Related literature   {#sec1}
====================

For the synthesis of different triazole thione compounds, see: Wujec *et al.* (2004[@bb19]); Zamani *et al.* (2004[@bb20]); Pitucha *et al.* (2007[@bb15]); Farghaly & El-Kashef (2006[@bb6]); Guelerman *et al.* (1998[@bb9]); Salgin-Gökşen *et al.* (2007[@bb16]). For the biological activity of triazole thio­nes, see: Amir & Kumar (2007[@bb1]); Gokce *et al.* (2001[@bb8]); Ezabadi *et al.* (2008[@bb5]); Mazzone *et al.* (1981[@bb13]); Küçükgüzel *et al.* (2008[@bb12]); Dogan *et al.* (2005[@bb4]); Kane *et al.* (1994[@bb11]); Kane *et al.* (1988[@bb10]). For ring-puckering parameters, see: Cremer & Pople (1975[@bb3]).

Experimental   {#sec2}
==============

 {#sec2.1}

### Crystal data   {#sec2.1.1}

C~17~H~15~N~3~S*M* *~r~* = 293.39Orthorhombic,*a* = 6.2091 (9) Å*b* = 13.1804 (19) Å*c* = 17.391 (3) Å*V* = 1423.3 (4) Å^3^*Z* = 4Mo *K*α radiationμ = 0.22 mm^−1^*T* = 150 K0.25 × 0.15 × 0.08 mm

### Data collection   {#sec2.1.2}

Bruker SMART APEX CCD diffractometerAbsorption correction: multi-scan (*SADABS*; Bruker, 2013[@bb2]) *T* ~min~ = 0.80, *T* ~max~ = 0.9825736 measured reflections3564 independent reflections3274 reflections with *I* \> 2σ(*I*)*R* ~int~ = 0.048

### Refinement   {#sec2.1.3}

*R*\[*F* ^2^ \> 2σ(*F* ^2^)\] = 0.035*wR*(*F* ^2^) = 0.085*S* = 1.043564 reflections190 parametersH-atom parameters constrainedΔρ~max~ = 0.26 e Å^−3^Δρ~min~ = −0.15 e Å^−3^Absolute structure: Flack *x* determined using 1312 quotients \[(*I* ^+^)−(*I* ^−^)\]/\[(*I* ^+^)+(*I* ^−^)\] (Parsons *et al.*, 2013[@bb14])Absolute structure parameter: −0.02 (3)

 {#d5e571}

Data collection: *APEX2* (Bruker, 2013[@bb2]); cell refinement: *SAINT* (Bruker, 2013[@bb2]); data reduction: *SAINT*; program(s) used to solve structure: *SHELXTL* (Sheldrick, 2008[@bb17]); program(s) used to refine structure: *SHELXTL*; molecular graphics: *ORTEP-3 for Windows* (Farrugia, 2012[@bb7]); software used to prepare material for publication: *WinGX* (Farrugia, 2012[@bb7]) and *PLATON* (Spek, 2009[@bb18]).

Supplementary Material
======================

Crystal structure: contains datablock(s) global, I. DOI: [10.1107/S1600536814012409/xu5795sup1.cif](http://dx.doi.org/10.1107/S1600536814012409/xu5795sup1.cif)

Structure factors: contains datablock(s) I. DOI: [10.1107/S1600536814012409/xu5795Isup2.hkl](http://dx.doi.org/10.1107/S1600536814012409/xu5795Isup2.hkl)

###### 

Click here for additional data file.

Supporting information file. DOI: [10.1107/S1600536814012409/xu5795Isup3.cml](http://dx.doi.org/10.1107/S1600536814012409/xu5795Isup3.cml)

CCDC reference: [1005633](http://scripts.iucr.org/cgi-bin/cr.cgi?rm=csd&csdid=1005633)

Additional supporting information: [crystallographic information](http://scripts.iucr.org/cgi-bin/sendsupfiles?xu5795&file=xu5795sup0.html&mime=text/html); [3D view](http://scripts.iucr.org/cgi-bin/sendcif?xu5795sup1&Qmime=cif); [checkCIF report](http://scripts.iucr.org/cgi-bin/paper?xu5795&checkcif=yes)

Supporting information for this paper is available from the IUCr electronic archives (Reference: [XU5795](http://scripts.iucr.org/cgi-bin/sendsup?xu5795)).

JTM thanks Tulane University for support of the Tulane Crystallography Laboratory.

1. Comment
==========

Triazole thiones have been prepared by different methods based mostly on cyclodehydration of thiosemicarbazides with a variety of basic reagents such as sodium hydroxide (Wujec *et al.*, 2004; Zamani *et al.*, 2004; Pitucha *et al.*, 2007), potassium hydroxide (Farghaly & El-Kashef, 2006), sodium carbonate (Guelerman *et al.*, 1998) and triethylamine (Salgin-Gökşen *et al.*, 2007). On other hand the pharmacological properties such as anti-inflammatory, analgesic (Amir & Kumar, 2007; Gokce *et al.*, 2001), anti-bacterial, anti-fungal (Ezabadi *et al.*, 2008; Mazzone *et al.*, 1981), anti-tubercular, anti-viral (Küçükgüzel *et al.*, 2008), anti-tumoral (Dogan *et al.*, 2005), anti-convulsant (Kane *et al.*, 1994) and anti-depressant (Kane *et al.*, 1988) activities have been reported for mercapto-and thione-substituted 1,2,4-triazole systems. Based on above findings, we herein report the use of chloranil as a dehydrogenating agent of (1E)-3,4,4a,5,8,8a-hexahydronaphthalen-1(2*H*)-one *N*-phenylthiosemicarbazone to give the corresponding triazole thione compound.

In the title compound, the phenyl group (C3--C8) attached to N3 makes a dihedral angle of 57.29 (11)° with the mean plane of the triazole ring (N1--N3/C1/C2) which in turn makes an angle of 86.83 (12)° with the plane of the aromatic portion (C12--C17) of the tetrahydronaphthalene moiety (Fig. 1). A Cremer-Pople analysis of the conformation of the ring C2/C9--C12/C17 gave puckering parameters Q(2) = 0.356 (3) Å, Q(3) = -0.332 (3) Å and φ(2) = 275.4 (4)° (Cremer & Pople, 1975). In the solid there are no unusual intermolecular contacts. Only weak C---H···S and C---H···π interactions are observed (Table 1, Fig. 2).

2. Experimental {#experimental}
===============

A mixture of 1 mmol (299 mg) of (1E)-3,4,4a,5,8,8a-hexahydronaphthalen-1(2*H*)-one *N*-phenylthiosemicarbazone and 1 mmol (246 mg) of 2,3,5,6-tetrachloro-1,4-benzoquinone in 30 ml dry ethyl acetate was stirred for 96 h at room temperature. The precipitate was filtered off, dried under vacuum and recrytallized from ethanol to give pure orange crystals.

3. Refinement {#refinement}
=============

H atoms were placed in calculated positions with C---H = 0.95-0.99 Å, and refined in riding mode with U~iso~(H) = 1.2U~eq~(C).

Figures
=======

![Perspective view of the title compound with 50% probability ellipsoids.](e-70-0o740-fig1){#Fap1}

![Packing viewed down the a axis. Hydrogen atoms are omitted.](e-70-0o740-fig2){#Fap2}

Crystal data {#tablewrapcrystaldatalong}
============

  ------------------------------- ---------------------------------------
  C~17~H~15~N~3~S                 *F*(000) = 616
  *M~r~* = 293.39                 *D*~x~ = 1.369 Mg m^−3^
  Orthorhombic, *P*2~1~2~1~2~1~   Mo *K*α radiation, λ = 0.71073 Å
  Hall symbol: P 2ac 2ab          Cell parameters from 9998 reflections
  *a* = 6.2091 (9) Å              θ = 2.3--28.3°
  *b* = 13.1804 (19) Å            µ = 0.22 mm^−1^
  *c* = 17.391 (3) Å              *T* = 150 K
  *V* = 1423.3 (4) Å^3^           Column, orange
  *Z* = 4                         0.25 × 0.15 × 0.08 mm
  ------------------------------- ---------------------------------------

Data collection {#tablewrapdatacollectionlong}
===============

  ------------------------------------------------------------ --------------------------------------
  Bruker SMART APEX CCD diffractometer                         3564 independent reflections
  Radiation source: fine-focus sealed tube                     3274 reflections with *I* \> 2σ(*I*)
  Graphite monochromator                                       *R*~int~ = 0.048
  Detector resolution: 8.3660 pixels mm^-1^                    θ~max~ = 28.3°, θ~min~ = 1.9°
  φ and ω scans                                                *h* = −8→8
  Absorption correction: multi-scan (*SADABS*; Bruker, 2013)   *k* = −17→17
  *T*~min~ = 0.80, *T*~max~ = 0.98                             *l* = −23→23
  25736 measured reflections                                   
  ------------------------------------------------------------ --------------------------------------

Refinement {#tablewraprefinementdatalong}
==========

  ------------------------------------- ------------------------------------------------------------------------------------------------------------------------------------
  Refinement on *F*^2^                  Hydrogen site location: inferred from neighbouring sites
  Least-squares matrix: full            H-atom parameters constrained
  *R*\[*F*^2^ \> 2σ(*F*^2^)\] = 0.035   *w* = 1/\[σ^2^(*F*~o~^2^) + (0.0378*P*)^2^ + 0.4193*P*\] where *P* = (*F*~o~^2^ + 2*F*~c~^2^)/3
  *wR*(*F*^2^) = 0.085                  (Δ/σ)~max~ = 0.001
  *S* = 1.04                            Δρ~max~ = 0.26 e Å^−3^
  3564 reflections                      Δρ~min~ = −0.15 e Å^−3^
  190 parameters                        Absolute structure: Flack *x* determined using 1312 quotients \[(*I*^+^)-(*I*^-^)\]/\[(*I*^+^)+(*I*^-^)\] (Parsons *et al.*, 2013)
  0 restraints                          Absolute structure parameter: −0.02 (3)
  ------------------------------------- ------------------------------------------------------------------------------------------------------------------------------------

Special details {#specialdetails}
===============

  ------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------
  Geometry. Bond distances, angles *etc*. have been calculated using the rounded fractional coordinates. All su\'s are estimated from the variances of the (full) variance-covariance matrix. The cell e.s.d.\'s are taken into account in the estimation of distances, angles and torsion angles
  Refinement. Refinement on *F*^2^ for ALL reflections except those flagged by the user for potential systematic errors. Weighted *R*-factors *wR* and all goodnesses of fit *S* are based on *F*^2^, conventional *R*-factors *R* are based on *F*, with *F* set to zero for negative *F*^2^. The observed criterion of *F*^2^ \> σ(*F*^2^) is used only for calculating -*R*-factor-obs *etc*. and is not relevant to the choice of reflections for refinement. *R*-factors based on *F*^2^ are statistically about twice as large as those based on *F*, and *R*-factors based on ALL data will be even larger.
  ------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å^2^) {#tablewrapcoords}
==================================================================================================

  ------ -------------- -------------- -------------- -------------------- --
         *x*            *y*            *z*            *U*~iso~\*/*U*~eq~   
  S1     0.62076 (10)   0.54064 (5)    0.53367 (3)    0.0310 (2)           
  N1     0.6979 (4)     0.57824 (16)   0.68377 (12)   0.0330 (6)           
  N2     0.6462 (3)     0.54877 (15)   0.74954 (11)   0.0306 (6)           
  N3     0.4806 (3)     0.44434 (13)   0.66343 (10)   0.0222 (5)           
  C1     0.5921 (3)     0.51596 (16)   0.62549 (13)   0.0252 (6)           
  C2     0.5003 (3)     0.45985 (17)   0.74710 (12)   0.0231 (6)           
  C3     0.3302 (3)     0.37544 (16)   0.62918 (11)   0.0207 (6)           
  C4     0.3432 (3)     0.27253 (16)   0.64403 (12)   0.0240 (6)           
  C5     0.1925 (4)     0.20741 (17)   0.61087 (13)   0.0258 (6)           
  C6     0.0339 (4)     0.24503 (18)   0.56279 (12)   0.0266 (6)           
  C7     0.0221 (4)     0.34798 (18)   0.54906 (12)   0.0270 (6)           
  C8     0.1688 (3)     0.41375 (17)   0.58248 (12)   0.0241 (6)           
  C9     0.2844 (4)     0.48971 (19)   0.78250 (13)   0.0291 (7)           
  C10    0.3014 (4)     0.4969 (2)     0.86981 (14)   0.0346 (8)           
  C11    0.3616 (4)     0.39487 (19)   0.90331 (13)   0.0315 (7)           
  C12    0.5517 (4)     0.34643 (17)   0.86358 (12)   0.0243 (6)           
  C13    0.6703 (4)     0.27160 (18)   0.90093 (13)   0.0292 (7)           
  C14    0.8448 (4)     0.22515 (18)   0.86675 (14)   0.0314 (7)           
  C15    0.9049 (4)     0.25245 (18)   0.79299 (14)   0.0295 (7)           
  C16    0.7902 (4)     0.32656 (18)   0.75447 (12)   0.0245 (6)           
  C17    0.6145 (4)     0.37395 (16)   0.78893 (11)   0.0216 (5)           
  H4     0.45350        0.24650        0.67640        0.0290\*             
  H5     0.19880        0.13670        0.62140        0.0310\*             
  H6     −0.06640       0.20020        0.53940        0.0320\*             
  H7     −0.08750       0.37400        0.51640        0.0320\*             
  H8     0.15880        0.48470        0.57340        0.0290\*             
  H9A    0.23820        0.55600        0.76150        0.0350\*             
  H9B    0.17420        0.43860        0.76860        0.0350\*             
  H10A   0.41200        0.54780        0.88390        0.0420\*             
  H10B   0.16180        0.51930        0.89140        0.0420\*             
  H11A   0.39580        0.40350        0.95850        0.0380\*             
  H11B   0.23620        0.34880        0.89940        0.0380\*             
  H13    0.62990        0.25190        0.95150        0.0350\*             
  H14    0.92350        0.17460        0.89380        0.0380\*             
  H15    1.02430        0.22040        0.76900        0.0350\*             
  H16    0.83170        0.34540        0.70390        0.0290\*             
  ------ -------------- -------------- -------------- -------------------- --

Atomic displacement parameters (Å^2^) {#tablewrapadps}
=====================================

  ----- ------------- ------------- ------------- -------------- -------------- --------------
        *U*^11^       *U*^22^       *U*^33^       *U*^12^        *U*^13^        *U*^23^
  S1    0.0328 (3)    0.0327 (3)    0.0274 (3)    0.0027 (3)     0.0043 (2)     0.0093 (2)
  N1    0.0365 (11)   0.0290 (10)   0.0336 (11)   −0.0093 (9)    −0.0021 (9)    0.0033 (8)
  N2    0.0339 (10)   0.0242 (10)   0.0336 (10)   −0.0065 (9)    −0.0046 (9)    −0.0017 (8)
  N3    0.0257 (9)    0.0210 (10)   0.0199 (8)    −0.0036 (7)    −0.0028 (7)    0.0013 (7)
  C1    0.0243 (10)   0.0216 (11)   0.0298 (11)   0.0001 (8)     −0.0004 (9)    0.0021 (8)
  C2    0.0261 (9)    0.0217 (10)   0.0214 (10)   −0.0032 (9)    −0.0022 (8)    −0.0029 (8)
  C3    0.0248 (10)   0.0223 (10)   0.0151 (9)    −0.0019 (8)    −0.0002 (8)    −0.0011 (8)
  C4    0.0264 (10)   0.0238 (10)   0.0217 (9)    0.0010 (8)     −0.0047 (9)    0.0016 (8)
  C5    0.0314 (11)   0.0214 (11)   0.0246 (10)   −0.0027 (9)    −0.0011 (9)    −0.0009 (8)
  C6    0.0263 (10)   0.0311 (12)   0.0224 (10)   −0.0040 (9)    −0.0029 (8)    −0.0058 (9)
  C7    0.0250 (10)   0.0332 (12)   0.0227 (11)   0.0036 (9)     −0.0061 (9)    −0.0018 (9)
  C8    0.0286 (11)   0.0216 (10)   0.0221 (10)   0.0037 (8)     −0.0025 (9)    −0.0014 (8)
  C9    0.0282 (11)   0.0299 (12)   0.0293 (11)   0.0035 (9)     −0.0017 (10)   −0.0044 (9)
  C10   0.0372 (13)   0.0374 (14)   0.0292 (12)   0.0028 (11)    0.0060 (10)    −0.0088 (10)
  C11   0.0334 (12)   0.0390 (14)   0.0221 (11)   −0.0033 (11)   0.0055 (10)    −0.0027 (9)
  C12   0.0276 (10)   0.0264 (11)   0.0189 (10)   −0.0076 (8)    0.0006 (8)     −0.0037 (8)
  C13   0.0398 (13)   0.0270 (12)   0.0207 (10)   −0.0064 (9)    −0.0014 (9)    0.0010 (9)
  C14   0.0389 (13)   0.0255 (11)   0.0299 (11)   −0.0008 (9)    −0.0090 (10)   0.0028 (9)
  C15   0.0269 (10)   0.0298 (12)   0.0318 (12)   0.0005 (9)     −0.0013 (9)    −0.0016 (9)
  C16   0.0228 (9)    0.0305 (12)   0.0202 (10)   −0.0037 (9)    0.0012 (8)     0.0007 (9)
  C17   0.0228 (9)    0.0240 (10)   0.0179 (9)    −0.0048 (9)    −0.0026 (8)    −0.0010 (8)
  ----- ------------- ------------- ------------- -------------- -------------- --------------

Geometric parameters (Å, º) {#tablewrapgeomlong}
===========================

  --------------------- -------------- ----------------------- --------------
  S1---C1               1.639 (2)      C13---C14               1.379 (3)
  N1---N2               1.250 (3)      C14---C15               1.384 (3)
  N1---C1               1.460 (3)      C15---C16               1.382 (3)
  N2---C2               1.482 (3)      C16---C17               1.393 (3)
  N3---C1               1.344 (3)      C4---H4                 0.9500
  N3---C2               1.475 (3)      C5---H5                 0.9500
  N3---C3               1.432 (3)      C6---H6                 0.9500
  C2---C9               1.527 (3)      C7---H7                 0.9500
  C2---C17              1.521 (3)      C8---H8                 0.9500
  C3---C4               1.383 (3)      C9---H9A                0.9900
  C3---C8               1.385 (3)      C9---H9B                0.9900
  C4---C5               1.395 (3)      C10---H10A              0.9900
  C5---C6               1.384 (3)      C10---H10B              0.9900
  C6---C7               1.380 (3)      C11---H11A              0.9900
  C7---C8               1.385 (3)      C11---H11B              0.9900
  C9---C10              1.525 (3)      C13---H13               0.9500
  C10---C11             1.513 (4)      C14---H14               0.9500
  C11---C12             1.509 (3)      C15---H15               0.9500
  C12---C13             1.392 (3)      C16---H16               0.9500
  C12---C17             1.403 (3)                              
                                                               
  N2---N1---C1          110.2 (2)      C12---C17---C16         120.0 (2)
  N1---N2---C2          112.12 (19)    C3---C4---H4            120.00
  C1---N3---C2          110.15 (17)    C5---C4---H4            120.00
  C1---N3---C3          125.25 (18)    C4---C5---H5            120.00
  C2---N3---C3          123.53 (17)    C6---C5---H5            120.00
  S1---C1---N1          121.04 (16)    C5---C6---H6            120.00
  S1---C1---N3          132.35 (17)    C7---C6---H6            120.00
  N1---C1---N3          106.61 (19)    C6---C7---H7            120.00
  N2---C2---N3          100.87 (16)    C8---C7---H7            120.00
  N2---C2---C9          108.74 (18)    C3---C8---H8            120.00
  N2---C2---C17         106.86 (16)    C7---C8---H8            120.00
  N3---C2---C9          111.15 (17)    C2---C9---H9A           109.00
  N3---C2---C17         114.04 (17)    C2---C9---H9B           109.00
  C9---C2---C17         114.10 (18)    C10---C9---H9A          109.00
  N3---C3---C4          120.40 (17)    C10---C9---H9B          109.00
  N3---C3---C8          118.97 (19)    H9A---C9---H9B          108.00
  C4---C3---C8          120.61 (19)    C9---C10---H10A         110.00
  C3---C4---C5          119.16 (19)    C9---C10---H10B         110.00
  C4---C5---C6          120.5 (2)      C11---C10---H10A        110.00
  C5---C6---C7          119.7 (2)      C11---C10---H10B        110.00
  C6---C7---C8          120.5 (2)      H10A---C10---H10B       108.00
  C3---C8---C7          119.6 (2)      C10---C11---H11A        109.00
  C2---C9---C10         110.90 (19)    C10---C11---H11B        109.00
  C9---C10---C11        110.2 (2)      C12---C11---H11A        109.00
  C10---C11---C12       113.14 (19)    C12---C11---H11B        109.00
  C11---C12---C13       120.0 (2)      H11A---C11---H11B       108.00
  C11---C12---C17       122.1 (2)      C12---C13---H13         119.00
  C13---C12---C17       117.9 (2)      C14---C13---H13         119.00
  C12---C13---C14       122.0 (2)      C13---C14---H14         120.00
  C13---C14---C15       119.7 (2)      C15---C14---H14         120.00
  C14---C15---C16       119.6 (2)      C14---C15---H15         120.00
  C15---C16---C17       120.8 (2)      C16---C15---H15         120.00
  C2---C17---C12        120.4 (2)      C15---C16---H16         120.00
  C2---C17---C16        119.55 (18)    C17---C16---H16         120.00
                                                               
  C1---N1---N2---C2     1.3 (3)        N3---C2---C17---C16     38.4 (3)
  N2---N1---C1---S1     176.99 (17)    C9---C2---C17---C12     −16.1 (3)
  N2---N1---C1---N3     −2.6 (3)       C9---C2---C17---C16     167.6 (2)
  N1---N2---C2---N3     0.3 (2)        N3---C3---C4---C5       178.98 (19)
  N1---N2---C2---C9     −116.6 (2)     C8---C3---C4---C5       0.5 (3)
  N1---N2---C2---C17    119.8 (2)      N3---C3---C8---C7       −179.93 (18)
  C2---N3---C1---S1     −176.77 (17)   C4---C3---C8---C7       −1.4 (3)
  C2---N3---C1---N1     2.7 (2)        C3---C4---C5---C6       1.0 (3)
  C3---N3---C1---S1     −8.3 (3)       C4---C5---C6---C7       −1.5 (3)
  C3---N3---C1---N1     171.17 (19)    C5---C6---C7---C8       0.6 (3)
  C1---N3---C2---N2     −2.0 (2)       C6---C7---C8---C3       0.9 (3)
  C1---N3---C2---C9     113.2 (2)      C2---C9---C10---C11     −61.8 (3)
  C1---N3---C2---C17    −116.1 (2)     C9---C10---C11---C12    49.2 (3)
  C3---N3---C2---N2     −170.63 (17)   C10---C11---C12---C13   159.1 (2)
  C3---N3---C2---C9     −55.5 (3)      C10---C11---C12---C17   −21.2 (3)
  C3---N3---C2---C17    75.2 (2)       C11---C12---C13---C14   179.9 (2)
  C1---N3---C3---C4     130.6 (2)      C17---C12---C13---C14   0.1 (4)
  C1---N3---C3---C8     −50.9 (3)      C11---C12---C17---C2    4.2 (3)
  C2---N3---C3---C4     −62.4 (3)      C11---C12---C17---C16   −179.6 (2)
  C2---N3---C3---C8     116.1 (2)      C13---C12---C17---C2    −176.1 (2)
  N2---C2---C9---C10    −74.6 (2)      C13---C12---C17---C16   0.2 (3)
  N3---C2---C9---C10    175.21 (19)    C12---C13---C14---C15   −0.4 (4)
  C17---C2---C9---C10   44.5 (3)       C13---C14---C15---C16   0.4 (4)
  N2---C2---C17---C12   104.1 (2)      C14---C15---C16---C17   −0.2 (4)
  N2---C2---C17---C16   −72.2 (2)      C15---C16---C17---C2    176.1 (2)
  N3---C2---C17---C12   −145.4 (2)     C15---C16---C17---C12   −0.2 (4)
  --------------------- -------------- ----------------------- --------------

Hydrogen-bond geometry (Å, º) {#tablewraphbondslong}
=============================

Cg3 is the centroid of the benzene ring of the 1,2,3,4-tetrahydronaphthalene group.

  ------------------------ --------- --------- ----------- ---------------
  *D*---H···*A*            *D*---H   H···*A*   *D*···*A*   *D*---H···*A*
  C7---H7···S1^i^          0.95      2.86      3.568 (3)   132
  C6---H6···*Cg*3^ii^      0.95      2.84      3.602 (2)   138
  C16---H16···*Cg*3^iii^   0.95      2.90      3.676 (3)   139
  ------------------------ --------- --------- ----------- ---------------

Symmetry codes: (i) *x*−1, *y*, *z*; (ii) *x*−1/2, −*y*+1/2, −*z*+1; (iii) *x*+1, *y*, *z*.

###### Hydrogen-bond geometry (Å, °)

*Cg*3 is the centroid of the benzene ring of the 1,2,3,4-tetra­hydro­naphthalene group.

  *D*---H⋯*A*            *D*---H   H⋯*A*   *D*⋯*A*     *D*---H⋯*A*
  ---------------------- --------- ------- ----------- -------------
  C7---H7⋯S1^i^          0.95      2.86    3.568 (3)   132
  C6---H6⋯*Cg*3^ii^      0.95      2.84    3.602 (2)   138
  C16---H16⋯*Cg*3^iii^   0.95      2.90    3.676 (3)   139

Symmetry codes: (i) ; (ii) ; (iii) .
