54---H54A     119.0
  N1---C20---C21      121.4 (5)     C54---C55---C50      119.4 (7)
  N1---C20---C19      117.1 (4)     C54---C55---H55A     120.3
  C21---C20---C19     121.4 (5)     C50---C55---H55A     120.3
  C22---C21---C20     118.9 (5)     C56A---O12A---H12C   112.4
  C22---C21---H21A    120.5         O11A---C56A---O12A   123.9 (10)
  C20---C21---H21A    120.5         O11A---C56A---C57A   116.3 (10)
  C21---C22---C23     120.0 (5)     O12A---C56A---C57A   119.6 (8)
  C21---C22---H22A    120.0         C58A---C57A---C62A   120.0
  C23---C22---H22A    120.0         C58A---C57A---C56A   129.3 (5)
  C22---C23---C24     118.2 (5)     C62A---C57A---C56A   110.4 (5)
  C22---C23---H23A    120.9         C59A---C58A---C57A   120.0
  C24---C23---H23A    120.9         C59A---C58A---H58A   120.0
  N1---C24---C23      122.8 (5)     C57A---C58A---H58A   120.0
  N1---C24---H24A     118.6         C60A---C59A---C58A   120.0
  C23---C24---H24A    118.6         C60A---C59A---H59A   120.0
  O5---Pb2---O7       80.77 (10)    C58A---C59A---H59A   120.0
  O5---Pb2---N4       72.88 (10)    C59A---C60A---C61A   120.0
  O7---Pb2---N4       79.87 (11)    C59A---C60A---H60A   120.0
  O5---Pb2---N3       89.37 (11)    C61A---C60A---H60A   120.0
  O7---Pb2---N3       142.43 (11)   C62A---C61A---C60A   120.0
  N4---Pb2---N3       62.61 (12)    C62A---C61A---H61A   120.0
  O5---Pb2---O8       77.15 (11)    C60A---C61A---H61A   120.0
  O7---Pb2---O8       50.36 (10)    C61A---C62A---C57A   120.0
  N4---Pb2---O8       125.09 (11)   C61A---C62A---H62A   120.0
  N3---Pb2---O8       160.03 (11)   C57A---C62A---H62A   120.0
  O5---Pb2---O6       50.57 (9)     C56B---O12B---H12B   109.5
  O7---Pb2---O6       122.01 (10)   O11B---C56B---O12B   128.9 (10)
  N4---Pb2---O6       107.79 (11)   O11B---C56B---C57B   118.7 (11)
  N3---Pb2---O6       74.58 (11)    O12B---C56B---C57B   112.5 (10)
  O8---Pb2---O6       85.46 (11)    C58B---C57B---C62B   120.0
  O5---Pb2---O7^ii^   139.48 (9)    C58B---C57B---C56B   123.4 (8)
  O7---Pb2---O7^ii^   73.74 (10)    C62B---C57B---C56B   116.3 (8)
  N4---Pb2---O7^ii^   72.03 (10)    C57B---C58B---C59B   120.0
  N3---Pb2---O7^ii^   92.05 (10)    C57B---C58B---H58B   120.0
  O8---Pb2---O7^ii^   107.79 (10)   C59B---C58B---H58B   120.0
  O6---Pb2---O7^ii^   164.22 (10)   C60B---C59B---C58B   120.0
  C25---O5---Pb2      100.5 (2)     C60B---C59B---H59B   120.0
  C25---O6---Pb2      87.8 (3)      C58B---C59B---H59B   120.0
  C32---O7---Pb2      97.1 (3)      C61B---C60B---C59B   120.0
  C32---O8---Pb2      89.6 (3)      C61B---C60B---H60B   120.0
  C39---N3---C43      118.7 (4)     C59B---C60B---H60B   120.0
  C39---N3---Pb2      118.8 (3)     C62B---C61B---C60B   120.0
  C43---N3---Pb2      119.7 (3)     C62B---C61B---H61B   120.0
  C44---N4---C48      119.4 (4)     C60B---C61B---H61B   120.0
  C44---N4---Pb2      121.8 (3)     C61B---C62B---C57B   120.0
  C48---N4---Pb2      118.3 (3)     C61B---C62B---H62B   120.0
  O6---C25---O5       121.1 (4)     C57B---C62B---H62B   120.0
  ------------------- ------------- -------------------- ------------

Symmetry codes: (i) −*x*, −*y*+1, −*z*+2; (ii) −*x*+1, −*y*+1, −*z*+1.

Hydrogen-bond geometry (Å, °) {#tablewraphbondslong}
=============================

  ----------------------- --------- --------- ----------- ---------------
  *D*---H···*A*           *D*---H   H···*A*   *D*···*A*   *D*---H···*A*
  O10---H10···O5          0.85      1.83      2.670 (5)   171
  O12A---H12C···O9^iii^   0.85      1.62      2.459 (9)   169
  O12B---H12B···O4^iv^    0.85      1.81      2.612 (6)   158
  ----------------------- --------- --------- ----------- ---------------

Symmetry codes: (iii) *x*, *y*−1, *z*; (iv) −*x*, −*y*+1, −*z*+1.

###### Hydrogen-bond geometry (Å, °)

  *D*---H⋯*A*              *D*---H   H⋯*A*   *D*⋯*A*     *D*---H⋯*A*
  ------------------------ --------- ------- ----------- -------------
  O10---H10⋯O5             0.85      1.83    2.670 (5)   171
  O12*A*---H12*C*⋯O9^i^    0.85      1.62    2.459 (9)   169
  O12*B*---H12*B*⋯O4^ii^   0.85      1.81    2.612 (6)   158

Symmetry codes: (i) ; (ii) .
