Related literature {#sec1}
==================

For related literature, see: Barbour *et al.* (1993[@bb1]); Ibragimov *et al.* (2001[@bb2]); Sardone (1996[@bb3]); Sumarna *et al.* (2003[@bb7]); Weber *et al.* (1993[@bb8]).

Experimental {#sec2}
============

 {#sec2.1}

### Crystal data {#sec2.1.1}

C~38~H~26~O~2~·C~4~H~8~O~2~*M* *~r~* = 602.69Monoclinic,*a* = 11.645 (2) Å*b* = 16.364 (3) Å*c* = 17.471 (3) Åβ = 97.72 (3)°*V* = 3299.1 (10) Å^3^*Z* = 4Mo *K*α radiationμ = 0.08 mm^−1^*T* = 293 (2) K0.4 × 0.2 × 0.2 mm

### Data collection {#sec2.1.2}

Stoe STADI4 diffractometerAbsorption correction: none5807 measured reflections5650 independent reflections3654 reflections with *I* \> 2σ(*I*)3 standard reflections every 100 reflections intensity decay: 2.6%

### Refinement {#sec2.1.3}

*R*\[*F* ^2^ \> 2σ(*F* ^2^)\] = 0.068*wR*(*F* ^2^) = 0.141*S* = 1.205650 reflections424 parametersH atoms treated by a mixture of independent and constrained refinementΔρ~max~ = 0.24 e Å^−3^Δρ~min~ = −0.16 e Å^−3^

 {#d5e431}

Data collection: *STADI4* (Stoe & Cie, 1997[@bb6]); cell refinement: *STADI4*; data reduction: *X-RED* (Stoe & Cie, 1997[@bb6]); program(s) used to solve structure: *SHELXS97* (Sheldrick, 2008[@bb4]); program(s) used to refine structure: *SHELXL97* (Sheldrick, 2008[@bb4]); molecular graphics: *XP* (Siemens, 1994[@bb5]); software used to prepare material for publication: *SHELXL97*.

Supplementary Material
======================

Crystal structure: contains datablocks I, global. DOI: [10.1107/S1600536808023271/gk2155sup1.cif](http://dx.doi.org/10.1107/S1600536808023271/gk2155sup1.cif)

Structure factors: contains datablocks I. DOI: [10.1107/S1600536808023271/gk2155Isup2.hkl](http://dx.doi.org/10.1107/S1600536808023271/gk2155Isup2.hkl)

Additional supplementary materials: [crystallographic information](http://scripts.iucr.org/cgi-bin/sendsupfiles?gk2155&file=gk2155sup0.html&mime=text/html); [3D view](http://scripts.iucr.org/cgi-bin/sendcif?gk2155sup1&Qmime=cif); [checkCIF report](http://scripts.iucr.org/cgi-bin/paper?gk2155&checkcif=yes)

Supplementary data and figures for this paper are available from the IUCr electronic archives (Reference: [GK2155](http://scripts.iucr.org/cgi-bin/sendsup?gk2155)).

Comment
=======

Crystalline inclusion compounds (clathrates, host--guest complexes) are of increasing importance in supramolecular chemistry because of their significant potential in addressing a variety of fundamental and practical issues. 2,2\'-Bis(9-hydroxy-9-fluorenyl)biphenyl (I) is a host compound with good clathrate-forming ability and the crystal structures of its inclusion compounds with acetonitrile, cyclohexanone, n-propylamine (Barbour *et al.*, 1993), acetone (three solvates) (Sardone, 1996; Ibragimov *et al.*, 2001) and chloroform (two solvates) (Sumarna *et al.*, 2003) were reported. Here, we report the crystal structure of a host--guest complex of (I) with ethyl acetate which resembles closely that of (I) with acetone (1/1) (Sardone, 1996). The molecule of (I) has three conformational degrees of freedom (rotation around the central aryl--aryl single bond and rotations around the aryl--fluorenyl bonds), however it exhibits considerable conformational rigidity due to the stabilizing effect of the intramolecular O---H···O hydrogen bond between the hydroxyl groups (Fig. 1, Table 1). The crystal packing is mainly stabilized by van der Waals forces (Fig.2).

Experimental {#experimental}
============

2,2\'-Bis(9-hydroxy-9-fluorenyl)biphenyl was synthesized according to the procedure described by Weber *et al.*, (1993). The stable in the air crystals were grown by slow evaporation from ethyl acetate solution.

Refinement {#refinement}
==========

H atoms from the OH groups were located from difference Fourier maps and fully refined. The remaining H atoms were positioned geometrically (C---H 0.93--0.98 Å) and refined as riding on their carrier atoms with *U*~iso~(H) = 1.2*U*~eq~(C), except the methyl groups where *U*~iso~(H) = 1.5*U*~eq~(C).

Figures
=======

![Perspective view of the title compound, showing 30% probability displacement ellipsoids for the non-H atoms. Dashed lines represent hydrogen bonds.](e-64-o1627-fig1){#Fap1}

![Packing diagram of the title compound (I) viewed down the a axis. H atoms have been ommited for clarity. Hydrogen bonds are shown as dashed lines.](e-64-o1627-fig2){#Fap2}

Crystal data {#tablewrapcrystaldatalong}
============

  ----------------------------- -------------------------------------
  C~38~H~26~O~2~·C~4~H~8~O~2~   *F*~000~ = 1272
  *M~r~* = 602.69               *D*~x~ = 1.213 Mg m^−3^
  Monoclinic, *P*2~1~/*c*       Mo *K*α radiation λ = 0.71073 Å
  Hall symbol: -P 2ybc          Cell parameters from 25 reflections
  *a* = 11.645 (2) Å            θ = 10--20º
  *b* = 16.364 (3) Å            µ = 0.08 mm^−1^
  *c* = 17.471 (3) Å            *T* = 293 (2) K
  β = 97.72 (3)º                Block, colourless
  *V* = 3299.1 (10) Å^3^        0.4 × 0.2 × 0.2 mm
  *Z* = 4                       
  ----------------------------- -------------------------------------

Data collection {#tablewrapdatacollectionlong}
===============

  ------------------------------------------ ------------------------
  Stoe STADI4 diffractometer                 *R*~int~ = 0.0000
  Radiation source: fine-focus sealed tube   θ~max~ = 25.0º
  Monochromator: graphite                    θ~min~ = 2.6º
  *T* = 293(2) K                             *h* = −13→11
  ω/2θ scans                                 *k* = 0→19
  Absorption correction: none                *l* = 0→20
  5650 measured reflections                  3 standard reflections
  5807 independent reflections               every 100 reflections
  3654 reflections with *I* \> 2σ(*I*)       intensity decay: 2.6%
  ------------------------------------------ ------------------------

Refinement {#tablewraprefinementdatalong}
==========

  ---------------------------------------------------------------- --------------------------------------------------------------------------------------------------
  Refinement on *F*^2^                                             Hydrogen site location: inferred from neighbouring sites
  Least-squares matrix: full                                       H atoms treated by a mixture of independent and constrained refinement
  *R*\[*F*^2^ \> 2σ(*F*^2^)\] = 0.068                                *w* = 1/\[σ^2^(*F*~o~^2^) + (0.0281*P*)^2^ + 2.047*P*\] where *P* = (*F*~o~^2^ + 2*F*~c~^2^)/3
  *wR*(*F*^2^) = 0.141                                             (Δ/σ)~max~ \< 0.001
  *S* = 1.20                                                       Δρ~max~ = 0.24 e Å^−3^
  5650 reflections                                                 Δρ~min~ = −0.16 e Å^−3^
  424 parameters                                                   Extinction correction: SHELXL97 (Sheldrick, 2008), Fc^\*^=kFc\[1+0.001xFc^2^λ^3^/sin(2θ)\]^-1/4^
  Primary atom site location: structure-invariant direct methods   Extinction coefficient: 0.0048 (4)
  Secondary atom site location: difference Fourier map             
  ---------------------------------------------------------------- --------------------------------------------------------------------------------------------------

Special details {#specialdetails}
===============

  -----------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------
  Geometry. All e.s.d.\'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.\'s are taken into account individually in the estimation of e.s.d.\'s in distances, angles and torsion angles; correlations between e.s.d.\'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.\'s is used for estimating e.s.d.\'s involving l.s. planes.
  Refinement. Refinement of *F*^2^ against ALL reflections. The weighted *R*-factor *wR* and goodness of fit *S* are based on *F*^2^, conventional *R*-factors *R* are based on *F*, with *F* set to zero for negative *F*^2^. The threshold expression of *F*^2^ \> σ(*F*^2^) is used only for calculating *R*-factors(gt) *etc*. and is not relevant to the choice of reflections for refinement. *R*-factors based on *F*^2^ are statistically about twice as large as those based on *F*, and *R*- factors based on ALL data will be even larger.
  -----------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å^2^) {#tablewrapcoords}
==================================================================================================

  ------ -------------- -------------- --------------- -------------------- --
         *x*            *y*            *z*             *U*~iso~\*/*U*~eq~   
  O1     0.70308 (18)   0.69051 (14)   0.20949 (13)    0.0518 (6)           
  O2     0.63649 (17)   0.85042 (13)   0.21819 (12)    0.0470 (5)           
  C1     0.8676 (3)     0.62161 (19)   0.1739 (2)      0.0511 (8)           
  C2     0.8325 (3)     0.5837 (2)     0.1044 (2)      0.0716 (11)          
  H2A    0.7765         0.6073         0.0681          0.086\*              
  C3     0.8827 (4)     0.5090 (3)     0.0897 (3)      0.0937 (14)          
  H3A    0.8596         0.4822         0.0432          0.112\*              
  C4     0.9657 (5)     0.4747 (3)     0.1430 (4)      0.0995 (17)          
  H4A    0.9982         0.4248         0.1321          0.119\*              
  C5     1.0019 (3)     0.5126 (3)     0.2122 (3)      0.0828 (13)          
  H5A    1.0588         0.4889         0.2478          0.099\*              
  C6     0.9523 (3)     0.5867 (2)     0.2280 (2)      0.0616 (10)          
  C7     0.9683 (3)     0.6387 (2)     0.2964 (2)      0.0633 (10)          
  C8     1.0404 (4)     0.6306 (3)     0.3666 (3)      0.0891 (14)          
  H8A    1.0925         0.5874         0.3749          0.107\*              
  C9     1.0330 (5)     0.6877 (4)     0.4232 (3)      0.1026 (18)          
  H9A    1.0814         0.6831         0.4698          0.123\*              
  C10    0.9559 (4)     0.7516 (3)     0.4126 (2)      0.0903 (14)          
  H10A   0.9510         0.7885         0.4526          0.108\*              
  C11    0.8848 (3)     0.7614 (2)     0.3424 (2)      0.0701 (10)          
  H11A   0.8334         0.8050         0.3343          0.084\*              
  C12    0.8930 (3)     0.7041 (2)     0.28501 (19)    0.0545 (9)           
  C13    0.8229 (3)     0.70131 (18)   0.20394 (17)    0.0460 (7)           
  C14    0.8464 (3)     0.77519 (18)   0.15426 (17)    0.0434 (7)           
  C15    0.9585 (3)     0.8074 (2)     0.16490 (18)    0.0527 (8)           
  H15A   1.0139         0.7835         0.2013          0.063\*              
  C16    0.9899 (3)     0.8735 (2)     0.1234 (2)      0.0592 (9)           
  H16A   1.0655         0.8931         0.1315          0.071\*              
  C17    0.9087 (3)     0.9100 (2)     0.07009 (19)    0.0597 (9)           
  H17A   0.9284         0.9551         0.0422          0.072\*              
  C18    0.7978 (3)     0.87899 (19)   0.05842 (18)    0.0524 (8)           
  H18A   0.7434         0.9038         0.0219          0.063\*              
  C19    0.7638 (3)     0.81209 (18)   0.09903 (16)    0.0433 (7)           
  C20    0.6441 (3)     0.77988 (17)   0.06964 (16)    0.0423 (7)           
  C21    0.6384 (3)     0.73514 (19)   0.00138 (17)    0.0523 (8)           
  H21A   0.7072         0.7234         −0.0180         0.063\*              
  C22    0.5355 (3)     0.7074 (2)     −0.03899 (18)   0.0584 (9)           
  H22A   0.5351         0.6771         −0.0840         0.070\*              
  C23    0.4340 (3)     0.7258 (2)     −0.01101 (18)   0.0578 (9)           
  H23A   0.3637         0.7078         −0.0371         0.069\*              
  C24    0.4363 (3)     0.77059 (19)   0.05528 (18)    0.0514 (8)           
  H24A   0.3665         0.7831         0.0730          0.062\*              
  C25    0.5396 (3)     0.79833 (17)   0.09746 (16)    0.0414 (7)           
  C26    0.5264 (2)     0.84892 (18)   0.16933 (16)    0.0424 (7)           
  C27    0.4832 (3)     0.93557 (18)   0.14954 (17)    0.0470 (8)           
  C28    0.5316 (3)     0.9954 (2)     0.10912 (19)    0.0614 (9)           
  H28A   0.5993         0.9855         0.0878          0.074\*              
  C29    0.4774 (4)     1.0712 (2)     0.1008 (2)      0.0726 (11)          
  H29A   0.5088         1.1124         0.0733          0.087\*              
  C30    0.3779 (4)     1.0858 (2)     0.1327 (2)      0.0762 (12)          
  H30A   0.3433         1.1370         0.1270          0.091\*              
  C31    0.3284 (3)     1.0264 (2)     0.1728 (2)      0.0682 (10)          
  H31A   0.2605         1.0367         0.1938          0.082\*              
  C32    0.3816 (3)     0.9507 (2)     0.18140 (17)    0.0511 (8)           
  C33    0.3506 (3)     0.8771 (2)     0.22174 (17)    0.0503 (8)           
  C34    0.2593 (3)     0.8615 (3)     0.2634 (2)      0.0678 (11)          
  H34A   0.2048         0.9018         0.2692          0.081\*              
  C35    0.2510 (3)     0.7854 (3)     0.2959 (2)      0.0734 (12)          
  H35A   0.1899         0.7743         0.3235          0.088\*              
  C36    0.3315 (3)     0.7256 (3)     0.28821 (19)    0.0673 (10)          
  H36A   0.3241         0.6746         0.3105          0.081\*              
  C37    0.4236 (3)     0.7407 (2)     0.24757 (18)    0.0548 (9)           
  H37A   0.4785         0.7005         0.2425          0.066\*              
  C38    0.4321 (3)     0.81679 (19)   0.21478 (16)    0.0451 (8)           
  C39    0.5324 (3)     0.5281 (3)     0.1162 (2)      0.0869 (13)          
  H39A   0.5772         0.4805         0.1328          0.130\*              
  H39B   0.5655         0.5751         0.1437          0.130\*              
  H39C   0.5330         0.5360         0.0618          0.130\*              
  C40    0.4118 (4)     0.5169 (2)     0.1319 (2)      0.0696 (11)          
  C41    0.2259 (3)     0.5774 (3)     0.1255 (3)      0.0903 (13)          
  H41A   0.2232         0.5760         0.1807          0.108\*              
  H41B   0.1883         0.5287         0.1026          0.108\*              
  C42    0.1664 (4)     0.6520 (3)     0.0910 (3)      0.0979 (15)          
  H42A   0.0869         0.6516         0.1003          0.147\*              
  H42B   0.1695         0.6527         0.0364          0.147\*              
  H42C   0.2043         0.6997         0.1142          0.147\*              
  O3     0.3748 (3)     0.45679 (18)   0.15903 (17)    0.0996 (10)          
  O4     0.3455 (2)     0.58069 (16)   0.11015 (16)    0.0795 (8)           
  H2     0.677 (3)      0.741 (2)      0.223 (2)       0.092 (14)\*         
  H1     0.627 (3)      0.883 (2)      0.257 (2)       0.098 (15)\*         
  ------ -------------- -------------- --------------- -------------------- --

Atomic displacement parameters (Å^2^) {#tablewrapadps}
=====================================

  ----- ------------- ------------- ------------- -------------- -------------- --------------
        *U*^11^       *U*^22^       *U*^33^       *U*^12^        *U*^13^        *U*^23^
  O1    0.0430 (13)   0.0475 (14)   0.0667 (15)   −0.0008 (11)   0.0142 (11)    0.0074 (12)
  O2    0.0447 (13)   0.0490 (13)   0.0467 (13)   0.0032 (10)    0.0036 (10)    −0.0076 (11)
  C1    0.0485 (19)   0.0426 (19)   0.065 (2)     −0.0026 (16)   0.0176 (17)    0.0049 (17)
  C2    0.082 (3)     0.051 (2)     0.084 (3)     0.002 (2)      0.018 (2)      −0.008 (2)
  C3    0.119 (4)     0.057 (3)     0.112 (4)     0.005 (3)      0.040 (3)      −0.018 (3)
  C4    0.107 (4)     0.050 (3)     0.155 (5)     0.011 (3)      0.068 (4)      0.007 (3)
  C5    0.063 (3)     0.059 (3)     0.132 (4)     0.013 (2)      0.037 (3)      0.035 (3)
  C6    0.050 (2)     0.048 (2)     0.089 (3)     0.0038 (17)    0.021 (2)      0.021 (2)
  C7    0.049 (2)     0.066 (2)     0.074 (3)     −0.0098 (19)   0.0057 (19)    0.030 (2)
  C8    0.071 (3)     0.097 (4)     0.094 (3)     −0.016 (3)     −0.007 (3)     0.050 (3)
  C9    0.104 (4)     0.126 (5)     0.071 (3)     −0.048 (4)     −0.016 (3)     0.042 (3)
  C10   0.099 (4)     0.116 (4)     0.054 (3)     −0.047 (3)     0.007 (2)      0.004 (3)
  C11   0.071 (3)     0.079 (3)     0.061 (2)     −0.021 (2)     0.011 (2)      0.002 (2)
  C12   0.053 (2)     0.057 (2)     0.053 (2)     −0.0129 (18)   0.0085 (16)    0.0087 (17)
  C13   0.0390 (18)   0.0460 (18)   0.0540 (19)   −0.0014 (14)   0.0100 (14)    0.0024 (15)
  C14   0.0471 (19)   0.0391 (17)   0.0466 (18)   −0.0027 (14)   0.0155 (15)    −0.0051 (14)
  C15   0.047 (2)     0.056 (2)     0.055 (2)     −0.0029 (17)   0.0090 (16)    −0.0008 (17)
  C16   0.056 (2)     0.063 (2)     0.063 (2)     −0.0176 (18)   0.0205 (18)    −0.0044 (19)
  C17   0.073 (3)     0.053 (2)     0.056 (2)     −0.0111 (19)   0.0217 (19)    0.0012 (17)
  C18   0.061 (2)     0.048 (2)     0.0491 (19)   −0.0008 (17)   0.0138 (16)    0.0026 (16)
  C19   0.0537 (19)   0.0388 (17)   0.0392 (16)   0.0013 (15)    0.0131 (14)    −0.0020 (14)
  C20   0.0490 (19)   0.0391 (17)   0.0389 (16)   0.0011 (14)    0.0066 (14)    0.0019 (13)
  C21   0.063 (2)     0.050 (2)     0.0453 (18)   0.0062 (17)    0.0116 (16)    −0.0004 (15)
  C22   0.083 (3)     0.051 (2)     0.0395 (18)   −0.0038 (19)   0.0034 (18)    −0.0082 (16)
  C23   0.066 (2)     0.059 (2)     0.0458 (19)   −0.0139 (18)   −0.0034 (17)   −0.0015 (17)
  C24   0.051 (2)     0.054 (2)     0.0489 (19)   −0.0045 (16)   0.0051 (16)    0.0017 (16)
  C25   0.0466 (19)   0.0363 (16)   0.0411 (16)   −0.0015 (14)   0.0054 (14)    0.0038 (13)
  C26   0.0416 (18)   0.0440 (18)   0.0418 (17)   0.0010 (14)    0.0059 (14)    −0.0029 (14)
  C27   0.055 (2)     0.0431 (18)   0.0416 (17)   0.0042 (15)    0.0021 (15)    −0.0021 (15)
  C28   0.078 (3)     0.051 (2)     0.057 (2)     0.0031 (19)    0.0170 (19)    −0.0005 (17)
  C29   0.110 (3)     0.046 (2)     0.061 (2)     0.006 (2)      0.008 (2)      0.0046 (18)
  C30   0.113 (4)     0.055 (2)     0.058 (2)     0.033 (2)      0.003 (2)      −0.0008 (19)
  C31   0.077 (3)     0.072 (3)     0.056 (2)     0.029 (2)      0.0095 (19)    0.002 (2)
  C32   0.053 (2)     0.055 (2)     0.0449 (18)   0.0139 (17)    0.0031 (15)    −0.0025 (16)
  C33   0.0410 (19)   0.067 (2)     0.0424 (17)   0.0075 (17)    0.0030 (14)    −0.0042 (16)
  C34   0.044 (2)     0.102 (3)     0.058 (2)     0.012 (2)      0.0087 (17)    0.001 (2)
  C35   0.052 (2)     0.117 (4)     0.052 (2)     −0.015 (2)     0.0106 (18)    0.007 (2)
  C36   0.067 (2)     0.083 (3)     0.051 (2)     −0.018 (2)     0.0041 (19)    0.0135 (19)
  C37   0.056 (2)     0.055 (2)     0.053 (2)     −0.0053 (17)   0.0055 (17)    0.0032 (16)
  C38   0.0438 (18)   0.052 (2)     0.0393 (17)   −0.0020 (15)   0.0046 (14)    −0.0004 (15)
  C39   0.072 (3)     0.086 (3)     0.099 (3)     0.003 (2)      −0.003 (2)     0.013 (3)
  C40   0.086 (3)     0.062 (3)     0.057 (2)     −0.009 (2)     −0.004 (2)     0.015 (2)
  C41   0.072 (3)     0.103 (4)     0.100 (3)     −0.019 (3)     0.027 (3)      0.007 (3)
  C42   0.071 (3)     0.095 (3)     0.130 (4)     0.000 (3)      0.024 (3)      −0.001 (3)
  O3    0.119 (2)     0.086 (2)     0.091 (2)     −0.0147 (19)   0.0023 (18)    0.0400 (18)
  O4    0.0705 (18)   0.0692 (18)   0.101 (2)     −0.0052 (14)   0.0190 (15)    0.0229 (15)
  ----- ------------- ------------- ------------- -------------- -------------- --------------

Geometric parameters (Å, °) {#tablewrapgeomlong}
===========================

  ------------------ ----------- ------------------- -----------
  O1---C13           1.423 (3)   C22---C23           1.372 (5)
  O1---H2            0.93 (4)    C22---H22A          0.9300
  O2---C26           1.442 (3)   C23---C24           1.368 (4)
  O2---H1            0.88 (4)    C23---H23A          0.9300
  C1---C2            1.375 (5)   C24---C25           1.399 (4)
  C1---C6            1.394 (4)   C24---H24A          0.9300
  C1---C13           1.524 (4)   C25---C26           1.529 (4)
  C2---C3            1.394 (5)   C26---C27           1.528 (4)
  C2---H2A           0.9300      C26---C38           1.532 (4)
  C3---C4            1.369 (6)   C27---C28           1.372 (4)
  C3---H3A           0.9300      C27---C32           1.396 (4)
  C4---C5            1.373 (6)   C28---C29           1.391 (5)
  C4---H4A           0.9300      C28---H28A          0.9300
  C5---C6            1.388 (5)   C29---C30           1.372 (5)
  C5---H5A           0.9300      C29---H29A          0.9300
  C6---C7            1.457 (5)   C30---C31           1.370 (5)
  C7---C12           1.382 (5)   C30---H30A          0.9300
  C7---C8            1.397 (5)   C31---C32           1.384 (4)
  C8---C9            1.370 (6)   C31---H31A          0.9300
  C8---H8A           0.9300      C32---C33           1.464 (4)
  C9---C10           1.375 (7)   C33---C38           1.386 (4)
  C9---H9A           0.9300      C33---C34           1.390 (4)
  C10---C11          1.394 (5)   C34---C35           1.378 (5)
  C10---H10A         0.9300      C34---H34A          0.9300
  C11---C12          1.385 (5)   C35---C36           1.374 (5)
  C11---H11A         0.9300      C35---H35A          0.9300
  C12---C13          1.537 (4)   C36---C37           1.386 (5)
  C13---C14          1.534 (4)   C36---H36A          0.9300
  C14---C15          1.396 (4)   C37---C38           1.379 (4)
  C14---C19          1.404 (4)   C37---H37A          0.9300
  C15---C16          1.378 (4)   C39---C40           1.478 (5)
  C15---H15A         0.9300      C39---H39A          0.9600
  C16---C17          1.372 (5)   C39---H39B          0.9600
  C16---H16A         0.9300      C39---H39C          0.9600
  C17---C18          1.377 (4)   C40---O3            1.197 (4)
  C17---H17A         0.9300      C40---O4            1.323 (4)
  C18---C19          1.391 (4)   C41---O4            1.454 (4)
  C18---H18A         0.9300      C41---C42           1.491 (5)
  C19---C20          1.514 (4)   C41---H41A          0.9700
  C20---C21          1.393 (4)   C41---H41B          0.9700
  C20---C25          1.403 (4)   C42---H42A          0.9600
  C21---C22          1.383 (4)   C42---H42B          0.9600
  C21---H21A         0.9300      C42---H42C          0.9600
                                                     
  C13---O1---H2      106 (2)     C24---C23---H23A    120.0
  C26---O2---H1      106 (3)     C22---C23---H23A    120.0
  C2---C1---C6       120.9 (3)   C23---C24---C25     122.5 (3)
  C2---C1---C13      128.0 (3)   C23---C24---H24A    118.7
  C6---C1---C13      111.1 (3)   C25---C24---H24A    118.7
  C1---C2---C3       118.5 (4)   C24---C25---C20     118.2 (3)
  C1---C2---H2A      120.8       C24---C25---C26     115.7 (3)
  C3---C2---H2A      120.8       C20---C25---C26     126.1 (3)
  C4---C3---C2       120.6 (5)   O2---C26---C27      110.9 (2)
  C4---C3---H3A      119.7       O2---C26---C25      108.4 (2)
  C2---C3---H3A      119.7       C27---C26---C25     112.5 (2)
  C3---C4---C5       121.3 (4)   O2---C26---C38      110.0 (2)
  C3---C4---H4A      119.4       C27---C26---C38     101.5 (2)
  C5---C4---H4A      119.4       C25---C26---C38     113.4 (2)
  C4---C5---C6       118.9 (4)   C28---C27---C32     120.5 (3)
  C4---C5---H5A      120.6       C28---C27---C26     129.3 (3)
  C6---C5---H5A      120.6       C32---C27---C26     110.2 (3)
  C5---C6---C1       119.9 (4)   C27---C28---C29     118.6 (3)
  C5---C6---C7       131.5 (4)   C27---C28---H28A    120.7
  C1---C6---C7       108.6 (3)   C29---C28---H28A    120.7
  C12---C7---C8      119.6 (4)   C30---C29---C28     120.5 (4)
  C12---C7---C6      109.0 (3)   C30---C29---H29A    119.7
  C8---C7---C6       131.4 (4)   C28---C29---H29A    119.7
  C9---C8---C7       118.7 (5)   C31---C30---C29     121.4 (3)
  C9---C8---H8A      120.6       C31---C30---H30A    119.3
  C7---C8---H8A      120.6       C29---C30---H30A    119.3
  C8---C9---C10      121.7 (5)   C30---C31---C32     118.5 (3)
  C8---C9---H9A      119.2       C30---C31---H31A    120.7
  C10---C9---H9A     119.2       C32---C31---H31A    120.7
  C9---C10---C11     120.3 (5)   C31---C32---C27     120.4 (3)
  C9---C10---H10A    119.8       C31---C32---C33     130.7 (3)
  C11---C10---H10A   119.8       C27---C32---C33     108.8 (3)
  C12---C11---C10    118.0 (4)   C38---C33---C34     119.7 (3)
  C12---C11---H11A   121.0       C38---C33---C32     109.1 (3)
  C10---C11---H11A   121.0       C34---C33---C32     131.1 (3)
  C7---C12---C11     121.6 (3)   C35---C34---C33     118.9 (3)
  C7---C12---C13     111.0 (3)   C35---C34---H34A    120.6
  C11---C12---C13    127.4 (3)   C33---C34---H34A    120.6
  O1---C13---C1      107.5 (2)   C36---C35---C34     121.1 (3)
  O1---C13---C14     112.8 (2)   C36---C35---H35A    119.4
  C1---C13---C14     112.6 (2)   C34---C35---H35A    119.4
  O1---C13---C12     110.2 (2)   C35---C36---C37     120.5 (4)
  C1---C13---C12     100.4 (3)   C35---C36---H36A    119.7
  C14---C13---C12    112.7 (3)   C37---C36---H36A    119.7
  C15---C14---C19    118.1 (3)   C38---C37---C36     118.5 (3)
  C15---C14---C13    117.2 (3)   C38---C37---H37A    120.7
  C19---C14---C13    124.8 (3)   C36---C37---H37A    120.7
  C16---C15---C14    122.4 (3)   C37---C38---C33     121.2 (3)
  C16---C15---H15A   118.8       C37---C38---C26     128.4 (3)
  C14---C15---H15A   118.8       C33---C38---C26     110.3 (3)
  C17---C16---C15    119.4 (3)   C40---C39---H39A    109.5
  C17---C16---H16A   120.3       C40---C39---H39B    109.5
  C15---C16---H16A   120.3       H39A---C39---H39B   109.5
  C16---C17---C18    119.2 (3)   C40---C39---H39C    109.5
  C16---C17---H17A   120.4       H39A---C39---H39C   109.5
  C18---C17---H17A   120.4       H39B---C39---H39C   109.5
  C17---C18---C19    122.7 (3)   O3---C40---O4       122.3 (4)
  C17---C18---H18A   118.7       O3---C40---C39      125.3 (4)
  C19---C18---H18A   118.7       O4---C40---C39      112.4 (3)
  C18---C19---C14    118.3 (3)   O4---C41---C42      107.5 (3)
  C18---C19---C20    114.4 (3)   O4---C41---H41A     110.2
  C14---C19---C20    126.7 (3)   C42---C41---H41A    110.2
  C21---C20---C25    117.8 (3)   O4---C41---H41B     110.2
  C21---C20---C19    114.2 (3)   C42---C41---H41B    110.2
  C25---C20---C19    127.6 (3)   H41A---C41---H41B   108.5
  C22---C21---C20    123.2 (3)   C41---C42---H42A    109.5
  C22---C21---H21A   118.4       C41---C42---H42B    109.5
  C20---C21---H21A   118.4       H42A---C42---H42B   109.5
  C23---C22---C21    118.4 (3)   C41---C42---H42C    109.5
  C23---C22---H22A   120.8       H42A---C42---H42C   109.5
  C21---C22---H22A   120.8       H42B---C42---H42C   109.5
  C24---C23---C22    120.0 (3)   C40---O4---C41      117.0 (3)
  ------------------ ----------- ------------------- -----------

Hydrogen-bond geometry (Å, °) {#tablewraphbondslong}
=============================

  ----------------- ---------- ---------- ----------- ---------------
  *D*---H···*A*     *D*---H    H···*A*    *D*···*A*   *D*---H···*A*
  O2---H1···O3^i^   0.88 (4)   1.90 (4)   2.779 (3)   173 (4)
  O1---H2···O2      0.93 (4)   1.84 (4)   2.739 (3)   161 (3)
  ----------------- ---------- ---------- ----------- ---------------

Symmetry codes: (i) −*x*+1, *y*+1/2, −*z*+1/2.

###### Hydrogen-bond geometry (Å, °)

  *D*---H⋯*A*     *D*---H    H⋯*A*      *D*⋯*A*     *D*---H⋯*A*
  --------------- ---------- ---------- ----------- -------------
  O2---H1⋯O3^i^   0.88 (4)   1.90 (4)   2.779 (3)   173 (4)
  O1---H2⋯O2      0.93 (4)   1.84 (4)   2.739 (3)   161 (3)

Symmetry code: (i) .
