ChemTEB Classification Datasets
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Chemical Classification Datasets for Evaluating Text Embedding Models
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===================== Product Identification =====================
Product ID:TRX-200 (BULK & TUBES), 1018B
Preparer's Name:LINDA SUE SHEPHERD
CAGE:0AV13
CAGE:0AV13
CAGE:0ZUM2
============= Composition/Information on Ingredients =============
Ingred Name:PETROLEUM DISTILLATE; (PETROLEUM OIL MIXTURE)
CAS:8002-05-9
RTECS #:SE7449000
OSHA PEL:5 MG/M3 (MFR)
ACGIH TLV:5 MG/M3 (MFR)
===================== Hazards Identification =====================
LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:EYES: MAY CAUSE IRRITATION. INGESTION:
MAY CAUSE VOMITING, NAUSEA OR DIARRHEA. INHALATION: NOT EXPECTED TO
BE A PROBLEM. MASSIVE EXPOSURE TO FUMES MAY CAUSE HEADACHES,
DIZZINESS, AND/OR DROWSINESS. SK IN: MAY CAUSE IRRITATION.
Explanation of Carcinogenicity:NOT RELEVANT.
Effects of Overexposure:SEE HEALTH HAZARDS.
Medical Cond Aggravated by Exposure:DERMATITIS.
======================= First Aid Measures =======================
First Aid:EYES: FLUSH WITH WATER USING EYECUP OR FOUNTAIN FOR AT LEAST
15 MINUTES. SEEK MEDICAL ATTENTION IF DISCOMFORT PERSISTS.
INGESTION: DO NOT INDUCE VOMITING. GIVE 3-4 GLASSES OF WATER. GET
MEDICAL ATTENT ION. INHALATION: REMOVE TO FRESH AIR. SKIN: REMOVE
CONTAMINATED CLOTHING. WASH WITH SOAP AND WATER.
===================== Fire Fighting Measures =====================
Flash Point Method:COC
Flash Point:>400F,>204C
Extinguishing Media:DRY CHEMICAL (PREFERRED), CARBON DIOXIDE, FOAM,
WATER.
Fire Fighting Procedures:USE NIOSH APPROVED SCBA & FULL PROTECTIVE
EQUIPMENT .
Unusual Fire/Explosion Hazard:EMPTY CONTAINERS MAY RETAIN PRODUCT
RESIDUE INCLUDING FLAMMABLE OR EXPLOSIVE VAPORS. DO NOT CUT, DRILL,
GRIND OR WELD ON OR NEAR, PART FULL OR EMPTY DRUM.
================== Accidental Release Measures ==================
Spill Release Procedures:STOP FLOW, DIKE SPILL. ELIMINATE ALL IGNITION
SOURCES. ABSORB ON INERT MATERIAL AND SCRAPE UP.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
======================Handling and Storage ======================
Handling and Storage Precautions:AVOID PROLONGED EXPOSURE TO MIST AND
VAPORS. AVOID FLAMES, SPARKS AND HOT SURFACES. KEEP CONTAINERS
CLOSED. SHELF LIFE IN ONE YEAR.
Other Precautions:EMPTY CONTAINERS MAY CONTAIN EXPLOSIVE GAS. KEEP OUT
OF REACH OF CHILDREN.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:NONE REQUIRED. NIOSH APPROVED RESPIRATOR
APPROPRIATE FOR EXPOSURE OF CONCERN .
Ventilation:NONE REQUIRED IN EXCESS TO NORMAL VENTILATION.
Other Protective Equipment:EYE WASH FOUNTAIN & DELUGE SHOWER WHICH MEET
ANSI DESIGN CRITERIA . OIL RESISTANT APRON.
Work Hygienic Practices:DO NOT WORK IN OIL SOAKED CLOTHING. WASH HANDS
WITH SOAP AND WATER AFTER HANDLING AND BEFORE EATING.
Supplemental Safety and Health
VP: <0.01 @ 20C.
================== Physical/Chemical Properties ==================
Vapor Pres:SUPDAT
Solubility in Water:NEGLIGIBLE
Appearance and Odor:RED GEL; OIL ODOR.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
CHLORINE OR OXYGEN.
Stability Condition to Avoid:AVOID OXIDIZING ATMOSPHERES.
Hazardous Decomposition Products:THERMAL - UNIDENTIFIED ORGANICS
OXIDATION - OXIDES OF CARBON.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH LOCAL, STATE AND
FEDERAL REGULATIONS.
======================= Other Information =======================
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eyes_protection_mandatory
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===================== Product Identification =====================
Product ID:SF99 SOLVENT KAMPEL BLEND 3293
CAGE:2L263
CAGE:2L263
============= Composition/Information on Ingredients =============
Ingred Name:TOLUENE (SARA III)
CAS:108-88-3
RTECS #:XS5250000
Fraction by Wt: >9%
Other REC Limits:375 MG/CUM
OSHA PEL:200 PPM/150 STEL
ACGIH TLV:50 PPM; 9293
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Ingred Name:2-BUTANONE (METHYL ETHYL KETONE) (MEK)
CAS:78-93-3
RTECS #:EL6475000
Fraction by Wt: >9%
Other REC Limits:590 MG/CUM
OSHA PEL:200 PPM
ACGIH TLV:590 MG/CUM
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
Ingred Name:ISOPROPANOL (ISOPROPYL ALCOHOL), 2-PROPANOL, DIMETHYL
CARBINOL
CAS:67-63-0
RTECS #:NT8050000
Fraction by Wt: >9%
Other REC Limits:400 PPM
OSHA PEL:400 PPM
ACGIH TLV:400 PPM
Ingred Name:METHYL ISOAMYL KETONE, MIAK, 5-METHYL-2-HEXANONE
CAS:110-12-3
RTECS #:MP3850000
Fraction by Wt: >9%
Other REC Limits:50 PPM
OSHA PEL:100 PPM
ACGIH TLV:50 PPM; 9293
===================== Hazards Identification =====================
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:INGESTION: ANESTHETIC. INHALATION:
RESPIRATORY TRACT IRRITATION & NERVOUS SYSTEM DEPRESSION.
EYES/SKIN: IRRITATION.
Explanation of Carcinogenicity:NONE
Effects of Overexposure:INGESTION: ANESTHETIC. INHALATION: RESPIRATORY
TRACT IRRITATION & NERVOUS SYSTEM DEPRESSION. EYES/SKIN:
IRRITATION.
======================= First Aid Measures =======================
First Aid:SKIN/EYES: FLUSH W/PLENTY OF WATER FOR 15 MIN. INHALATION:
REMOVE TO FRESH AIR, IF BREATHING IS DIFFICULT GIVE OXYGEN. IF
BREATHING STOPS GIVE ARTIFICIAL RESPIRATION. INGESTION: CALL
PHYSICIAN IMMEDIA TELY. DON'T INDUCE VOMITING. HAVE PATIENT LIE
DOWN & KEEP WARM. VOMITING MAY LEAD TO ASPIRATION INTO LUNGS WHICH
MAY BE FATAL. OBTAIN MEDICAL ATTENTION IN ALL CASES.
===================== Fire Fighting Measures =====================
Flash Point Method:TCC
Flash Point:28F
Upper Limits:1.7%
Extinguishing Media:NFPA CLASS B EXTINGUISHER (CO2 OR FOAM) FOR CLASS 1
B LIQUID FIRES.
Fire Fighting Procedures:WATER SPRAY CAN PROTECT FIRE FIGHTERS & COOL
CLOSED CONTAINERS. USE FOG NOZZLES IF WATER IS USED.
Unusual Fire/Explosion Hazard:CLOSED CONTAINERS MAY EXPLODE IF EXPOSED
TO EXTREME HEAT.
================== Accidental Release Measures ==================
Spill Release Procedures:SMALL-MOP W/ABSORBENT MATERIAL & TRANSFER TO
HOOD. LARGE-STOP SPILL, DIKE AREA TO PREVENT SPREAD. PUMP LIQUID TO
SALAVAGE TANK & ABSORB REMAINDER & SHOVEL INTO CONTAINERS.
======================Handling and Storage ======================
Handling and Storage Precautions:DON'T STORE >120F. STORE LARGE AMOUNTS
IN STRUCTURES MADE FOR OSHA CLASS 1 B LIQUIDS.
Other Precautions:AVOID FREE FALL OF LIQUID. GROUND CONTAINERS WHEN
POURING. DON'T FLAME CUT SAW, BRAZE, OR WELD. EMPTY CONTAINER
HAZARDOUS.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:NIOSH/OSHA APPROVED AIR PACK
Ventilation:LOCAL EXHAUST
Supplemental Safety and Health
BOILING RANGE: 172-297F
================== Physical/Chemical Properties ==================
Boiling Pt:B.P. Text:SEE SUPP
Vapor Pres:31.0
Vapor Density:3.0
Spec Gravity:0.836
Evaporation Rate & Reference:(ETHER=1) 5.8
Appearance and Odor:CLEAR WATER-WHITE, KETONE ODOR
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZERS SUCH AS PERMANGANATE
Stability Condition to Avoid:HEAT, SPARKS, NON-EXPLOSION PROOF ELECTRIC
EQUIPMENT & OPEN FLAME.
Hazardous Decomposition Products:C0 & CO2
==================== Disposal Considerations ====================
Waste Disposal Methods:SMALL-EVAPORATE UNTIL ALL VAPORS ARE GONE.
LARGE-RECYCLE OR INCINERATE. DISPOSE OF IN ACCORDANCE W/LOCAL,
FEDERAL & STATE REGULATIONS.
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eyes_protection_mandatory
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===================== Product Identification =====================
Product ID:COPOLYMER OF 2-CHLORO-1, 3-BUTADIENE AND (SUP DAT)
Preparer's Name:F M LOGULLO
CAGE:0ERJ7
CAGE:0ERJ7
CAGE:18873
============= Composition/Information on Ingredients =============
Ingred Name:2-CHLORO-1,3-BUTADIENE POLYMERS AND COPOLYMERS; (COPOLYMER
OF 2-CHLORO-1,3-BUTADIENE AND 2-ETHYLHEXYL METHACRYLATE)
CAS:31454-65-6
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:METHACRYLIC ACID, 2-ETHYLHEXYL ESTER; (2-ETHYLHEXYL
METHACRYLATE)
CAS:688-84-6
RTECS #:OZ4630000
Fraction by Wt: 1%
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:TALC (POWDER), CONTAINING NO ASBESTOS FIBERS
CAS:14807-96-6
RTECS #:WW2710000
Fraction by Wt: 1%
OSHA PEL:20 MPPCF Z-3
ACGIH TLV:2 MG/M3 RDUST
Ingred Name:RESP PROT: USE NIOSH/MSHA APPRVD POS PRESS AIR SUPP RESP IF
THERE IS ANY POTENTIAL FOR UNCONTROLLED RELEASE, (ING 5)
RTECS #:9999999ZZ
Ingred Name:ING 4: EXPOS LEVELS ARE NOT KNOWN/ANY OTHER CIRCUMSTANCES
WHERE AIR PURIFYING RESPS MAY NOT PROVIDE ADEQUATE PROTECTION.
RTECS #:9999999ZZ
===================== Hazards Identification =====================
LD50 LC50 Mixture:LD50 (ORAL RAT): 20000 MG/KG.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:ACUTE: INGEST: ONE TYPE OF NEOPRENE
WAS TESTED FOR ORAL TOXICITY IN RATS. LD-50 IS IN EXCESS OF 20000
MG/KG WHICH IS LOW TOXICITY. OTHER TYPES OF NEOPRENE ARE PREDICTED
TO HAVE SAME LOW TOXICITY. SKIN : RESIDUAL 2-ETHYLHEXYL
METHACRYLATE MAY CAUSE SKIN IRRIT & SENSIT IN SOME INDIVIDUALS.
AVOID PRLNG/ (EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT.
Effects of Overexposure:HLTH HAZ: RPTD CONT W/SKIN. EYES: MECH IRRIT
ONLY. INHAL: AVOID BRTHG DUST FROM FREE TALC LEFT IN BAG. TALC IS
DUST WHICH MAY CAUSE SORE THROAT & PAINS IN LUNGS & CHEST. AT
PROCESSING TEMPS > 200C, FU MES IRRIT TO EYES, NOSE, & THROAT MAY
BE PRODUCED. THIS EXPOS MAY RSLT IN REDDENING, TEARING, & ITCH OF
EYES (SUP DAT)
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
======================= First Aid Measures =======================
First Aid:INHAL: NO SPECIFIC INTERVENTION INDICATED AS CMPD IS NOT
LIKELY TO BE HAZ BY INHAL. CONSULT MD IF NEC. SKIN: FLUSH W/WATER
AFTER CONT. WASH CONTAM CLTHG BEFORE REUSE. EYES: IMMED FLUSH
W/PLENTY OF WAT ER FOR AT LEAST 15 MIN. CALL MD. INGEST: NO
SPECIFIC INTERVENTION IS INDICATED AS COMPOUND IS NOT LIKELY TO BE
HAZARDOUS BY INGESTION. CONSULT MD IF NECESSARY.
===================== Fire Fighting Measures =====================
Flash Point Method:COC
Flash Point:>500F,>260C
Extinguishing Media:USE WATER, FOAM, DRY CHEMICAL, CARBON DIOXIDE.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA & FULL
PROTECTIVE EQUIPMENT .
Unusual Fire/Explosion Hazard:COMPLETE COMBUST GIVES HYDROGEN CHLORIDE,
CARBON DIOXIDE, SULFUR OXIDE & WATER. INCOMPLETE COMBUST GIVES IN
ADDN CARBON MONOXIDE, ORG ACIDS, (SUP DAT)
================== Accidental Release Measures ==================
Spill Release Procedures:REVIEW FIRE AND EXPLOSION HAZARDS AND SAFETY
PRECAUTIONS BEFORE PROCEEDING WITH CLEAN-UP. USE APPROPRIATE
PERSONAL PROTECTIVE EQUIPMENT DURING CLEAN-UP. RECOVER UNDAMAGED
AND MINIMALLY CONTAMINATED MA TERIAL FOR REUSE OR RECLAMATION.
SHOVEL/SWEEP UP.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
======================Handling and Storage ======================
Handling and Storage Precautions:STORE IN COOL PLACE. KEEP CONTAINER
TIGHTLY CLOSED. USE ONLY WITH ADEQUATE VENTILATION.
Other Precautions:NONE SPECIFIED BY MANUFACTURER.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:NIOSH/MSHA APPRVD AIR PURIFYING RESP W/ORG VAP
CARTRIDGE W/DUST/MIST CANISTER MAY BE PERMISSIBLE UNDER CERTAIN
CIRCUMSTANCES WHERE AIRBORNE CONCS ARE EXPECTED TO EXCEED EXPOS
LIM. PROT PROVIDED BY AIR PURIFYING RESPS IS LIMITED. (ING 4)
Ventilation:LOCAL VENTILATION SHOULD BE USED OVER PROCESSING EQUIPMENT.
Other Protective Equipment:IF POTENTIAL CONT W/HOT/MOLTEN MATL, WEAR
HEAT RESIST CLTHG & FOOTWEAR. ANSI APPRVD EMER EYEWASH & DELUGE
SHOWER .
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
TRADE NAME/PART #: 2-ETHYLHEXYL METHACRYLATE. EXPLO HAZ: ALDEHYDES, &
ALCOHOLS. EFTS OF OVEREXP: & SORENESS IN NOSE & THROAT, TOGETHER
W/COUGHING. CHRONIC: NONE KNOWN. WASTE DISP METH: COMBUST PRODS.
TREATMENT, STOR, TRANSPORTATION, & DISPMUST BE I/A/W APPLIC FED,
STATE, & LOC REGS.
================== Physical/Chemical Properties ==================
Solubility in Water:NEGLIGIBLE
Appearance and Odor:PALE CREAM CHIPS, WITH MILD CHARACTERISTIC ODOR
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
NONE REASONABLY FORESEEABLE.
Stability Condition to Avoid:TEMPERATURES ABOVE 200C.
Hazardous Decomposition Products:HAZARDOUS GASES/VAPORS PRODUCED ARE
CARBON MONOXIDE, HYDROGEN CHLORIDE, AND ORGANIC ACIDS, ALDEHYDES,
ALCOHOLS.
==================== Disposal Considerations ====================
Waste Disposal Methods:PREFERRED OPTIONS FOR DISP ARE (1) RECYCLING,
(2) INCIN W/ENERGY RECOVERY, & (3) LANDFILL. HIGH FUEL VALUE OF
THIS PROD MAKES OPTION 2 VERY DESIRABLE FOR MATL THAT CANNOT BE
RECYCLED, BUT INCIN MUST B E CAPABLE OF SCRUBBING OUT ACIDIC (SUP
DAT)
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eyes_protection_mandatory
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===================== Product Identification =====================
Product ID:H-251, THINNER
CAGE:11931
CAGE:11931
============= Composition/Information on Ingredients =============
Ingred Name:2-ETHOXYETHYL ACETATE (CELLOSOLVE ACETATE) (EGEEA)
CAS:111-15-9
RTECS #:KK8225000
Fraction by Wt: 50%
OSHA PEL:S,100 PPM
ACGIH TLV:S, 5 PPM; 9192
Ingred Name:TOLUENE (SARA III)
CAS:108-88-3
RTECS #:XS5250000
Fraction by Wt: 25%
OSHA PEL:200 PPM/150 STEL
ACGIH TLV:50 PPM; 9293
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Ingred Name:XYLENES (O-,M-,P- ISOMERS)(SARA III)
CAS:1330-20-7
RTECS #:ZE2100000
Fraction by Wt: 25%
OSHA PEL:100 PPM/150 STEL
ACGIH TLV:100 PPM/150STEL;9192
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
===================== Hazards Identification =====================
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:ACUTE: IRRITATION TO SKIN, EYES, AND
RESPIRATORY SYSTEM WHEN OVEREXPOSED.
Effects of Overexposure:IRRITATION TO SKIN, EYES, AND RESPIRATORY
SYSTEM WHEN OVEREXPOSED.
Medical Cond Aggravated by Exposure:PULMONARY DISORDERS
======================= First Aid Measures =======================
First Aid:INHALATION: FRESH AIR AND TREATMENT FOR EFFECT OF
SOLVENTS-CONTACT PHYSICIAN. EYES: FLUSH 10 MINUTES WITH CLEAN COOL
WATER-CONSULT EYE PHYSICIAN. SKIN: WASH WITH MILD SOAP AND CLEAN
WATER. INGESTION: DO NOT INDUCE VOMITING-CONSULT PHYSICIAN.
===================== Fire Fighting Measures =====================
Flash Point Method:TCC
Flash Point:48F,8.8C
Autoignition Temp:Autoignition Temp Text:997F
Lower Limits:1.2
Upper Limits:7.1
Extinguishing Media:DRY CHEMICAL, FOAM, CARBON DIOXIDE
Fire Fighting Procedures:WEAR SELF-CONTAINED BREATHING APPARATUS WHEN
FIGHTING FIRE IN CONFINED AREA.
Unusual Fire/Explosion Hazard:VAPORS HEAVIER THAN AIR AND MAY TRAVEL
ALONG THE GROUND. ELIMINATE ALL IGNITION SOURCES.
================== Accidental Release Measures ==================
Spill Release Procedures:DIKE AREA TO CONTAIN MATERIAL, PUMP INTO
PROPER WASTE CONTAINER. CLEAN AREA WITH OIL ABSORBENCY MATERIAL.
Neutralizing Agent:NONE
======================Handling and Storage ======================
Handling and Storage Precautions:DO NOT EXPOSE TO TEMPERATURE IN EXCESS
OF 120F.
Other Precautions:KEEP AWAY FROM SOURCES OF IGNITION OR OPEN FLAME.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:NIOSH/MSHA SELF CONTAINED BREATHING APPARATUS.
Ventilation:MECHANICAL (GENERAL): 60 FT./MIN. VENTILATION LOCAL: 20
FT./MIN.
Other Protective Equipment:CHEMICAL RESISTANT CLOTHING, RUBBER BOOTS
Work Hygienic Practices:AFTER USE, WASH SKIN WITH MILD SOAP AND WATER.
Supplemental Safety and Health
NONE
================== Physical/Chemical Properties ==================
HCC:F2
Boiling Pt:B.P. Text:200F,93C
Vapor Pres:25
Vapor Density:3.2
Spec Gravity:0.92
Solubility in Water:NEGLIGIBLE
Appearance and Odor:CLEAR COLORLESS LIQUID, PLEASANT SWEET ODOR
Percent Volatiles by Volume:100
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS
Stability Condition to Avoid:HIGH TEMPERATURE
Hazardous Decomposition Products:CARBON DIOXIDE, CARBON MONOXIDE,
HYDROCARBON PRODUCTS.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSE IN ACCORDANCE WITH APPLICABLE FEDERAL,
STATE AND LOCAL REGULATIONS FOR FLAMMABLE ORGANIC SOLVENTS.
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eyes_protection_mandatory
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===================== Product Identification =====================
Product ID:TYPES 793/795 DRY SILVER PAPER
CAGE:1LF36
CAGE:39711
CAGE:1LF36
============= Composition/Information on Ingredients =============
Ingred Name:CELLULOSE (PAPER FIBER)
CAS:9004-34-6
RTECS #:FJ5691460
Fraction by Wt: 80-90% %
Other REC Limits:NONE RECOMMENDED
OSHA PEL:15 MG/M3 TDUST
ACGIH TLV:10 MG/M3; 9293
Ingred Name:POLYVINYL BUTYRAL RESIN
CAS:63148-65-2
RTECS #:TR4955000
Fraction by Wt: 2-5% %
Other REC Limits:NONE RECOMMENDED
Ingred Name:BEHENIC ACID
CAS:112-85-6
Fraction by Wt: 1-3% %
Other REC Limits:NONE RECOMMENDED
Ingred Name:CELLULOSE ACETATE (RESIN)
CAS:9004-35-7
Fraction by Wt: 2-5% %
Other REC Limits:NONE RECOMMENDED
Ingred Name:SILVER BEHENATE (SARA III)
CAS:2489-05-6
Fraction by Wt: <1.0% %
Other REC Limits:NONE RECOMMENDED
OSHA PEL:0.01 MG/M3 (AG)
ACGIH TLV:0.01 MG/M3 (AG)
Ingred Name:2,2'-METHYLENE-BIS-6-(TERT BUTYL)-P-CRESOL
CAS:119-47-1
RTECS #:PA3500000
Fraction by Wt: 1-3% %
Other REC Limits:NONE RECOMMENDED
Ingred Name:MERCURIC BROMIDE (SARA III)
CAS:7789-47-1
RTECS #:OV7415000
Fraction by Wt: <0.1% %
Other REC Limits:NONE RECOMMENDED
OSHA PEL:S, C, 0.1 MG/M3
ACGIH TLV:S, 0.1 MG/M3
Ingred Name:SILVER BROMIDE (SARA III)
CAS:7785-23-1
Fraction by Wt: <0.1% %
Other REC Limits:NONE RECOMMENDED
===================== Hazards Identification =====================
Routes of Entry: Inhalation:NOSkin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:NO ADVERSE HEALTH EFFECTS, BECAUSE NO
EXPOSURE IS EXPECTED.
Explanation of Carcinogenicity:2,2'-METHYLENEBIS
(6-TERT-BUTYL-P-CRESOL) FED TO RATS AT 50 MG/KG/DAY FOR 10 MONTHS
CAUSES PHYSICAL CHANGE IN THE TESTES
Effects of Overexposure:NONE.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
======================= First Aid Measures =======================
First Aid:NO NEED FOR FIRST AID IS ANTICIPATED.
===================== Fire Fighting Measures =====================
Extinguishing Media:WATER, CARBON DIOXIDE, DRY CHEMICAL
Fire Fighting Procedures:WEAR SELF-CONTAINED BREATHING APPARATUS AND
FULL PROTECTIVE GEAR.
Unusual Fire/Explosion Hazard:NONE SPECIFIED BY MANUFACTURER.
================== Accidental Release Measures ==================
Neutralizing Agent:NONE.
======================Handling and Storage ======================
Handling and Storage Precautions:STORE IN A COOL PLACE AWAY FROM
SOURCES OF IGNITION.
Other Precautions:MAINTAIN REGULAR CLEANING OF IMAGING EQUIPMENT BY AN
AUTHORIZED SERVICE TECHNICIAN TO AVOID DUST BUILDUP. AVOID SKIN AND
EYE CONTACT OR INHALATION OF PAPER DUST THAT MAY COLLECT INSIDE
============= Exposure Controls/Personal Protection =============
Respiratory Protection:NONE NORMALLY REQUIRED.
Ventilation:USE IN A WELL-VENTILATED AREA.
Other Protective Equipment:NONE NORMALLY REQUIRED.
Work Hygienic Practices:WASH HANDS AFTER USE AND BEFORE EATING,
DRINKING, OR SMOKING.
Supplemental Safety and Health
NONE SPECIFIED BY MANUFACTURER.
================== Physical/Chemical Properties ==================
HCC:N1
Solubility in Water:SLIGHT
Appearance and Odor:WHITE COATED PAPER, SLIGHT ODOR
Percent Volatiles by Volume:NIL
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
NONE SPECIFIED BY MANUFACTURER.
Stability Condition to Avoid:AVOID EXPOSURE TO LIGHT, ELEVATED
TEMPERATURES, AND HUMID CONDITIONS.
Hazardous Decomposition Products:CARBON DIOXIDE, CARBON MONOXIDE,
HYDROCARBONS, AND TRACES OF MERCURY OXIDES AND HYDROGEN BROMIDE.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH LOCAL, STATE AND
FEDERAL REGULATIONS. EPA HAZARDOUS WASTE NUMBER = D009.
MANUFACTURER RECOMMENDS RECLAMATION OF SILVER AND MERCURY AT
PERMITTED SITE.
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eyes_protection_not_mandatory
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===================== Product Identification =====================
Product ID:METALCLAD SPEEDALLOY ACTIVATOR PART B
Kit Part:Y
Preparer's Name:F. LAUMAN
CAGE:00933
CAGE:00933
============= Composition/Information on Ingredients =============
Ingred Name:POLYMERCAPTAN. VP:0.01
Fraction by Wt: 40%
Ingred Name:SILICA
CAS:7631-86-9
Fraction by Wt: 54%
OSHA PEL:0.1 MG/M3 (MFR)
ACGIH TLV:0.1 MG/M3 (MFR)
Ingred Name:SILICA DERIVATIVES; (COLLOIDAL SILICA)
CAS:67762-90-7
Fraction by Wt: 2%
OSHA PEL:20 MPPCF (MFR)
ACGIH TLV:5 MG/M3 (MFR)
===================== Hazards Identification =====================
LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:EYES:CAN CAUSE IRRITATION. MAY CAUSE
CHEMICAL BURN IN EYES. SKIN:PROLONGED OR REPEATED CONTACT CAN CAUSE
MODERATE IRRITATION, DERMATITIS. INHAL:CAN CAUSE RESPIRATORY
IRRITATION. INGEST:SLIGHTLY TOXIC.IARC MONOGRAPHS CONCLUDE THERE
IS LIMITED EVIDENCE OF CARCINOGENICITY OF CRYSTALLINE SILICA TO
HUMANS.
Explanation of Carcinogenicity:NOT RELEVANT.
Effects of Overexposure:SEE HEALTH HAZARDS.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
======================= First Aid Measures =======================
First Aid:EYES:FLUSH W/LGE AMTS OF WATER FOR AT LEAST 15 MINS LIFTING
EYELIDS OCCASNLY. GET MD PROMPTLY. SKIN:WASH THORO W/SOAP & WATER.
REMOVE CONTAMD CLTHG PROMPLY. WASH CLTHG BEFORE REUSE. INGEST:DO
NOT INDU CE VOM! KEEP PERS WARM, QUIET & GET MD.ASPIR OF MATL INTO
LUNGS DUE TO VOM CAN CAUSE CHEM PNEUMONITIS WHICH CAN BE FATAL.
INHAL:MOVE AFFECTED PERS TO FRESH AIR. IF BRTHG IS DFCLT, ADMIN
(SUPP DATA)
===================== Fire Fighting Measures =====================
Flash Point Method:TCC
Flash Point:>200F,>93C
Extinguishing Media:CARBON DIOXIDE, DRY CHEMICAL, FOAM & WATER FOG. USE
WATER FOR COOLING MATERIAL STORED IN VICINITY OF FIRE.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA & FULL
PROTECTIVE EQUIPMENT .
Unusual Fire/Explosion Hazard:NONE.
================== Accidental Release Measures ==================
Spill Release Procedures:SMALL/LARGE SPILL: SCRAPE UP/SOAK UP
W/ABSORBENT MATERIAL.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
======================Handling and Storage ======================
Handling and Storage Precautions:EXPOSURE TO AIR WILL CAUSE SKINNING &
RENDER MATERIAL UNFIT FOR USE.
Other Precautions:NONE.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:IF TLV OF PROD IS EXCEEDED, A NIOSH/MSHA APPRVD
AIR SUPPLY RESP IS ADVISED IN ABSENCE OF PROPER ENVIRON CONTROL.
OSHA REGS ALSO PERMIT OTHER NIOSH/MSHA APPRVD RESPS UNDER SPECIFIED
CNDTNS. (SEE YOUR S FTY EQUIP SUPPLIER.) (SUPP DATA)
Ventilation:PROVIDE SUFFICIENT MECHANICAL (GENERAL &/OR LOCAL EXHAUST)
VENTILATION TO MAINTAIN EXPOSURE BELOW TLV.
Other Protective Equipment:EYE WASH & SAFETY SHOWER.
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
FIRST AID PROC:OXYGEN. IF BREATHING HAS STOPPED, GIVE ARTIFICIAL
RESPIRATION. KEEP PERSON WARM, QUIET & GET MEDICAL ATTENTION. RESP
PROT:ENGINEERING OR ADMINISTRATIVE CONTROLS SHOULD BE IMPLEMENTED
TOREDUCE EXPOSURE.
================== Physical/Chemical Properties ==================
HCC:N1
Vapor Pres:SEE INGRED
Vapor Density:HVR/AIR
Spec Gravity:1.63
Evaporation Rate & Reference:0 (N-BUTYL ACETATE=1)
Appearance and Odor:CREAM COLOR PASTE; DISAGREEABLE ODOR.
Percent Volatiles by Volume:0
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
AVOID CONTACT W/STRONG OXIDIZERS & ACIDS.
Stability Condition to Avoid:KEEP AWAY FROM HEAT & OPEN FLAME.
Hazardous Decomposition Products:MAY FORM CARBON MONOXIDE & DIOXIDE;
OXIDES OF NITROGEN.
==================== Disposal Considerations ====================
Waste Disposal Methods:SMALL/LARGE SPILL: INCINERATE OR LANDFILL IN
ACCORDANCE W/ALL FEDERAL, STATE & LOCAL REGULATIONS.
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===================== Product Identification =====================
Product ID:DIESEL FUEL ANTI-GEL M22-16
CAGE:77628
CAGE:77628
============= Composition/Information on Ingredients =============
Ingred Name:ALIPHATIC PETROLEUM DISTILLATE
CAS:8002-05-9
Fraction by Wt: >50%
ACGIH TLV:300 PPM
Ingred Name:AROMATIC PETROLEUM DISTILLATE
CAS:64742-95-6
Fraction by Wt: 15-30%
ACGIH TLV:100 PPM
Ingred Name:AROMATIC HYDROCARBON SOLVENT
CAS:64742-94-5
Fraction by Wt: 15-30%
===================== Hazards Identification =====================
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Health Hazards Acute and
Chronic:EYE:IRRITANT.SKIN:DEFATTING,DRYNESS,DERMATITIS.INHALATION:E
XCESSIVE INHALATION CAN CAUSE DIZZINESS,STUPOR.INGESTION:HARMFUL IF
SWALLOWED.IF ASPIRATED INTO LUNGS,CAN CAUSE LUNG IRRITATION.
======================= First Aid Measures =======================
First Aid:EYE CONTACT:FLUSH EYE WITH WATER FOR 15 MIN.SKIN CONTACT:WASH
WITH SOAP AND WATER.INHALATION:MOVE TO FRESH AIR.INGESTION:DO NOT
INDUCE VOMITING.DRINK WATER.CONSULT PHYSICIAN IMMEDIATELY.
===================== Fire Fighting Measures =====================
Flash Point:120F
Extinguishing Media:FOAM,CO2,DRY CHEMICAL
Fire Fighting Procedures:WEAR SELF-CONTAINED,POSITIVE PRESSURE
BREATHING APPARATUS AND PROTECTIVE CLOTHING.
================== Accidental Release Measures ==================
Spill Release Procedures:WIPE UP WITH RAGS.OBSERVING HEALTH
HAZARDS,REMOVE IGNITION SOURCES,VENTILATE AREA.CONFINE SPILL AND
TRANSFER TO WASTE DRUM.
======================Handling and Storage ======================
Handling and Storage Precautions:STORE AT TEMPERATURES BELOW 120F,AWAY
FROM IGNITION SOURCES AND OXIDIZING AGENTS.
Other Precautions:KEEP AWAY FROM CHILDREN.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:IF TLV IS EXCEEDED WEAR NIOSH APPROVED
RESPIRATOR.
Ventilation:GENERAL
Other Protective Equipment:NEOPRENE APRON
Supplemental Safety and Health
================== Physical/Chemical Properties ==================
Boiling Pt:B.P. Text:320F
Spec Gravity:0.8
Solubility in Water:INSOLUBLE
Appearance and Odor:CLEAR AMBER LIQUID
Percent Volatiles by Volume:>70%
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
OXIDIZING AGENTS
Hazardous Decomposition Products:FIRE:NORMAL PRODUCTS OF
COMBUSTION;CARBON DIOXIDE,CARBON MONOXIDE,SMOKE.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH ALL APPLICABLE
GOVERNMENT LAWS AND REGULATIONS.
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===================== Product Identification =====================
Product ID:MEDIUM DRY AQUEOUS RECORDER INK, 61102BEMA
Preparer's Name:GEORGE SARKISIAN
CAGE:17405
CAGE:17405
============= Composition/Information on Ingredients =============
Ingred Name:AMMONIUM,
(4-(P-(DIMETHYLAMINO)-ALPHA-(P-(ETHYL(M-SULFOBENZYL) AMINO PHENYL)
BENZYLIDE
NE)-2,5-CYCLOHEXADIEN-1-YLIDENE)ETHYL(M-SULFOBENZYL)-,HYDROXIDE,INN
ER SALT,SODIUM SALT;(C.I. ACID VIOLET 49, DYE)
CAS:1694-09-3
RTECS #:BQ1140000
Fraction by Wt: 0.5-1.5%
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:WATER % (WT): 98.5 - 99.5
CAS:7732-18-5
RTECS #:ZC0110000
Fraction by Wt: >98.5%
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:NON-HAZARDOUS INGREDIENTS
OSHA PEL:N/K
ACGIH TLV:N/K
===================== Hazards Identification =====================
LD50 LC50 Mixture:LD50 (ORAL, RAT): >5 GM/KG
Routes of Entry: Inhalation:NOSkin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:YES OSHA:NO
Health Hazards Acute and Chronic:ACUTE: SKIN: CAN CAUSE IRRITATION AND
SKIN STAINING. EYES: CONTACT MAY CAUSE IRRITATION. INHALATION:
INHALATION OF VAPORS MAY RESULT IN RESPIRATORY IRRITATION.
INGESTION: MAY RESULT IN GASTRIC DISTURB ANCE. CHRONIC: NONE
EXPECTED BASED ON EMPLOYEE HISTORY OF EXPOSURE.
Explanation of Carcinogenicity:C. I. ACID VIOLET 49: IARC MONOGRAPHS,
SUPP VOL 7, PG 56, 1987: GROUP 2B.
Effects of Overexposure:SEE HEALTH HAZARDS.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
======================= First Aid Measures =======================
First Aid:EYE: FLUSH WITH WATER FOR AT LEAST 15 MINUTES MINIMUM. IF
IRRITATION PERSISTS, GET PROMPT MEDICAL ATTENTION. SKIN: REMOVE
CONTAMINATED CLOTHING AND WASH SKIN THOROUGHLY WITH SOAP AND WATER.
INHAL: REM OVE PERSON TO FRESH AIR. AID BREATHING IF NECESSARY AND
GET MEDICAL ATTENTION. INGESTION: IF SWALLOWED, DILUTE WITH WATER
AND INDUCE VOMITING. GET MEDICAL ATTENTION.
===================== Fire Fighting Measures =====================
Flash Point:NOT FLAMMABLE
Extinguishing Media:USE MEDIA PROPER TO PRIMARY CAUSE OF FIRE.
Fire Fighting Procedures:USE NIOSH APPROVED SCBA & FULL PROTECTIVE
EQUIPMENT .
Unusual Fire/Explosion Hazard:NONE SPECIFIED BY MANUFACTURER.
================== Accidental Release Measures ==================
Spill Release Procedures:WIPE UP SPILLS WITH TOWELS OR CLOTHS. REMOVE
STAINS WITH SOAPY WATER.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
======================Handling and Storage ======================
Handling and Storage Precautions:NO SPECIAL REQUIREMENTS.
Other Precautions:NONE.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:NIOSH APPROVED ORGANIC VAPOR RESPIRATOR, IF
VAPORS OR MIST ARE GENERATED.
Ventilation:MECHANICAL (GENERAL) VENTILATION IS SATISFACTORY.
Other Protective Equipment:EYE WASH FOUNTAIN & DELUGE SHOWER WHICH MEET
ANSI DESIGN CRITERIA .
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
VAPOR DENSITY: DUE TO H*2O ONLY.
================== Physical/Chemical Properties ==================
Boiling Pt:B.P. Text:>212F,>100C
Vapor Pres:DUE TO H*20 ONLY
Vapor Density:SUPDAT
Spec Gravity:1.038-1.055 (H*20=1)
pH:4.0-8.0
Evaporation Rate & Reference:DUE TO H*2O ONLY
Solubility in Water:COMPLETE
Appearance and Odor:BLACK, RED, BLUE, GREEN, ORANGE, PURPLE; SLIGHT
CHARACTERISTIC ODOR.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
REACTS WITH STRONG OXIDIZING AGENTS.
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:ACROLEIN.
==================== Disposal Considerations ====================
Waste Disposal Methods:WASTE DISPOSAL SHOULD BE IN ACCORDANCE WITH
EXISTING FEDERAL, STATE, AND LOCAL ENVIRONMENTAL CONTROL
REGULATIONS.
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===================== Product Identification =====================
Product ID:AROCLOR 1242 MIX, 32109
CAGE:0JL17
CAGE:0JL17
============= Composition/Information on Ingredients =============
Ingred Name:POLYCHLORINATED BIPHENYL (ARCOLOR 1242); (AROCHLOR 1242)
CAS:53469-21-9
RTECS #:TQ1356000
Fraction by Wt: 0.1%
OSHA PEL:1 MG/M3, S
ACGIH TLV:1 MG/M3, S
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB
Ingred Name:HEXANE
CAS:110-54-3
RTECS #:MN9275000
Fraction by Wt: 99.9%
OSHA PEL:50 PPM
ACGIH TLV:50 PPM
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB
===================== Hazards Identification =====================
LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:ACUTE: IRRITANT, CONVULSIONS,
UNCONSCIOUSNESS. CHRONIC: DERMATITIS.
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:DRYNESS AND ITCHING; MILD DEPRESSION,
CONVULSIONS, UNCONSCIOUSNESS.
Medical Cond Aggravated by Exposure:DERMATITIS.
======================= First Aid Measures =======================
First Aid:EYES: REMOVE CONT LENSES IF PRESENT. HOLD LIDS OPEN &
IRRIGATE W/LG VOL OF WATER FOR @ LST 15 MIN. SEEK MED TRTMT. SKIN:
IMMED WASH W/SOAP & WATER. CONTINUE RINSING W/LG VOL OF WATER FOR
15 MIN. INHAL : REMOVE TO FRESH AIR. RESTORE &/OR SUPPORT BRTHG.
HAVE TRAINED PERSON ADMINISTER OXYGEN IF NEEDED. SEEK MED TRTMT.
INGEST: DRINK LG QTY OF WATER. DO NOT INDUCE VOMIT. CONT POIS CTL
CTR.
===================== Fire Fighting Measures =====================
Flash Point:-9F,-23C
Lower Limits:1.2%
Upper Limits:7.7%
Extinguishing Media:DRY CHEMICAL, CO2, HALON, ALCOHOLS, FOAM, WATER
SPRAY AS APPROPRIATE FOR SURROUNDING FIRE AND MATERIALS.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA AND FULL
PROTECTIVE EQUIPMENT . KEEP FIRE-EXPOSED CONTAINERS COOL WITH WATER
SPRAY.
Unusual Fire/Explosion Hazard:MAY FORM EXPLOSIVE VAPOR/AIR MIXTURES.
================== Accidental Release Measures ==================
Spill Release Procedures:WEAR PERSONAL PROTECTIVE EQUIPMENT. ABSORB
SMALL SPILLS ON PAPER, VERMICULITE, OR OTHER ABSORBENT. COLLECT AND
STORE IN CLOSED CONTAINER FOR DISPOSAL.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
======================Handling and Storage ======================
Handling and Storage Precautions:HANDLE WITH UTMOST CARE. AVOID ALL
CONTACT AND INHALATION. STORE IN AN EXPLOSION PROOF REFRIGERATOR @
4C. KEEP IN A TIGHTLY CLSD CONTR @ ALL TIMES.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:NIOSH/MSHA APPROVED RESPIRATOR WITH ORGANIC
VAPOR CARTRIDGE.
Ventilation:USE IN AN AREA PROVIDED WITH GENERAL AND LOCAL EXHAUST
VENTILATION MEETING OSHA REQUIREMENTS.
Other Protective Equipment:PROTECTIVE CLOTHING MEETING LAB SAFETY
REQUIREMENTS.
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
NONE SPECIFIED BY MANUFACTURER.
================== Physical/Chemical Properties ==================
HCC:F2
Boiling Pt:B.P. Text:>151F,>66C
Vapor Pres:124@20C
Solubility in Water:NEGLIGIBLE
Appearance and Odor:COLORLESS/HYDROCARBON
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS LIKE LIQUID CHLORINE AND CONCENTRATED OXYGEN.
Stability Condition to Avoid:HEAT, SPARKS, OPEN FLAMES.
Hazardous Decomposition Products:NONE SPECIFIED BY MANUFACTURER.
==================== Disposal Considerations ====================
Waste Disposal Methods:INCINERATE AT AN APPROVED FACILITY I/A/W
FEDERAL, STATE, AND LOCAL REGULATIONS.
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===================== Product Identification =====================
Product ID:DEGREASER SOLVENT
CAGE:0JVH6
CAGE:0JVH6
============= Composition/Information on Ingredients =============
Ingred Name:ORANGE OIL, TERPENES (NON-HAZARDOUS)
CAS:68647-72-3
Other REC Limits:NONE RECOMMENDED
Ingred Name:PARAFFINIC OILS (NON-HAZARDOUS)
CAS:64771-72-8
Other REC Limits:NONE RECOMMENDED
===================== Hazards Identification =====================
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:EYE: IRRIT, TEARING, REDNESS. SKIN:
DEFATTING, DRYNESS, DERMATITIS. INHAL: RESPIRATORY TRACT IRRIT,
NAUSEA, DIZZY, HEADACHE. INGEST: ACUTE ORAL TOXICITY, NAUSEA,
VOMIT, GI IRRIT, ASPIRATION INTO LUNGS .
======================= First Aid Measures =======================
First Aid:EYE: FLUSH W/WATER FOR 15 MINUTES. SKIN: WASH W/SOAP AND
WATER. INHAL: GET FRESH AIR. INGEST: DONT INDUCE VOMIT. PRODUCT
CONTAINS HYDROCARBONS. IN ALL CASES, GET MED AID.
===================== Fire Fighting Measures =====================
Flash Point Method:TCC
Flash Point:144F,62C
Autoignition Temp:Autoignition Temp Text:410F
Lower Limits:1.3
Upper Limits:8.9
Extinguishing Media:CO2, FOAM, DRY CHEMICAL, CLASS B FOR FIRE
PROCEDURES.
Fire Fighting Procedures:COMBUSTIBLE LIQUID, CAN FORM COMBUSTIBLE
MIXTURES AT OR ABOVE FLASH POINT.
================== Accidental Release Measures ==================
Spill Release Procedures:LAND SPILL: REMOVE IGNITS, CONTAIN SPILL,
RECOVER FREE PRODUCTS, ABSORB W/SUITABLE CHEMICAL ABSORBENT FOR
DISPOSAL. WATER SPILL: REMOVE FROM WATER BY SKIMMING, OR USE
SUITABLE ABSORBENT.
======================Handling and Storage ======================
Handling and Storage Precautions:STORAGE TEMPERATURE AMBIENT KEEP AWAY
FROM HEAT AND IGNITS. KEEP PRODUCT CONTAINER CLOSED WHEN NOT IN
USE.
============= Exposure Controls/Personal Protection =============
Ventilation:MECHANICAL DILUTION VENTILATION RECOMMENDED IN CONFINED
AREAS, HEATED >AMBIENT TEMPERATURES OR IS AGITATED.
Supplemental Safety and Health
NK
================== Physical/Chemical Properties ==================
Boiling Pt:B.P. Text:380 TO 430F
Vapor Pres:<1 @ 20C
Vapor Density:>1 AIR=1
Spec Gravity:0.76
VOC Pounds/Gallon:756
pH:NA
Evaporation Rate & Reference:3.2 N BUAC = 100
Solubility in Water:NON-MISCIBLE
Appearance and Odor:COLORLESS LIQUID, W/CHARACTERISTIC ODOR.
Percent Volatiles by Volume:100
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS
Hazardous Decomposition Products:CARBON DIOXIDE, CARBON MONOXIDE,
SMOKE.
==================== Disposal Considerations ====================
Waste Disposal Methods:INCINERATE OR BURY IN APPROVED LANDFILL IN
ACCORDANCE W/STATE, FEDERAL AND LOCAL REGULATIONS.
======================= Other Information =======================
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=======================================================
Product ID: 84-9802-0072-3 00-51111-43913-5, DISKETTE (SUPDAT)
Cage: EO130
=======================================================
Contractor Summary
=======================================================
Cage: 06XS2
Box: UNKNOW
Cage: EO130
=======================================================
Ingredients
=======================================================
Cas: 67-63-0
RTECS #: NT8050000
% Wt: 100
OSHA PEL: 400 PPM
ACGIH TLV: 400 PPM; 500 STEL
=======================================================
Health Hazards Data
=======================================================
LD50 LC50 Mixture: NONE SPECIFIED BY MANUFACTURER.
Route Of Entry Inds - Inhalation: YES
Skin: YES
Ingestion: YES
Carcinogenicity Inds - NTP: NO
IARC: NO
OSHA: NO
Effects of Exposure: EYES: MOD EYE IRRIT: SIGNS/SYMPS CAN INCL REDNESS,
SWELLING, PAIN, TEARING & HAZY VISION. SKIN: MILD SKIN IRRIT: SIGNS/SYMPS
CAN INCL REDNESS, SWELLING & ITCHING. INHAL: CNS DEPRESS: SIGNS/SYMPS CAN
I NCL HEADACHE, DIZZINESS, DROWSINESS, INCOORDINATION, SLOWED REACTION TIME,
SLURRED SPEECH, GIDDINESS & (EFTS OF OVEREXP)
Explanation Of Carcinogenicity: NOT RELEVANT
Signs And Symptions Of Overexposure: HLTH HAZ: UNCON. IRRIT (UPPER
RESPIRATORY): SIGNS/SYMPS CAN INCL SORENESS OF NOSE & THROAT, COUGHING
& SNEEZING. INGEST: IRRIT OF GI TISSUES: SIGNS/SYMPS CAN INCL PAIN,
VOMITING, ABDOMINAL TENDERNESS, NAUSEA, BLOOD IN VOMITUS & BLOOD IN
FECES. CNS DEPRESS: SIGNS/SYMPS CAN INCL HEADACHE, DIZZINESS, DROWSINESS,
MUSC WEAKNESS, INCOORD, SLOWED RXN TIME, FATIGUE, BLURRED VISION, SLURRED
SPEECH, GIDDINE SS, TREMORS & CONVULSIONS. ASPIR PNEUM: SIGNS/SYMPS CAN
INCLUDE COUGH, DFCLTY BRTHG, WHEEZING, COUGHING UP BLOOD & PNEUM WHICH
CAN BE FATAL.
Medical Cond Aggravated By Exposure: NONE SPECIFIED BY MANUFACTURER.
First Aid: EYES: IMMED FLUSH EYES W/LARGE AMOUNTS OF WATER FOR AT LEAST 15
MINUTES. GET IMMED MED ATTN. SKIN: FLUSH SKIN W/LARGE AMOUNTS OF WATER. IF
IRRITATION PERSISTS, GET MED ATTN. INHAL: IF SIGNS/SYMPS OCCU R, REMOVE
PERSON TO FRESH AIR. IF SIGNS/SYMPS CONTINUE, CALL MD. INGEST: IF SWALLOWED,
CALL MD IMMED. ONLY INDUCE VOMITING AT INSTRUCTION OF MD. NEVER GIVE ANYTHING
BY MOUTH TO AN UNCONSCIOUS PERSON.
=======================================================
Handling and Disposal
=======================================================
Spill Release Procedures: REFER TO OTHER SECTIONS OF MSDS FOR INFO REGARDING
PHYSICAL & HEALTH HAZARDS, RESPIRATORY PROTECTION, VENTILATION &
PERSONAL PROTECTIVE EQUIPMENT. IN USA CALL 612-733-1110 OR 612-733-6100 FOR
24-HR SP ILL ASSISTANCE. EXTINGUISH ALL IGNITION SOURCES. COVER W/ABSORBENT
MATL. COLLECT SPILLED MATL. CLEAN UP RESIDUE. PLACE IN APPRVD METAL
CONTAINER.
Neutralizing Agent: NONE SPECIFIED BY MANUFACTURER.
Waste Disposal Methods: DISPOSAL MUST BE I/A/W FEDERAL, STATE & LOCAL REGS
(FP N). INCINERATE IN AN INDUSTRIAL OR COMMERCIAL FACILITY. DISPOSE OF WASTE
PRODUCT IN A FACILITY PERMITTED TO ACCEPT CHEMICAL WASTE. MATL TO BE DIS
POSED HAS A US EPA HAZ NUMBER D001 (IGNITABLE).
Handling And Storage Precautions: FLAMMABLE LIQUID AND VAPOR. KEEP AWAY FROM
HEAT, SPARKS, OPEN FLAME AND OTHER SOURCES OF IGNITION.
Other Precautions: AVOID EYE CONTACT. AVOID SKIN CONTACT. DO NOT INGEST. KEEP
OUT OF THE REACH OF CHILDREN.
=======================================================
Fire and Explosion Hazard Information
=======================================================
Flash Point Text: 53.0F,11.7C
Lower Limits: 2.00%
Upper Limits: 12.00%
Extinguishing Media: CARBON DIOXIDE, FOAM, DRY CHEMICAL, WATER FOG.
Fire Fighting Procedures: USE NIOSH APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT
(FP N).
Unusual Fire/Explosion Hazard: NONE.
=======================================================
Control Measures
=======================================================
Respiratory Protection: AVOID BREATHING OF VAPORS.USE NIOSH APPROVED RESPIRATOR
APPROPRIATE FOR EXPOSURE OF CONCERN (FP N).
Ventilation: USE IN A WELL-VENTILATED AREA.
Other Protective Equipment: ANSI APPROVED EYE WASH & DELUGE SHOWER (FP N).
Work Hygienic Practices: NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health: MFR'S TRADE NAME/PART NO: HEAD CLEANING KIT
(FLUIDS AND PACKETS).
=======================================================
Physical/Chemical Properties
=======================================================
B.P. Text: 130F,54C
Vapor Pres: 33
Vapor Density: 5.0
Spec Gravity: 0.600 (H*2O=1)
VOC Grams/Liter: 785
Evaporation Rate & Reference: 0.80 (H*2O=1)
Solubility in Water: 100 G/100 CC
Appearance and Odor: CLEAR LIQUID; ALCOHOL ODOR.
Percent Volatiles by Volume: 100
=======================================================
Reactivity Data
=======================================================
Stability Indicator: YES
Stability Condition To Avoid: HEAT.
Materials To Avoid: NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products: CARBON MONOXIDE AND CARBON DIOXIDE.
Hazardous Polymerization Indicator: NO
Conditions To Avoid Polymerization: NOT RELEVANT
=======================================================
Toxicological Information
=======================================================
=======================================================
Ecological Information
=======================================================
=======================================================
=======================================================
=======================================================
Regulatory Information
=======================================================
=======================================================
Other Information
=======================================================
=======================================================
HAZCOM Label
=======================================================
Product ID: 84-9802-0072-3 00-51111-43913-5, DISKETTE (SUPDAT)
Cage: EO130
Assigned IND: Y
Company Name: IMATION ENTERPRISES CORPORATION
Street: 1 IMATION PLACE
Zipcode: 55128-1110
Label Required IND: Y
Date Of Label Review: 01/13/1997
Status Code: C
Label Date: 01/13/1997
Origination Code: G
Skin Protection IND: YES
Signal Word: DANGER
Respiratory Protection IND: YES
Health Hazard: Moderate
Contact Hazard: Moderate
Fire Hazard: Severe
Reactivity Hazard: None
Hazard And Precautions: EXTREMELY FLAMMABLE. ACUTE: EYES: MODERATE EYE
IRRITATION WITH REDNESS, SWELLING, PAIN, TEARING AND HAZY VISION. SKIN: MILD
SKIN IRRITATION WITH REDNESS, SWELLING AND ITCHING. INHALATION: CNS DEPRESSI
ON WITH HEADACHE, DIZZINESS, DROWSINESS, INCOORDINATION, SLOWED REACTION
TIME, SLURRED SPEECH, GIDDINESS AND UNCONSCIOUSNESS. IRRITATION. INGESTION:
IRRITATION OF GI TISSUE, CNS DEPRESSION, ASPIRATION PNEUMONITIS. CHRONIC:
NONE LISTED BY MANUFACTURER.
=======================================================
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===================== Product Identification =====================
Product ID:ECONOMISER
CAGE:ALLXS
CAGE:023L7
CAGE:ALLXS
============= Composition/Information on Ingredients =============
Ingred Name:ALUMINUM OXIDE; (FUSED ALUMINUM OXIDE) (SARA 313)
CAS:1344-28-1
RTECS #:BD1200000
Fraction by Wt: 48-92%
OSHA PEL:15 MG/M3 TDUST
ACGIH TLV:10 MG/M3 TDUST
Ingred Name:SILICON CARBIDE
CAS:409-21-2
RTECS #:VW0450000
Fraction by Wt: 48-92%
OSHA PEL:15 MG/M3 TDUST
ACGIH TLV:10 MG/M3 TDUST
Ingred Name:FLUORIDE; (FLUORIDES (AS F))
CAS:16984-48-8
RTECS #:LU6290000
Fraction by Wt: 8-24%
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:SULFUR
CAS:7704-34-9
RTECS #:WS4250000
Fraction by Wt: 1-8%
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:IRON OXIDE (RED)
CAS:1309-37-1
RTECS #:NO7400000
Fraction by Wt: 2-10%
OSHA PEL:10 MG/M3 (FE)
ACGIH TLV:5MG(FE)/M3FUME, B2
Ingred Name:CALCIUM OXIDE
CAS:1305-78-8
RTECS #:EW3100000
Fraction by Wt: 0-1%
OSHA PEL:5 MG/M3
ACGIH TLV:2 MG/M3
===================== Hazards Identification =====================
LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:MATERIALS GENERATED WHEN A WHEEL IS
USED HAVE NOT BEEN IDENTIFIED BUT ARE CONSIDERED NUISANCE DUST BY
FEDERAL OSHA. ACUTE: INHALATION: COUGHING, SHORTNESS OF BREATH.
SKIN: SOME MAY EXPERIENCE SKIN IRR ITATION. EYES: DUSTS MAY
IRRITATE. CHRONIC: MAY AFFECT BREATHING CAPACITY.
Explanation of Carcinogenicity:NOT RELEVANT.
Effects of Overexposure:SEE HEALTH HAZARDS.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
======================= First Aid Measures =======================
First Aid:INHALATION: REMOVE TO FRESH AIR. ARTIFICIAL RESPIRATION AS
NEEDED. OBTAIN MEDICAL ASSISTANCE. SKIN: WASH WITH SOAP AND WATER.
OBTAIN MEDICAL ASSISTANCE. EYES: WASH WITH LARGE AMOUNTS OF WATER
FOR AT L EAST 15 MINUTES. OBTAIN FIRST AID AND/OR MEDICAL
ASSISTANCE IF NEEDED. INGESTION: CALL MD IMMEDIATELY .
===================== Fire Fighting Measures =====================
Extinguishing Media:PRODUCT IS NON-FLAMMABLE. USE MEDIA SUITABLE FOR
SURROUNDING FIRE .
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA & FULL
PROTECTIVE EQUIPMENT .
Unusual Fire/Explosion Hazard:NONE SPECIFIED BY MANUFACTURER.
================== Accidental Release Measures ==================
Spill Release Procedures:NONE SPECIFIED BY MANUFACTURER.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
======================Handling and Storage ======================
Handling and Storage Precautions:STORE WHEELS IN A FLAT POSITION.
Other Precautions:NONE SPECIFIED BY MANUFACTURER.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:USE NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE
FOR EXPOSURE OF CONCERN .
Ventilation:MECHANICAL. SEE OSHA 29 CFR 1910.94.
Other Protective Equipment:EMERGENCY EYEWASH & DELUGE SHOWER MEETING
ANSI DESIGN CRITERIA . WHEEL GUARD; SEE OSHA 29 CFR 1910.25.
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
NONE SPECIFIED BY MANUFACTURER.
================== Physical/Chemical Properties ==================
Spec Gravity:2-3
Solubility in Water:INSOLUBLE
Appearance and Odor:BROWN TO BLACK SOLID, WITH TYPICAL RUBBER ODOR
Percent Volatiles by Volume:0
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
NONE SPECIFIED BY MANUFACTURER.
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:ONE.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSE OF IN ACCORDANCE W/LOCAL, STATE &
FEDERAL REGULATIONS .
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===================== Product Identification =====================
Product ID:ETHAFOAM 220 ANTI-STATIC PLANK POLYETHYLENE
CAGE:96717
CAGE:96717
============= Composition/Information on Ingredients =============
Ingred Name:WAX/POLYETHYLENE FOAM
CAS:8002-74-2
RTECS #:RV0350000
Fraction by Wt: 84- 100%
Other REC Limits:NONE SPECIFIED
Ingred Name:DICHLORODIFLUOROMETHANE (SARA III)
CAS:75-71-8
RTECS #:PA8200000
Fraction by Wt: 0 - 3%
Other REC Limits:NONE SPECIFIED
OSHA PEL:1000 PPM
ACGIH TLV:1000 PPM; 9192
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
Ozone Depleting Chemical:1
Ingred Name:DICHLOROTETRAFLUOROETHANE (SARA III)
CAS:76-14-2
RTECS #:KI1101000
Fraction by Wt: 0 - 11%
Other REC Limits:NONE SPECIFIED
OSHA PEL:1000 PPM
ACGIH TLV:1000 PPM; 9192
Ozone Depleting Chemical:1
Ingred Name:ETHOXYLATED ALKYL AMINE/ANTI-STATIC ADDITIVE
CAS:61791-44-4
Other REC Limits:NONE SPECIFIED
===================== Hazards Identification =====================
Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:ACUTE-EYE:SOLID/DUST MAY CAUSE
IRRITATION/CORNEAL INJURY.SKIN:NON-IRRITATING.MECHANICAL INJURY
ONLY.INHALATION:DUST/VAPORS MAY CAUSE IRRITATION OF UPPER
RESPIRATORY TRACT.INGESTION:MAY CAUSE CHOKING.C HRONIC-NONE
Effects of Overexposure:DUST MAY CAUSE EYE IRRITATION/CORNEAL INJURY.
MECHANICAL INJURY OF SKIN ONLY.DUST/VAPORS (AT HIGH TEMPERATURES)
MAY CAUSE IRRITATION OF UPPER RESPIRATORY TRACT. INGESTION MAY
CAUSE CHOKING.
Medical Cond Aggravated by Exposure:PERSONS WITH A HISTORY OF AILMENTS
OR WITH A PRE-EXISTING DISEASE INVOLVING THE SKIN, OR RESPIRATORY
TRACT MAY BE AT INCREASED RISK FROM EXPOSURE.
======================= First Aid Measures =======================
First Aid:INHALATION:REMOVE TO FRESH AIR.CONSULT A
PHYSICIAN.EYES:IMMEDIATELY FLUSH WITH WATER FOR AT LEAST 5 MINUTES
HOLDING EYELIDS OPEN.MECHANICAL EFFECTS ONLY.SKIN/INGESTION:NO
ADVERSE EFFECTS ANTICIPATED.N OTE TO PHYSICIAN:NO SPECIFIC
ANTIDOTE.SUPPORTIVE CARE.TREATMENT BASED ON JUDGMENT OF THE
PHYSICIAN IN RESPONSE TO REACTIONS OF THE PATIENT.
===================== Fire Fighting Measures =====================
Extinguishing Media:USE WATER FOG
Fire Fighting Procedures:WEAR FIRE FIGHTING PROTECTIVE EQUIPMENT AND A
FULL FACED SELF CONTAINED BREATHING APPARATUS OPERATED IN POSITIVE
PRESSURE. COOL FIRE EXPOSED CONTAINERS WITH H2O
Unusual Fire/Explosion Hazard:DENSE SMOKE
================== Accidental Release Measures ==================
Spill Release Procedures:PICK UP AND HANDLE AS ANY OTHER INERT
MATERIAL.
Neutralizing Agent:NOT APPLICABLE.
======================Handling and Storage ======================
Handling and Storage Precautions:STORAGE-STORE IN A COOL AREA AWAY FROM
EXCESSIVE HEAT,FLAME/SOURCES OF IGNITION.
Other Precautions:LARGE QUANTITIES OF THIS PRODUCT CAN CAUSE CORROSION
OF HEATERS AND EVENTUALLY CREATE HOLES IN THE COMBUSTION CHAMBER
LEADING TO THE RELEASE OF COMBUSTION GASES AND CARBON MONOXIDE.
THIS PRODUCT IS CO MBUSTIBLE AND CAN BURN RAPIDLY.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:NO RESPIRATORY PROTECTION SHOULD BE NEEDED.
Ventilation:GOOD GENERAL VENTILATION. LOCAL EXHAUST VENTILATION MAY BE
NECESSARY FOR SOME OPERATIONS SUCH AS HOT-WIRE CUTTING.
Other Protective Equipment:EYE WASH STATION, SAFETY SHOWER, WORK
CLOTHING
Work Hygienic Practices:OBSERVE GOOD PERSONAL HYGIENE PRACTICES AND
RECOMMENDED PROCEDURES.
Supplemental Safety and Health
================== Physical/Chemical Properties ==================
HCC:N1
Spec Gravity:0.02 - 0.06
Solubility in Water:INSOLUBLE
Appearance and Odor:CELLULAR SOLID PLASTIC FOAM WITH NO ODOR
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS
Stability Condition to Avoid:FIRE AND TEMPERATURES ABOVE 625F(329C)
Hazardous Decomposition Products:CARBON MONOXIDE AND OTHER TOXIC
SUBSTANCES
==================== Disposal Considerations ====================
Waste Disposal Methods:REUSE OR BURY IN AN APPROVED LANDFILL. DISPOSAL
MUST BE MADE IN ACCORDANCE WITH ALL APPLICABLE FEDERAL, STATE AND
LOCAL LAWS AND REGULATIONS.
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===================== Product Identification =====================
Product ID:2242 HARD HAT FLUORESCENT TOPCOAT
CAGE:08882
CAGE:08882
============= Composition/Information on Ingredients =============
Ingred Name:TOLUENE (IARC CARC- GROUP 3) *95-4*
CAS:108-88-3
RTECS #:XS5250000
Fraction by Wt: 10%
Other REC Limits:375 MG/CUM
OSHA PEL:100 PPM
ACGIH TLV:100 PPM
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Ingred Name:STODDARD SOLVENT (PETROLEUM DISTILLATE), MINERAL SPIRITS
CAS:8052-41-3
RTECS #:WJ8925000
Fraction by Wt: 10%
Other REC Limits:525 MG/CUM
OSHA PEL:500 PPM
ACGIH TLV:100 PPM
Ingred Name:MEDIUM ALIPHATIC NAPHTHA (AROMATIC 100), PARAFFIN-NAPTHANES
MINERAL SPIRITS
CAS:64742-88-7
Fraction by Wt: 5%
Other REC Limits:100 PPM
OSHA PEL:500 PPM
ACGIH TLV:100 PPM
Ingred Name:BUTANE, N-BUTANE
CAS:106-97-8
RTECS #:EJ4200000
Fraction by Wt: 10%
Other REC Limits:800 PPM
OSHA PEL:800 PPM
ACGIH TLV:1900 MG/CUM
Ingred Name:PROPANE (DIMETHYLMETHANE)*95-4*
CAS:74-98-6
RTECS #:TX2275000
Fraction by Wt: 25%
Other REC Limits:1800 MG/CUM
OSHA PEL:1000 PPM
ACGIH TLV:SIMPLE ASPHYXIANT
Ingred Name:HEXANE, N-HEXANE
CAS:110-54-3
RTECS #:MN9275000
Fraction by Wt: 15%
Other REC Limits:50 PPM
OSHA PEL:1800 MG/CUM
ACGIH TLV:176 MG/CUM
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB
===================== Hazards Identification =====================
Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:INHALATION: HARMFUL. MAY AFFECT THE
BRAIN/NERVOUS SYSTEM. CAUSES NOSE & THROAT IRRITATION. SKIN:
IRRITATION, DERMATITIS. EYES: IRRITATION. INGESTION: GI IRRITATION.
SOLVENTS MAY CAUSE PERMANENT BRAIN/ NERVOUS SYSTEM DAMAGE. (SEE
SUPP)
Explanation of Carcinogenicity:NONE
Effects of Overexposure:DIZZINESS, HEADACHE, NAUSEA, STAGGERING GAIT,
CONFUSION, UNCONSCIOUSNESS, COMA, IRRITATION, VOMITING, DIARRHEA.
======================= First Aid Measures =======================
First Aid:INHALATION: REMOVE TO FRESH AIR, RESTORE BREATHING. EYES:
FLUSH IMMEDIATELY W/LARGE AMOUNTS OF WATER FOR 15 MINS. SKIN: WASH
W/SOAP & WATER. INGESTION: DON'T INDUCE VOMITING. KEEP WARM &
QUIET. ASPIRA TION OF MATERIAL INTO LUNGS CAN CAUSE CHEMICAL
PNEUMONITIS WHICH CAN BE FATAL. OBTAIN MEDICAL ATTENTION IN ALL
CASES.
===================== Fire Fighting Measures =====================
Flash Point Method:TCC
Flash Point:<-25F
Extinguishing Media:CO2, DRY CHEMICAL/FOAM
Fire Fighting Procedures:WEAR FULL PROTECTIVE EQUIPMENT W/SCBA. WATER
SPRAY MAY BE INEFFECTIVE. USE WATER TO COOL CLOSED CONTAINERS. IF
WATER IS USED, FOG NOZZLES ARE PREFERRED.
Unusual Fire/Explosion Hazard:CLOSED CONTAINERS MAY EXPLODE WHEN
EXPOSED TO EXTREME HEAT. DON'T APPLY TO HOT SURFACES.
================== Accidental Release Measures ==================
Spill Release Procedures:REMOVE IGNITION SOURCES, VENTILATE AREA &
REMOVE W/INERT ABSORBENT & NON-SPARKING TOOLS.
======================Handling and Storage ======================
Handling and Storage Precautions:DON'T STORE >120F. PROTECT FROM
FREEZING. DON'T PUNCTURE/INCINERATE CONTAINERS.
Other Precautions:INTENTIONAL MISUSE BY DELIBERATELY CONCENTRATING &
INHALING CONTENTS MAY BE HARMFUL/FATAL.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:USE NIOSH APPROVED CHEMICAL CARTRIDGE RESPIRATOR
TO REMOVE SOLID AIRBORNE OVERSPRAY PARTICLES & ORGANIC VAPORS
DURING SPRAYING. CONFINED AREAS: NIOSH APPROVED SUPPLIED AIR
RESPIRATORS/HOODS.
Ventilation:GENERAL DILUTION/LOCAL EXHAUST VENTILATION IN VOLUME &
PATTERN TO KEEP TLVS < ACCEPTABLE LIMITS.
Work Hygienic Practices:REMOVE/LAUNDER CONTAMINATED CLOTHING BEFORE
REUSE.
Supplemental Safety and Health
HEALTH HAZARDS CONT'D: OVEREXPOSURE TO TOLUENE, EFFECTS IN HUMANS HAVE
INCLUDED LIVER & CARDIAC ABNORMALITIES. OVEREXPOSURE TO HEXANE IN
HIGH VAPOR CONCENTRATIONS (1000-1500 PPM) OVER A PERIOD OF SEVE RAL
MONTHS MAY CAUSE PERIPHERAL POLYNEUROPATHY WHICH HAS THE POTENTIAL
OF BECOMING IRREVERSIBLE.
================== Physical/Chemical Properties ==================
Boiling Pt:B.P. Text:31-396F
Vapor Density:>1
Evaporation Rate & Reference:SLOWER THAN ETHER
Percent Volatiles by Volume:85-90
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS
Stability Condition to Avoid:HEAT, ELECTRICAL EQUIPMENT, SPARKS, OPEN
FLAMES, HOT SURFACES, IGNITION SOURCES, FREEZING.
Hazardous Decomposition Products:OPEN FLAME: CO, CO2, UNIDENTIFIABLE
ORGANIC COMPOUNDS.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSE OF IAW/FEDERAL, STATE & LOCAL
REGULATIONS. DON'T INCINERATE CLOSED CONTAINERS.
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===================== Product Identification =====================
Product ID:GALLIUM(III) OXIDE 99.9+%, 21506-6
CAGE:60928
CAGE:60928
============= Composition/Information on Ingredients =============
Ingred Name:GALLIUM OXIDE; (GALLIUM(III) OXIDE)
CAS:12024-21-4
RTECS #:LW9650000
Fraction by Wt: 99.9%+
OSHA PEL:N/K
ACGIH TLV:N/K
===================== Hazards Identification =====================
LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:ACUTE: MAY BE HARMFUL BY INHALATION,
INGESTION, OR SKIN ABSORPTION. MAY CAUSE EYE AND SKIN IRRITATION.
TO THE BEST OF MFR KNOWLEDGE, THE CHEMICAL, PHYSICAL, AND
TOXICOLOGICAL PROPERTIES HAVE NOT BEEN THOROUGHLY INVESTIGATED.
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:SEE HEALTH HAZARDS.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
======================= First Aid Measures =======================
First Aid:EYES: IMMED FLUSH WITH COPIOUS AMOUNTS OF WATER FOR AT LEAST
15 MINUTES. SKIN: IMMED FLUSH WITH COPIOUS AMOUNTS OF WATER. WASH
CONTAMINATED CLOTHING BEFORE REUSE. INHAL: REMOVE TO FRESH AIR. IF
NOT BR EATHING GIVE ARTF RESP. IF BREATHING ISDIFFICULT, GIVE
OXYGEN. INGEST: WASH OUT MOUTH W/WATER PROVIDED PERSON IS
CONSCIOUS. CALL A PHYSICIAN.
===================== Fire Fighting Measures =====================
Extinguishing Media:WATER SPRAY. CARBON DIOXIDE, DRY CHEMICAL POWDER OR
APPRORPIATE FOAM.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA AND FULL
PROTECTIVE EQUIPMENT .
Unusual Fire/Explosion Hazard:EMITS TOXIC FUMES UNDER FIRE CONDITIONS.
================== Accidental Release Measures ==================
Spill Release Procedures:WEAR NIOSH/MSHA APPROVED RESPIRATOR, CHEMICAL
BAG AND HOLD FOR WASTE DISP. AVOID RAISING DUST. VENT AREA & WASH
SPILL SITE AFTER MAT L PICKUP IS COMPLETE.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
======================Handling and Storage ======================
Handling and Storage Precautions:AVOID INHAL. AVOID CONT W/EYES, SKIN &
CLTHG. AVOID PRLNGD/RPTD EXPOS. KEEP TIGHTLY CLOSED. STORE IN A
COOL DRY PLACE.
Other Precautions:NONE SPECIFIED BY MANUFACTURER.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:NIOSH/MSHA APPROVED RESPIRATOR.
Ventilation:MECHANICAL EXHAUST REQUIRED.
Other Protective Equipment:SAFETY SHOWER AND EYE BATH.
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING.
Supplemental Safety and Health
NONE SPECIFIED BY MANUFACTURER.
================== Physical/Chemical Properties ==================
HCC:N1
Spec Gravity:5.880
Appearance and Odor:WHITE CRYSTALLINE POWDER
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS.
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:NATURE OF DECOMPOSITION PRODUCTS NOT
KNOWN.
==================== Disposal Considerations ====================
Waste Disposal Methods:BURY IN A LANDFILL SITE APPROVED FOR THE
DISPOSAL OF CHEMICAL AND HAZARDOUS WASTES. OBSERVE ALL FEDERAL,
STATE AND LOCAL ENVIROMENTAL REGULATIONS.
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===================== Product Identification =====================
Product ID:METHYL ALCOHOL, A452SK 1
CAGE:1B464
CAGE:1B464
============= Composition/Information on Ingredients =============
Ingred Name:METHANOL; (METHYL ALCOHOL) (SARA 313) (CERCLA)
CAS:67-56-1
RTECS #:PC1400000
OSHA PEL:200 PPM, S
ACGIH TLV:200PPM/250STEL, S
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
Ingred Name:SUP DAT: DIHYDRIDE, CARBON TETRACHLORIDE + METALS,
CHLOROFORM + HEAT, CHLOROFORM + SODIUM HYDROXIDE, CYANURIC (ING 3)
RTECS #:9999999ZZ
Ingred Name:ING 2: CHLORIDE, DIETHYL ZINC, NITRIC ACID, & POTASSIUM
TERTBUTOXIDE. PLEASE REFER TO THE NFPA FIRE PROTECTION (ING 4)
RTECS #:9999999ZZ
Ingred Name:ING 3: GUIDE FOR ALL SPECIFICS.
RTECS #:9999999ZZ
Ingred Name:EFTS OF OVEREXP: CHRONIC INHALATION & INGESTION MAY CAUSE
EFFECTS SIMILAR TO THOSE OF ACUTE INHALATION & INGESTION.
RTECS #:9999999ZZ
Ingred Name:FIRST AID PROC: INDUCE VOMIT BY GIVING 1 TEASPOON OF SYRUP
OF IPECAC. INHAL: GET MED AID IMMED. REMOVE FROM (ING 7)
RTECS #:9999999ZZ
Ingred Name:ING 6: EXPOS TO FRESH AIR IMMED. IF NOT BRTHG, GIVE ARTF
RESP. IF BRTHG IS DFCLT, GIVE OXYGEN. NOTES TO MD: (ING 8)
RTECS #:9999999ZZ
Ingred Name:ING 7: SYMPS MAY BE DELAYED. METABOLISM OF MEOH CAN BE
PREVENTED BY ADMIN OF ETOH BY QUALIFIED MED PERS. (ING 9)
RTECS #:9999999ZZ
Ingred Name:ING 8: NO SPECIFIC ANTIDOTE EXISTS.
RTECS #:9999999ZZ
Ingred Name:OTHER PREC: AWAY FROM INCOMPATIBLE SUBSTANCES.
RTECS #:9999999ZZ
===================== Hazards Identification =====================
LD50 LC50 Mixture:LD50 (ORAL RAT): 5628 MG/KG.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:TARGET ORGANS: KIDNEYS, CNS, LIVER,
CARDIOVASCULAR SYS, EYES. ACUTE: EYES: MOD IRRIT. VAPS MAY CAUSE
IRRIT. MAY CAUSE PAINFUL SENSIT TO LIGHT. SKIN: MAY CAUSE IRRIT.
MAY BE ABSORBED THRU SKIN IN HARMF UL AMTS. INGEST: MAY CAUSE IRRIT
OF DIGESTIVE TRACT, RESP FAILURE, VASCULAR COLLAPSE & DMG, KIDNEY
(EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT.
Effects of Overexposure:HLTH HAZ: FAILURE. INHAL: MAY CAUSE RESP TRACT
IRRIT, LIVER & KIDNEY DMG. MAY CAUSE ADVERSE CNS EFTS INCL HDCH,
CONVLS, & POSS DEATH. MAY CAUSE VISUAL IMPAIRMENT & POSS PERM
BLINDNESS. MAY CAUSE EFTS SIMILAR TO THOSE DESCRIBED FOR INGEST.
CHRONIC: PRLNG/RPTD SKIN CONT CAN CAUSE DERM. (ING 5)
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
======================= First Aid Measures =======================
First Aid:EYES: FLUSH W/PLENTY OF WATER FOR AT LEAST 15 MIN, OCCAS
LIFTING UPPER & LOWER LIDS. GET MED AID IMMED. DO NOT ALLOW VICTIM
TO RUB EYES/KEEP EYES CLSD. SKIN: FLUSH W/PLENTY OF SOAP & WATER
FOR AT LEAS T 15 MIN WHILE REMOVING CONTAM CLTHG & SHOES. GET MED
AID IF IRRIT DEVELOPS/PERSISTS. INGEST: IF VICTIM IS CONSCIOUS &
ALERT, GIVE 2-4 CUPFULS OF MILK/WATER. GET MED AID IMMED. (ING 6)
===================== Fire Fighting Measures =====================
Flash Point:52.0F,11.1C
Lower Limits:6.0%
Upper Limits:36.0%
Extinguishing Media:FOR SMALL FIRES, USE DRY CHEMICAL, CARBON DIOXIDE,
WATER SPRAY OR ALCOHOL-RESISTANT FOAM.
Fire Fighting Procedures:WEAR NIOSH APPROVED SCBA AND FULL PROTECTIVE
EQUIPMENT . USE WATER SPRAY TO COOL FIRE-EXPOSED CONTAINERS. WATER
MAY BE INEFFECTIVE.
Unusual Fire/Explosion Hazard:CONTRS CAN BUILD UP PRESS IF EXPOSED TO
HEAT &/FIRE. VAPS CAN TRAVEL TO SOURCE OF IGNIT & FLASH BACK.
DURING FIRE, IRRIT & HIGHLY TOX GASES MAY BE (SUP DAT)
================== Accidental Release Measures ==================
Spill Release Procedures:SCOOP UP WITH A NON-SPARKING TOOL, THEN PLACE
INTO A SUITABLE CONTAINER FOR DISPOSAL. USE WATER SPRAY TO DISPERSE
THE GAS/VAPOR. REMOVE ALL SOURCES OF IGNITION. ABSORB SPILL USING
AN ABSORBENT, NON-CO MBUSTIBLE MATERIAL SUCH AS EARTH, SAND.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
======================Handling and Storage ======================
Handling and Storage Precautions:USE WITH ADEQUATE VENTILATION. EMPTY
CONTAINERS RETAIN PRODUCT RESIDUE (LIQUID AND/OR VAPOR), AND CAN BE
DANGEROUS.
Other Precautions:DO NOT PRESSURIZE, CUT, WELD, BRAZE, SOLDER, DRILL,
GRIND/EXPOSE SUCH CONTRS TO HEAT, SPKS & OPEN FLAMES. DO NOT GET ON
SKIN/IN EYES. DO NOT INGEST/INHALE. KEEP AWAY FROM SOURCES OF
IGNIT. STORE IN CO OL, DRY, WELL-VENTILATED AREA (ING 10)
============= Exposure Controls/Personal Protection =============
Respiratory Protection:FOLLOW THE OSHA RESPIRATOR REGULATIONS FOUND IN
29 CFR 1010.134. ALWAYS USE A NIOSH APPROVED RESPIRATOR WHEN
NECESSARY.
Ventilation:USE ADEQUATE GENERAL/LOCAL EXHAUST VENTILATION TO KEEP
AIRBORNE CONCENTRATIONS BELOW PERMISSIBLE EXPOSURE LIMITS.
Other Protective Equipment:ANSI APPROVED EMERGENCY EYEWASH & DELUGE
SHOWER . WEAR APPROPRIATE PROTECTIVE CLOTHING TO PREVENT SKIN
EXPOSURE.
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING. REMOVE
CONTAMINATED CLOTHING AND WASH BEFORE REUSE.
Supplemental Safety and Health
EXPLO HAZ: GENERATED BY THERMAL DECOMP/COMBUST. FLAMM LIQ. CAN RELEASE
VAPS THAT FORM EXPLO MIXS AT TEMPS ABOVE FLASH POINT. MATLS TO
AVOID: SODIUM HYPOCHLORITE). ACTIVE METALS (SUCH AS POTASSIUM & MA
GNESIUM). SUBSTANCE IS ALSO INCOMPATIBLE W/SPECIFIC CHEMS INCL:
ACETYL BROMIDE, ALKYL ALUMINUM SALTS, BERYLLIUM (ING 2)
================== Physical/Chemical Properties ==================
Boiling Pt:B.P. Text:147F,64C
Melt/Freeze Pt:M.P/F.P Text:-144F,-98C
Vapor Pres:29
Vapor Density:1.1
Spec Gravity:0.8 (H*2O=1)
pH:NEUT
Evaporation Rate & Reference:5.2 (ETHER=1)
Solubility in Water:SOLUBLE
Appearance and Odor:CLEAR, COLORLESS LIQUID, SLIGHT ALCOHOL-LIKE ODOR
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
OXIDANTS (SUCH AS BARIUM PERCHLORATE, BROMINE, CHLORINE, HYDROGEN
PEROXIDE, LEAD PERCHLORATE, PERCHLORIC ACID, (SUP DAT)
Stability Condition to Avoid:HIGH TEMPERATURES, INCOMPATIBLE MATERIALS,
IGNITION SOURCES.
Hazardous Decomposition Products:CARBON MONOXIDE, CARBON DIOXIDE,
FORMALDEHYDE.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSE OF IN A MANNER CONSISTENT WITH FEDERAL,
STATE, AND LOCAL REGULATIONS. THIS MATERIAL IS BANNED FROM LAND
DISPOSAL ACCORDING TO RCRA.
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=======================================================
Product ID: BERYLLIUM
Cage: 0YZE5
Box: 30188
=======================================================
Contractor Summary
=======================================================
Cage: 0YZE5
Box: 30180
=======================================================
Ingredients
=======================================================
Cas: 7440-41-7
RTECS #: DS1750000
% Wt: 0.1
OSHA PEL: 0.002 MG/M3, Z-2
ACGIH TLV: .002 MG/M3, A2
-----------------------------
Cas: 7697-37-2
RTECS #: QU5775000
% Wt: 2
OSHA PEL: 2 PPM
ACGIH TLV: 2 PPM/4 STEL
EPA Rpt Qty: 1000 LBS
DOT Rpt Qty: 1000 LBS
=======================================================
Health Hazards Data
=======================================================
LD50 LC50 Mixture: NONE SPECIFIED BY MANUFACTURER.
Route Of Entry Inds - Inhalation: YES
Skin: YES
Ingestion: NO
Carcinogenicity Inds - NTP: YES
IARC: YES
OSHA: NO
Effects of Exposure: ACUTE:INHALATION:MAY CAUSE MILD IRRITATION OF RESPIRATORY
TRACT. AS A SUSPECTED CANCER HAZARD IN HUMANS BECAUSE OF BERYLLIUM COMPONENT
INHALATION IS PRIMARY ROUTE OF EXPOSURE. INGESTION:SYMPTOMS ARE E XPECTED TO
BE LESS SEVERE THAN EXPOSURETO HIGHER CONCENTRATIONS OF ACID (HYDROCHLORIC OR
NITRIC) (EFTS OF OVEREXP)
Explanation Of Carcinogenicity: BERYLLIUM:IARC MONO, SUPP, VOL 7, PG 127,
1987:GROUP 2A. NTP 7TH ANNUAL RPT ON CARCINS, 1994:ANTIC TO BE
CARCIN.(SUPDAT)
Signs And Symptions Of Overexposure: HLTH HAZ:WHERE SYMP MAY INCL BURNING
SENSATION, VOMITING & DIARRHEA. SKIN:SYMP ARE EXPECTED TO BE LESS SEVERE
THAN EXPOSURE TO HIGHER CONC OF ACID (HYDROCHLORIC OR NITRIC) WHERE SYMP MAY
INCL IRRITATI ON, REDNESS, PAIN & BURNS. CHRONIC:SUSPECTED CARCIN
PROPERTIES IN HUMANS DUE TO INHALATION OF BERYLLIUM COMPOUNDS.
Medical Cond Aggravated By Exposure: NONE SPECIFIED BY MANUFACTURER.
First Aid: CALL A PHYSICIAN. INHAL:REMOVE TO FRESH AIR. SUPPORT BREATHING (GIVE
O*2/ARTF RESP) (FP N). INGEST:DO NOT INDUCE VOMITING, IF CONSCIOUS GIVE
WATER, MILK. EYES/SKIN:FLUSH WITH PLENTY OF WATER FOR @ LEA ST 15 MINUTES.
=======================================================
Handling and Disposal
=======================================================
Spill Release Procedures: REMOVE SOURCE OF IGNITION IF HYDROGEN IS A HAZARD.
PROVIDE OPTIMUM VENTILATION. FLUSH TO HOLDING AREA OF NEUTRALIZATION.
Neutralizing Agent: NONE SPECIFIED BY MANUFACTURER.
Waste Disposal Methods: FOLLOW FEDERAL, STATE AND LOCAL REGULATIONS FOR ACID
WASTE. EPA HAZARDOUS WASTE #P015.
Handling And Storage Precautions: KEEP CONTAINER TIGHTLY CLOSED.
Other Precautions: NONE SPECIFIED BY MANUFACTURER.
=======================================================
Fire and Explosion Hazard Information
=======================================================
Extinguishing Media: MEDIA SUITABLE FOR SURROUNDING FIRE (FP N).
Fire Fighting Procedures: USE NIOSH/MSHA APPROVED SCBA & FULL PROTECTIVE
EQUIPMENT (FP N).
=======================================================
Control Measures
=======================================================
Respiratory Protection: NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE FOR EXPOSURE
OF CONCERN (FP N).
Ventilation: LOCAL EXHAUST.
Other Protective Equipment: LAB COAT/APRON; VENT HOOD. ANSI APPRVD EMERGENCY
EYE WASH & DELUGE SHOWER (FP N).
Work Hygienic Practices: NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health: EXPLAN OF CARCIN:HUMAN:LUNG FIBROSIS. EYE
PROT:FULL LENGTH FACESHIELD (FP N).
=======================================================
Physical/Chemical Properties
=======================================================
B.P. Text: 212F,100C
Spec Gravity: 1 (H*2O=1)
Evaporation Rate & Reference: NOT KNOWN
Solubility in Water: COMPLETE
Appearance and Odor: CLEAR, COLORESS, ODORLESS SOLUTION.
=======================================================
Reactivity Data
=======================================================
Stability Indicator: YES
Stability Condition To Avoid: METALS, HYDROXIDES, CARBONATES, CYANIDES.
Materials To Avoid: STRONG REDUCING AGENTS.
Hazardous Decomposition Products: NO, NO*2, GAS.
Hazardous Polymerization Indicator: NO
Conditions To Avoid Polymerization: NOT RELEVANT.
=======================================================
Toxicological Information
=======================================================
=======================================================
Ecological Information
=======================================================
=======================================================
=======================================================
=======================================================
Regulatory Information
=======================================================
=======================================================
Other Information
=======================================================
=======================================================
HAZCOM Label
=======================================================
Product ID: BERYLLIUM
Cage: 0YZE5
Company Name: HIGH-PURITY STANDARDS INC
Street: 2040 SAVAGE RD
PO Box: 30180
Zipcode: 29417
Label Required IND: Y
Date Of Label Review: 10/16/1995
Status Code: C
Label Date: 10/16/1995
Origination Code: G
Chronic Hazard IND: Y
Skin Protection IND: YES
Signal Word: WARNING
Respiratory Protection IND: YES
Health Hazard: Moderate
Contact Hazard: Moderate
Fire Hazard: None
Reactivity Hazard: None
Hazard And Precautions: ACUTE:INHALATION:MAY CAUSE MILD IRRITATION OF
RESPIRATORY TRACT. AS A SUSPECTED CANCER HAZARD IN HUMANS BECAUSE OF
BERYLLIUM COMPONENT INHALATION IS PRIMARY ROUTE OF EXPOSURE.
INGESTION:SYMPTOMS ARE E XPECTED TO BE LESS SEVERE THAN EXPOSURETO HIGHER
CONCENTRATIONS OF ACID (HYDROCHLORIC OR NITRIC) WHERE SYMPTOMS MAY INCLUDE
BURNING SENSATION, VOMITING AND DIARRHEA. SKIN:MAY INCLUDE IRRITATION, REDNE
SS, PAIN AND BURNS. CHRONIC:CANCER HAZARD. CONTAINS BERYLLIUM WHICH IS LISTED
AS A HUMAN LUNG CARCINOGEN (FP N).
=======================================================
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===================== Product Identification =====================
Product ID:WT-230 CLT-100
CAGE:3V338
CAGE:3V338
============= Composition/Information on Ingredients =============
Ingred Name:MORPHOLINE
CAS:110-91-8
RTECS #:QD6475000
Fraction by Wt: 10%
Other REC Limits:20 PPM
OSHA PEL:S,20 PPM/30 STEL
ACGIH TLV:S, 20 PPM; 9192
Ingred Name:SODIUM SULFITE
CAS:7757-83-7
RTECS #:WE2150000
Fraction by Wt: 8%
Other REC Limits:5 MG/CUM (DUST)
Ingred Name:SODIUM HYDROXIDE (SARA III)
CAS:1310-73-2
RTECS #:WB4900000
Fraction by Wt: 3%
Other REC Limits:2MG/M3 CEILING NIOSH
OSHA PEL:2 MG/M3
ACGIH TLV:C 2 MG/M3; 9293
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
===================== Hazards Identification =====================
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:EYES/SKIN/INGESTION: CORROSIVE, HIGHLY
IRRITATING & TISSUE DAMAGE/DESTRUCTION. INHALATION: CORROSIVE,
HIGHLY IRRITATING TO RESPIRATORY TRACT & MUCOUS MEMBRANES, TISSUE
DAMAGE/DESTRUCTION.
Explanation of Carcinogenicity:NONE
Effects of Overexposure:EYES/SKIN/INGESTION: CORROSIVE, HIGHLY
IRRITATING, & TISSUE DAMAGE/DESTRUCTION. INHALATION: CORROSIVE,
HIGHLY IRRITATING TO RESPIRATORY TRACT & MUCOUS MEMBRANE, TISSUE
DAMAGE/DESTRUCTION. REPEATED TIS SUE DAMAGE MAY RESULT IN
ACCUMULATION OF SCAR TISSUE.
Medical Cond Aggravated by Exposure:ANY TISSUE IRRITATION
======================= First Aid Measures =======================
First Aid:EYES: IRRIGATE W/WATER FOR 15 MIN. SKIN: WASH OFF & RINSE
THOROUGHLY W/WATER. INHALATION: REMOVE TO FRESH AIR. INGESTION:
DON'T INDUCE VOMITING. DRINK A SOLUTION OF VINEGAR & WATER FOLLOWED
BY CLEAR W ATER. OBTAIN MEDICAL ATTENTION IN ALL CASES.
===================== Fire Fighting Measures =====================
Extinguishing Media:USE MEDIA APPROPRIATE FOR SURROUNDING FIRE.
Fire Fighting Procedures:NON-COMBUSTIBLE
================== Accidental Release Measures ==================
Spill Release Procedures:DON'T DRAIN INTO SEWERS OR SURFACE WATERS.
SOAK UP IN ABSORBENT MATERIAL & SEAL IN PROPERLY LABELLED
NON-LEAKING CONTAINERS FOR PROPER HAZARDOUS WASTE DISPOSAL.
======================Handling and Storage ======================
Handling and Storage Precautions:STORE IN ORIGINAL SHIPPING CONTAINERS.
KEEP CONTAINERS SEALED WHEN NOT IN USE. PROTECT FROM FREEZING. KEEP
OUT OF THE REACH OF CHILDREN.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:AS REQUIRED
Ventilation:AS REQUIRED
Other Protective Equipment:RUBBER BOOTS & APRON, EYEWASH STATION &
SAFETY SHOWERS.
Work Hygienic Practices:DON'T EAT OR DRINK IN WORK AREAS. WASH HANDS
BEFORE USING RESTROOM FACILITIES.
Supplemental Safety and Health
================== Physical/Chemical Properties ==================
Boiling Pt:B.P. Text:212F
Spec Gravity:1.12
Evaporation Rate & Reference:(WATER = 1): 1
Solubility in Water:MISCIBLE
Appearance and Odor:CLEAR, COLORLESS LIQUID W/MORPHOLINE ODOR.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
OXIDIZING & REDUCING AGENTS, ALUMINUM, & ACIDS.
Stability Condition to Avoid:FREEZING, EXTREME HEAT
Hazardous Decomposition Products:SULFUR OXIDES, NITROGEN, HYDROGEN GAS,
& SULFUR DIOXIDE GAS.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSE OF IN AUTHORIZED HAZARDOUS WASTE
DISPOSAL IN ACCORDANCE W/FEDERAL, STATE, & LOCAL REGULATIONS.
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===================== Product Identification =====================
Product ID:AMMONIUM SULFATE
Preparer's Name:MICHAEL RASZEJA
CAGE:6V042
CAGE:6V042
============= Composition/Information on Ingredients =============
Ingred Name:AMMONIUM SULFATE (SOLUTION) (SARA 313)
CAS:7783-20-2
RTECS #:BS4500000
Fraction by Wt: 100%
Other REC Limits:NONE RECOMMENDED
===================== Hazards Identification =====================
LD50 LC50 Mixture:ORAL LD50 (RAT) IS 3000 MG/KG
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:LOW HAZARD AT TEMPERATURE BELOW 100C.
ESSENTIALLY NON-TOXIC. EXCERCISE APPROPIATE PROCEDURES TO MIMIZE
POTENTIAL HAZARD.
Explanation of Carcinogenicity:NOT CARCINOGENIC.
Effects of Overexposure:CAUSES SNEEZING-MILD NOSEBLEED TO SENITIZED
PERSONS.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
======================= First Aid Measures =======================
First Aid:INGESTION-IF CONSCIOUS, GIVE ONE OR TWO GLASSES OF WATER TO
DRINK & CALL PHYSCIAN. INHALATION-REMOVE TO FRESH AIR. IF NOT
BREATHING GIVE ARTIFICIAL RESPIRATION. IF BREATHING IS DIFFICULT,
GIVE OXYGEN. GET MEDICAL ATTENTION. SKIN-FLUSH THOROUGHLY WITH
WATER, THEN WASH WITH MILD SOAP & WATER. EYES-FLUSH THOROUGHLY WITH
WATER FOR AT LEAST 15 MIN. GET MEDICAL ATTENTION.
===================== Fire Fighting Measures =====================
Flash Point:NON-COMBUSTIBLE
Extinguishing Media:USE ANY SUITABLE FOR EXTINGUISHING SUPPORT FIRE.
Fire Fighting Procedures:IN FIRE CONDITIONS, WEAR A NIOSH/MSHA-APPROVED
SELF-CONTAINED BREATHING APPARATUS AND FULL PROTECTIVE EQUIPMENT.
Unusual Fire/Explosion Hazard:NONCOMBUSTIBLE. MELTS & DECOMPOSES WITH
EMISSION OF A MIXTURE OF AMMONIA & SULFUR TRIOXIDE AT ABOUT 455F.
================== Accidental Release Measures ==================
Spill Release Procedures:RECOVER FOR USE IF NOT CONTAMINATED. SWEEP UP
SPILL AND PLACE IN A SUITABLE CONTAINER.
======================Handling and Storage ======================
Handling and Storage Precautions:STORE IN A COOL, DRY PLACE. KEEP
CONTAINER TIGHTLY CLOSED WHEN NOT IN USE. WASH THOROUGHLY AFTER
HANDLING.
Other Precautions:AVOID CONTACT WITH SKIN, EYES AND CLOTHING. REMOVE
AND WASH CONTAMINATED CLOTHING.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:NONE SHOULD BE NEEDED IN NORMAL LABORATORY
HANDLING. IF DUSTY CONDITION EXIST WORK IN VENTILATED HOOD OR WEAR
A NIOSH APPROVED DUST MASK.
Ventilation:LOCAL EXHAUST-YES. MECHANICAL-IF DUSTY.
STATION, VENTILATION HOOD.
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING.
Supplemental Safety and Health
FOR LABORATORY USE ONLY. NOT FOR DRUG, FOOD OR HOSUHOLD USE. KEEP OUT
OF REACH OF CHLIDREN.
================== Physical/Chemical Properties ==================
HCC:N1
Boiling Pt:B.P. Text:NA
Decomp Temp:Decomp Text:536F,280C
Vapor Pres:SOILD
Vapor Density:4.6
Spec Gravity:1.769
Evaporation Rate & Reference:NA
Solubility in Water:70.6 GRAMS/100ML
Appearance and Odor:BROWNISH-GRAY TO WHITE CRYSTAL; ODORLESS.
Percent Volatiles by Volume:NA
Corrosion Rate:NA
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZERS (POTASSIUM CHLORATE, POTASSIUM NITRATE, POTASSIUM
NITRILE).
Stability Condition to Avoid:EXCESSIVE TEMPERATURES AND HEAT.
Hazardous Decomposition Products:THERMAL DECOMPOSITION OR BURNING MAY
PRODUCE CARBON MONOXIDE AND/OR CARBON DIOXIDE, OXIDES OF NITROGEN,
OXIDES OF SULFUR
==================== Disposal Considerations ====================
Waste Disposal Methods:DISCHARGE, TREATMENT, OR DISPOSAL MAY BE SUBJECT
TO LOCAL, STATE AND FEDERAL LAWS. THESE DISPOSAL GUIDELINES ARE
INTENDED FOR THE DISPOSAL OF CATALOG-SIZE QUANTITIES ONLY. DISSOLVE
IN WATER AND FLUSHTO SEWER WITH COPIOUS AMOUNTS OF WATER.
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===================== Product Identification =====================
Product ID:169 3894 FLEXICOLOR STABILIZER & REPLENISHER, WORKING SOLN
Kit Part:Y
CAGE:19139
CAGE:19139
CAGE:5K871
============= Composition/Information on Ingredients =============
Ingred Name:WATER
CAS:7732-18-5
RTECS #:ZC0110000
Fraction by Wt: 95-100%
Other REC Limits:NONE RECOMMENDED
Ingred Name:FORMALDEHYDE (SARA 302/313) (CERCLA)
CAS:50-00-0
RTECS #:LP8925000
Fraction by Wt: <1%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:SEE 1910.1048
ACGIH TLV:C 0.3 PPM, A2; 9596
EPA Rpt Qty:100 LBS
DOT Rpt Qty:100 LBS
Ingred Name:METHYL ALCOHOL (METHANOL) (SARA 313) (CERCLA)
CAS:67-56-1
RTECS #:PC1400000
Fraction by Wt: <1%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:S, 200 PPM
ACGIH TLV:S,200PPM/250STEL; 96
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
Ingred Name:ORGANO SILICONE
Fraction by Wt: <1%
Other REC Limits:NONE RECOMMENDED
Ingred Name:NONIONIC SURFACTANT (NEW JERSEY TRADE SECRET:
80100185-5062P)
Fraction by Wt: <1%
Other REC Limits:NONE RECOMMENDED
===================== Hazards Identification =====================
LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:YES
Health Hazards Acute and Chronic:INHAL:FORMALDEHYDE DETECTABLE BY SOME
@<1PPM.MILD SENSORY IRRIT OF EYE/NOSE/THROAT @2-5PPM,UNPLEASANT
@5-10PPM,INTOLERABLE @HI CONCEN CAUSING SEVERE BURN SENS OF
NOSE/THROAT W/COUGH.RESP SEN IN SOME.E YE:SEVERE BURNS.VAP
IRRIT,TEARING.SKIN:IRRIT,ALLERGIC SKIN
RX.INGEST:FATAL,BLINDNESS.CAN'T BE NONPOIS.BURNS(SIGNS/SYMPT)
Explanation of Carcinogenicity:CONTAINS FORMALDEHYDE [50-00-0] WHICH IS
LISTED BY NTP AND IARC AND REGULATED BY OSHA AS A CARCINOGEN FRM
PART A.
Effects of Overexposure:HEALTH
HAZ:MOUTH,ESOPHAGUS,STOMACH.RETINAL/KIDNEY DMG MAY OCCUR.IMMED
SEVERE ABD
PAIN,W/VOMIT,NAU,DIARR,DIZZ,UNCONSC,COMA,ANURIA,CONVULS,DEATH. HI
CONCEN INHAL OF FORMALDEHYDE:CHEST CONSTRICTION,HEADA
CHE,BRONCHOPNEUMONIA,DYSPHAGIA,EDEMA,SPASMS OF LARYNX/DYSPNEA.
Medical Cond Aggravated by Exposure:EXPOSURE TO FORMALDEHYDE AMY CAUSE
RESP SENSITIZATION IN SOME INDIVIDUALS OR AGGRAVATE PRE-EXISTING
ASTHMATIC CONDITIONS.
======================= First Aid Measures =======================
First Aid:INHAL:MOVE TO FRESH AIR.TREAT SYMPTOMATICALLY.SYMPTOMS OCCUR
GET MED ATTN. EYES:IMMED FLUSH W/PLENTY OF WATER FOR @LEAST
15MINS.GET MED ATTN. SKIN:IMMED FLUSH W/PLENTY OF WATER FOR @LEAST
15MINS WHILE REMOVING CONTAMIN CLOTH/SHOES.IRRIT/ALLERGIC SKIN
REACTION DEVELOPS GET MED ATTN. INGEST:DRINK 1-2 GLASSES OF
WAER.SEEK MED ATTN.
===================== Fire Fighting Measures =====================
Flash Point:NONE,NON-COMBUST
Lower Limits:NA
Upper Limits:NA
Extinguishing Media:USE APPROPRIATE AGENT FOR ADJACENT FIRE.
Fire Fighting Procedures:WEAR SELF-CONTAINED BREATHING APPARATUS &
PROTECTIVE CLOTHING.
Unusual Fire/Explosion Hazard:NONE.
================== Accidental Release Measures ==================
Spill Release Procedures:FLUSH TO SEWER W/LG AMTS OF WATER.OTHERWISE
ABSORB W/VERMICULITE OR O
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
======================Handling and Storage ======================
Handling and Storage Precautions:KEEP CONTAINERS TIGHTLY CLOSED WHEN
NOT IN USE. KEEP AWAY FROM INCOMPATIBLE MATERIALS. USE ONLY WITH
ADEQUATE VENTILATION.
Other Precautions:WASH THOROUGHLY AFTER HANDLING. DO NOT BREATH VAPOR.
DO NOT GET IN EYES, ON SKIN, ON CLOTHES.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:A FULL FACEPEICE WITH CARTIDGES OR CANISTERS
SPECIFICALLY APPROVED BY NIOSH FOR PROTECTION AGAINST FORMALDEHYDE
OR A TYPE C SUPPLIED AIR RESPIRATOR OR AN APPROPRIATE NIOSH
APPROVED RESPIRATOR FOR ORGA NIC VAPORS SHOULD BE WORN IF NEEDED.
Ventilation:LOCAL EXHAUST VENTILATION OR AN ENCLOSED HANDLING SYSTEM
MAY BE NEEDED TO CONTROL AIR CONTAMINANTS.
Other Protective Equipment:USE CHEMICAL PROTECTIVE CLOTHING MADE
MATERIAL IMPERVIOUS TO FORMALDEHYDE AND THE USE OF OTHER PROTECTIVE
CLOTHING.
Work Hygienic Practices:THE ROUTINE USE OF A NON-ALKALINE (ACID) TYPE
OF SKIN CLEANER & REGULAR CLEANING OF WORKING SURFACE.
Supplemental Safety and Health
MSDS IS FOR WORKING SOLUTION. SEE PNI B FOR PART B; PNI A FOR PART A.
KIT CONSISTS OF PART A, 1-6 OUNCE BOTTLE OF FORMALDEHYDE SOLUTION;
PART B 1-1 OUNCE BOTTLE OF NON-HAZARDOUS LIQUID-WHICH WHEN MIXE D
WITH WATER MAKE 5 GALLONS WORKING SOLUTION.
================== Physical/Chemical Properties ==================
HCC:F5
Boiling Pt:B.P. Text:>212F,>100C
Melt/Freeze Pt:M.P/F.P Text:NP
Decomp Temp:Decomp Text:NP
Vapor Pres:18 @20C
Vapor Density:0.6
Spec Gravity:1.00
pH:7.2
Evaporation Rate & Reference:NP
Solubility in Water:COMPLETE
Appearance and Odor:LIQUID, COLORLESS, FORMALDEHYDE ODOR.
Percent Volatiles by Volume:100
Corrosion Rate:NP
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
NONE W/COMMON MATLS & CONTAMINANTS W/WHICH THE MATL MAY REASONABLY COME
INTO CONTACT.
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:NONE (NON-COMBUSTIBLE).
==================== Disposal Considerations ====================
Waste Disposal Methods:FLUSH TO SEWER WITH LARGE AMOUNTS OF WATER OR
CONTACT A LICENSED CHEMICAL WASTE DISPOSAL AGENCY. DISCHARGE MAY BE
SUBJECT TO LOCAL, STATE AND FEDERAL REGULATIONS.
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===================== Product Identification =====================
Preparer's Name:DOD HMIS/DGSC-SSH
CAGE:JO772
CAGE:14153
CAGE:JO772
============= Composition/Information on Ingredients =============
Ingred Name:ASBESTOS, CHRYSOTILE
CAS:12001-29-5
RTECS #:CI6478500
OSHA PEL:0.2 FIBERS/CC
ACGIH TLV:2 FIBERS/CC; A1;9192
Ingred Name:ASBESTOS & NATURAL/SYNTHETIC RUBBER COMPOSITION
RTECS #:9999999ZZ
Ingred Name:GENERIC "MSDS". SPECIFIC ASBESTOS TYPE NOT KNOWN. ONE
CITED IS ASSUMED. INFORMATION BASED ON SEGMENT "M" OF "DLSC TIR"
RTECS #:9999999ZZ
===================== Hazards Identification =====================
Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:YES
Health Hazards Acute and Chronic:ACUTE: NO ACUTE EFFECTS ARE KNOWN;
CHRONIC: DUST FROM ABRASIVE ACTIONS(EG. CUTTING, MACHINING,
FILING, ETC.) MAYCONTAIN ASBESTOS FIBERS. CHRONIC OVEREXPOSURE
TO AIRBORNE FIBERS MAY LEAD TO ASBESTOSIS & MESOTHELIOMA.
SMOKINGCOMBINED W/FIBER INHALATION GREATLY INCREASES LUNG
CANCER RISK!
Explanation of Carcinogenicity:OVEREXPOSURE TO AIRBORNE CONCENTRATIONS
OF ASBESTOS MAY LEAD TO ASBESTOSIS AND MESOTHELIOMA.
Effects of Overexposure:INHAL: INHALATION OF AIRBORNE DUST CONTAINING
ASBESTOS FIBERS ON REPEATED EXPOSURE MAY CAUSE OR CAN LEAD TO
ASBESTOSIS/ MESOTHELIOMA; SKIN: N/K; EYE: POTENTIAL IRRITATION
FROM AIRBORNE DUST; INGEST: N/K.
Medical Cond Aggravated by Exposure:RESPIRATORY DEFICIENCIES DUE TO
REPEATED INHALATION OF AIRBORNE FIBERS.
======================= First Aid Measures =======================
First Aid:INHAL: REMOVE TO FRESH AIR. OBTAIN MEDICAL ADVICE; SKIN:
WASH EXPOSED AREA WITH SOAP & WATER; EYE: FLOOD W/ WATER. IF
IRRITATION OCCURS, GET MEDICAL ATTN; INGEST: CONSULT A
PHYSICIAN; OTHER: CHANGE CLOTHING AS REQUIRED TO AVOIDCARRYING
DUST PARTICLES INTO OTHER AREAS
===================== Fire Fighting Measures =====================
Flash Point:NONE
Extinguishing Media:MATERIAL IS NOT FLAMMABLE ; USE MEDIA APPROPRIATE
FOR SURROUNDING FIRE.
Fire Fighting Procedures:COMBUSTION PRODUCTS OF THIS MATERIAL MAY BE
TOXIC. USE A SELF-CONTAINED BREATHING APPARATUS WHEN FIGHTING FIRES
INVOLVING CHEMICAL PRODUCTS.
Unusual Fire/Explosion Hazard:NONE KNOWN
================== Accidental Release Measures ==================
Spill Release Procedures:USE PROPER PERSONAL PROTECTION. VACUUM OR WET
CLEAN IF DUST IS INVOLVED. ANY VACUUM SYSTEM SHOULD BE EQUIPPED W/
AN OUTLET "HEPA" FILTER TO PREVENT REINTRODUCING ASBESTOS FIBERS TO
THE ATMOSPHERE.
======================Handling and Storage ======================
Handling and Storage Precautions:HANDLE IN A MATTER TO MINIMIZE
FORMATION OR RETENTION OF AIRBORNE DUST. USE PROPER PERSONAL
PROTECTION FOR TASK AT HAND. CHECK W/YOUR SAFETY OFFICE!!!
Other Precautions:AS MANUFACTURED, LOCKED-IN ASBESTOS DOES NOT PRESENT
A HAZARD. ONLY WHEN THE ITEM IS SUBJECTED TO ABRASIVE ACTIONS &
DUST IS GENERATED, THEN ASBESTOS FIBERS MAY BE RELEASED & BECOME
AIRBORNE.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:IF EXPOSURES EXCEED ESTABLISHED LIMITS, A
NIOSH/MSHA APPROVED RESPIRATOR FOR ASBESTOS SHOULD BE USED.
CONSULT YOUR SAFETY OFFICE/IH PERSONNEL FOR GUIDANCE FOR THE TASK
AT HAND.
Ventilation:LOCAL EXHAUST IS RECOMMENDED IN SITUATIONS WHERE DUST IS
GENERATED BY ABRASIVE ACTIONS, ABRASION OR OTHER MEANS.
Other Protective Equipment:AS REQUIRED FOR TASK AT HAND, AND THE
GUIDANCE SET FORTH BY YOUR SAFETY OFFICE OR IH PERSONNEL
Work Hygienic Practices:DONOT INHALE DUST CREATED BY ABRADING ACTIONS.
USE FULL PROTECTION AGAINST AIRBORNE FIBERS. AVOID AIRBORNE DUST
CREATION
Supplemental Safety and Health
GENERIC "MSDS" CREATED FOR "NSN" IDENTIFIED BY "DISC" AS CONTAINING
ASBESTOS.WHEN A MANUFACTURER'S SPECIFIC "MSDS" IS PROVIDED FOR
MATERIAL PROCURED UNDER THIS NSN, THIS GENERIC "MSDS" WILL BE
REMOVED.
================== Physical/Chemical Properties ==================
HCC:T6
Evaporation Rate & Reference:NONE
Solubility in Water:NOT SOLUBLE
Appearance and Odor:MANUFACTURED COMMODITY DESCRIBED BY LOGISTICS:
"ITEM-NAME"
Percent Volatiles by Volume:NONE
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
NONE KNOWN
Stability Condition to Avoid:NONE KNOWN
==================== Disposal Considerations ====================
Waste Disposal Methods:DUST SHOULD BE HANDLED AS A HAZARDOUS AIR
POLLUTANT I/A/W 40CFR61 SUBPART "M" PERTAINING TO ASBESTOS. USE
LANDFILLS APPROVED FOR ASBESTOS DISPOSAL. NOTE IF ITEM UNDER
CONSIDERATION FOR DISPOSAL IS "FRIABLE OR NON-FRIABLE".
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===================== Product Identification =====================
Product ID:FLYTEK FLY BAIT
CAGE:51112
CAGE:8C885
CAGE:51112
============= Composition/Information on Ingredients =============
Ingred Name:METHOMYL (LANNATE)(SARA III)
CAS:16752-77-5
RTECS #:AK2975000
Other REC Limits:NONE SPECIFIED
OSHA PEL:2.5 MG/M3
ACGIH TLV:2.5 MG/M3; 9192
EPA Rpt Qty:100 LBS
DOT Rpt Qty:100 LBS
Ingred Name:SUCROSE
CAS:57-50-1
RTECS #:WN6500000
Other REC Limits:NONE SPECIFIED
OSHA PEL:15 MG/M3 TDUST
ACGIH TLV:10 MG/M3; 9192
Ingred Name:9-TRICOSENE,(Z)-
CAS:27519-02-4
RTECS #:YD0807000
Other REC Limits:NONE RECOMMENDED
===================== Hazards Identification =====================
LD50 LC50 Mixture:LD50 (ORAL RAT) = 3,000 MG/KG
Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Explanation of Carcinogenicity:NONE OF THE LISTED INGREDIENTS IS A
CARCINOGEN ACCORDING TO NTP, IARC, OSHA.
Effects of Overexposure:SEE HEALTH HAZARDS SECTION.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
======================= First Aid Measures =======================
First Aid:PRODUCT IS A CHOLINESTERASE INHIBITOR.ATROPINE IS
ANTIDOTAL.IN CASE OF TOXIC SIGNS,I.V.ADMINISTRATION TO EFFECT MAY
BE PREFERABLE.IF SWALLOWED,CALL A PHYSICIAN IMMEDIATELY.IF
CONSCIOUS,DRINK 1 OR 2 GL ASSES OF WATER & INDUCE VOMITING.IF ON
SKIN,WASH WITH SOAP & WATER.REMOVE CONTAMINATED CLOTHING & CLEAN
BEFORE REUSE.IF IN EYES,IMMEDIATELY FLUSH WITH GENTLY FLOWING WATER
& CALL A PHYSICIAN.
===================== Fire Fighting Measures =====================
Extinguishing Media:USE WATER FOG, CARBON DIOXIDE, FOAM, OR DRY
CHEMICAL FOR SURROUNDING FIRE.WATER MAY INCREASE CONTAMINATION
HAZARD.
Fire Fighting Procedures:FIRE FIGHTERS SHOULD USE NIOSH-APPROVED
POSITIVE PRESSURE, SELF-CONTAINED BREATHING APPARATUS. MOVE PEOPLE
UPWIND FROM FIRE/SMOKE.
Unusual Fire/Explosion Hazard:WILL IGNITE IF EXPOSED TO INTENSE
HEAT/OPEN FLAME. BURNING PRODUCES TOXIC FUMES AND CARBON MONOXIDE
FROM INCOMPLETE COMBUSTION.FIRE/HEAT MAY RUPTURE CONTAINER.
================== Accidental Release Measures ==================
Spill Release Procedures:SMALL AMOUNTS MAY BE SWEPT UP AND SPREAD IN
PLANNED USE AREAS AS DIRECTED ON LABEL OR PLACED IN CONTAINER FOR
DISPOSAL.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
======================Handling and Storage ======================
Handling and Storage Precautions:STORE IN A COOL,DRY,VENTILATED
AREA.MAY BE HARMFUL IF SWALLOWED,INHALED,OR ABSORBED THROUGH
SKIN.KEEP AWAY FROM FOODSTUFFS,CHILDREN & ANIMALS.
Other Precautions:DO NOT CONTAMINATE FEED OR FOODSTUFFS.DO NOT BREATHE
FUMES OR VAPORS.DO NOT GET ON SKIN OR IN EYES.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:IF PROLONGED EXPOSURE IS EXPECTED OR IN
EXCESSIVE AIRBORNE EXPOSURES, WEAR AN MSHA/NIOSH APPROVED PESTICIDE
RESPIRATOR (ORGANIC VAPOR CARTRIDGE PLUS DUST PREFILTER) IN
COMPLIANCE WITH CFR 29-1910,34.
Ventilation:MECHANICAL (GENERAL)
Other Protective Equipment:EYE WASH STATION AND SAFETY SHOWER
RECOMMENDED. INDUSTRIAL-TYPE WORK CLOTHING.
Work Hygienic Practices:OBSERVE GOOD PERSONAL HYGIENE PRACTICES AND
RECOMMENDED PROCEDURES. DO NOT WEAR CONTAMINATED CLOTHING OR
FOOTWEAR.
Supplemental Safety and Health
================== Physical/Chemical Properties ==================
HCC:T5
Spec Gravity:>1
Solubility in Water:SOLUBLE
Appearance and Odor:SOLID YELLOW GRANULES WITH CHARACTERISTIC SULFUROUS
ODOR
Percent Volatiles by Volume:0
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS AND REACTIVE METALS.
Stability Condition to Avoid:HIGH TEMPERATURES AND FLAMES
Hazardous Decomposition Products:CARBON MONOXIDE, CARBON DIOXIDE AND
OXIDES OF NITROGEN.
==================== Disposal Considerations ====================
Waste Disposal Methods:PESTICIDE THAT CANNOT BE USED ACCORDING TO LABEL
SHOULD BE DISPOSED OF IN ACCORDANCE WITH ALL APPLICABLE FEDERAL,
STATE AND LOCAL REGULATIONS.
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===================== Product Identification =====================
Product ID:CALCIUM CHLORIDE FLAKE, 77-80%
Preparer's Name:ALICE MARTINO
CAGE:2R467
CAGE:2R467
============= Composition/Information on Ingredients =============
Ingred Name:CALCIUM CHLORIDE
CAS:10043-52-4
RTECS #:EV9800000
Fraction by Wt: 90-92%
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:SODIUM CHLORIDE
CAS:7647-14-5
RTECS #:VZ4725000
Fraction by Wt: 1-2%
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:POTASSIUM CHLORIDE
CAS:7447-40-7
RTECS #:TS8050000
Fraction by Wt: 2-3%
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:POTASSIUM CHLORIDE; (POTASSIUM CHLORIDE TRACE MINERAL
SALTS)
CAS:7447-40-7
RTECS #:TS8050000
Fraction by Wt: <2%
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:WATER
CAS:7732-18-5
RTECS #:ZC0110000
Fraction by Wt: BALANCE
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:SUPDAT:NO SPECIFIC ANTIDOTE. SUPPORTIVE CARE. TREATMENT
BASED ON JUDGMENT OF THE MD IN RESPONSE TO RXNS OF THE PATIENT.
RTECS #:9999999ZZ
Ingred Name:SPILL PORC:SPILLED PROD, CREATING A SLIPPING HAZ. AVOID BY
THOROUGHLY H*2O RINSING SURFS. LRG SPILL:WEAR (ING 8)
RTECS #:9999999ZZ
Ingred Name:ING 7:APPROP, IMPERVIOUS SAFETY APPAREL DURING CLEAN-UP:
SEE OTHER PREC SECTION. IF POSS, RECOVER QUICKLY INTO (ING 9)
RTECS #:9999999ZZ
Ingred Name:ING 8:SUITABLE DRY, SEALABLE CNTNRS FOR REUSE. AVOID ENTRY
OF LRG AMT OF PROD INTO SEWERS, NATURAL WATERS, & (ING 10)
RTECS #:9999999ZZ
Ingred Name:ING 9:DRINKING WATER SCOURCES. MINIMIZE CONTACT WITH
VEGETATION, ANIMALS AND FISH LIFE.
RTECS #:9999999ZZ
Ingred Name:VENT:10 MG/CUM. THERE IS NOT OSHA PEL OR ACGIH TLV FOR
CALCIUM CHLORIDE.
RTECS #:9999999ZZ
Ingred Name:OTHER PREC:CNTCT W/CALCIUM CLORIDE. EMPTY CNTNRS USUALLY
CONTAIN A RESIDUE. ALL PRECS ARE TO BE OBSERVED. (ING 13)
RTECS #:9999999ZZ
Ingred Name:ING 12:PROFESSIONALLY RECONDITION FOR REUSE/PROPERLY
DISPOSE OF "EMPTY" CNTNRS. FOLLOW NORMAL GOOD HOUSEKEEPING (ING 14)
RTECS #:9999999ZZ
Ingred Name:ING 13:PRACTICES TO AVOID SKIN/EYE CNTCT, AVOID BRTHG DUST,
& NOT SMOKING/EATING IN AREA. SKIN PROT:FOR BRIEF (ING 15)
RTECS #:9999999ZZ
Ingred Name:ING 14:CNTCT, NO PRECS OTHER THAN CLEAN BODY-COVERING CLTHG
SHOULD BE NEEDED. PROT CLTHG IMPERVIOUS TO THIS MATL(ING 16)
RTECS #:9999999ZZ
IMPERVIOUS TO THIS MATL. IF SKIN COMES IN CONTACT W/CALCIUM (ING
17)
RTECS #:9999999ZZ
Ingred Name:ING 16:CHLORIDE/W/CONTAMINATED CLOTHING, WASH SKIN AREA
WITH SOAP AND WATER; LAUNDER CLOTHING BEFORE REUSE. (ING 18)
RTECS #:9999999ZZ
Ingred Name:ING 17:IT IS GENERALLY RECOGNIZED THAT CONTACT LENSES
SHOULD NOT BE WORN WHEN WORKING WITH CHEMICALS BECAUSE (ING 19)
RTECS #:9999999ZZ
Ingred Name:ING 18:CONTACT LENSES MAY CONTRIBUTE TO THE SEVERITY OF AN
EYE INJURY.
RTECS #:9999999ZZ
Ingred Name:MATLS TO AVOID:CHLORIDE WHICH IS CORROSIVE, IRRITATING AND
REACTIVE. REACTS W/WATER-REACTIVE MATERIALS SUCH AS SODIUM.
RTECS #:9999999ZZ
Ingred Name:EYE PROT:AND FULL LENGTH FACESHIELD .
RTECS #:9999999ZZ
===================== Hazards Identification =====================
LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:EYES:CAUSES MOD TO SEV IRRIT W/CORNEAL
INJURY, WHICH MAY BE SLOW TO HEAL. WHEN DISSOLVING, THE HEAT PRDCED
MAY CAUSE MORE INTENSE EFTS AS WELL AS THERMAL BURNS. SKIN:SHORT,
SINGLE EXPOS NOT LIKELY TOCAUSE SIGNIFICANT SKIN IRRIT.
PRLNG/RPTD EXPOS MAY CAUSE IRRIT, EVEN A BURN. MAY CAUSE MORE
SEVERE (EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT.
Effects of Overexposure:HLTH HAZ:RESPONSE IF SKIN IS DAMP &/ABRADED
(SCRATCHED/CUT)/IF MATL IS CONFINED TO SKIN. WHEN DISSOLVING, HEAT
GENERATED MAY CAUSE MORE INTENSE EFTS AS WELL AS THERMAL BURNS.
INGEST:SINGLE DOSE TOX IS LOW. SMALL AMTS SWALLOWED INCIDENTAL TO
NORM HNDLG NOT LIKELY TO CAUSE INJURY. LRG AMTS MAY CAUSE INJURY.
(SUPDAT)
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
======================= First Aid Measures =======================
First Aid:EYES:IRRIGATE W/FLOWING H*2O IMMEDIATELY & CONTINUOUSLY FOR
AT LEAST 15 MIN. CONSULT MED PERS. SKIN:WASH OFF IN FLOWING
H*2O/SHOWER. INGEST:SEEK MED ATTN. DO NOT INDUCE VOMIT UNLESS
DIRECTED TO DO SO BY MED PERS. (NEVER GIVE ANYTHING BY
MOUTH/ATTEMPT TO INDUCE VOMIT IN AN UNCON PERS.) INHAL:REMOVE TO
FRESH AIR IF EFTS OCCUR. CONSULT A MD. NOTE TO MD:IF BURN IS
PRESENT, TREAT AS ANY THERMAL(SUPDAT)
===================== Fire Fighting Measures =====================
Extinguishing Media:USE MEDIA APPROPRIATE TO SOURCE OF FIRE.
Fire Fighting Procedures:USE NIOSH APPROVED SCBA & FULL PROTECTIVE
EQUIPMENT .
Unusual Fire/Explosion Hazard:NONE.
================== Accidental Release Measures ==================
Spill Release Procedures:LOSSES INCIDENTAL TO CORRECT APPLICATN OF THIS
PROD IN ITS INTENDED USES ARE NOT EXPECTED TO BE HARMFUL TO THE
ENVIRONMENT. SMALL QTIES MAY BE FLUSHED AWAY W/PLENTY OF H*20.
WALKING SURF MAY REMAIN WE T LONGER DUE TO MOISTURE BEING HELD BY
(ING 7)
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
======================Handling and Storage ======================
Handling and Storage Precautions:STORE IN DRY AREA; KEEP CNTNR CLSD.
WHEN EXPOSED TO THE ATM, CALCIUM CHLORIDE WILL PICKUP H*2O, FORM A
SOLN OR CAKE THE EXPOSED SURFACE OF THE MATL.
Other Precautions:IF DISSOLVING CALCIUM CHLORIDE TO MAKE A SOLN:ALWAYS
USE COOL H*2O (<80F,27C); HEAT WILL BE GENERATED WHEN CALCIUM
CHLORIDE DISSOLVES. ALWAYS ADD CALCIUM CHALORIDE TO H*20 WHILE
STIRRING. LEATHER CLTH G & SHOES WILL BE DMGD BY (ING 12)
============= Exposure Controls/Personal Protection =============
Respiratory Protection:IN DUSTY ATMOSPHERES USE A NIOSH APPROVED DUST
RESPIRATOR.
Ventilation:GENERAL &/LOC EXHST VENT TO CONTROL AIRBORNE LEVELS BELOW
THE EXPOS GUIDELINES. MFRS EXPOS GUIDELINE IS (ING 11)
Other Protective Equipment:EYE WASH FOUNTAIN & DELUGE SHOWER WHICH MEET
ANSI DESIGN CRITERIA .
Work Hygienic Practices:WASH AFTER HNDLG & BEFORE EATING,
DRINKING/SMOKING. TO AVOID SECONDARY EXPOS, SHOWER & WASH GARMENTS
AFTER HNDLG.
Supplemental Safety and Health
SOL IN H*2O:VERY SOLUBLE. CALCIUM CHLORIDE IS HYDROSCOPIC (ABSORBS
MOISTURE FROM ENVIRONMENT). EFTS OF OVEREXP:INGEST MAY CAUSE IRRIT
OF THE MOUTH, THROAT & GI TRACT. INHAL:DUST MAY CAUSE IRRIT TO UPP
ER RESP TRACT. VAPS ARE UNLIKELY DUE TOPHYSICAL PROPERTIES. FIRST
AID PROC:BURN AFTER DECONTAMINATION. (ING 6)
================== Physical/Chemical Properties ==================
Boiling Pt:B.P. Text:347F,175C
Vapor Pres:1.0 @ 20C
Spec Gravity:1.85
Solubility in Water:SUPDAT
Appearance and Odor:FLAKE, WHITE TO OFF-WHITE SOLID FLAKE; ODOR: NONE
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
WILL CORRODE MOST METALS; ATTACKS ALUMINUM, ITS ALLOYS & YELLOW BRASS.
REACTS W/SULFURIC ACID TO FORM HYDROGEN (ING 20)
Stability Condition to Avoid:DECOMPOSES AT 349F.
Hazardous Decomposition Products:NOT APPLICABLE.
==================== Disposal Considerations ====================
Waste Disposal Methods:COMPLY WITH FEDERAL, STATE AND LOCAL LAWS,
REGULATIONS AND PROCEDURES. PRODUCT AS SOLD IS NOT A RCRA LISTED OR
CHARACTERISTIC HAZARDOUS WASTE.
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===================== Product Identification =====================
Product ID:2-101200-1, 30903861 FIREX CARTRIDGE
Preparer's Name:JOEL GEVING
CAGE:54181
CAGE:54181
============= Composition/Information on Ingredients =============
Ingred Name:LEAD AZIDE
CAS:13424-46-9
RTECS #:OF8650000
Fraction by Wt: <1%
Ingred Name:ZIRCONIUM
CAS:7440-67-7
RTECS #:ZH7070000
Fraction by Wt: <1%
OSHA PEL:5 MG/CUM
ACGIH TLV:5 MG/CUM
Ingred Name:POTASSIUM PERCHLORATE
CAS:7778-74-7
RTECS #:SC9700000
Fraction by Wt: <1%
Ingred Name:GRAPHITE
CAS:7782-42-5
RTECS #:MD9659600
Fraction by Wt: <0.1%
Other REC Limits:2.5MG/CUM
ACGIH TLV:2 MG/CUM RESP IC
Ingred Name:1,1-DIFLUOROETHENE, TETRAFLUOROETHENE,
1,1,2,3,3,3-HEXAFLUORO-1-PROPANE POLYMER
CAS:25190-89-0
Fraction by Wt: <0.1%
===================== Hazards Identification =====================
Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:EYES/SKIN: IF PRODUCT SEAL RUPTURES,
MAY CAUSE IRRITATION. INHALATION: RESPIRATORY IRRITANT. INGESTION:
POISONOUS.
Explanation of Carcinogenicity:NONE
Effects of Overexposure:IRRITATION
Medical Cond Aggravated by Exposure:PRE-EXISTING PULMONARY DISEASES
SUCH AS EMPHYSEMA, ASTHMA.
======================= First Aid Measures =======================
First Aid:EYES: IF EXPOSED TO FRAGMENTATION, BANDAGE EYES. IGNITION
BYPRODUCTS, REMOVE CONTACT LENSES IMMEDIATELY, FLUSH W/WATER FOR 15
MINS. SKIN: WASH OFF ANY RESIDUE W/SOAP & WATER. INHALATION: REMOVE
TO FRE SH AIR. GIVE CPR/OXYGEN IF NECESSARY. OBTAIN MEDICAL
ATTENTION IN ALL CASES. NOTE TO PHYSICIAN: USE SUPPORTIVE CARE.
TREATMENT SHOULD BE BASED ON JUDGEMENT OF PHYSICIAN & REACTIONS OF
THE PATIENT.
===================== Fire Fighting Measures =====================
Extinguishing Media:PERMANENTLY-INSTALLED: AUTOMATIC WATER
SPRINKLER/DELUGE SYSTEM IS RECOMMENDED.
Fire Fighting Procedures:DON'T ATTEMPT TO MANUALLY FIGHT FIRES.
IMMEDIATELY EVACUATE AREA, USING AS MUCH PROTECTIVE COVER AS
POSSIBLE & ACTIVATE DELUGE & ALARM SYSTEMS.
Unusual Fire/Explosion Hazard:SENSITIVE TO SHOCK/IMPACT/FRICTION/STATIC
DISCHARGE/HIGH PRESSURE/TEMP. MAY DEFLAGRATE/DETONATE IF EXPOSED
RELEASING TOXIC FUMES/HEAT/SHOCK WAVES & FRAGMENTS.
================== Accidental Release Measures ==================
Spill Release Procedures:SMALL: IF SEAL RUPTURES, BARRICADE AREA,
ELIMINATE IGNITION SOURCES. USE A SOFT BRISTLE BRUSH & A CONDUCTIVE
RUBBER PAN/RUBBER SHOVEL TO CLEAN UP. USE CONDUCTIVE CONTAINERS &
GROUND ALL CONTAINERS WHE N TRANSFERRING MATERIAL. (SEE SUPP)
======================Handling and Storage ======================
Handling and Storage Precautions:STORE IN APPROVED STORAGE MAGAZINES
ONLY. STORAGE & HANDLING MUST CONFORM TO APPROPRIATE
QUANTITY/DISTANCE REQUIREMENTS, BARRICADING/GROUNDING/LIMITS.
Other Precautions:KEEP PRODUCT COOL & DRY IN STORAGE. HANDLING & USE OF
EXPLOSIVES & RELATED DANGEROUS MATERIALS MUST BE LIMITED TO
PERSONNEL AUTHORIZED/TRAINED IN THIS AREA. REFER TO ON INSTRUCTIONS
TO HANDLING, STORA GE, USE & DISPOSAL OF EXPLOSIVES.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:USE A NIOSH/MSHA APPROVED RESPIRATOR IF EXPOSED
TO PARTICULATE MATTER. USE A NIOSH/MSHA APPROVED RESPIRATOR FOR
PROTECTION AGAINST TOXIC GASEOUS IGNITION BYPRODUCTS.
Ventilation:GENERAL MECHANICAL: MODERATE FLOW FOR PARTICULATE/IGNITION
BYPRODUCT REMOVAL. EXPLOSION PROOF EQUIPMENT IS REQUIRED.
Other Protective Equipment:100% COTTON UNDERWEAR & FLAME-RESISTANT,
FULL-BODY COVERALLS, CONDUCTIVE SHOES, SAFETY
SHOWER/EYEWASH/LAUNDRY FACILITIES
Supplemental Safety and Health
SPILL CONT': LARGE: SOIL-REMOVE ALL CONTAMINATED SOIL, DISPOSE OF AS
HAZARDOUS WASTE. WATER: FLUSH W/COPIOUS AMOUNTS OF WATER. COLLECT
TO DISPOSE OF AS HAZARDOUS WASTE.
================== Physical/Chemical Properties ==================
Spec Gravity:>1
Solubility in Water:<0.1%
Appearance and Odor:METALLIC ORDNANCE HARDWARE; ODORLESS
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
OTHER HAZARDOUS MATERIALS
Stability Condition to Avoid:SHOCK, IMPACT, FRICTION, ELECTROSTATIC
DISCHARGE, HIGH PRESSURE, HIGH TEMPS, OPEN FLAME, CHEMICAL/PHYSICAL
CONTAMINATION
Hazardous Decomposition Products:LEAD, ZIRCONIUM & FLUORINE COMPOUNDS,
HYDROGEN FLUORIDE GAS, POTASSIUM CHLORIDE
==================== Disposal Considerations ====================
Waste Disposal Methods:EXPLOSIVES/DANGEROUS MATERIAL SHOULD BE
DESTROYED BY OPEN BURNING/OPEN DETONATION IN AN APPROVED
INCINERATOR. BY CHEMICAL TREATMENT/DESTRUCTION. CONTAMINATED
PROPERTY MUST NOT BE BURIED. DISPOSE OF IA W/LOCAL, STATE & FEDERAL
REGULATIONS. D003/D008.
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===================== Product Identification =====================
Product ID:ARDROX 9D6/D495A
Preparer's Name:SHEREE L.KINZEL
CAGE:23373
CAGE:23373
============= Composition/Information on Ingredients =============
Ingred Name:METHYL CHLOROFORM (1,1,1-TRICHLOROEHANE) (SARA III)
CAS:71-55-6
RTECS #:KJ2975000
Fraction by Wt: 87.0%
Other REC Limits:NONE SPECIFIED
OSHA PEL:350 PPM/450 STEL
ACGIH TLV:350 PPM/450STEL;9192
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Ozone Depleting Chemical:1
Ingred Name:OTHER COMPONENTS
Other REC Limits:NONE SPECIFIED
===================== Hazards Identification =====================
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:ACUTE:IRRITATION OF
EYES,SKIN,RESPIRATORY OR G.I.TRACTS;CNS EFFECTS LIKE
HEADACHE,DIZZINESS,NAUSEA AND VOMITING. REDNESS/TEAR OR BURNS OF
EYES/SKIN POSSIBLE.CHRONIC:DRYING OF SKIN,DEFATTING OR DERMATI TIS.
Explanation of Carcinogenicity:DATA PER MSDS
Effects of Overexposure:MAY CAUSE IRRITATION OF EYES,SKIN,RESPIRATORY
OR G.I.TRACTS;MAY CAUSE HEADACHE,DIZZINESS,NAUSEA,VOMITING OR GI
TRACT DISTURBANCES POSSIBLE.BURNS OR REDNESS OF EYES/CRACKING OR
DRYNESS OF SKIN.
Medical Cond Aggravated by Exposure:PERSONS WITH A HISTORY OF AILMENTS
OR WITH A PRE-EXISTING DISEASE INVOLVING THE EYES, SKIN, OR
RESPIRATORY TRACT MAY BE AT INCREASED RISK FROM EXPOSURE.
======================= First Aid Measures =======================
First Aid:INHALATION:REMOVE TO FRESH AIR. RESUSCITATE IF NOT BREATHING.
GET MEDICAL ATTENTION. EYES:IMMEDIATELY FLUSH WITH PLENTY OF WATER
FOR 15 MINUTES HOLDING EYELIDS OPEN. GET MEDICAL ATTENTION.
SKIN:REMOVE CONTAMINATED CLOTHING. WASH WITH SOAP AND WATER. IF
IRRITATION PERSISTS, GET MEDICAL ADVICE. INGESTION:DO NOT INDUCE
VOMITING. GIVE NOTHING BY MOUTH IF UNCONSCIOUS. GET IMMEDIATE
MEDICAL ATTENTION.
===================== Fire Fighting Measures =====================
Flash Point Method:TCC
Flash Point:NONE
Extinguishing Media:WATER SPRAY,DRY CHEMICAL,CO*2 AND WATER FOG
Fire Fighting Procedures:FIRE FIGHTERS SHOULD USE NIOSH APPROVED SCBA &
FULL PROTECTIVE EQUIPMENT WHEN FIGHTING CHEMICAL FIRE. USE WATER
SPRAY TO COOL NEARBY CONTAINERS EXPOSED TO FIRE.
Unusual Fire/Explosion Hazard:CONTAINERS MAY RUPTURE DUE TO EXTREME
HEAT.TOXIC VAPORS OF PHOSGENEN ARE EXPECTED
================== Accidental Release Measures ==================
Spill Release Procedures:USE PROPER PERSONAL PROTECTION;REMOVE ALL
IGNITION SOURCES. CONTAIN FREE MATERIAL IF POSSIBLE;USE SUITABLE
INERT ABSORBENT MATERIAL AND RECOVER FOR PROPER DISPOSAL IN AN
APPROVED CONTAINER.
Neutralizing Agent:NOT APPLICABLE.
======================Handling and Storage ======================
Handling and Storage Precautions:STORE IN A COOL, DRY, WELL VENTILATED
AREA. KEEP CONTAINERS TIGHTLY CLOSED WHEN NOT IN USE. KEEP AWAY
FROM NAKED FLAMES.
Other Precautions:DO NOT TAKE INTERNALLY. DO NOT BREATHE MIST. AVOID
PROLONGED OR REPEATED BREATHING OF VAPOR. AVOID CONTACT WITH EYES.
USE WITH ADEQUATE VENTILATION. WASH THOROUGHLY AFTER HANDLING.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:USE NIOSH/MSHA APPROVED RESPIRATOR AS REQUIRED
IF ABOVE PEL/TLV OR SCBA IN AN ENCLOSED AREA.
Ventilation:LOCAL/GENERAL TO MAINTAIN PEL/TLV.
Other Protective Equipment:EYE WASH STATION AND SAFETY SHOWER,WORK
CLOTHING AND APRON AS REQUIRED.
Work Hygienic Practices:OBSERVE GOOD PERSONAL HYGIENE PRACTICES AND
RECOMMENDED PROCEDURES. DO NOT WEAR CONTAMINATED CLOTHING OR
FOOTWEAR.
Supplemental Safety and Health
AVOID PROLONGED OR REPEATED EXPOSURE. DO NOT GET ON SKIN OR IN EYES. DO
NOT BREATHE VAPORS OR MISTS.
================== Physical/Chemical Properties ==================
HCC:T4
Boiling Pt:B.P. Text:165F,74C
Vapor Pres:110
Vapor Density:4.5
Spec Gravity:1.3
Evaporation Rate & Reference:6.0 (N-BUTYL ACETATE=1)
Solubility in Water:NEGLIGIBLE
Appearance and Odor:WHITE POWDER SUSPENDED IN COLORLESS
LIQUID,CHARACTERISTIC ODOR
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG ALKALIES,ALKALI METALS.
Stability Condition to Avoid:HIGH TEMPERATURES ,SPARKS AND NAKED
FLAMES.
Hazardous Decomposition Products:HYDROGEN CHLORIDE ;VERY SMALL AMOUNT
OF PHOSGENE AND CHLORINE.
==================== Disposal Considerations ====================
Waste Disposal Methods:CONSULT LOCAL AUTHORITIES.DISPOSAL MUST BE MADE
IN ACCORDANCE WITH ALL APPLICABLE FEDERAL, STATE AND LOCAL LAWS AND
REGULATIONS.
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===================== Product Identification =====================
Product ID:IODINE MONOCHLORIDE, 98% 20822-1
CAGE:60928
CAGE:60928
============= Composition/Information on Ingredients =============
Ingred Name:IODINE CHLORIDE (IODINE MONOCHLORIDE, 98%)
CAS:7790-99-0
RTECS #:NN1650000
Fraction by Wt: 98%
.
RTECS #:9999999ZZ
Other REC Limits:NONE SPECIFIED
===================== Hazards Identification =====================
LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:ACUTE:HARMFUL IF INGESTED, INHALED OR
ABSORBED THROUGH SKIN. MATL IS EXTREMELY DESTRUCTIVE TO TISS OF MUC
MEMB & UPPER RESP TRACT, EYES & SKIN. INHAL MAY BE FATAL AS RESULT
OF SPASM, INFLAMM & EDEMA O F LARYNX & BRONCHI, CHEM PNEUMONITIS &
PULMONARY EDEMA. WARNING:ATTACKS SKIN, FORMING DARK, PAINFUL (SEE
SUPP DATA)
Explanation of Carcinogenicity:NONE SPECIFIED BY MANUFACTURER.
Effects of Overexposure:BURNING SENSATION, COUGHING, WHEEZING,
LARYNGITIS, SHORTNESS OF BREATH, HEADACHE, NAUSEA AND VOMITING.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
======================= First Aid Measures =======================
First Aid:EYES:IMMEDIATELY FLUSH W/COPIOUS AMTS OF WATER FOR AT LEAST
15 MINUTES. ASSURE ADEQ FLUSHING BY SEPARATING LIDS W/FINGERS.
SKIN:IMMEDIATELY FLUSH W/COPIOUS AMTS OF WATER FOR 15 MINUTES WHILE
REMOVING CONTAM CLTHG/SHOES. WASH CONTAM CLTHG BEFORE REUSE.
DISCARD CONTAM SHOES. INHAL:REMOVE TO FRESH AIR. SUPPORT BREATHING
(GIVE O*2/ARTF RESP), CALL MD. INGEST:CALL MD IMMEDIATELY .
===================== Fire Fighting Measures =====================
Extinguishing Media:DRY CHEMICAL POWDER. DO NOT USE WATER.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA AND FULL
PROTECTIVE EQUIPMENT . PREVENT CONTACT WITH SKIN AND EYES.
Unusual Fire/Explosion Hazard:EMITS TOXIC FUMES UNDER FIRE CONDITIONS.
================== Accidental Release Measures ==================
Spill Release Procedures:EVACUATE AREA. WEAR NIOSH/MSHA APPRVD SCBA,
PLACE IN CLOSED CONTAINERS FOR DISPOSAL. VENTILATE AREA & WASH
SPILL SITE AFTER MATERIAL PICKUP IS COMPELTE.
Neutralizing Agent:SEE WASTE DISPOSAL METHOD.
======================Handling and Storage ======================
Handling and Storage Precautions:REFRIGERATE. HANDLE/STORE UNDER
NITROGEN. KEEP TIGHTLY CLOSED. AVOID PRLNGD/RPTD EXPOSURE. DO NOT
GET IN EYES, ON SKIN OR CLTHG.
Other Precautions:LIGHT SENSITIVE. AIR & MOISTURE SENSITIVE. CORROSIVE.
IODINE MONOCHLORIDE EXPLODES ON CNTCT W/POTASSIUM WHILE A MIXTURE
W/SODIUM EXPLODES ONLY ON IMPACT. ALUMINUM FOIL IGNITES ONLY AFTER
PRLNGD CNTCT. ON MIXING W/PHOSPHOROUS (SEE SUPP DATA)
============= Exposure Controls/Personal Protection =============
Respiratory Protection:WEAR APPROPRIATE NIOSH/MSHA APPROVED RESPIRATOR.
Ventilation:USE ONLY IN CHEMICAL FUME HOOD.
Other Protective Equipment:PROTECTIVE CLOTHING. SAFETY SHOWER AND EYE
BATH. FACESHIELD (8-INCH MINIMUM).
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING.
Supplemental Safety and Health
HLTH HAZ:PATCHES. EFTIVE COUNTERMEASURE.IMMED WASH W/20% HYDROCHLORIC
ACID, FOLLOW BY FLUSHING FOR AT LEAST 15 MIN W/WATER. WASTE DISP
METH:GENERATE HEAT & FUMES WHICH CAN BE CONTROLLED BY RATE OF ADD
ITION. OBSERVE ALL FED, STATE & LOCAL LAWS. OTHER PREC:TRICHLORIDE,
AN INTENSELY EXOTHERMIC REACTION OCCURS. (INGRED-02)
================== Physical/Chemical Properties ==================
HCC:C1
Boiling Pt:B.P. Text:207F,97C
Appearance and Odor:NONE SPECIFIED BY MANUFACTURER.
================= Stability and Reactivity Data =================
STRONG BASES.
Stability Condition to Avoid:AIR AND MOISTURE SENSITIVE, MAY DISCOLOR
ON EXPOSURE TO LIGHT.
Hazardous Decomposition Products:HYDROGEN CHLORIDE GAS, HYDROGEN
IODIDE.
==================== Disposal Considerations ====================
Waste Disposal Methods:SMALL QTYS:SLOWLY ADD TO LG STIRRED EXCESS OF
WATER. ADJUST PH TO NEUTRAL, SEPARATE ANY INSOLUBLE SOLIDS/LIQS &
PACKAGE FOR HAZ WASTE DISP. FLUSH AQUEOUS SOLN DOWN DRAIN W/PLENTY
OF WATER. HYDROLYSIS/ NEUTRALIZATION REACTIONS MAY (SEE SUPP DATA)
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===================== Product Identification =====================
Product ID:5255 HIGH PERFORMANCE ACRYLIC COATING
CAGE:08882
CAGE:08882
============= Composition/Information on Ingredients =============
Ingred Name:PROPANOIC ACID, 2-METHYL, MONOESTER
W/2,2,4-TRIMETHYL-1,3-PENTANEDIOL, TEXANOL(ESTER ALCOHOL)
CAS:25265-77-4
RTECS #:UF6000000
Fraction by Wt: 5%
Ingred Name:DIETHYLENE GLYCOL METHYL ETHER, 2-(2-METHOXYETHOXY) ETHANOL
METHYL CARBITOL
CAS:111-77-3
RTECS #:KL6125000
Fraction by Wt: 0.3%
Ingred Name:1,2-PROPANEDIOL (PROPYLENE GLYCOL)
CAS:57-55-6
RTECS #:TY2000000
Fraction by Wt: 5%
===================== Hazards Identification =====================
Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:INHALATION: IRRITATION OF NOSE, THROAT
& LUNGS. SKIN/EYES: PRIMARY IRRITANT. INGESTION: GI IRRITATION.
Explanation of Carcinogenicity:NONE
Effects of Overexposure:IRRITATION, HEADACHE, NAUSEA, VOMITING,
DIARRHEA.
======================= First Aid Measures =======================
First Aid:INHALATION: REMOVE TO FRESH AIR. EYES: FLUSH IMMEDIATELY
W/LARGE AMOUNTS OF WATER FOR 15 MINS. SKIN: WASH AFFECTED AREA
W/SOAP & WATER. INGESTION: DILUTE STOMACH CONTENTS W/TWO GLASSES OF
WATER & INDU CE VOMITING BY EITHER GIVING IPECAC SYRUP/BY PLACING
TWO FINGERS AT BACK OF THROAT. NEVER GIVE ANYTHING BY MOUTH TO AN
UNCONSCIOUS PERSON. OBTAIN MEDICAL ATTENTION IN ALL CASES.
===================== Fire Fighting Measures =====================
Flash Point:>200F
Fire Fighting Procedures:WATER MAY BE USED TO COOL CLOSED CONTAINERS TO
PREVENT BUILD-UP OF STEAM. IF WATER IS USED, FOG NOZZLES ARE
PREFERRED.
Unusual Fire/Explosion Hazard:CLOSED CONTAINERS MAY EXPLODE WHEN
EXPOSED TO EXTREME HEAT DUE TO BUILD-UP OF STEAM.
================== Accidental Release Measures ==================
Spill Release Procedures:SOAK UP LIQUID W/ABSORBENT & SHOVEL INTO WASTE
CONTAINER. WASH AREA W/WATER & FLUSH TO SEWER SERVICED BY WASTE
WATER TREATMENT FACILITY.
======================Handling and Storage ======================
Handling and Storage Precautions:KEEP FROM FREEZING.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:WEAR A NIOSH APPROVED CHEMICAL CARTRIDGE
RESPIRATOR TO REMOVE SOLID AIRBORNE PARTICLES OF OVERSPRAY DURING
SPRAY APPLICATION.
Ventilation:GENERAL DILUTION/LOCAL EXHAUST IN VOLUME & PATTERN TO KEEP
TLV BELOW ACCEPTABLE LIMITS.
Work Hygienic Practices:REMOVE/LAUNDER CONTAMINATED CLOTHING BEFORE
REUSE.
Supplemental Safety and Health
================== Physical/Chemical Properties ==================
Boiling Pt:B.P. Text:302-385F
Vapor Density:>1
pH:8-9.2
Evaporation Rate & Reference:SLOWER THAN ETHER
Percent Volatiles by Volume:60-70
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS.
Stability Condition to Avoid:EXTREME HEAT, OPEN FLAME, FREEZING.
Hazardous Decomposition Products:CO & CO2.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSE OF IAW/FEDERAL, STATE & LOCAL
REGULATIONS.
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===================== Product Identification =====================
Product ID:5102, SOLID COLORS AUTOMOTIVE TOUCH-UP
CAGE:9P972
CAGE:86142
CAGE:9P972
============= Composition/Information on Ingredients =============
Ingred Name:ING 4: USED TO EFFECTIVELY MINIMIZE EMPLOYEE EXPOSURE: LOC
EXHST VENT, ENCLOSED SYS DESIGN, PROCESS ISOLATION (ING 6)
RTECS #:9999999ZZ
Ingred Name:ING 5: & REMOTE CONTROL IN COMBINATION W/APPROP USE OF
PERSONAL PROTECTIVE EQUIPMENT & PRUDENT WORK PRACTICES. (ING 7)
RTECS #:9999999ZZ
Ingred Name:ING 6: THESE TECHNIQUES MAY NOT NECESSARILY ADDRESS ALL
ISSUES PERTAINING TO YOUR OPERATIONS. WE, THEREFORE, (ING 8)
RTECS #:9999999ZZ
Ingred Name:ING 7: RECOMMEND THAT YOU CONSULT WITH EXPERTS OF YOUR
CHOICE TO DETERMINE WHETHER OR NOT YOUR PROGRAMS ARE ADEQUATE.
RTECS #:9999999ZZ
Ingred Name:2-PENTANONE, 4-METHYL; (METHYL ISOBUTYL KETONE) (SARA III)
CAS:108-10-1
RTECS #:SA9275000
Fraction by Wt: 30-50%
OSHA PEL:50 PPM;75 STEL
ACGIH TLV:50 PPM;75 STEL
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
Ingred Name:CYCLOHEXANONE (SARA III)
CAS:108-94-1
RTECS #:GW1050000
Fraction by Wt: 5-10%
OSHA PEL:25 PPM, S
ACGIH TLV:25 PPM, S
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
Ingred Name:XYLENE (SARA III)
CAS:1330-20-7
RTECS #:ZE2100000
Fraction by Wt: 10-30%
OSHA PEL:100 PPM;150 STEL
ACGIH TLV:100 PPM;150 STEL
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Ingred Name:SUPP DATA: BELOW ACCEPTABLE CRITERIA. ENGINEERING CONTROLS:
THE FOLLOWING EXPOSURE CONTROL TECHNIQUES MAY BE (ING 5)
RTECS #:9999999ZZ
===================== Hazards Identification =====================
LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:ACUTE: SKIN ABSORP/INGEST: NOT
EXPECTED TO BE HARMFUL UNDER NORMAL CONDITIONS OF USE. IF
ACCIDENTALLY SWALLOWED, BURNS OR IRRIT TO MUC MEMBS, ESOPHAGUS OR
GI TRACT CAN RESULT. INHAL:MAY BE HARMFUL IF INHALED. LIQ/VAP MAY
CAUSE IRRIT OF NOSE, THROAT & LUNGS. SKIN: MAY CAUSE IRRIT ON
PROLONGED OR (EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZ: REPEATED CNTCT. EYES: CAUSES IRRIT.
INGRED 1: CAN CAUSE CNS DEPRESS. SIGNS & SMPS MAY INCL HDCH, DIZZ,
NAUS, VOMIT, UNCON & EVEN ASPHY. INGRED 2 & 3: CAN CAUSE LIVER &
KIDNEY DMG. CAN CAUSE CNS DEPRESS. SIGNS & SYMPS MAY INCLUDE HDCH,
DIZZ, NAUS, VOMIT, UNCON & EVEN ASPHY.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
======================= First Aid Measures =======================
First Aid:SKIN ABSORP:IMMED FLUSH EYE/SKIN W/PLENTY OF WATER FOR @ LST
15 MIN. INGEST: DILUTE BY DRINKING LRG QTYS OF WATER. IMMED CNTCT
POIS CTL CTR/HOSPITAL EMERGENCY ROOM FOR ANY OTHER ADDITIONAL
TREATMENT D IRECTIONS. INHAL:REMOVE TO FRESH AIR. IF NOT BRTHG,
GIVE ARTF RESP, PREFERABLY MOUTH-TO-MOUTH. SKIN:FLUSH WITH WATER.
EYE:IMMED FLUSH W/ PLENTY OF WATER FOR @ LST 15 MIN. EYELIDS SHOULD
BE (SUPP DATA)
===================== Fire Fighting Measures =====================
Flash Point:65.3F,18.5C
Extinguishing Media:USE DRY CHEMICAL, "ALCOHOL" FOAM OR CO2. WATER MAY
BE INEFTIVE, BUT SHOULD BE USED TO COOL FIRE-EXPOSED CNTNRS COOL.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA AND FULL
PROTECTIVE EQUIPMENT .
Unusual Fire/Explosion Hazard:KEEP LIQ & VAP AWAY FROM HEAT, SPARKS,
FLAME & OTHER IGNIT SOURCES INCL, BUT NOT LIMITED TO, PILOT LIGHTS,
HEATERS, CIGARETTES, ELECTIC MOTORS AND (SUPP DATA)
================== Accidental Release Measures ==================
Spill Release Procedures:ELIMINATE ALL IGNITION SOURCES. SOAK UP WITH
ABSORBENT MATERIAL AND REMOVE TO A CHEMICAL DISPOSAL AREA. PREVENT
ENTRY INTO NATURAL BODIES OF WATER.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
======================Handling and Storage ======================
Handling and Storage Precautions:KEEP CONTAINER CLOSED. STORE IN A
COOL, DRY PLACE. AVOID PROLONGD OR REPEATED CONTACT WITH EYES, SKIN
OR CLTHG. AVOID BREATHING VAPOR.
Other Precautions:HANDLE IN ACCORDANCE WITH GOOD INDUSTRIAL HYGIENE AND
SAFETY PRACTICES. THESE PRACTICES INCLUDE AVOIDING UNNECESSARY
EXPOSURE AND REMOVAL OF THE MATERIAL FROM EYES, SKIN AND CLOTHING.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:WHERE AIR CONTAMS CAN EXCEED ACCEPTABLE
CRITERIA, USE NIOSH/MSHA APPROVED RESP PROT EQUIP. RESPS SHOULD BE
SELECTED BASED ON THE FORM AND CONC OF CONTAMS IN AIR IN ACCORD
W/OSHA 29 CFR 1910.134 OR OTH ER APPLICABLE STDS OR GUIDELINES.
Ventilation:IF AIRBORNE CONTAMS ARE GENERATED WHEN MATL IS HEATED/
HANDLED, SUFFICIENT VENT IN VOL & AIR FLOW PATTERNS (SUPP DATA)
Other Protective Equipment:NONE SPECIFIED BY MANUFACTURER.
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING.
Supplemental Safety and Health
% VOL: 58.3-79.0 (WT). EXPLO HAZS: STATIC DISCHARGE. VAP IS HVR/AIR &
MAY SETTLE IN LOW PLACES OR TRAVEL OUTWARD TO A SOURCE OF IGNIT AND
FLASHBACK. FIRST AID PROC: HELD APART DURING IRRIGATION TO INS URE
WATER CNTCT W/ENTIR SURF OF EYES & LIDS. CALL MD. VENT: SHOULD BE
PROVIDED TO KEEP AIR CONTAM CONC LEVELS (ING 4)
================== Physical/Chemical Properties ==================
HCC:F3
Spec Gravity:0.88-1.27
Solubility in Water:SLIGHT
Appearance and Odor:COLORED LIQUID, SOLVENT ODOR.
Percent Volatiles by Volume:SUPDAT
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
NONE SPECIFIED BY MANUFACTURER.
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:CO, CO2.
==================== Disposal Considerations ====================
Waste Disposal Methods:RECOVER FREE LIQUID. ABSORB RESIDUE AND DISPOSE
OF ACCORDING TO LOCAL, STATE/PROVINCIAL, AND FEDERAL REQUIREMENTS.
EMPTY CONTAINER: MAY CONTAIN EXPLOSIVE VAPORS. DO NOT CUT, PUNCTURE
OR WELD ON OR NEA RBY.
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===================== Product Identification =====================
Product ID:ETHYLENE GLYCOL MONOMETHYL ETHER, NC9476220
CAGE:1B464
CAGE:1B464
============= Composition/Information on Ingredients =============
Ingred Name:2-METHOXYETHANOL; (ETHYLENE GLYCOL MONOMETHYL ETHER).
LD50:(ORAL,RAT) 2370 MG/KG. NIOSH: 0.1 PPM TWA; 0.3 MG/M3 TWA 200
PPM IDLH (NOT APPLICABLE BECAUSE OF NIOSH REL). EINECS/ELINCS:
203-713-7.
CAS:109-86-4
RTECS #:KL5775000
> Wt:98.
OSHA PEL:80 MG/M3;25 PPM
ACGIH TLV:16 MG/M3;5 PPM
===================== Hazards Identification =====================
LD50 LC50 Mixture:SEE INGREDIENT & TOXICOLOGICAL INFO.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:ACUTE: EYE: MAY CAUSE MODERATE
IRRITATION. MAY CAUSE TRANSIENT CORNEAL INJURY. SKIN: MAY BE
ABSORBED THROUGH SKIN IN HARMFUL AMOUNTS. IF ABSORBED, CAUSES
SYMPTOMS SIMILAR TO THOSE OF INGESTION. INGEST ION: CAUSES
DIGESTIVE TRACT IRRITATION. MAY CAUSE LIVER AND KIDNEY DAMAGE.
EXPOSURE MAY CAUSE ANEMIA AND BLOOD ABNORMALITIES. MAY CAUSE
CENTRAL NERVOUS SYSTEM DEPRESSION. INHALATION: MAY CAUSE RESPIRA
TORY TRACT IRRITATION. MAY CAUSE LIVER AND KIDNEY DAMAGE. MAY CAUSE
DYSPNEA (DIFFICULT BREATHING FROM SHORTNESS OF BREATH. CHRONIC: MAY
CAUSE BONE MARROW ABNORMALITIES WITH DAMAGE TO BLOOD FORMING TIS
SUES. MAY CAUSE ANEMIA(EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT LISTED BY ACGIH, IARC, NIOSH, NTP OR
OSHA.
Effects of Overexposure:HLTH HAZS: AND OTHER BLOOD CELL ABNORMALITIES.
MAY CAUSE REPRODUCTIVE AND FETAL EFFECTS. NOTE: ETHYLENE GLYCOL
MONOMETHYL ETHER APPEARS ON THE NAVY LIST OF OCCUPATIONAL CHEMICAL
REPRODUCTIVE HAZARDS. SEEK CONSULTATION FROM APPROPRIATE HEALTH
PROFESSIONALS CONCERNING LATEST HAZARD LIST INFORMATION AND SAFE
HANDLING AND EXPOSURE INFORMATION . TARGET ORGANS: BLOOD, KIDNEYS,
CENTRAL NERVOUS SYST EM, LIVER, BONE MARROW, REPRODUCTIVE SYSTEM.
======================= First Aid Measures =======================
First Aid:EYES:IMMED FLUSH W/PLENTY OF WATER FOR AT LST 15 MINS, OCCAS
LIFTING UPPER & LOWER LIDS. GET MED AID. SKIN:GET MED AID IMMED.
IMMED FLUSH W/PLENTY OF SOAP & WATER FOR AT LST 15 MINS WHILE
REMOVING CON TAM CLTHG & SHOES. INGEST:IF VICTIM IS CONSCIOUS &
ALERT, GIVE 2-4 CUPFULS OF MILK/WATER. NEVER GIVE ANYTHING BY MOUTH
TO UNCONSCIOUS PERS. GET MED AID IMMED. INDUCE VOMIT BY GIVING 1
TSP OF SYRUP OF IPECAC. INHAL:REMOVE FROM EXPOS TO FRESH AIR
IMMED. IF NOT BRTHG, GIVE ARTF RESP. IF BRTHG IS DFCLT, GIVE OXYG.
GET MED AID. NOTES TO MD:TREAT SYMPTOMATICALLY & SUPPORTIVELY.
ANTIDOTE:NO SPECIFIC ANTI DOTE EXISTS.
===================== Fire Fighting Measures =====================
Flash Point:=41.7C, 107.F
Autoignition Temp:=285.C, 545.F
Lower Limits:1.8%
Upper Limits:14%
Extinguishing Media:FOR SMALL FIRES, USE WATER SPRAY, DRY CHEMICAL,
CARBON DIOXIDE OR CHEMICAL FOAM.
Fire Fighting Procedures:USE NIOSH APPROVED SCBA AND FULL PROTECTIVE
EQUIPMENT . USE WATER SPRAY TO COOL FIRE-EXPOSED CONTAINERS.
Unusual Fire/Explosion Hazard:WARNING! FLAMMABLE LIQUID. VAPORS MAY
FORM AN EXPLOSIVE MIXTURE WITH AIR. VAPORS CAN TRAVEL TO A SOURCE
OF IGNITION AND FLASH BACK. NFPA RATING: HEALTH - 2; FLAMMABILITY -
2; REACTIVITY - 0.
================== Accidental Release Measures ==================
Spill Release Procedures:WEAR A NIOSH APPROVED SELF CONTAINED BREATHING
APPARATUS AND APPROPRIATE PERSONAL PROTECTION. USE PROPER PERSONAL
PROTECTIVE EQUIPMENT AS INDICATED IN EXPOSURE CONTROLS, PERSONAL
PROTECTION SECTION. A BSORB SPILL WITH INERT MATERIAL (E.G., DRY
SAND OR EARTH), THEN PLACE INTO A CHEMICAL WASTE CONTAINER. REMOVE
ALL SOURCES OF IGNITION.
======================Handling and Storage ======================
Handling and Storage Precautions:KEEP AWAY FROM SOURCES OF IGNIT. DO
NOT STORE IN DIRECT SUNLIGHT. STORE IN TIGHTLY CLSD CNTNR. STORE IN
COOL, DRY, WELL-VENTED AREA AWAY FROM INCOMPAT SUBSTANCES. DO NOT
EXPOSE TO AIR. DO NOT GET ON S KIN OR IN EYES. DO NOT INGEST OR
INHALE. AVOID EXPOSURE - OBTAIN SPECIAL INSTRUCTIONS BEFORE USE.
Other Precautions:USE W/ADEQ VENT. GROUND & BOND CNTNRS WHEN
TRANSFERRING MATL. USE SPK-PROOF TOOLS & EXPLO PROOF EQUIP. EMPTY
CNTNRS RETAIN PROD RESIDUE, (LIQ &/OR VAP), & CAN BE DANGEROUS.
KEEP CNTNR TIGHTLY CLSD. DO NOT PRESSURIZE, CUT, WELD, BRAZE,
SOLDER, DRILL, GRIND/EXPOSE EMPTY CNTNRS TO HEAT, SPKS/OPEN FLAME
S. IN CASE (SUPDAT)
============= Exposure Controls/Personal Protection =============
Respiratory Protection:FOLLOW THE OSHA RESPIRATOR REGULATIONS FOUND IN
29 CFR 1910.134 OR EUROPEAN STANDARD EN 149. ALWAYS USE A NIOSH OR
EUROPEAN STANDARD EN 149 APPROVED RESPIRATOR WHEN NECESSARY.
Ventilation:USE ADEQUATE GENERAL OR LOCAL EXHAUST VENTILATION TO KEEP
AIRBORNE CONCENTRATIONS BELOW THE PERMISSIBLE EXPOSURE LIMITS.
FACESHIELD .
Other Protective Equipment:ANSI APPROVED EYE WASH & DELUGE SHOWER .
WEAR APPROPRIATE PROTECTIVE CLOTHING TO PREVENT SKIN EXPOSURE.
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING. REMOVE
CONTAMINATED CLOTHING AND WASH BEFORE REUSE.
Supplemental Safety and Health
OTHER PREC:OF ACCIDENT/IF YOU FEEL UNWELL, SEEK MED ADVICE IMMED (SHOW
LBL WHERE POSS). -- PHYSICAL & CHEM PROPERTIES: MOLECULAR FORMULA:
C3H8O2. MOLECULAR WT: N/P. -- OTHER INFO:OEL-AUSTRALIA, UNITED
KINGDOM:TWA 5 PPM (16 MG/M3); SKIN OEL-BELGIUM, DENMARK, FRANCE,
JAPAN, THE NETHERLANDS:TWA 5 PPM (ECOLOGICAL INFO)
================== Physical/Chemical Properties ==================
Boiling Pt:=124.2C, 255.6F
Melt/Freeze Pt:=-85.C, -121.F
Decomp Temp:Decomp Text:NOT AVAILABLE
Vapor Pres:9.7 MM HG @ 25C
Vapor Density:2.6(AIR=1)
Spec Gravity:0.966 @ 20C
pH:NOT AVAILABLE
Viscosity:NOT AVAILABLE
Solubility in Water:MISCIBLE
Appearance and Odor:COLORLESS LIQUID; PLEASANT ODOR - WEAK ODOR.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
OXIDIZING AGENTS AND ALKALIES. SUBSTANCE CAN REACT WITH AIR TO FORM
EXPLOSIVE PEROXIDES.
Stability Condition to Avoid:STABLE UNDER NORMAL TEMPERATURES AND
PRESSURES. AVOID INCOMPATIBLE MATERIALS, IGNITION SOURCES, EXCESS
HEAT.
Hazardous Decomposition Products:CARBON MONOXIDE, CARBON DIOXIDE.
Conditions to Avoid Polymerization:HAS NOT BEEN REPORTED.
=================== Toxicological Information===================
Toxicological Information:CAS # 109-86-4: RTECS # KL5775000: LD50/LC50:
LC50:(INHAL,MOUSE) 1480 PPM/7H; LC50:(INHAL,RAT) 1500 PPM/7H;
LD50:(ORAL,MOUSE) 2560 MG/KG; LD50:(ORAL,RABBIT) 890 MG/KG;
LD50:(SKIN,RABBIT) 1280 MG/KG. E PIDEMIOLOGY:NO INFO AVAIL.
TERATOGENICITY:EFTS ON NEWBORN:BEHAVIORAL, INHAL-RAT TCLO=25
PPM/7H; BIOCHEM & METABOLIC, ORAL-RAT TDLO=175 MG/KG; GROWTH
STATISTICS, INHAL-RAT TCLO=100 PPM/6H. EMBRYO/FETUS :DEATH,
ORAL-MONKEY TDLO=930 MG/KG; FETOTOXICITY, ORAL-RAT TDLO=350 MG/KG.
SPECIFIC DEVEL ABNORMS: CARDIOVASCULAR, ORAL-RAT TDLO=175 MG/KG;
CNS & UROGENITAL, INTRAPERITONEAL(IPR)-RAT TDLO=190 MG/KG; M
USCULOSKELETAL, (ECOLOGICAL INFO)
===================== Ecological Information =====================
Ecological:ECOTOXICITY:NO INFO AVAIL. ENVIRON FATE:NO INFO REPORTED.
PHYSICAL/CHEM:NO INFO AVAIL. OTHER:NONE. -- TOX INFO:IPR-RAT
TDLO=330 MG/KG. REPRO EFTS:FERTILITY:ABORTION, ORAL-MONKEY TDLO=930
MG/KG; FEMALE INDEX, INHAL-RAT TCLO=100 PPM/6H; LITTER SIZE,
INHAL-MOUSE TCLO=50 PPM/6H. PATERNAL EFTS:SPERMATOGENESIS, ORAL-RAT
TDLO=250 M/KG; TESTES/SPERM DUCT/EPIDIDYMIS, ORAL-RAT TDLO=100
MG/KG. NEUROTOXICITY/ MUTAGENICITY:NO INFO AVAIL. OTHER
STUDIES:PLEASE REFER TO RTECS KL5775000 FOR ADDNL INFO. -- SUPP
DATA:(16 MG/M3); SKIN OEL-FINLAND:TWA 25 PPM (80 MG/M3); STEL 40
PPM (12 MG/M3); SKIN OEL-GERMANY:TWA 5 PPM (15 MG/M3); (TRANSPORT
INFO)
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSE OF IN A MANNER CONSISTENT WITH FEDERAL,
STATE AND LOCAL REGULATIONS. RCRA: D-SERIES MAXIMUM CONCENTRATION
OF CONTAMANTS; D-SERIES CHRONIC TOXICITY REFERENCE LEVELS;
F-SERIES; P-SERIES; & U-SER IES: NONE LISTED.
=================== MSDS Transport Information ===================
Transport Information:U.S. DOT:SHIPPING NAME:ETHYLENE GLYCOL MONOMETHYL
ETHER; HAZ CLASS:3; UN #:UN1188; PACKING GRP:III. IATA;
RID/ADR/IMO:SHIPPING NAME:NO INFO AVAIL. CANADA TDG:SHIPPING
NAME:ETHYLENE GLYCOL MONOMETHYL E THER; HAZ CLASS:3; UN #:UN1188;
PACKINGGRP:III; ADDNL INFO:FL PT:39C (102.2F). -- ECOLOGICAL
INFO:SKIN OEL-HUNGARY:TWA 15 MG/M3; STEL 30 MG/M3; SKIN OEL-THE
PHILIPPINES, TURKEY:TWA 25 PPM (80 MG/M3);SKIN OEL-POLAND:TWA 50
MG/M3; OEL-RUSSIA:TWA 5 PPM; OEL-SWEDEN:TWA 5 PPM (16 MG/M3); STEL
10 PPM (30 MG/M3); SKIN OEL-SWITZERLAND:TWA 5 PPM (15 MG/M3); STEL
10 PPM (30 MG/M3; SKIN JAN 9 OEL IN BULGARI A, COLOMBIA, JORDAN,
(SARA TITLE III)
===================== Regulatory Information =====================
SARA Title III Information:SECTION 302 (RQ):NONE OF CHEMS IN THIS MATL
HAVE RQ. SECTION 302 (TPQ):NONE OF CHEMS IN THIS PROD HAVE TPQ.
SARA CODES: CAS # 109-86-4:ACUTE, CHRONIC, FLAMM. SECTION 313:THIS
MATL CONTAINS 2-METHOXYET HANOL (CAS # 109-86-4, 98%), WHICH IS
SUBJECT TO REPORTING REQUIREMENTS OF SECTION 313 OF SARA TITLE III
& 40 CFR PART 373. -- TRANSPORT INFO:KOREA, NEW ZEALAND, SINGAPORE,
VIETNAM: CHECK ACGIH TLV.
Federal Regulatory Information:TSCA:CAS # 109-86-4 IS LISTED ON TSCA
INVENTORY. HLTH & SFTY REPORTING LIST:NONE OF CHEMS ARE ON HLTH &
SFTY REPORTING LIST. CHEM TEST RULES:NONE OF CHEMS IN THIS PROD ARE
UNDER CHEM TEST RULE. SECTIO N 12B:NONE OF CHEMS ARE LISTED UNDER
TSCA SECTION 12B. TSCA SIGNIFICANT NEW USE RULE:NONE OF CHEMS IN
THIS MATL HAVE SNUR UNDER TSCA. CLEAN AIR ACT:THIS MATL DOES NOT
CONTAIN ANY HAZ AIR POLLUTANTS; C LASS 1/CLASS 2 OZONE DEPLETORS.
CLEAN WATER ACT:NONE OF CHEMS IN THIS PROD ARE LISTED AS HAZ
SUBSTAN CES; PRIORITY/TOX POLLUTANTS UNDER CWA. OSHA:NONE OF CHEMS
IN THIS PROD ARE CONSIDERED HIGHLY HAZ BY OSHA. EUROPEAN/ (STATE
REGULATORY INFO)
State Regulatory Information:CAS # 109-86-4 CAN BE FOUND ON FOLLOWING
STATE RIGHT TO KNOW LISTS: CALIFORNIA, NEW JERSEY, FLORIDA,
PENNSYLVANIA, MINNESOTA, MASSACHUSETTS. FOLLOWING STATEMENT(S)
IS(ARE) MAKE IN ORDER TO COMPLY W/CA LIFORNIA SAFE DRINKING WATER
ACT: WARNING:THIS PROD CONTAINS 2-METHOXYETHANOL, CHEM KNOWN TO
STATE OF CALIFORNIA TO CAUSE BIRTH DEFECTS/OTHER REPRO HARM.
CALIFORNIA NO SIGNIFICANT RISK LEVEL:NONE OF C HEMS IN THIS PROD
ARE LISTED. -- FED REGULATORY:INTERNATIONAL REGS:EUROPEAN LABELING
I/A/W EC DIRECT IVES:HAZ SYMBOLS: T F. RISK PHRASES: R 10 - FLAMM.
R 20/21/22 - HARMFUL BY INHAL, IN CONT W/SKIN & IF SWALLOWED. R 60
- MAY (OTHER INFO)
======================= Other Information =======================
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===================== Product Identification =====================
Product ID:SPEEDY-STRIP
CAGE:22969
CAGE:22969
============= Composition/Information on Ingredients =============
Ingred Name:METHYLENE CHLORIDE(SARA III)
CAS:75-09-2
RTECS #:PA8050000
Fraction by Wt: 68%
Other REC Limits:A2 CARCINOGEN
OSHA PEL:500 PPM/C,1000; Z2
ACGIH TLV:50 PPM, A2; 9192
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Ingred Name:METHYL ALCOHOL (METHANOL) (SARA III)
CAS:67-56-1
RTECS #:PC1400000
Fraction by Wt: 10%
Other REC Limits:200 PPM
OSHA PEL:S,200PPM/250STEL
ACGIH TLV:S,200PPM/250STEL; 93
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
===================== Hazards Identification =====================
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:INHALATION: MAY CAUSE DIZZINESS,
UNCONSCIOUSNESS, LIVER & KIDNEY DAMAGE. EYES: PAIN & IRRITATION.
SKIN: IRRITATION & DERMATITIS.
Explanation of Carcinogenicity:NONE
Effects of Overexposure:INHALATION: DIZZINESS, UNCONSCIOUSNESS,
LIVER/KIDNEY DAMAGE. EYES: PAIN & IRRITATION. SKIN: IRRITATION &
DERMATIITS.
======================= First Aid Measures =======================
First Aid:SKIN: WASH W/HAND SOAP & WATER, APPLY MILD SKIN CREAM.
CONTACT PHYSICIAN. EYES: FLUSH W/WATER FOR AT LEAST 15 MINS. GET
MED ATT. INHALATION: MOVE TO FRESH AIR, GIVE OXYGEN IF NEEDED. IF
UNCONSCIOUS, G IVE ARTIFICIAL RESPIRATION. NEVER GIVE FLUIDS/INDUCE
VOMITING IF PATIENT IS UNCONSCIOUS/HAVING CONVULSIONS. GET MED ATT.
===================== Fire Fighting Measures =====================
Flash Point:NOT FLAMMABLE
================== Accidental Release Measures ==================
Spill Release Procedures:WEAR SELF-CONTAINED BREATHING APPARATUS/AIR
SUPPLIED RESPIRATOR. EVACUATE THE AREA. MOVE UPWIND. DIKE AREA TO
CONTAIN SPILL. ABSORB W/ABSORBENT MATERIALS SUCH AS SAW
DUST/VERMICULITE & SHOVEL INTO APP ROPRIATE DISPOSAL CONTAINERS.
======================Handling and Storage ======================
Handling and Storage Precautions:KEEP CONTAINER CLOSED WHEN NOT IN USE.
STORE AT NORMAL ROOM TEMPERATURE. VAPORS ARE HEAVIER THAN AIR &
WILL COLLECT IN LOW AREAS.
Other Precautions:A SPILL/LEAK MAY CONTAMINATE UNDER GROUND WATER
SUPPLY. DON'T TRANSFER INTO UN-MARKED CONTAINERS.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:USE NIOSH APPROVED RESPIRATOR IF VENTILATION IS
INADEQUATE.
Ventilation:PROVIDE LOCAL EXHAUST/MECHANICAL VENTILATION TO PROVIDE
ADEQUATE FRESH AIR & FOR ENCLOSED AREAS.
Other Protective Equipment:RUBBER APRON & BOOTS, EYE WASH STATION.
Supplemental Safety and Health
================== Physical/Chemical Properties ==================
Boiling Pt:B.P. Text:104F
Vapor Pres:349
Vapor Density:>AIR
Spec Gravity:1.32
Evaporation Rate & Reference:(BU AC = 1): 0.71
Solubility in Water:SOLUBLE
Appearance and Odor:VISCOUS LIQUID. ORGANIC SOLVENT ODOR.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
DON'T MIX W/LIQUID OXYGEN/STRONG OXIDANTS.
==================== Disposal Considerations ====================
Waste Disposal Methods:DON'T FLUSH INTO SEWER. CONTAMINATED ABSORBENT
MATERIAL MUST BE DISPOSED OF IN AN APPROVED HAZARDOUS WASTE
FACILITY IN ACCORDANCE W/LOCAL, STATE & FEDERAL REGULATIONS.
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===================== Product Identification =====================
Product ID:CHROMIUM 1000 UG/ML (0.1% W/V)
Preparer's Name:SUSAN C TYMINST
CAGE:0EK28
CAGE:0EK28
============= Composition/Information on Ingredients =============
Ingred Name:AMMONIUM DICHROMATE
CAS:7789-09-5
RTECS #:HX7650000
Fraction by Wt: 0-1%
OSHA PEL:0.1 MG/CUM
ACGIH TLV:0.05 MG/CUM
EPA Rpt Qty:10 LBS
DOT Rpt Qty:10 LBS
Ingred Name:NITRIC ACID, HYDROGEN NITRATE
CAS:7697-37-2
RTECS #:QU5775000
Fraction by Wt: 0-5%
OSHA PEL:5 MG/CUM
ACGIH TLV:5.2 MG/CUM
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
===================== Hazards Identification =====================
LD50 LC50 Mixture:ORAL LD50 (RAT): 1870 MG/KG
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:YES
Health Hazards Acute and Chronic:EYES: IRRITATION & BURNS. SKIN: BURNS.
INHALATION: IRRITATION TO NOSE & THROAT, COUGHING, DIFFICULT
BREATHING.
Explanation of Carcinogenicity:SEE INGREDIENTS.
Effects of Overexposure:EYES: IRRITATION & BURNS. SKIN: BURNS.
INHALATION: IRRITATION TO NOSE & THROAT, COUGHING, DIFFICULT
BREATHING.
======================= First Aid Measures =======================
First Aid:INGESTION: DON'T INDUCE VOMITING. IF CONSCIOUS, GIVE WATER,
MILK, OR MILK OF MAGNESIA. EYES/SKIN: FLUSH W/PLENTY OF WATER FOR
AT LEAST 15 MINS. OBTAIN MEDICAL ATTENTION IN ALL CASES.
===================== Fire Fighting Measures =====================
Extinguishing Media:USE APPROPRIATE EXTINGUISHING MEDIA.
Fire Fighting Procedures:WEAR PROPER PROTECTIVE EQUIPMENT &
SELF-CONTAINED BREATHING APPARATUS W/FULL FACEPIECE IN POSITIVE
PRESSURE MODE.
================== Accidental Release Measures ==================
Spill Release Procedures:WEAR PROTECTIVE EQUIPMENT. STOP LEAK SAFELY.
USE WATER SPRAY TO REDUCE VAPORS. TAKE UP W/SAND OR OTHER
NON-COMBUSTIBLE ABSORBENT MATERIAL & PLACE INTO CONTAINER FOR LATER
DISPOSAL. FLUSH SPILL AREA W/ WATER.
======================Handling and Storage ======================
Handling and Storage Precautions:KEEP CONTAINER TIGHTLY CLOSED. STORE
IN CORROSION PROOF AREA. AVOID INHALATION OF VAPORS & CONTACT
W/EYES & SKIN.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:WEAR NIOSH APPROVED RESPIRATOR.
Ventilation:LOCAL EXHAUST: REQUIRED, VENT HOOD
Other Protective Equipment:LAB COAT, APRON
Work Hygienic Practices:REMOVE/LAUNDER CONTAMINATED CLOTHING & SHOES
BEFORE REUSE.
Supplemental Safety and Health
================== Physical/Chemical Properties ==================
Boiling Pt:B.P. Text:212F
Spec Gravity:1
Solubility in Water:COMPLETE
Appearance and Odor:PALE YELLOW, CLEAR SOLUTION W/NO ODOR.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
ORGANIC MATERIALS, STRONG REDUCING AGENTS
Hazardous Decomposition Products:OXIDES OF NITROGEN
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSE OF IN ACCORDANCE W/LOCAL, STATE, &
FEDERAL REGULATIONS. D002 (CORROSIVE WASTE).
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===================== Product Identification =====================
Product ID:SILVER NITRATE SOLUTIONS & CONCENTRATE 40170, SS72 1
CAGE:1B464
CAGE:1B464
============= Composition/Information on Ingredients =============
Ingred Name:WATER LD50 (ORAL MOUSE): 50 MG/KG
CAS:7732-18-5
RTECS #:ZC0110000
Fraction by Wt: BALANCE
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:SILVER (I) NITRATE (1:1) (SARA 313) (CERCLA) LD50 (ORAL
MOUSE): 50 MG/KG
CAS:7761-88-8
RTECS #:VW4725000
Fraction by Wt: 15.0%
OSHA PEL:0.01 MG(AG)/M3
ACGIH TLV:0.01 MG(AG)/M3
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB
===================== Hazards Identification =====================
LD50 LC50 Mixture:SEE INGREDIENTS.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:ACUTE: EYE/SKIN: CAUSES IRRIT. INGEST:
CAUSES GI IRRIT W/NAUS, VOMIT & DIARR. INHAL: CAUSES RESP TRACT
IRRIT. CHRONIC: MAY CAUSE METHEMOGLOBINEMIA, WHICH IS CHARACTERIZED
BY CHOCOLATE-BROWN COLORED BL OOD, HDCH, WEAK, DIZZ, BREATH
SHORTNESS, CYANOSIS, RAPID HEART RATE, UNCON & POSS DEATH. (EFFECTS
OF OVEREXPOSURE)
Explanation of Carcinogenicity:NOT RELEVANT.
Effects of Overexposure:HLTH HAZ: CHRONIC INHAL/INGEST OF SILVER
NITRATE MAY CAUSE "ARGYRIA", WHICH IS CHARACTERIZED BY BLUE-GRAY
PIGMENTATION OF SKIN & MUC MEMBS. THE CNDTN DEVELOPS SLOWLY,
USUALLY AFTER 2-25 YRS OF EXPOS. CHRONIC SKIN CONT MAY CAUSE LOC
ARGYRIA, A PERM DISCOLORATION OF SKIN.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
======================= First Aid Measures =======================
First Aid:EYES: FLUSH W/PLENTY OF WATER FOR AT LEAST 15 MIN, OCCAS
LIFTING UPPER & LOWER LIDS. GET MED AID. SKIN: FLUSH W/PLENTY OF
SOAP & WATER FOR AT LEAST 15 MIN WHILE REMOVING CONTAM CLTHG &
SHOES. GET MED AID IF IRRIT DEVELOPS/PERSISTS. INGEST:IF VICTIM IS
CONSCIOUS & ALERT, GIVE 2-4 CUPFULS OF MILK/WATER. NEVER GIVE
ANYTHING BY MOUTH TO AN UNCON PERS. GET MED AID. INHAL: REMOVE FROM
EXPOS (SUP DAT)
===================== Fire Fighting Measures =====================
Extinguishing Media:FOR SMALL FIRES, USE DRY CHEMICAL, CARBON DIOXIDE,
WATER SPRAY OR ALCOHOL-RESISTANT FOAM.
Fire Fighting Procedures:WEAR NIOSH APPROVED SCBA & FULL PROTECTIVE
EQUIPMENT .
Unusual Fire/Explosion Hazard:NONE SPECIFIED BY MANUFACTURER.
================== Accidental Release Measures ==================
Spill Release Procedures:USE PROPER PERSONAL PROTECTIVE EQUIPMENT, AS
INDICATED IN "CONTROL MEASURES" SECTION. ABSORB SPILL WITH INERT
MATERIAL (E.G., DRY SAND OR EARTH), THEN PLACE INTO A CHEMICAL
WASTE CONTAINER.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
======================Handling and Storage ======================
Handling and Storage Precautions:AVOID CONTACT WITH SKIN AND EYES.
AVOID INGESTION AND INHALATION. USE WITH ADEQUATE VENTILATION.
Other Precautions:STORE IN A TIGHTLY CLOSED CONTAINER. STORE IN A COOL,
DRY, WELL-VENTILATED AREA AWAY FROM INCOMPATIBLE SUBSTANCES.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:FOLLOW THE OSHA RESPIRATOR REGULATIONS FOUND IN
29CFR 1010.134. ALWAYS USE A NIOSH-APPROVED RESPIRATOR WHEN
NECESSARY.
Ventilation:USE ADEQUATE VENTILATION TO KEEP AIRBORNE CONCENTRATIONS
LOW.
Other Protective Equipment:ANSI APPROVED EMERGENCY EYEWASH & DELUGE
SHOWER . WEAR APPROPRIATE PROTECTIVE CLOTHING TO PREVENT SKIN
EXPOSURE.
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
MATLS TO AVOID: & NITRIC ACID, ETHYLENE HYDROPEROXIDE, HYDROGEN
PEROXIDE, MAGNESIUM ARSENIC, & CUPROUS ACETYLIDE. FIRST AID PROC:
TO FRESH AIR IMMED. IF NOT BRTHG, GIVE ARTF RESP. IF BRTHG IS
DFCLT, G IVE OXYGEN. GET MED AID IF COUGH/OTHER SYMPS APPEAR. NOTES
TO MD: TREAT SYMPTOMATICALLY & SUPPORTIVELY.
================== Physical/Chemical Properties ==================
Vapor Pres:14 @ 20C
Vapor Density:0.7
Spec Gravity:1.0-1.1
Evaporation Rate & Reference:1 (ETHER=1)
Solubility in Water:COMPLETELY SOLUBLE
Appearance and Odor:COLORLESS LIQUID
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
SILVER NITRATE IS INCOMPATIBLE W/ACETYLENE, AMMONIUM HYDROXIDE,
AZIRIDINE, CALCIUM CARBIDE, ETHANOL, ETHANOL (SUP DAT)
Stability Condition to Avoid:INCOMPATIBLE MATERIALS.
Hazardous Decomposition Products:NITROGEN OXIDES, SILVER OXIDES.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSE OF IN A MANNER CONSISTENT WITH FEDERAL,
STATE, AND, LOCAL REGULATIONS.
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===================== Product Identification =====================
Product ID:229H9502, DEVRAN 229 ACRYLIC EPOXY GLOSS (SUPP DATA)
Kit Part:Y
CAGE:1HK86
CAGE:1HK86
============= Composition/Information on Ingredients =============
Ingred Name:ING 17:LG QTYS IN BLDGS TO COMPLY W/OSHA 1910.106. KEEP
CNTNR CLSD WHEN NOT IN USE. DO NOT TRANSFER CONTENTS TO (ING 19)
RTECS #:9999999ZZ
Ingred Name:ING 18:BOTTLES/OTHER UNLABELED CNTNRS. DO NOT REUSE EMPTY
CNTNRS. IF THIS MATL IS PART OF 2 COMPONENT PROD, THEN(ING 20)
RTECS #:9999999ZZ
Ingred Name:ING 19:MIXT OF BASE & CONVERTER PORTIONS WILL HAVE HAZARDS
OF BOTH COMPONENTS.
RTECS #:9999999ZZ
Ingred Name:SUPDAT:FILTER DESIGNED TO REMOVE DECOMP PARTICULATES &
VAPS. WHEN USED IN CONFINED AREAS, USE NIOSH APPRVD AIR (ING 22)
RTECS #:9999999ZZ
Ingred Name:ING 21:SUPPLY RESPS/HOODS. USE NIOSH APPRVD CHEM RESP WHEN
FLAME CUTTING, WELDING, BRAZING & SANDING MATL COATED W/PROD.
RTECS #:9999999ZZ
Ingred Name:VENT:MIXING, APPLICATN & CURING AREAS & TO REMOVE SANDING
DUSTS OF DRIED COATINGS & DECOMP PRODS DURING WELDING (ING 24)
RTECS #:9999999ZZ
Ingred Name:ING 23:& FLAME CUTTING ON SURFS COATED W/THIS PROD. VAPS
MAY SPREAD LONG DISTS. PVNT BUILD-UP BY REMOVING HEAVY (ING 25)
RTECS #:9999999ZZ
Ingred Name:ING 24:SOLVENT VAPORS FROM LOWER LEVELS OF THE WORK AREA.
ELIMINATE ALL IGNITION SOURCES.
RTECS #:9999999ZZ
Ingred Name:ACETIC ACID, HEXYL ESTER; (HEXYL ACETATE.) VP:1. MFR CAS #
88230-35-7
CAS:142-92-7
RTECS #:AT0875000
Fraction by Wt: 15%
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:ACETIC ACID, BUTYL ESTER; (N-BUTYL ACETATE) (CERCLA).
VP:13. LD50:(ORAL,RAT) 15 GM/KG.
CAS:123-86-4
RTECS #:AF7350000
Fraction by Wt: 20%
OSHA PEL:150 PPM
ACGIH TLV:150 PPM;200 STEL
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
Ingred Name:BUTYL ALCOHOL; (N-BUTYL ALCOHOL) (SARA 313) (CERCLA).
VP:4.2. LD50:(ORAL,RAT) 2.5 GM/KG.
CAS:71-36-3
RTECS #:EO1400000
Fraction by Wt: 5%
OSHA PEL:100 PPM
ACGIH TLV:50 PPM, S, C
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
Ingred Name:ACETIC ACID, 2-METHOXY-1-METHYLETHYL ESTER;(PROPYLENE
GLYCOL MONOMETHYLETHER ACETATE). VP:2.7. LD50:(ORAL,RAT)8.5 GM/KG.
CAS:108-65-6
RTECS #:AI8925000
Fraction by Wt: 15%
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:XYLENE (SARA 313) (CERCLA). VP:6. LD50:(ORAL,RAT) >5
GM/KG.
CAS:1330-20-7
RTECS #:ZE2100000
Fraction by Wt: <5%
OSHA PEL:100 PPM
ACGIH TLV:100 PPM;150 STEL
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Ingred Name:TOLUENE (SARA 313) (CERCLA)
CAS:108-88-3
RTECS #:XS5250000
OSHA PEL:200 PPM
ACGIH TLV:50 PPM, S
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Ingred Name:PROPANE, 1-CHLORO-2, 3-EPOXY-; (EPICHLOROHYDRIN) (SARA
302/313) (CERCLA)
CAS:106-89-8
RTECS #:TX4900000
OSHA PEL:5 PPM, S
ACGIH TLV:2 PPM, S
EPA Rpt Qty:100 LBS
DOT Rpt Qty:100 LBS
Ingred Name:EXPLO HAZ:BEYOND CLSD DOORS. DUE TO PRESS BUILD-UP, CLSD
CNTNRS EXPOS TO EXTREME HEAT MAY EXPLODE. NEVER USE A (ING 12)
RTECS #:9999999ZZ
Ingred Name:ING 11:WELDING/CUTTING TORCH ON/NEAR CNTNR (EVEN EMPTY) AS
PROD/ITS RESIDUE MAY IGNITE. DURING EMER CNDTNS (ING 13)
RTECS #:9999999ZZ
Ingred Name:ING 12:OVEREXP TO DECOMP PRODS MAY CAUSE HLTH HAZ. SYMPS
MAY NOT BE IMMED APPARENT. OBTAIN MED ASSISTANCE.
RTECS #:9999999ZZ
Ingred Name:EFTS OF OVEREXP:REPRO HARM/CANCER. NOTE:TOLUENE APPEARS ON
NAV LIST OF OCCUP CHEM REPRO HAZS. SEEK CONSULTATION (ING 15)
RTECS #:9999999ZZ
Ingred Name:ING 14:FROM APPROP HLTH PROFESSIONALS CONCERNING LATEST HAZ
LIST INFO & SAFE HNDLG & EXPOS INFO .
RTECS #:9999999ZZ
Ingred Name:FIRST AID PROC:IMMED. DO NOT INDUCE VOMIT. ASPIR OF MATL
CAN CAUSE CHEM PNEUM WHICH CAN BE FATAL.
RTECS #:9999999ZZ
Ingred Name:OTHER PREC:OF VAPS BY MAINTAINING CONTINUOUS FLOW OF FRESH
AIR. DO NOT STORE >120F/NEAR FIRE/OPEN FLAME. STORE (ING 18)
RTECS #:9999999ZZ
Ingred Name:ACRYLIC RESIN
Fraction by Wt: 25%
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:EPOXY RESIN
CAS:25068-38-6
RTECS #:KC2100000
Fraction by Wt: 10%
OSHA PEL:N/K
ACGIH TLV:N/K
===================== Hazards Identification =====================
LD50 LC50 Mixture:SEE INGREDIENTS.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO
Health Hazards Acute and Chronic:ACUTE:INHAL:IRRIT OF RESP TRACT; HDCH,
NAUS, DIZZ, WEAK & FATG. EXTREME EXPOS CAN RSLT IN UNCON & EVEN
RESP ARREST. SKIN/EYE CONT:CAUSE IRRIT. MAY BE HARMFUL IF ABSORBED
THRU SKIN. INGEST:CAN CAUSE ST OM &/OR INTEST IRRIT, NAUS, VOMIT &
DIARR. CHRONIC:RPTS HAVE ASSOC RPTD & PRLNG OCCUP OVEREXP TO SOLVS
(EFTS OF OVEREXP)
Explanation of Carcinogenicity:EPICHLOROHYDRIN:IARC MONOGRAPHS, SUPP,
VOL 7 PG 202, 1987:GRP 2A. NTP 7TH ANNUAL RPT ON CARCINS,
1994:ANTIC TO (SUPDAT)
Effects of Overexposure:HLTH HAZ:W/PERM BRAIN & NERV SYS DMG.
PRLNG/RPTD BRTHG OF SPRAY MIST &/OR SANDING DUST OVER A PERIOD OF
YRS MAY CAUSE DUST DISEASE OF THE LUNGS. NOTICE:INTENTIONAL MISUSE
BY DELIB CONC & INHAL CONTENT S MAY BE HARMFUL/FATAL. WARNING:THIS
PROD CNTNS CHEM KNOWN TO STATE OF CALIFORNIA TO CAUSE BIRTH
DEFECTS, OTHER (ING 14)
Medical Cond Aggravated by Exposure:NONE, WHEN USED I/A/W SAFE HANDLING
& USE INFORMATION.
======================= First Aid Measures =======================
First Aid:INHAL:IF YOU EXPER DFCLTY IN BRTHG, LEAVE AREA TO OBTAIN
FRESH AIR. IF CONTINUED DFCLTY IS EXPER, SUMMON MED ASSISTANCE
IMMED. IF BRTHG CEASES, RESTORE USING APPRVD CPR TECHNIQUES &
SUMMON HELP IMMED.EYES:FLUSH IMMED W/LG AMTS OF WATER FOR AT LST
15 MINS. GET MED ATTN. SKIN:WASH AFFECTED AREAS W/SOAP & WATER.
REMOVE SOILED CLTHG. GET MED ASSISTANCE IF IRRIT PERSISTS.
INGEST:CONSULT MD (ING 16)
===================== Fire Fighting Measures =====================
Flash Point Method:SCC
Flash Point:80.0F,26.7C
Lower Limits:1%
Extinguishing Media:IN CASE OF FIRE USE CO*2, DRY CHEMICAL, FOAM OR
OTHER NFPA APPROVED METHOD FOR TREATING A CLASS B FIRE.
Fire Fighting Procedures:USE NIOSH APPRVD SCBA & FULL PROT EQUIP .
SUMMON PROFESSIONAL FIREFIGHTERS. WATER SPRAY MAY BE INEFT. IF
WATER IS USED, FOG NOZZ PREF. IF EXPOS TO(SUPDAT)
Unusual Fire/Explosion Hazard:FLAMM LIQ-CLASS IC. KEEP CNTNRS TIGHTLY
CLSD. ISOLATE FROM HEAT, ELEC EQUIP, SPKS & FLAME. VAPS MAY CAUSE
FLASH FIRE, IGNIT EXPLO & SPREAD LONG DISTS & (ING 11)
================== Accidental Release Measures ==================
Spill Release Procedures:REMOVE ALL SOURCES OF IGNIT (FLAMES, HOT SURFS
& ELEC, STATIC/FRICTIONAL SPKS). PVNT BRTHG OF VAPS. VENT AREA.
BEFORE ATTEMPTING CLEAN-UP, REFER TO HAZ CAUT INFO IN OTHER
SECTIONS OF THIS MSDS. CONTAI N SPILLED MATL & REMOVE W/INERT
ABSORB & (SUPDAT)
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
======================Handling and Storage ======================
Handling and Storage Precautions:DO NOT BREATHE VAPS, SPRAY
MIST/SANDING DUST. DO NOT GET ON SKIN/IN EYES. KEEP AWAY FROM HEAT,
SPKS & FLAMES. DO NOT SMOKE. OBSERVE ALL APPLIC PRECS.
Other Precautions:EXTING ALL PILOT LIGHTS & TURN OFF ALL SOURCES OF
IGNIT INCL HEATERS, FANS & OTHER NON-EXPLO-PROOF ELEC EQUIP, DURING
USE & UNTIL ALL VAPS ARE GONE. VAPS MAY IGNITE EXPLOSIVELY & SPREAD
LONG DISTS & B EYOND CLSD DOORS. PVNT BUILD-UP (ING 17)
============= Exposure Controls/Personal Protection =============
Respiratory Protection:WHEN SPRAY APPLIED IN OUTDOOR/OPEN AREAS &
DURING SANDING/GRINDING OPERATIONS, USE NIOSH APPRVD MECH FILTER
RESP TO REMOVE SOLID AIRBORNE PARTICLES OF OVERSPRAY & SANDING
DUST. WHEN USED IN RESTRICTED VENT AREAS, WEAR NIOSH APPRVD
(SUPDAT)
Ventilation:PROVIDE GEN DILUTION/LOC EXHST VENT IN VOL & PATTERN TO
KEEP AIR CONC BELOW CURRENT APPLIC SFTY & HLTH STDS IN (ING 23)
Other Protective Equipment:ANSI APPRVD EYE WASH FOUNTAIN & DELUGE
SHOWER . SOLV IMPERMEABLE CLTHG & BOOTS TO PREVENT SKIN CONTACT ARE
REC.
Work Hygienic Practices:REMOVE & WASH SOILED CLOTHING BEFORE REUSE.
WASH HANDS BEFORE EATING OR SMOKING.
Supplemental Safety and Health
MFR'S TRADE NAME/PART NO:COATING - NEUTRAL TINT BASE. FIRE FIGHT
PROC:FIRE/EXTREME HEAT, WATER SHOULD BE USED TO COOL CLSD CNTNRS &
PVNT PRESS BUILD UP/POSS AUTO-IGNIT. EXPLAN OF CARCIN:BE CARCIN.
HUM AN:RESP CANCER. SPILL PROC:NON-SPKING TOOLS. STORE IN CLSD
CNTNR UNTIL PROPERLY DISP OF. RESP PROT:CHEM/MECH (ING 21)
================== Physical/Chemical Properties ==================
Boiling Pt:B.P. Text:>244F,>118C
Vapor Pres:SEE INGS
Vapor Density:HVR/AIR
Spec Gravity:0.99
VOC Pounds/Gallon:563
Evaporation Rate & Reference:SLOWER THAN ETHER
Appearance and Odor:NONE SPECIFIED BY MANUFACTURER.
Percent Volatiles by Volume:63.8
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
AVOID CONTACT W/STRONG OXIDIZING AGENTS.
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:MAY CAUSE TOXIC FUMES WHEN HEATED TO
DECOMPOSITION. FUMES MAY CONTAIN CARBON MONOXIDE, CARBON DIOXIDE.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSE OF I/A/W LOCAL, STATE & FEDERAL
REGULATIONS. INCINERATE ONLY IN APPROVED FACILITY. DO NOT
INCINERATE CLOSED CONTAINERS.
======================= Other Information =======================
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===================== Product Identification =====================
Product ID:KAPTON POLYMIDE FILM TYPE CR
CAGE:0ERJ7
CAGE:0ERJ7
CAGE:18873
============= Composition/Information on Ingredients =============
Ingred Name:INERT POLYIMIDE FILM
RTECS #:9999999ZZ
Fraction by Wt: 100%
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:ACETAMIDE, N,N - DIMETHYL -; (DIMETHYL ACETAMIDE (RESIDUAL
IN FILM))
CAS:127-19-5
RTECS #:AB7700000
Fraction by Wt: <1%
OSHA PEL:S, 10 PPM
ACGIH TLV:S, 10 PPM; 9495
Ingred Name:POLYIMIDE POLYMER (AS NUISANCE DUST)
CAS:25038-81-7
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:ALUMINUM OXIDE (2:3); (ALUMINA) (SARA 313)
CAS:1344-28-1
RTECS #:BD1200000
Fraction by Wt: <35%
OSHA PEL:15 MG/M3 TDUST
ACGIH TLV:10 MG/M3 TDUST; 9495
Ingred Name:FIRST AID PROC: DUPONT CAUTION BULLETIN NO. H-50102.
RTECS #:9999999ZZ
Ingred Name:VENT: "KAPTON" ARE INVOLVED, NORM AIR CIRCULATION MAY BE
ALL THAT IS NEEDED IN CASE OF OVERHEATING. WHETHER/NOT (ING 7)
RTECS #:9999999ZZ
Ingred Name:ING 6: EXISTING VENT IS ADEQUATE AT HIGHER TEMP WILL DEPEND
ON COMBINED FACTORS OF FILM QTY, TEMP & EXPOSURE TIME.
RTECS #:9999999ZZ
===================== Hazards Identification =====================
LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:BEFORE USING "KAPTON" POLYIMIDE FILMS,
READ BULLETIN ON SAFE HNDLG & USE. INHAL: NOT A PROBABLE ROUTE OF
EXPOS FOR FILM. EXPOS TO ALUMINA/CARBON BLACK ENCAPSULATED IN
POLYMER IS NOT LIKELY. FOR THE PO LYMER FROM WHICH THE FILM IS
MADE, DUPONT RECS TREATING POLYMER DUST AS A NUISANCE PARTICULATE.
(EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT.
Effects of Overexposure:HLTH HAZ: SKIN: NO IRRITATION IS EXPECTED FROM
HANDLING FILM. LESS THAN 1 PPM DIMETHYL ACETAMIDE WAS EXTRACTED
FROM FILM BY DISTILLED WATER AT 40 DEG C FOR 4 HOURS. EYE &
INGESTION: NOT A PROBABLE ROU TE OF EXPOSURE FOR FILM.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
======================= First Aid Measures =======================
First Aid:INGEST: CALL MD IMMED . INHAL: REMOVE TO FRESH AIR. SUPPORT
BRTHG (GIVE O*2/ARTF RESP) . SKIN: WASH W/SOAP & H*2O AFTER HNDLG.
IF SKIN IRRIT DEVELOPS, CONSULT A MD. EYE: FLUSH W/H*2O FOR A T
LEAST 15 MINS. CONSULT A MD IF IRRIT PERSISTS. ADDITIONAL INFO: MED
USE: CAUTION: DO NOT USE IN MED APPLICATIONS INVOLVING PERM
IMPLANTATION IN HUMAN BODY. FOR OTHER MED APPLICATIONS SEE (ING 5)
===================== Fire Fighting Measures =====================
Extinguishing Media:WATER, FOAM, DRY CHEMICAL, CO*2.
Fire Fighting Procedures:USE NIOSH APPROVED SCBA & FULL PROTECTIVE
EQUIPMENT .
Unusual Fire/Explosion Hazard:FLAMM PROPERTIES: NOT A FIRE/EXPLOSION
HAZ. FLAMMABILITY CHARACT OF POLYIMIDE FILM IS RPTD AS
"SELF-ENTINGUISHING". "KAPTON" CHARS BUT DOES NOT BURN IN (SUPDAT)
================== Accidental Release Measures ==================
Spill Release Procedures:SAFEGUARDS (PERSONNEL): NOTE: REVIEW FIRE
FIGHTING MEASURES & HANDLING (PERSONNEL) SECTIONS BEFORE PROCEEDING
W/CLEAN-UP. USE NIOSH APPRVD APPROPRIATE PERSONAL PROT EQUIPMENT
DURING CLEAN-UP. ACCIDENT AL RELEASE MEASURES: PICK UP TO PVNT
SLIPPING HAZ.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
======================Handling and Storage ======================
Handling and Storage Precautions:STORE AWAY FROM FLAMMABLE MATERIALS.
Other Precautions:NONE SPECIFIED BY MANUFACTURER.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:RESPIRATORS ARE NOT NEEDED FOR NORMAL USE. NIOSH
APPROVED RESPIRATOR APPROPRIATE FOR EXPOSURE OF CONCERN .
Ventilation:SAFE HNDLG OF "KAPTON" POLYIMIDE FILMS AT HIGH TEMPS (ABOVE
200 DEG C) REQS ADEQ VENT IF SMALL QTIES OF (ING 6)
Other Protective Equipment:ANSI APPRVD EMER EYE WASH & DELUGE SHOWER .
SPECIAL PROTECTIVE CLOTHING IS NOT NEEDED FOR NORMAL USE.
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING.
Supplemental Safety and Health
EXPLO HAZ: AIR. "KAPTON" WILL BURN IN AN ATM OF 100% OXYGEN. MAJOR
OFF-GASES ARE CARBON DIOXIDE & CARBON MONOXIDE. PROCESSING OF
"KAPTON" POLYIMIDE FILMS CAN CAUSE GENERATION OF STATIC CHARGE.
PRECAUT IONS FOR STATIC CHARGES SHOULD ALSO BE TAKEN WHEN REMOVING
PLASTIC FILMS USED AS PROT PACKAGING FOR "KAPTON".
================== Physical/Chemical Properties ==================
Melt/Freeze Pt:M.P/F.P Text:NONE
Spec Gravity:>1.4
Solubility in Water:INSOLUBLE
Appearance and Odor:LIGHT AMBER TRANSPARENT FILM; NO ODOR.
Percent Volatiles by Volume:1 MAX
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
NONE REASONABLY FORESEEABLE.
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:AT TEMPERATURES ABOVE 400 DEG C, THE
MAJOR OFF GASES ARE CARBON MONOXIDE AND CARBON DIOXIDE.
==================== Disposal Considerations ====================
Waste Disposal Methods:LANDFILL OR INCINERATE IN COMPLIANCE WITH
FEDERAL, STATE, AND LOCAL REGULATIONS.
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===================== Product Identification =====================
Product ID:SNOFLO
CAGE:BASFC
CAGE:BASFC
CAGE:0PK40
============= Composition/Information on Ingredients =============
Ingred Name:PROPRIETARY INGREDIENTS
Fraction by Wt: 4%
Ingred Name:ETHYLENE GLYCOL, GLYCOL
CAS:107-21-1
RTECS #:KW2975000
Fraction by Wt: 85-95%
Other REC Limits:10 MG/CUM
ACGIH TLV:C 127 MG/CUM
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB
Ingred Name:POTASSIUM PHOSPHATE, DIBASIC *92-4*
CAS:7758-11-4
Fraction by Wt: 2%
Ingred Name:WATER
CAS:7732-18-5
RTECS #:ZC0110000
Fraction by Wt: 0.7%
Ingred Name:GLYCOL ETHERS, DIETHYLENE GLYCOL, 2,2-OXYBISETHANOL
CAS:111-46-6
RTECS #:ID5950000
Fraction by Wt: 0-10%
===================== Hazards Identification =====================
Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:EYES/SKIN: IRRITATION. INGESTION:
ABDOMINAL DISTRESS, CNS DEPRESSION, POSSIBLY RESPIRATORY &/OR
KIDNEY FAILURE.
Explanation of Carcinogenicity:NONE
Effects of Overexposure:INGESTION: LIVER & KIDNEY DAMAGE.
Medical Cond Aggravated by Exposure:SKIN, RESPIRATORY DISORDERS, OR
IMPAIRED FUNCTION OF THE LIVER/KIDNEYS.
======================= First Aid Measures =======================
First Aid:SKIN: WASH W/SOAP & WATER. EYES: FLUSH W/WATER FOR 15 MINS.
INGESTION: DILUTE W/WATER & INDUCE VOMITING. NEVER GIVE FLUIDS OR
INDUCE VOMITING IF VICTIM IS UNCONSCIOUS OR HAVING CONVULSIONS.
INHALATION : REMOVE TO FRESH AIR. AID IN BREATHING, IF NECESSARY.
NOTE: ADMINISTRATION OF ETHANOL MAY COUNTERACT THE EFFECTS OF
ETHYLENE GLYCOL (METABOLIC ACIDOSIS & RENAL DAMAGE). OBTAIN MED
ATTN IN ALL CASES.
===================== Fire Fighting Measures =====================
Flash Point Method:COC
Flash Point:250F
Extinguishing Media:WATER FOG, ALCOHOL FOAM, CO2 OR DRY CHEMICAL
EXTINGUISHING MEDIA.
Fire Fighting Procedures:FIRE FIGHERS SHOULD USE A SELF CONTAINED
BREATHING APPARATUS & TURNOUT GEAR.
Unusual Fire/Explosion Hazard:VAPORS FROM HEATED (ABOVE FLASHPOINT) OF
PRODUCT MAY TRAVEL TO A SOURCE OF IGNITION & FLASH BACK.
AUTOIGNITION: 775F
================== Accidental Release Measures ==================
Spill Release Procedures:CONTAIN, SOLIDIFY & PLACE IN A SUITABLE
CONTAINER FOR DISPOSAL IN A LICENSED FACILITY. COVER SPILLS W/SOME
INERT ABSORBENT MATERIAL. SWEEP UP & PLACE IN A WASTE DISPOSAL
CONTAINER. FLUSH AREA W/WATER.
======================Handling and Storage ======================
Other Precautions:AVOID BREATHING VAPORS OR FUMES OF HEATED PRODUCT OR
BURNING PRODUCT.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:IF VAPORS OR MISTS ARE GENERATED, USE A
NIOSH/MSHA APPROVED ORGANIC VAPOR/MIST RESPIRATOR.
Ventilation:LOCAL EXHAUST
Other Protective Equipment:COVERALLS, APRON, BOOTS
Work Hygienic Practices:REMOVE/LAUNDER CONTAMINATED CLOTHING BEFORE
REUSE.
Supplemental Safety and Health
================== Physical/Chemical Properties ==================
Boiling Pt:B.P. Text:330F
Vapor Pres:18
Spec Gravity:1.135
Solubility in Water:COMPLETE
Appearance and Odor:GREEN LIQUID W/GLYCOL ODOR.
Percent Volatiles by Volume:9-11
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
==================== Disposal Considerations ====================
Waste Disposal Methods:MATERIAL IS A CERCLA HAZARDOUS SUBSTANCE. RQ=
1LB. INCINERATE OR BURY IN A RCRA LICENSED FACILITY. DON'T
DISCHARGE INTO WATERWAYS OR SEWER SYSTEMS. DISPOSE CONTAINERS IN A
LICENSED FACILITY. CRUSH OR OTHER TO PREVENT UNAUTHORIZED REUSE.
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=======================================================
Product ID: LUBE-A-TUBE KS-S COMPOUND, 303850
Cage: TO179
Proprietary Ind: Y
=======================================================
Contractor Summary
=======================================================
Cage: TO179
=======================================================
Ingredients
=======================================================
-----------------------------
=======================================================
Health Hazards Data
=======================================================
Route Of Entry Inds - Inhalation: NO
Skin: NO
Ingestion: NO
Carcinogenicity Inds - NTP: NO
IARC: NO
OSHA: NO
Effects of Exposure: EFFECTS OF OVEREXPOSURE : NO KNOWN EFFECTS.
Signs And Symptions Of Overexposure: NO KNOWN EFFECTS.
First Aid: EYES: FLUSH WITH WATER. IF IRRITAION OCCURS & PERSISTS, SEEK
MEDICAL AID. INGESTION: CONTACT A PHYSICIAN IMMEDIATELY (FP N). INHALATION:
REMOVE TO FRESH AIR. SUPPORT BREATHING. CONTACT A PHYSICIAN IMM EDIATELY (FP
N). SKIN CONTACT: FLUSH WITH COPIOUS AMOUNTS OF WATER. CONTACT A PHYSICIAN
(FP N).
=======================================================
Handling and Disposal
=======================================================
Spill Release Procedures: RECOVER FREE PRODUCT OR WASH WITH WATER.
Waste Disposal Methods: DISPOSE ACCORDING TO LOCAL, STATE AND FEDERAL
REGULATIONS.
Handling And Storage Precautions: PROTECT FROM FREEZING.
=======================================================
Fire and Explosion Hazard Information
=======================================================
Flash Point: >204.4C, 400.F
Lower Limits: UNKNOWN
Upper Limits: UNKNOWN
Extinguishing Media: CARBON DIOXIDE, FOAM OR DRY CHEMICAL.
Fire Fighting Procedures: USE NIOSH APPROVED SELF-CONTAINED BREATHING APPARATUS
AND FULL PROTECTIVE EQUIPMENT (FP N). TREAT AS AN OIL FIRE.
Unusual Fire/Explosion Hazard: NONE.
=======================================================
Control Measures
=======================================================
Respiratory Protection: A NIOSH APPROVED RESPIRATOR APPROPRIATE FOR THE
EXPOSURE OF CONCERN (FP N). NOT NORMALLY REQUIRED (MFR).
Ventilation: NOT NORMALLY REQUIRED.
(MFR).
Other Protective Equipment: NONE.
Supplemental Safety and Health: FLASH POINT: >400F - >204C (FOR ANHYDROUS
MATERIAL). PH= 9.0-9.8 (10% SOLUTION).
=======================================================
Physical/Chemical Properties
=======================================================
Spec Gravity: 0.96 - 1.00
PH: 9.0 - 9.8
Solubility in Water: EMULSIFIES.
Appearance and Odor: LIGHT YELLOW GREASE - MILD FATTY ODOR.
=======================================================
Reactivity Data
=======================================================
Stability Indicator: YES
Materials To Avoid: STRONG OXIDIZING AGENTS.
Hazardous Decomposition Products: NONE
Hazardous Polymerization Indicator: NO
Conditions To Avoid Polymerization: WILL NOT OCCUR.
=======================================================
Toxicological Information
=======================================================
Toxicological Information: THRESHOLD LIMIT VALUE NOT ESTABLISHED.
=======================================================
Ecological Information
=======================================================
=======================================================
=======================================================
Transport Information: D.O.T. PROPER SHIPPING NAME: NOT REGULATED.
=======================================================
Regulatory Information
=======================================================
=======================================================
Other Information
=======================================================
Other Information: /NFPA RATINGS: HEALTH=0; FLAMMABILITY=0; REACTIVITY=0. THIS
MSDS SUPERSEDES: MAY 20, 1993.
=======================================================
HAZCOM Label
=======================================================
Product ID: LUBE-A-TUBE KS-S COMPOUND, 303850
Cage: TO179
Assigned IND: Y
Company Name: RICHARDS APEX INCORPORATED
Street: 4202-24 MAIN ST
Zipcode: 19127-1698
Label Required IND: Y
Date Of Label Review: 12/02/2000
Status Code: A
Origination Code: F
Skin Protection IND: NO
Signal Word: NONE
Respiratory Protection IND: NO
Health Hazard: None
Contact Hazard: None
Fire Hazard: None
Reactivity Hazard: None
Hazard And Precautions: EFFECTS OF OVEREXPOSURE - NO KNOWN EFFECTS.
=======================================================
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===================== Product Identification =====================
Product ID:GLEITMO 700 MOLYBDENUM DISULPHIDE PASTE W/SYNTHETIC OIL
Preparer's Name:RUDOLF GRUBER
CAGE:GO583
CAGE:10873
CAGE:GO583
============= Composition/Information on Ingredients =============
Ingred Name:MOLYBDENUM DISULFIDE
CAS:1317-33-5
RTECS #:QA4697000
OSHA PEL:15 MG/CUM AS (MO)
ACGIH TLV:10 MG/CUM AS (MO)
Ingred Name:SYNTHETIC OIL
===================== Hazards Identification =====================
LD50 LC50 Mixture:ORAL LD50(LAB ANIMAL): >10ML/KG BASE OIL
Routes of Entry: Inhalation:NOSkin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:GLEITMO 700 IS BELIEVED TO BE
NON-HAZARDOUS WHEN USED PROPERLY.
Explanation of Carcinogenicity:NONE
Effects of Overexposure:GLEITMO 700 IS BELIEVED TO BE NON-HAZARDOUS
WHEN USED PROPERLY.
======================= First Aid Measures =======================
First Aid:SKIN: WASH W/SOAP & WATER. EYES: FLUSH W/LARGE AMOUNTS OF
WATER. OBTAIN MEDICAL ATTENTION IN ALL CASES.
===================== Fire Fighting Measures =====================
Flash Point:392F
Extinguishing Media:WATERSPRAY, DRY CHEMICAL, FOAM, CO2
Fire Fighting Procedures:USE SCBA.
================== Accidental Release Measures ==================
Spill Release Procedures:PREVENT ENTRY INTO SEWERS & WATERWAYS. AVOID
CONTACT W/EYES & SKIN.
======================Handling and Storage ======================
Handling and Storage Precautions:STORE IN CLEAN, DRY PLACE. NO SPECIAL
HANDLING IS REQUIRED.
Other Precautions:AVOID CONTACT W/EYES & SKIN.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:UNDER NORMAL CONDITIONS OF USE, NO RESPIRATORY
PROTECTION IS REQUIRED.
Other Protective Equipment:NO SPECIAL PROTECTIVE MEASURES ARE
NECESSARY.
Supplemental Safety and Health
================== Physical/Chemical Properties ==================
Solubility in Water:INSOLUBLE
Appearance and Odor:BLACK GREASE; ODORLESS
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS.
Stability Condition to Avoid:TEMPS >572F.
Hazardous Decomposition Products:THERMAL: CO, CO2, SULFUR DIOXIDE.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSE OF IAW/FEDERAL, STATE & LOCAL
REGULATIONS. DON'T DUMP INTO SEWERS, ON THE GROUND/INTO ANY BODY OF
WATER.
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===================== Product Identification =====================
Product ID:METERPAK #215
CAGE:LO289
CAGE:0SL71
CAGE:LO289
============= Composition/Information on Ingredients =============
Ingred Name:NA
Fraction by Wt: NA
Other REC Limits:NA
OSHA PEL:NA
ACGIH TLV:NA
===================== Hazards Identification =====================
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:PRODUCT SOLD IN WATER SOLUBLE POUCHES
& DIRECT CONTACT W/POWDER UNLIKELY DURING NORMAL USE. HOWEVER UNDER
UPSET CONDITIONS, INHALATION OF DUST MAY CAUSE ALLERGIC REACTIONS
IN SUSCEPTIBLE PEOPLE. ENZYM ES MAY CAUSE EYE IRRITATION ON
CONTACT.MAY PRODUCE RESPIRATORY ALLERGIES (ASTHMA) & SKIN
IRRITATION IN EXPOSED WORKERS.
Effects of Overexposure:ALLERGIC TYPE REACTIONS, IRRITATION TO SKIN.
Medical Cond Aggravated by Exposure:ALLERGIES
======================= First Aid Measures =======================
First Aid:EYES: FLUSH THOROUGHLY W/WATER & SEEK MEDICAL ATTN. SKIN:
WASH THOROUGHLY W/SOAP & WATER. REMOVE CONTAMINATED CLOTHES & WASH
BEFORE REUSE. INHALATION: IF ALLERGIC RESPONSE IS EXHIBITED, SEEK
MEDICAL A TTN.
===================== Fire Fighting Measures =====================
Flash Point:NA
Lower Limits:NA
Upper Limits:NA
Extinguishing Media:NO SPECIAL REQUIREMENTS
Fire Fighting Procedures:NO SPECIAL REQUIREMENTS
Unusual Fire/Explosion Hazard:NONE
================== Accidental Release Measures ==================
Spill Release Procedures:POWDERS SHOULD BE VACUUMED OR MOISTENED
W/WATER & REMOVED. COLLECTED WASTE WATER SHOULD BE RETURNED TO
SYSTEM OR SEALED IN CONTAINERS TO PREVENT DUST GENERATION.
======================Handling and Storage ======================
Handling and Storage Precautions:MAINTAIN GOOD HOUSEKEEPING. AVOID
GENERATION OF DUST OR AEROSOL. AVOID EXPOSURE OF ENZYME PRODUCT TO
CONDITIONS OF HIGH TEMPERATURE & HUMIDITY WHICH*
Other Precautions:*MAY REDUCE PRODUCT ACTIVITY.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:NOT NORMALLY REQUIRED, HOWEVER UNDER
UNUSUAL/UPSET CONDITIONS, RESPIRATORY EQUIPMENT MUST BE SELECTED &
USED IN ACCORDANCE WITH OSHA/NIOSH GUIDELINES.
Ventilation:LOCAL EXHAUST: SHOULD BE SUFFICIENT TO PREVENT DUST
RELEASE.
Other Protective Equipment:SUFFICIENT TO PREVENT DIRECT SKIN CONTACT.
Work Hygienic Practices:MAINTAIN GOOD HOUSEKEEPING. AVOID GENERATION OF
DUST. WASH HANDS THOROUGHLY AFTER HANDLING.
Supplemental Safety and Health
DUSTING LIKELY.
================== Physical/Chemical Properties ==================
Boiling Pt:B.P. Text:NA
Melt/Freeze Pt:M.P/F.P Text:NA
Vapor Pres:NA
Vapor Density:NA
Spec Gravity:NA
Evaporation Rate & Reference:NA
Solubility in Water:APPRECIABLE
Appearance and Odor:GREEN POWDER, TYPICAL ENZYME ODOR, PACKAGED IN
WATER SOLUBLE POUCHES
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
NK
Stability Condition to Avoid:ENZYME ACTIVITY MAY BE AFFECTED BY
EXPOSURE TO HIGH TEMPERATURES & MOISTURE.
==================== Disposal Considerations ====================
Waste Disposal Methods:LANDFILL THE ABSORBED MATERIAL IN CLOSED
CONTAINERS IN ACCORDANCE W/FEDERAL, STATE, LOCAL REGULATIONS.
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===================== Product Identification =====================
Product ID:86 PROCLEAN SURFACE CLEANER
CAGE:ACMEA
CAGE:ACMEA
============= Composition/Information on Ingredients =============
Ingred Name:ISOPARAFFINIC HYDROCARBONS (NAPHTHA PETROLEUM),
HYDROTREATED HEAVY, NON AROMATIC HEAVY NAPHTHA) ISOPAR G *93-3*
CAS:64742-48-9
Fraction by Wt: 95%
OSHA PEL:300 PPM
ACGIH TLV:300 PPM
Ingred Name:KEROSENE (PETROLEUM), HYDROTREATED; PETROLEUM DISTILLATE,
HYDROTREATED ,(MINERAL SPIRITS)
CAS:64742-47-8
RTECS #:OA5504000
Fraction by Wt: 5%
OSHA PEL:100 PPM
ACGIH TLV:100 PPM
Ingred Name:WEIGHT PER GALLON IN POUNDS: 6.20
RTECS #:9999999WG
Ingred Name:VOL ORGANIC CMPD: 6.20 LBS/GAL
RTECS #:9999999VO
===================== Hazards Identification =====================
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:IRRITATION OF EYES/SKIN/RESPIRATORY
SYSTEM. CNS DEPRESSION. CHRONIC EXPOSURE MAY CAUSE ADVERSE EFFECTS
TO LIVER/URINARY/BLOOD FORMING/REPRODUCTIVE/CARDIOVASCULAR
SYSTEMS/PERMANENT BRAIN/CNS DAMAGE. EX TREME ACUTE EXPOSURE MAY
CAUSE UNCONSCIOUSNESS & POSSIBBLY DEATH.
Explanation of Carcinogenicity:NONE
Effects of Overexposure:INHALATION:
HEADACHE/DIZZINESS/NAUSEA/COORDINATION LOSS/UNCONSCIOUSNESS/DEATH.
SKIN/EYES: REDNESS/ITCH/BURNING SENSATION. SYMPTOMS MAY NOT BE
IMMEDIATELY APPARENT.
======================= First Aid Measures =======================
First Aid:INHALATION: REMOVE TO FRESH AIR. IF PROBLEMS REMAIN OR OCCUR
DURING USE, IMMEDIATELY GET MEDICAL ATTENTION. SKIN: WASH W/SOAP &
WATER. REMOVE CONTAMINATED CLOTHING. EYES: FLUSH W/PLENTY OF WATER
FOR 1 5 MINS. INGESTION: OBTAIN MEDICAL ATTENTION IN ALL CASES.
===================== Fire Fighting Measures =====================
Flash Point:44F
Lower Limits:0.7%
Upper Limits:36.5%
Extinguishing Media:CO2, DRY CHEMICAL, FOAM
Fire Fighting Procedures:FULL PROTECTIVE EQUIPMENT INCLUDING SCBA.
WATER SPRAY MAY BE INEFFECTIVE. IF WATER IS USED, FOG NOZZLES ARE
PREFERABLE.
Unusual Fire/Explosion Hazard:WATER MAY BE USED TO COOL CLOSED
CONTAINERS TO PREVENT PRESSURE BUILD-UP, POSSIBLE AUTOIGNITION, OR
EXPLOSION WHEN EXPOSED TO EXTREME HEAT. FLAMMABLE.
================== Accidental Release Measures ==================
Spill Release Procedures:REMOVE IGNITION SOURCES. VENTILATE AREA.
REMOVE W/INERT ABSORBENT.
======================Handling and Storage ======================
Handling and Storage Precautions:USE ONLY IN ADEQUATE VENTILATION. KEEP
AWAY FROM HEAT, SPARKS, OPEN FLAME. DURING USE & UNTIL ALL VAPORS
ARE GONE; KEEP ARE VENTILATED. DON'T SMOKE.
Other Precautions:EXTINGUISH ALL FLAMES, PILOT LIGHTS & HEATERS. TURN
OFF STOVES/ELECTRIC TOOLS/APPLIANCES & OTHER IGNITION SOURCES.
CONSULT NFPA CODE. USE APPROVED BONDING/GROUNDING PROCEDURES. KEEP
CONTAINER CLOSED W HEN NOT IN USE. DON'T TAKE INTERNALLY.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:IF PERSONAL EXPOSURE CANNOT BE CONTROLLED BELOW
TLV BY VENTILATION, USE A FITTED ORGANIC VAPOR/PARTICULATE
RESPIRATOR APPROVED BY NIOSH/MSHA. WHEN SANDING/ABRADING DRIED
FILM, USE A NIOSH/MSHA DUST/MI ST RESPIRATOR.
Ventilation:LOCAL EXHAUST: PREFERABLE. GENERAL EXHAUST ACCEPTABLE IF
EXPOSURE TO MATERIALS IS MAINTAINED BELOW APPLICABLE LIMITS.
Work Hygienic Practices:WASH HANDS AFTER USING. REMOVE/LAUNDER
CONTAMINATED CLOTHING BEFORE REUSE.
Supplemental Safety and Health
TRANSFER ONLY TO APPROVED CONTAINERS W/COMPLETE & APPROPRIATE LABELING.
KEEP OUF OF REACH OF CHILDREN. INTENTIONAL MISUSE BY DELIBERATELY
CONCENTRATING & INHALING THE CONTENTS CAN BE HARMFUL OR FATAL.
================== Physical/Chemical Properties ==================
Boiling Pt:B.P. Text:132-395F
Vapor Density:>1
Spec Gravity:0.75-0.84
Evaporation Rate & Reference:SLOWER THAN ETHER
Percent Volatiles by Volume:100
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
Stability Condition to Avoid:HEAT/SPARKS/OPEN FLAMES/PILOT LIGHTS &
OTHER SOURCES OF IGNITION.
Hazardous Decomposition Products:CO2, CO
==================== Disposal Considerations ====================
Waste Disposal Methods:PRODUCT WASTE MAY BE HAZARDOUS AS DEFINED UNDER
THE RCRA. TEST WASTE FOR IGNITABILITY TO DETERMINE THE APPLICABLE
EPA HAZARDOUS WASTE NUMBERS. INCINERATE IN APPROVED FACILITY. DON'T
INCINERATE CLOSED CONTAINER. DISPOSE OF IAW FED/STATE/LOCAL REGS.
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eyes_protection_mandatory
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Safety Data Sheets Eyes Protection Classification
This dataset contains Safety Data Sheets (SDS) sourced from Kaggle, consisting of over 200,000 documents. SDS are detailed documents providing essential information on the properties and hazards of chemicals, ensuring user safety and compliance with regulatory standards. A subset of these documents was pre-processed, cleaned, and annotated to classify whether eye protection is required when handling materials. The labels were extracted using a combination of large language models (LLMs) and regular expressions.
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